AU2001286812A1 - Highly durable hydrophobic coatings and methods - Google Patents
Highly durable hydrophobic coatings and methodsInfo
- Publication number
- AU2001286812A1 AU2001286812A1 AU2001286812A AU8681201A AU2001286812A1 AU 2001286812 A1 AU2001286812 A1 AU 2001286812A1 AU 2001286812 A AU2001286812 A AU 2001286812A AU 8681201 A AU8681201 A AU 8681201A AU 2001286812 A1 AU2001286812 A1 AU 2001286812A1
- Authority
- AU
- Australia
- Prior art keywords
- silicon oxide
- anchor layer
- pdmso
- layer
- linked
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/42—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating of an organic material and at least one non-metal coating
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/002—Priming paints
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/18—Processes for applying liquids or other fluent materials performed by dipping
- B05D1/185—Processes for applying liquids or other fluent materials performed by dipping applying monomolecular layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/60—Deposition of organic layers from vapour phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/213—SiO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/76—Hydrophobic and oleophobic coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/152—Deposition methods from the vapour phase by cvd
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31609—Particulate metal or metal compound-containing
- Y10T428/31612—As silicone, silane or siloxane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Wood Science & Technology (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
Abstract
Substrates have a hydrophobic surface coating comprised of the reaction products of a chlorosilyl group containing compound and an alkylsilane. Most preferably the substrate is glass. In one preferred form of the invention, highly durable hydrophobic coatings may be formed by forming a silicon oxide anchor layer or hybrid organo-silicon oxide anchor layer from a humidified reaction product of silicon tetrachloride or trichloromethylsilane, followed by the vapor-deposition of a chloroalkylsilane. Such a silicon oxide anchor layer will advantageously have a root mean square surface roughness of less than about 6.0 nm (preferably less than about 5.0 nm) and a low haze value of less than about 3.0% (preferably less than about 2.0%). Another embodiment of the present invention include the simultaneous humidified vapor deposition of a chlorosilyl group containing compound and a chloroalkylsilane. Specifically, in certain preferred embodiments, the simultaneous vapor deposition onto a glass substrate of silicon tetrachloride (SiCl4) and dimethyldichlorosilane (DMDCS) results in a hydrophobic coating comprised of cross-linked polydimethylsiloxane (PDMSO), which may then be capped with a fluoroalkylsilane (FAS). The cross-linked PDMSO layer may be formed on the surface of the glass substrate, or a silicon oxide anchor layer may be deposited under the cross-linked (PDMSO) layer. SiCl4 ,trimethylchlorosilane (TMCS), trichloromethylsilane and combinations of these silanes therein may also be simultaneously vapor deposited onto a substrate surface so as to achieve hydrophobic coatings of exceptional durability.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US23633500P | 2000-09-29 | 2000-09-29 | |
US60236335 | 2000-09-29 | ||
US09921303 | 2001-08-03 | ||
US09/921,303 US6743516B2 (en) | 2000-09-29 | 2001-08-03 | Highly durable hydrophobic coatings and methods |
PCT/US2001/026691 WO2002028956A1 (en) | 2000-09-29 | 2001-08-28 | Highly durable hydrophobic coatings and methods |
Publications (1)
Publication Number | Publication Date |
---|---|
AU2001286812A1 true AU2001286812A1 (en) | 2002-04-15 |
Family
ID=26929682
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU2001286812A Abandoned AU2001286812A1 (en) | 2000-09-29 | 2001-08-28 | Highly durable hydrophobic coatings and methods |
Country Status (8)
Country | Link |
---|---|
US (1) | US6743516B2 (en) |
EP (1) | EP1328579B1 (en) |
AT (1) | ATE549302T1 (en) |
AU (1) | AU2001286812A1 (en) |
CA (1) | CA2423657C (en) |
ES (1) | ES2384374T3 (en) |
PL (1) | PL200431B1 (en) |
WO (1) | WO2002028956A1 (en) |
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US7914897B2 (en) | 2003-06-23 | 2011-03-29 | University Of Zurich | Superhydrophobic coating |
US20040261703A1 (en) | 2003-06-27 | 2004-12-30 | Jeffrey D. Chinn | Apparatus and method for controlled application of reactive vapors to produce thin films and coatings |
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-
2001
- 2001-08-03 US US09/921,303 patent/US6743516B2/en not_active Expired - Lifetime
- 2001-08-28 CA CA 2423657 patent/CA2423657C/en not_active Expired - Fee Related
- 2001-08-28 ES ES01966284T patent/ES2384374T3/en not_active Expired - Lifetime
- 2001-08-28 PL PL361891A patent/PL200431B1/en unknown
- 2001-08-28 AU AU2001286812A patent/AU2001286812A1/en not_active Abandoned
- 2001-08-28 EP EP20010966284 patent/EP1328579B1/en not_active Expired - Lifetime
- 2001-08-28 WO PCT/US2001/026691 patent/WO2002028956A1/en active Application Filing
- 2001-08-28 AT AT01966284T patent/ATE549302T1/en active
Also Published As
Publication number | Publication date |
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CA2423657C (en) | 2008-11-18 |
WO2002028956A1 (en) | 2002-04-11 |
ES2384374T3 (en) | 2012-07-04 |
EP1328579B1 (en) | 2012-03-14 |
CA2423657A1 (en) | 2002-04-11 |
US6743516B2 (en) | 2004-06-01 |
ATE549302T1 (en) | 2012-03-15 |
PL200431B1 (en) | 2009-01-30 |
US20020064663A1 (en) | 2002-05-30 |
EP1328579A1 (en) | 2003-07-23 |
EP1328579A4 (en) | 2008-07-30 |
PL361891A1 (en) | 2004-10-04 |
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