RU93048468A - VINYL AROMATIC MONOMER POLYMERIZATION INHIBITORS - Google Patents

VINYL AROMATIC MONOMER POLYMERIZATION INHIBITORS

Info

Publication number
RU93048468A
RU93048468A RU93048468/04A RU93048468A RU93048468A RU 93048468 A RU93048468 A RU 93048468A RU 93048468/04 A RU93048468/04 A RU 93048468/04A RU 93048468 A RU93048468 A RU 93048468A RU 93048468 A RU93048468 A RU 93048468A
Authority
RU
Russia
Prior art keywords
vinyl aromatic
aromatic monomer
polymerization inhibitors
monomer polymerization
compound
Prior art date
Application number
RU93048468/04A
Other languages
Russian (ru)
Other versions
RU2116285C1 (en
Inventor
А.Е.Винтер Роланд
Ли Шенг-Шинг
Р.Гетичэр Лесли
Х.фон Ан Фолкер
Original Assignee
Циба-Гейги АГ
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/921,824 external-priority patent/US5254760A/en
Application filed by Циба-Гейги АГ filed Critical Циба-Гейги АГ
Publication of RU93048468A publication Critical patent/RU93048468A/en
Application granted granted Critical
Publication of RU2116285C1 publication Critical patent/RU2116285C1/en

Links

Claims (1)

Ингибирование полимеризации винил-ароматического соединения, такого как стирол, во время его перегонки или очистки, особенно эффективно проходит в присутствии по крайней мере одного стабильного нитроксильного соединения вместе с по крайней мере одним ароматическим нитросоединением.Inhibition of the polymerization of a vinyl aromatic compound, such as styrene, during distillation or purification, is particularly effective in the presence of at least one stable nitroxyl compound together with at least one aromatic nitro compound.
RU93048468A 1992-07-29 1993-07-12 Composition that prevents premature polymerization of vinyl aromatic compounds, and method of prevention of polymerization of vinyl aromatic compounds RU2116285C1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/921,824 US5254760A (en) 1992-07-29 1992-07-29 Inhibiting polymerization of vinyl aromatic monomers
US07/921824 1992-07-29

Publications (2)

Publication Number Publication Date
RU93048468A true RU93048468A (en) 1997-01-20
RU2116285C1 RU2116285C1 (en) 1998-07-27

Family

ID=25446025

Family Applications (1)

Application Number Title Priority Date Filing Date
RU93048468A RU2116285C1 (en) 1992-07-29 1993-07-12 Composition that prevents premature polymerization of vinyl aromatic compounds, and method of prevention of polymerization of vinyl aromatic compounds

Country Status (14)

Country Link
US (1) US5254760A (en)
EP (1) EP0581737B1 (en)
JP (1) JP2855399B2 (en)
KR (1) KR0177045B1 (en)
CN (1) CN1041513C (en)
AU (1) AU666024B2 (en)
BR (1) BR9303023A (en)
CA (1) CA2101359C (en)
DE (1) DE69310044T2 (en)
ES (1) ES2101995T3 (en)
MX (1) MX9304506A (en)
RU (1) RU2116285C1 (en)
SA (1) SA93140161B1 (en)
TW (1) TW226023B (en)

Families Citing this family (83)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW294658B (en) 1994-06-02 1997-01-01 Nippon Catalytic Chem Ind
US5728872A (en) * 1994-06-27 1998-03-17 Lutz Riemenschneider Stabilized acrylic acid compositions
ES2126185T3 (en) * 1994-08-19 1999-03-16 Huels Chemische Werke Ag INHIBITION OF THE POLYMERIZATION OF STYRENE.
US5888356A (en) * 1994-08-19 1999-03-30 Huels Aktiengesellschaft Inhibition of polymerization of vinylaromatic or vinylaliphatic
US5545786C1 (en) * 1994-11-28 2001-10-16 Ciba Geigy Corp Method for inhibiting premature polymerization of vinyl aromatic monomers
DE19510184A1 (en) * 1995-03-21 1996-09-26 Basf Ag 4-acylaminopiperidine-N-oxyls
US5616774A (en) * 1995-04-14 1997-04-01 Ciba-Geigy Corporation Inhibition of unsaturated monomers with 7-aryl quinone methides
DE19531649A1 (en) * 1995-08-29 1997-03-06 Basf Ag Dowel compound for chemical fastening technology
US5629426A (en) * 1995-11-09 1997-05-13 Ciba-Geigy Corporation Carbonate-mediated hydrogen peroxide oxidations of 4-hydroxy-2,2,6,6-tetramethylpiperidine
US5654434A (en) * 1995-11-09 1997-08-05 Ciba-Geigy Corporation Hydrogen peroxide oxidation of 4-hydroxy-2, 2, 6, 6-tetramethylpiperidine
DE19609312A1 (en) * 1996-03-09 1997-09-11 Basf Ag Stabilized monomer composition
US5777126A (en) * 1996-05-01 1998-07-07 Ciba Specialty Chemicals Corporation Carbonate-mediated hydrogen peroxide oxidation of 4-acylamino-2,2,6,6-tetramethylpiperidine
ES2162299T5 (en) * 1996-06-05 2010-09-13 Basf Se BLENDS CONTAINING MONOMERS AND STABILIZERS.
US5711767A (en) * 1996-07-11 1998-01-27 Ciba Specialty Chemicals Corporation Stabilizers for the prevention of gum formation in gasoline
GB9614854D0 (en) * 1996-07-15 1996-09-04 Marks A H & Co Ltd Free radical scavengers
US6409887B1 (en) 1996-07-15 2002-06-25 Aah Marks And Company Limited Polymerization inhibitor
DE19638868A1 (en) * 1996-09-23 1998-03-26 Basf Ag Stabilized monomer composition
EP0845448B1 (en) * 1996-12-02 2002-01-30 Ondeo Nalco Energy Services, L.P. Inhibiting polymerization of vinyl aromatic monomers
DE19651307A1 (en) * 1996-12-10 1998-06-18 Basf Ag Mixtures of compounds containing vinyl group-containing compounds and stabilizers
US5847035A (en) * 1997-03-13 1998-12-08 Uniroyal Chemical Company, Inc. Substituteed tetrahydropyrimidine derivatives and their use as polymerization inhibitors for vinyl aromatic compounds
ID20069A (en) * 1997-03-20 1998-09-24 Ciba Sc Holding Ag POLYMERIZATION INHIBITOR PROCESS
US6281311B1 (en) * 1997-03-31 2001-08-28 Pmd Holdings Corp. Controlled free radical polymerization process
US5932735A (en) * 1997-06-13 1999-08-03 Ciba Specialty Chemicals Corporation Derivatives of 1-oxyl-4-hydroxy-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers
DE19725519A1 (en) * 1997-06-17 1998-12-24 Basf Ag Mixture of substances containing compounds containing vinyl groups and stabilizers
US5969369A (en) * 1997-08-29 1999-10-19 Fogarty; Charles M. Infrared emissive module
US5869717A (en) * 1997-09-17 1999-02-09 Uop Llc Process for inhibiting the polymerization of vinyl aromatics
US5955643A (en) * 1997-10-17 1999-09-21 Nalco/Exxon Energy Chemicals, L.P. Composition and method for inhibiting polymerization during the anaerobic of styrene
US5880230A (en) * 1997-12-31 1999-03-09 Nalco/Exxon Energy Chemicals, L.P. Shortstop agents for vinyl polymerizations
US6024894A (en) * 1998-03-25 2000-02-15 Betzdearborn Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
US5907071A (en) * 1998-04-21 1999-05-25 Betzdearborn Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
US5910232A (en) * 1998-06-10 1999-06-08 Nalco/Exxon Energy Chemicals, L.P. Method for inhibiting polymer formation in styrene processing
JP4499919B2 (en) 1998-07-14 2010-07-14 チバ ホールディング インコーポレーテッド Derivatives of 1-oxyl-4-hydroxy- or 4-amino-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth) acrylate monomers
AU760809B2 (en) * 1998-09-09 2003-05-22 Baker Hughes Incorporated Styrene monomer polymerization inhibition using substituted dihydroxyarenes and nitroxides
WO2000036052A1 (en) * 1998-12-17 2000-06-22 Nalco/Exxon Energy Chemicals, L.P. Inhibiting polymerization of vinyl aromatic monomers using synergistic mixtures containing nitroxide stabilizers
US20040019247A1 (en) * 1999-02-26 2004-01-29 Basf Aktiengesellschaft Continuous recovery of styrene from a styrene-containing mixture
DE19922103A1 (en) * 1999-05-17 2000-11-23 Basf Ag Inhibiting polymerisation of vinyl monomers using composition containing nitroxyl compound, a preferably aromatic nitro compound as retarder, oxygen and optionally transition metal compound and co-stabilizer
DE19926758A1 (en) 1999-06-11 2000-12-14 Basf Ag Method for preventing undesired polymerization in a substance mixture containing ethylenically unsaturated compounds
US6395943B1 (en) 1999-08-10 2002-05-28 Uop Llc Process for inhibiting the polymerization of vinyl aromatic compounds
US6395942B1 (en) 1999-08-10 2002-05-28 Uop Llc Increasing the thermal stability of a vinyl aromatic polymerization inhibitor
US6300533B1 (en) 1999-08-16 2001-10-09 Uniroyal Chemical Company, Inc. Inhibition of polymerization of ethylenically unsaturated monomers
US6342648B1 (en) * 1999-09-30 2002-01-29 Baker Hughes Incorporated Methods and compositions for inhibiting vinyl aromatic monomer polymerization
AR029410A1 (en) 1999-12-02 2003-06-25 Crompton Corp METHOD FOR INHIBITING PREMATURE POLYMERIZATION OF ETHENICALLY INSATURED MONOMERS AND COMPOSITIONS OF THE SAME
CN1238312C (en) 1999-12-02 2006-01-25 克鲁普顿公司 Inhibition of polymerization of unsaturated monomers
ES2292487T3 (en) * 1999-12-03 2008-03-16 Chemtura Corporation COMPOSITION AND METHOD TO INHIBIT POLYMERIZATION AND POLYMER GROWTH.
US6403850B1 (en) 2000-01-18 2002-06-11 Uniroyal Chemical Company, Inc. Inhibition of polymerization of unsaturated monomers
US6344560B1 (en) * 2000-05-03 2002-02-05 Uniroyal Chemical Company, Inc. Nitroaromatic solubilizer for nitroxyls in aromatic solvents
US6339177B1 (en) 2000-05-24 2002-01-15 Sea Lion Technology, Inc. Dinitroalkyl aromatics polymerization retarders or inhibitors and methods for making and for using same
US6447649B1 (en) 2000-07-24 2002-09-10 Ge Betz, Inc. Polymerization inhibitor for vinyl-containing materials
CA2417147A1 (en) * 2000-08-02 2002-02-07 Uniroyal Chemical Company, Inc. Recycle of nitroxyl-containing streams at low temperature
US7045647B2 (en) 2000-10-16 2006-05-16 Uniroyal Chemical Company, Inc. Blends of quinone alkide and nitroxyl compounds and polymerization inhibitors
US6685823B2 (en) * 2000-10-16 2004-02-03 Uniroyal Chemical Company, Inc. C-nitrosoaniline compounds and their blends as polymerization inhibitors
US20030009031A1 (en) * 2001-04-30 2003-01-09 Mikolaj Jawosiuk Novel hindered spiro-ketal nitroxides
US6639026B2 (en) 2001-05-22 2003-10-28 Ge Betz, Inc. Methods and compositions for inhibiting polymerization of vinyl monomers
US6579442B2 (en) 2001-05-22 2003-06-17 Ge Betz, Inc. Methods and compositions for inhibiting polymerization of vinyl monomers
JP2003119205A (en) * 2001-10-12 2003-04-23 Asahi Denka Kogyo Kk Polymerization inhibitor composition
US6563753B1 (en) * 2001-11-16 2003-05-13 Agilent Technologies, Inc. Sense amplifier with independent write-back capability for ferroelectric random-access memories
WO2003054083A1 (en) 2001-12-20 2003-07-03 Ami - Agrolinz Melamine International Gmbh Additive for inhibiting photolytic degradation reactions in aminoplasts
DE60335783D1 (en) * 2002-02-15 2011-03-03 Chemtura Corp Nitrosophenole und c-nitrosoaniline als polymerisationsinhibitoren
US6960279B2 (en) * 2002-05-06 2005-11-01 Fina Technology, Inc. Method for stabilizing vinyl aromatic monomers using selected polymerization inhibitors and polymers prepared therewith
US20060069219A1 (en) * 2004-09-28 2006-03-30 Vilan Kosover Sulfonated phenols with nitrophenols as polymerization inhibitors
US7691952B2 (en) * 2004-09-28 2010-04-06 Chemtura Corporation Sulfonated nitrophenols as polymerization inhibitors
US7696290B2 (en) * 2004-12-03 2010-04-13 Crompton Corporation Aromatic sulfonic acids, amines, and nitrophenols in combination with nitroxyl radical-containing compounds or C-nitrosanilines as polymerization inhibitors
JP2006176417A (en) * 2004-12-21 2006-07-06 Hakuto Co Ltd Method for controlling polymerization of aromatic vinyl compound
JP4679144B2 (en) * 2004-12-28 2011-04-27 伯東株式会社 Method for inhibiting polymerization of divinylbenzene and copolymer containing styrene or styrene derivative
WO2006083923A1 (en) 2005-02-04 2006-08-10 Chemtura Corporation Means for controlling the exothermic reaction of styrenic monomers with sulfonic acids
US7553896B2 (en) * 2005-06-17 2009-06-30 Chemtura Corporation Ortho-nitrosophenols as polymerization inhibitors
CA2630854C (en) * 2005-12-14 2016-01-26 Novartis Ag Method for preparing silicone hydrogels
CN101410355B (en) 2006-03-24 2013-09-18 伯东株式会社 Method of inhibiting polymerization of aromatic vinyl compound
WO2007118794A1 (en) 2006-04-13 2007-10-25 Ciba Holding Inc. Sulphonium salt initiators
US8512934B2 (en) 2007-10-10 2013-08-20 Basf Se Sulphonium salt initiators
GB0903005D0 (en) 2009-02-23 2009-04-08 Nufarm Ltd Composition for controlling polymerisation
GB201011594D0 (en) 2010-07-09 2010-08-25 Nufarm Uk Ltd Retarder composition
US9206268B2 (en) 2011-09-16 2015-12-08 General Electric Company Methods and compositions for inhibiting polystyrene formation during styrene production
CN102516005A (en) * 2011-11-21 2012-06-27 上海泰顿化工有限公司 Combination for nitroxyl compounds and application of combination
SG11201402730TA (en) 2011-11-29 2014-07-30 Dorf Ketal Chemicals India Private Ltd Amine based additive composition for control and inhibition of polymerization of styrene, and method of use thereof
CN104350095B (en) 2011-12-02 2016-08-24 多尔夫凯塔尔化学制品(I)私人有限公司 For controlling and suppress compositions of additives based on amine and nitrogen oxides and the using method thereof of styrene polymerization
BR112014013855B1 (en) 2011-12-09 2020-11-17 Dorf Ketal Chemicals (I) Private Limited additive composition for the control and inhibition of polymerization of aromatic vinyl monomers and method of using it
US8901362B2 (en) 2012-02-02 2014-12-02 General Electric Company Methods and compositions for styrene inhibition via in situ generation of quinone methides
WO2014053714A1 (en) 2012-10-02 2014-04-10 Bluestar Silicones France Sas Cationically cross-linkable/polymerisable composition comprising an iodonium borate and releasing an acceptable odour
ES2624415T3 (en) 2014-09-08 2017-07-14 Evonik Degussa Gmbh (Thio) phenolic acetals as agents that inhibit the polymerization of olefinically unsaturated monomers
TWI669317B (en) 2014-09-22 2019-08-21 德商贏創德固賽有限責任公司 Method for improved reactive monomer production
CN110382556B (en) * 2017-03-09 2021-10-15 埃科莱布美国股份有限公司 Polymerization inhibitor composition
JP7228877B2 (en) * 2018-12-05 2023-02-27 精工化学株式会社 Method for producing polymerizable vinyl compound

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US465441A (en) * 1891-12-15 weisser
GB1218456A (en) * 1968-09-06 1971-01-06 Bp Chem Int Ltd Process for the stabilisation of butadiene
GB1346774A (en) * 1970-10-05 1974-02-13 Bp Chem Int Ltd Stabilisation of acrylonitrile
US3733326A (en) * 1971-03-10 1973-05-15 Sankyo Co Inhibition of the polymerization of vinyl monomers
US3988212A (en) * 1975-03-21 1976-10-26 Cosden Technology, Inc. Polymerization inhibitor for vinyl aromatic compounds
US4086147A (en) * 1976-12-10 1978-04-25 Cosden Technology, Inc. Polymerization inhibitor for vinyl aromatic compounds
US4105506A (en) * 1977-02-24 1978-08-08 Cosden Technology, Inc. Polymerization inhibitor for vinyl aromatic compounds
US4132603A (en) * 1977-11-23 1979-01-02 Cosden Technology, Inc. Polymerization inhibitor for vinyl aromatic compounds
US4132602A (en) * 1977-11-23 1979-01-02 Cosden Technology, Inc. Polymerization inhibitor for vinyl aromatic compounds
US4252615A (en) * 1978-07-18 1981-02-24 Cosden Technology, Inc. Polymerization inhibitor for vinyl aromatic compounds
JPS5846496B2 (en) * 1979-09-07 1983-10-17 大阪有機化学工業株式会社 Method for preventing popcorn polymerization of α,β-unsaturated carboxylic acid esters
US4341600A (en) * 1981-04-06 1982-07-27 Cosden Technology, Inc. Polymerization inhibitor for vinyltoluene
SU1027150A1 (en) * 1981-10-21 1983-07-07 Научно-Исследовательский Институт Механики И Физики При Саратовском Ордена Трудового Красного Знамени Государственном Университете Им.Н.Г.Чернышевского Process for stabilizing styrene of methylmethacrylate
US4376678A (en) * 1982-07-29 1983-03-15 American Hoechst Corporation Method of inhibiting polymerization of vinyl aromatic compounds
US4466904A (en) * 1983-01-10 1984-08-21 Cosden Technology, Inc. Polymerization co-inhibitors for vinyl aromatic compounds
US4468343A (en) * 1983-04-11 1984-08-28 Cosden Technology, Inc. Polymerization co-inhibitors for vinyl aromatic compounds
SU1139722A1 (en) * 1983-04-12 1985-02-15 Ереванское Отделение Охтинского Ордена Ленина И Ордена Трудового Красного Знамени Научно-Производственного Объединения "Пластполимер" Method of inhibiting styrene polymerization
JPS6036501A (en) * 1983-08-10 1985-02-25 Adeka Argus Chem Co Ltd Vinyl polymerization inhibitor
US4654451A (en) * 1985-12-27 1987-03-31 Atlantic Richfield Company Inhibiting polymerization of vinyl aromatic monomers
US4664845A (en) * 1986-01-09 1987-05-12 Uniroyal Chemical Company, Inc. Phenylenediamine solubilizer for dinitrophenol in aromatic solvent
US4670131A (en) * 1986-01-13 1987-06-02 Exxon Chemical Patents Inc. Method for controlling fouling of hydrocarbon compositions containing olefinic compounds
EP0240297A1 (en) * 1986-04-01 1987-10-07 Betz Europe, Inc. Inhibiting polymerization of vinyl aromatic compounds
JPS63316745A (en) * 1987-06-19 1988-12-26 Mitsubishi Petrochem Co Ltd Prevention of polymerization of aromatic vinyl compound
SU1558888A1 (en) * 1987-12-11 1990-04-23 Всесоюзный Научно-Исследовательский Институт Химических Реактивов И Особочистых Химических Веществ Method of inhibiting styrene polymerization
US4967027A (en) * 1987-12-22 1990-10-30 Mitsubishi Petrochemical Co., Ltd. Method of inhibiting polymerization of styrenes
JPH01165534A (en) * 1987-12-22 1989-06-29 Mitsubishi Petrochem Co Ltd Polymerization inhibitor for styrenes
MX170841B (en) * 1988-09-26 1993-09-20 Goodyear Tire & Rubber IMPROVED PROCESS FOR CATALYZED SYNTHESIS OF N-SUBSTITUTED METHACRYLAMINATES AND ACRYLIMIDS
JPH02270837A (en) * 1989-04-11 1990-11-05 Mitsui Petrochem Ind Ltd Isopropenylacetophenone composition

Similar Documents

Publication Publication Date Title
RU93048468A (en) VINYL AROMATIC MONOMER POLYMERIZATION INHIBITORS
CA2101359A1 (en) Inhibiting polymerization of vinyl aromatic monomers
ES2096220T3 (en) COMPOSITIONS AND METHODS TO INHIBIT THE VINYL-AROMATIC MONOMER POLYMERIZATION.
DE69431765D1 (en) Composition of propylene polymers
DE69317485D1 (en) Polymerization process
FI943116A0 (en) Polymerization of ethylene copolymers
DE69232193D1 (en) Olefin polymerization catalyst
DE69302824T2 (en) POLYMERIZATION OF VINYL FLUORIDE
KR950701303A (en) Inhibitor of polymerization for aromatic vinyl compounds
CA1267659C (en) Inhibiting polymerization of vinyl aromatic monomers
ES2023284B3 (en) INHIBITING COMPOSITION OF POLYMERIZATION FOR VINYL AROMATIC COMPOUNDS
DE69710163D1 (en) Inhibition of the polymerization of vinyl aromatic monomers
FI920185A0 (en) POLYMERIZATION OF WATER CONDITIONING MONOMER.
ATE197306T1 (en) DUAL ACTION INHIBITORS CONTAINING 1,2-DIAZEPINE
DK0629215T4 (en) Polymerization process Polymerization process
BR9104888A (en) INHIBITOR AND PROCESS FOR THE INHIBITION OF POLYMERIZATION OF A VINYL COMPOUND
BR9901816A (en) Process for inhibiting the formation of styrene polymer.
DE69304612D1 (en) Polymer scale inhibitor
DE69213225D1 (en) Polymerization of olefins
DE69408215D1 (en) Polymer scale inhibitor
DE69314762D1 (en) Polymer scale inhibitor
BR9407148A (en) Process to inhibit the polymerization of a vinyl aromatic compound
DE69304574D1 (en) Polymer scale inhibitor
DE69210046T2 (en) FLAMMABLE RESISTANT CARBONATE POLYMER MIXTURES CONTAINING LOW MOLECULAR HALOGENED EPOXY COMPOUNDS
DK0535458T3 (en) Photochemically reactive initiators for radical polymerization