RU2643381C1 - Method of manufacturing of two-cavity monoblock casing of bandpass filter - Google Patents
Method of manufacturing of two-cavity monoblock casing of bandpass filter Download PDFInfo
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/24—Producing shaped prefabricated articles from the material by injection moulding
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- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
- C04B2235/3222—Aluminates other than alumino-silicates, e.g. spinel (MgAl2O4)
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
- C04B2235/3232—Titanium oxides or titanates, e.g. rutile or anatase
- C04B2235/3234—Titanates, not containing zirconia
- C04B2235/3236—Alkaline earth titanates
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/602—Making the green bodies or pre-forms by moulding
- C04B2235/6022—Injection moulding
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/44—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminates
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/46—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates
- C04B35/462—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates
- C04B35/465—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on titanium oxides or titanates based on titanates based on alkaline earth metal titanates
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
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Abstract
Description
Изобретение относится к области радиоэлектроники и может быть использовано при изготовлении полосно-пропускающих фильтров (ППФ).The invention relates to the field of electronics and can be used in the manufacture of bandpass filters (PPF).
Известен способ изготовления корпуса двухрезонаторного моноблока полосно-пропускающего фильтра, включающий получение порошковой смеси, содержащей карбонат бария, оксид титана, оксид самария, оксид неодима и оксид висмута, добавление в полученную смесь пластификатора (полиэтиленгликоля), литье готовой смеси под давлением и отжиг полученной заготовки при температуре 1300-1500°C в течение 4-6 часов (см. US 6900150 В2, 31.05.2005).A known method of manufacturing a housing of a two-cavity monoblock bandpass filter, including obtaining a powder mixture containing barium carbonate, titanium oxide, samarium oxide, neodymium oxide and bismuth oxide, adding plasticizer (polyethylene glycol) to the resulting mixture, injection molding the finished mixture and annealing the resulting preform at a temperature of 1300-1500 ° C for 4-6 hours (see US 6900150 B2, 05/31/2005).
Недостаток известного способа состоит в том, что его применение приводит к низкой термической стабильности и высокому уровню диэлектрических потерь в ППФ.The disadvantage of this method is that its use leads to low thermal stability and a high level of dielectric loss in PPF.
Известный способ принят в качестве ближайшего аналога заявленного способа.The known method is adopted as the closest analogue of the claimed method.
Задачей заявленного изобретения является создание способа изготовления корпуса двухрезонаторного моноблока полосно-пропускающего фильтра, лишенного указанных недостатков.The objective of the claimed invention is to provide a method of manufacturing a housing of a two-cavity monoblock bandpass filter, devoid of these disadvantages.
В результате достигается технический результат, состоящий в повышении термической стабильности и снижении уровня диэлектрических потерь ППФ при сохранении коэффициента прямоугольности на уровне, достаточно низком для обеспечения высокой селективности ППФ, а также в обеспечении повторяемости радиотехнических параметров при серийном изготовлении ППФ.The result is a technical result consisting in increasing thermal stability and reducing the level of dielectric loss of PPF while maintaining the squareness coefficient at a level low enough to ensure high selectivity of PPF, as well as to ensure the repeatability of radio parameters in serial production of PPF.
Конкретно, указанный технический результат достигается посредством создания способа изготовления корпуса двухрезонаторного моноблока полосно-пропускающего фильтра, включающего получение порошковой смеси LaAlO3 в количестве 30-40 мас. % и CaTiO3 - остальное, добавление в полученную смесь пластификатора, выбранного из группы, включающей в себя стеарин, парафин и пчелиный воск, в количестве 7,0-8,9 мас. %, литье готовой смеси под давлением и отжиг полученной заготовки в две стадии, при этом предварительную стадию проводят при температуре 100-300°C в течение 2-4 часов, а окончательную стадию - при температуре 1300-1500°C в течение 4 часов.Specifically, the specified technical result is achieved by creating a method of manufacturing a housing of a two-cavity monoblock band-pass filter, comprising obtaining a powder mixture of LaAlO 3 in an amount of 30-40 wt. % and CaTiO 3 - the rest, adding to the resulting mixture a plasticizer selected from the group including stearin, paraffin and beeswax, in an amount of 7.0-8.9 wt. %, casting the finished mixture under pressure and annealing the obtained preform in two stages, with the preliminary stage being carried out at a temperature of 100-300 ° C for 2-4 hours, and the final stage at a temperature of 1300-1500 ° C for 4 hours.
Применение при изготовлении заготовок корпусов двухрезонаторных моноблоков ППФ литья под давлением обеспечивает повторяемость радиотехнических параметров при серийном изготовлении ППФ за счет минимизации при использовании данной технологии количества технологических параметров, влияющих на качество готовой продукции.The use of injection molding in the manufacture of billet housings for two-cavity monoblocks PPF ensures the repeatability of radio engineering parameters in serial production of PPF by minimizing the use of this technology of the number of process parameters that affect the quality of the finished product.
Добавление в смесь пластификатора в количестве, меньшем, чем 7,0 мас. %, приводит к невозможности использования для формования заготовок корпусов литья под давлением.Adding plasticizer to the mixture in an amount less than 7.0 wt. %, makes it impossible to use injection molding bodies for forming blanks.
Добавление в смесь пластификатора в количестве, большем, чем 8,9 мас. %, приводит к увеличению размеров пор и общей пористости заготовок, что существенно повышает коэффициент прямоугольности ППФ.Adding plasticizer to the mixture in an amount greater than 8.9 wt. %, leads to an increase in pore size and the total porosity of the workpieces, which significantly increases the coefficient of rectangularity of the PPF.
Применение в качестве пластификатора стеарина, парафина или пчелиного воска обеспечивает высокую текучесть готовой смеси, что обуславливает возможность использования пластификатора в количестве до 7,0 мас. %.The use of stearin, paraffin or beeswax as a plasticizer provides high fluidity of the finished mixture, which makes it possible to use a plasticizer in an amount of up to 7.0 wt. %
Ниже представлены примеры реализации заявленного способа.Below are examples of the implementation of the claimed method.
Пример 1.Example 1
Получают (посредством измельчения на шаровой мельнице) порошковую смесь LaAlO3 в количестве 35 мас. % и CaTiO3 - остальное.Receive (by grinding in a ball mill) a powder mixture of LaAlO 3 in the amount of 35 wt. % and CaTiO 3 - the rest.
В полученную смесь добавляют парафин в количестве 7,8 мас. %.To the mixture add paraffin in an amount of 7.8 wt. %
Готовую смесь льют под давлением с использованием литейной формы. Полученные заготовки подвергают отжигу в две стадии. Первую стадию проводят при температуре 250°C в течение 2 часов, вторую стадию - при температуре 1350°C в течение 4 часов.The finished mixture is poured under pressure using a mold. The obtained preforms are annealed in two stages. The first stage is carried out at a temperature of 250 ° C for 2 hours, the second stage is carried out at a temperature of 1350 ° C for 4 hours.
Пример 2.Example 2
Получают (аналогично примеру 1) порошковую смесь LaAlO3 в количестве 30 мас. % и CaTiO3 - остальное.Get (analogously to example 1) a powder mixture of LaAlO 3 in the amount of 30 wt. % and CaTiO 3 - the rest.
В полученную смесь добавляют стеарин в количестве 7,1 мас. %.To the resulting mixture add stearin in an amount of 7.1 wt. %
Готовую смесь льют под давлением с использованием литейной формы. Полученные заготовки подвергают отжигу в две стадии. Первую стадию проводят при температуре 180°C в течение 3 часов, вторую стадию - при температуре 1470°C в течение 4 часов.The finished mixture is poured under pressure using a mold. The obtained preforms are annealed in two stages. The first stage is carried out at a temperature of 180 ° C for 3 hours, the second stage is carried out at a temperature of 1470 ° C for 4 hours.
Пример 3.Example 3
Получают (аналогично примерам 1 и 2) порошковую смесь LaAlO3 в количестве 40 мас. % и CaTiO3 - остальное.Get (similar to examples 1 and 2) a powder mixture of LaAlO 3 in an amount of 40 wt. % and CaTiO 3 - the rest.
В полученную смесь добавляют стеарин в количестве 7,8 мас. %.In the mixture add stearin in an amount of 7.8 wt. %
Готовую смесь льют под давлением с использованием литейной формы. Полученные заготовки подвергают отжигу в две стадии. Первую стадию проводят при температуре 260°C в течение 4 часов, вторую стадию - при температуре 1320°C в течение 4 часов.The finished mixture is poured under pressure using a mold. The obtained preforms are annealed in two stages. The first stage is carried out at a temperature of 260 ° C for 4 hours, the second stage is carried out at a temperature of 1320 ° C for 4 hours.
Готовый корпус (в частности, имеющий форму, раскрытую в US 4673902) шлифуют до необходимого размера, зависящего от заданной центральной частоты ППФ. Далее осуществляют металлизацию отверстий указанного корпуса серебряной пастой с образованием двухрезонаторного моноблока. Затем (методом трафаретной печати) осуществляют металлизацию граней моноблока с образованием на них топологического рисунка. Полученный в результате полосно-пропускающий фильтр устанавливают (методом поверхностного монтажа) на печатную плату, аналогично патенту US 4673902.The finished body (in particular, having the shape disclosed in US 4,673,902) is ground to the required size, depending on the given center frequency of the PPF. Then, the holes of the indicated case are metallized with silver paste to form a two-cavity monoblock. Then (by screen printing) metallization of the monoblock faces is carried out with the formation of a topological pattern on them. The resulting band-pass filter is mounted (by surface mounting) on a printed circuit board, similar to US Pat. No. 4,673,902.
Для предотвращения внешних механических воздействий и попаданий внутрь ППФ посторонних частиц (припоя, флюса) над двухрезонаторным моноблоком монтируют крышку.In order to prevent external mechanical influences and foreign particles (solder, flux) entering the PPF, a cover is mounted over the two-cavity monoblock.
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Citations (6)
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US5356844A (en) * | 1992-06-24 | 1994-10-18 | Kyocera Corporation | Dielectric ceramic composition and dielectric resonator |
RU2045496C1 (en) * | 1991-01-22 | 1995-10-10 | Малое предприятие "Экотех" | Slip composition for ceramic film making |
JPH09118562A (en) * | 1995-09-07 | 1997-05-06 | Korea Advanced Inst Of Sci Technol | Ceramic dielectric for high-frequency wave |
RU2242442C1 (en) * | 2003-04-17 | 2004-12-20 | Ненашева Елизавета Аркадьевна | Method for producing of solid solution composition for high-frequency and microwave technique |
US6900150B2 (en) * | 2003-04-29 | 2005-05-31 | Cts Corporation | Ceramic composition and method |
JP2012046374A (en) * | 2010-08-26 | 2012-03-08 | Kyocera Corp | Dielectric ceramic and resonator |
-
2016
- 2016-12-23 RU RU2016150763A patent/RU2643381C1/en active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2045496C1 (en) * | 1991-01-22 | 1995-10-10 | Малое предприятие "Экотех" | Slip composition for ceramic film making |
US5356844A (en) * | 1992-06-24 | 1994-10-18 | Kyocera Corporation | Dielectric ceramic composition and dielectric resonator |
JPH09118562A (en) * | 1995-09-07 | 1997-05-06 | Korea Advanced Inst Of Sci Technol | Ceramic dielectric for high-frequency wave |
RU2242442C1 (en) * | 2003-04-17 | 2004-12-20 | Ненашева Елизавета Аркадьевна | Method for producing of solid solution composition for high-frequency and microwave technique |
US6900150B2 (en) * | 2003-04-29 | 2005-05-31 | Cts Corporation | Ceramic composition and method |
JP2012046374A (en) * | 2010-08-26 | 2012-03-08 | Kyocera Corp | Dielectric ceramic and resonator |
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