RU2629681C1 - Method to produce film image based on composition for conductive ink, multi-layer polycarbonate product with such image and method for its production - Google Patents

Abstract

FIELD: technological processes.

SUBSTANCE: method to produce a film image based on composition for the conductive ink, including application of the composition and treatment thereof by UV radiation, so that the effects of UV radiation with the same spectrum of radiation on all UV LEDs correspond to the spectrum in which photographic initiators have the greatest sensitisation. The UV LEDs are fed with a series of current pulses which frequency ranges from 1 kHz to 10 MHz, and the composition comprises nanoparticles of metal complex compound obtained by reacting at least one metal or metal compound represented by the formula M_YZ, (1), where y = 1, 2, 3 … 10; M is a metal or a metal compound; Z is selected from a group consisting ammonium, oxygen, sulfur, halogen, cyano, carbonate, nitrate, sulfate, phosphate, acetylacetonate, alkoxide, carboxylate and derivatives thereof with at least one binder-based compound comprising a geminal-based polycarbonate derivative disubstituted dihydroxydiphenyl-cycloalkane represented by the formula

,

where R¹ and R² - hydrogen, halogen, chlorine or bromine, C₁-C₈-alkyl, C₅-C₆-cycloalkyl, C₆-C₁₀-aryl, preferably phenyl, and C₇-C₁₂aralkyl, preferably phenyl-C₁-C₄-alkyl, primarily benzyl, m-4, 5…7; R³ and R⁴ are C₁-C₆-alkyl; N is an integer greater than 20; X is geminal carbon, well as at least one supplement chosen from a group consisting of an oxidizer, a photoinitiator, a stabiliser, a solvent, a dispersant, a surface-active substance, a water, a thixotropic agent and a levelling agent. A multilayer polycarbonate article and a method for producing the multilayer polycarbonate article are also described.

EFFECT: film image based on the composition that does not form separating layers during lamination.

20 cl, 40 ex

Description

The present invention relates to a film image composition and a method for producing a film image based on a composition comprising metal compounds.

Currently, the creation of film images based on polycarbonate, including metal compounds, is an urgent issue. These compositions are widely used in the field of creating composite materials containing modification layers, as well as for color personalization of composite materials.

From US 5648414, publ. 07/15/1997 known composition for printing ink, containing in its composition as a binder aromatic thermoplastic polycarbonate, consisting of monomer units, which include bisphenol A and bisphenol TMS. The use of ink on this basis makes it possible to obtain coatings for substrates with high mechanical properties.

From RU 2497858, publ. 11/10/2013 there is a known method of manufacturing a composite with an inkjet layer between two polycarbonate layers, obtained by using the composite method, using this method to produce a valuable document and / or a document protected against forgery, as well as to a document thus produced which is protected against counterfeiting and / or valuable document.

From RU 2506167, publ. 02/10/2014 a method and a device for color personalization of security documents are known, as well as security documents with color personalization in the document structure. The structure of the document inside contains the source materials, which, through a local targeted exposure to energy, stimulate the conversion of various types of nanoparticles; wherein the color visual perception of the radiation of nanoparticles depends on their type and / or local concentration. As starting materials, nanoparticles are used, based on the combination of elements of groups II-VI, which usually have a large quantum yield of radiation intensity. Preferred compounds include, for example, cadmium sulfide or mercury sulfide, cadmium selenide or mercury selenide, cadmium telluride or mercury telluride, as well as ternary or quaternary compounds of these elements. Polycarbonate, primarily bisphenol-A, is used as the polymer matrix.

From RU 2507288 a composition is known in sensor and conductive ink for inkjet micro-printing based on organic suspensions of nanoparticles with a size of 30 nm based on tin and antimony hydroxides, as well as a method comprising hydrothermal treatment of tin and antimony hydroxides at a temperature of 170 ° C. for 48 hours.

The disadvantage of the ink described above is the insufficient strength of the fixation of the film image containing a composition based on polycarbonate in order to protect valuable documents from counterfeiting. This is due to poor compatibility with the polycarbonate components that make up the ink. In this connection, processes arise that cause partial destruction of the film image, with the formation of local darkening due to optical / thermal interactions.

The invention solves the technical problem of obtaining a film image based on a composition comprising polycarbonate, ensuring the application of images by inkjet printing, which satisfy all optical requirements, primarily color, while laminating their optical properties do not deteriorate, and which do not form separating layers when lamination, but rather even contribute to the formation of a monolithic composite of polymer layers.

The authors of the present invention have consistently worked to solve these problems and came to the implementation of the present invention. The present invention provides a composition for conductive inks having very high stability and making it easy to obtain thin films that are thermally exposed at optimal temperatures, thereby making it possible to obtain a uniform film or pattern with good conductivity, regardless of the substrate used, and the method for its preparation.

The essence of the method for obtaining a film image based on a composition for conductive inks is that it involves applying the composition and processing it with UV radiation so that the effect of UV radiation with the same emission spectrum of all UV LEDs corresponds to the region of the spectrum in which photoinitiators have the maximum sensitization; at the same time, a sequence of current pulses, the frequency of which is in the range from 1 kHz to 10 MHz, are supplied to the UV LEDs, and the composition contains nanoparticles of a metal complex compound obtained by the interaction of at least one metal or metal compound represented by the formula

where y = 1,2,3 ... 10;

M is a metal or metal compound;

Z is selected from the group consisting of ammonium, oxygen, sulfur, halogen, cyano, carbonate, nitrate, sulfate, phosphate, acetylacetonate, alkoxide, carboxylate and their derivatives with at least one binder-based compound comprising a geminally polycarbonate derivative disubstituted dihydroxydiphenyl-cycloalkane represented by the formula

where R ¹ and R ² are hydrogen, halogen, chlorine or bromine, C ₁ -C ₈ alkyl, C ₅ -C ₆ cycloalkyl, C ₆ -C ₁₀ aryl, preferably phenyl, and C ₇ -C ₁₂ aralkyl preferably phenyl-C ₁ -C ₄ -alkyl, especially benzyl,

m-4, 5 ... 7,

R ³ and R ⁴ are C ₁ -C ₆ alkyl,

n is an integer greater than 20,

X is geminal carbon,

as well as at least one additive selected from the group consisting of an oxidizing agent, a photoinitiator, a crosslinkable monomer and / or oligomer, a stabilizer, a solvent, a dispersant, a surfactant, a wetting agent, a thixotropic agent and a leveling agent.

The method can be characterized in that the polycarbonate derivative has an average molecular weight (average weight value) of at least 10,000, preferably from 20,000 to 300,000, where the X atoms in the alpha position relative to the diphenyl-substituted C (C ₁ ) atom are not disubstituted alkyls, with X atoms in the beta position relative to the diphenyl substituted C (C1) atom disubstituted by alkyls. The polycarbonate is formed on the basis of 4,4 '- (3,3,5-trimethylcyclohexane-1,1-diol) diphenol, 4,4' - (3,3-dimethylcyclohexane-1,1-diol) diphenol or 4,4 '- (2,4,4-trimethylcyclopentane-1,1-diol) -diphenol and can form copolymers consisting of monomer units based on geminally substituted dihydroxydiphenyl-cycloalkane, preferably 4,4' - (3,3, 5-trimethylcyclohexane-1,1-diol) -diphenol and monomer units based on bisphenol A, with their molar ratio greater than 0.2-0.8, respectively. Also, the method may be characterized in that the photoinitiator is selected from the group IRGACURE ^®, CHEMCURE ^® TPO and LUCIRIN ^®, and the stabilizer is at least one selected from amine compounds, ammonium compounds, phosphorus compounds, sulfur compounds, and mixtures thereof. Also, the method can be characterized in that the solvent is at least one selected from the group consisting of acetate, ether, ketone, aromatic solvent and halogenated hydrocarbon, ethylene glycol, ethyl acetate, butyl acetate, methoxypropyl acetate, diethyl ether, tetrahydrofuran, dioxane, methyl ethyl ketone, acetone, dimethylformamide, 1-methyl-2-pyrrolidone, hexane, heptane, dodecane, benzene, toluene, xylene, chloroform, methylene chloride, carbon tetrachloride, acetonitrile and dimethyl sulfoxide.

As crosslinkable monomers, for example, isobornyl (meth) acrylate (IBO (M) A), 2-phenylethyl (meth) acrylate (PE (M) A), ethoxylated 2-phenyl-ethoxy acrylates, methoxylated polyethylene glycol mono (meth) acrylates can be used. , alkoxylated tetrahydrofurfuryl (meth) acrylate, alkoxylated lauryl acrylate, alkoxylated phenyl acrylate, stearyl (meth) acrylate, lauryl (meth) acrylate, isodecyl (meth) acrylate, isooctyl acrylate, octyl acrylate, tridecyl, tridecyl nonylphenol (meth) acrylate cycle trimethylolpropaneformal acrylate, hycidyl methacrylate, propylene glycol monomethacrylate, 2- (2-ethoxyethoxy) ethyl acrylate (EOEOEA), methyl methacrylate (MMA), propoxylated allyl methacrylate, ethoxylated hydroxyethyl methacrylate (meth) -dioxide (methoxy) -dioxide (ethoxy) -dioxide (ethoxy) -dioxide , alkoxylated hexanediol diacrylates, alkoxylated cyclohexanedimethanoldi (meth) acrylates, 1,3-butylene glycol di (meth) acrylate, 1,4 butane dioldi (meth) acrylate, diethylene glycol (meth) acrylate, polyethylene glycol (200) diacrylate (400), polyethylene and (meth) acrylate, polyethylene glycol (600) di (meth) acrylate, ethoxylated bisphenol-A-di (meth) acrylates, tetraethylene glycol di (meth) acrylate, triethylene glycol di (meth) acrylate, ethylene glycol dimethacrylate, polyethylene glycol dimethacrylate di diphenyl di dipropyl (meth) acrylate, propoxylated trimethylol propane triacrylate, trimethylol propane tri (meth) acrylate, propoxylated glyceryl triacrylate (GPTA), dipentaerythritol hexaacrylate (DPHA), tripropylene glycol diacrylate (TPGDA), dipentaerythritol, Pentaerythritolpenta aeritrittriakrilat (PETIA), (ethoxylated) pentaeritrittetraakrilat, ditrimetilpropantetraakrilat, trimetilpropantriakrilat (TMREOTA) tritsiklodekandimetanoldiakrilat (TCDDMDA), dipentaeritritpentaakrilat, low molecular weight monofunctional urethane acrylates, epoxy acrylates or low molecular weight hydroxypropyl methacrylate (HPMA), the list of possible use of the crosslinkable monomer is not limited to the above compounds.

A multilayer polycarbonate product is also claimed, such as a plastic card, a document characterized in that it contains a film image obtained by the above method, the film image being fused with other layers of the product in the form of a monolithic compound.

A multilayer polycarbonate product can be characterized in that the film image is fused with other layers of the product by heating and / or sonication, and / or microwave processing, and / or high-frequency processing, and / or plasma processing, and / or processing by infrared radiation, and / or UV treatment.

Also claimed is a method for producing a multilayer polycarbonate product, comprising the steps of applying a film image and processing with UV radiation.

A method of producing a multilayer polycarbonate product can be characterized in that a film image is formed by coating a substrate, where the substrate is at least one component selected from the group consisting of metal, glass, silicon wafer, ceramic, polyester, polyimide, oilcloths, fibers, wood and paper. Also, the film image is applied by irrigation with dosing, inkjet printing, offset printing, screen printing, pad printing, intaglio printing, flexography, rotary printing, embossing, xerography or lithography, in which the film image is applied by dissolving the composition for conductive ink in at least one a solvent selected from the group consisting of glycol, ether, ester, ketone, aliphatic hydrocarbon, aromatic hydrocarbon and halogenated carbon odoroda.

In addition, the solvent is at least one solvent selected from the group consisting of ethyl hexyl alcohol, terpineol, ethylene glycol, ethyl acetate, butyl acetate, methoxypropyl acetate, carbitol acetate, ethyl carbitol acetate, methyl cellosolve, butyl cellosolve, diethyl ether tetra, tetraethyl ether, tetra, tetra, ether, tetra, tetra, ether, tetra, tetra, ether, tetra, tetra, ether, tetra, tetra, ether, tetra, tetra, ether, tetra, tetra, ether, tetra, ether, tetra , dimethylformamide, 1-methyl-2-pyrrolidone, hexane, heptane, dodecane, paraffin oil, white spirit, benzene, toluene, xylene, chloroform, methylene chloride, carbon tetrachloride, acetone Rila and dimethyl sulfoxide.

The invention uses bisphenols, which are 4,4'-diphenol, 1,1-bis (4-hydroxyphenyl) ethane, 2,2-bis (4-hydroxyphenyl) propane (usually called bisphenol A), 2 to produce polycarbon. , 2-bis- (4-hydroxy-3-methylphenyl) propane, 2,2-bis- (4-hydroxyphenyl) butane, 1,1-bis- (4-hydroxyphenyl) -1-phenylethane, 1,1-bis - (4-hydroxyphenyl) cyclohexane, 1,1-bis- (4-hydroxyphenyl) -3,3,5-trimethyl-cyclohexane, 2,2-bis- (4-hydroxyphenyl) pentane, 4,4 '- (p -phenylenediisopropylidene) diphenol, 4,4 '- (m-phenylenediisopropylidene) diphenol, 1,1-bis- (4-hydroxyphenyl) -4-isopropylcyclohexane.

EXAMPLE 1

Obtaining a film image based on a composition for conductive ink

The composition was obtained with stirring at room temperature a solution of 5 g of one of the polycarbonate variants described in formula (2) in 20 ml of chloroform, to which 1.00 g (15.74 mmol) of aluminum powder and 5 g of monomer crosslinked under exposure to UV radiation. Stirring was carried out at room temperature for 30 minutes. After which the solvent was removed from the reaction solution in vacuo to obtain 11 g of an aluminum complex compound. The resulting complex compound was passed 7 times through a three-roll mill, a stabilizer, a curing initiator and 5 ml of N-methylpyrrolidone as a solvent were added, thereby obtaining an ink composition. The ink composition was applied to the base (substrate) to obtain a uniform and neat film, which was treated with UV radiation. UV processing was carried out with the same emission spectrum of all UV LEDs, which corresponds to the spectral region in which photoinitiators have maximum sensitization. A sequence of current pulses was applied to the UV LEDs at a frequency of 1 kHz.

EXAMPLE 2

It is similar to Example 1, where diethyl ether is used as a solvent, and copper carbonate is used as a metal compound, in the quantitative ratios indicated in Example 1. Irradiation is carried out at a frequency of 5 kHz.

EXAMPLE 3

It is similar to Example 1, where diethylene glycol is used as a solvent, and vanadium oxide is used as a metal compound, in the quantitative ratios indicated in Example 1. Irradiation is carried out at a frequency of 25 kHz.

EXAMPLE 4

It is similar to Example 1, where manganese oxalate is used as a metal compound, in the quantitative ratios indicated in Example 1. Irradiation is carried out at a frequency of 50 kHz.

EXAMPLE 5

It is similar to Example 2, where 1-methoxypropanol is used as a solvent, and zinc powder is used as a metal compound, in the quantitative ratios indicated in Example 2. Irradiation is carried out at a frequency of 75 kHz.

EXAMPLE 6

Similar to Example 4, where palladium chloride is used as the metal compound, in the quantitative ratios indicated in Example 4. Irradiation is carried out at a frequency of 100 kHz.

EXAMPLE 7

It is similar to Example 6, where ethyl acetate is used as a solvent, and iron stearate is used as a metal compound, in the quantitative ratios indicated in Example 6. Irradiation is carried out at a frequency of 5 MHz.

EXAMPLES 8-16.

When repeating the basic parameters shown in Example 1, R ¹ and R ² were alternately used - hydrogen, halogen, chlorine or bromine,

C ₁ -C ₈ -alkyl,

C ₅ -C ₆ cycloalkyl,

C ₆ -C ₁₀ aryl, preferably phenyl,

C ₇ -C ₁₂ aralkyl (in example 11 phenyl-C ₁ -C ₄ -alkyl, and in Example 12-benzyl),

The number m varied in each example from 4, 5 to 7, which did not affect the result.

In Example 10, R ³ and R ⁴ are C ₁ -C ₆ alkyl,

In examples 8-12 varied n - 20, 22, 26.

EXAMPLE 13

X - geminal carbon and used surfactants (any known from the prior art).

EXAMPLE 14

Additionally, an oxidizing agent and a photoinitiator were added.

EXAMPLE 15-20.

In the examples, the additives of a stabilizer, a solvent, a dispersant, a surfactant, a wetting agent, a thixotropic agent and a leveling agent (known to a person skilled in the art) were varied. The results remained stable.

EXAMPLE 21-35.

The metal nanoparticles were used alternately in the experiments (Examples 25-29 metal compound) represented by Formula 1, alternately adding Ag, Au, Cu, Zn, Ni, Co, Pd, Pt, Ti, V, Mn, Fe, Cr, Zr, Nb Mo, W, Ru, Cd, Ta, Re, Os, Ir, Al, Ga, Ge, In, Sn, Sb, Pb, Bi, Sm, Eu, Ac, Th.

In Examples 25-29, compounds: copper oxide, zinc oxide, vanadium oxide, nickel sulfide, palladium chloride, copper carbonate.

Examples 31-48 used compounds of iron chloride, gold chloride, nickel chloride, cobalt chloride, bismuth nitrate, vanadium acetate, cobalt acetate, tin lactate, manganese oxalate, gold acetate, palladium oxalate, 2-ethylhexanoate copper, iron stearate, nickel formate ammonium molybdate, zinc citrate, bismuth acetate, cobalt carbonate, platinum chloride, hydrogen chlorarate, tetrabutoxy titanium, dimethoxy zirconium dichloride, aluminum isopropoxide, tantalum methoxide and indium acetylacetonate.

In Examples 1, 3, 15, a polycarbonate derivative was used, which has an average molecular weight (average weight value) of 10,000, 20,000, and 300,000, respectively.

In Examples 10, 13, 25, X atoms in the alpha position relative to the diphenyl-substituted C (C ₁ ) atom are unsubstituted with alkyl.

In Examples 23, 31, 35, X atoms are in a beta position relative to a diphenyl-substituted C (C ₁ ) atom disubstituted by alkyls.

In Examples 1, 3, 15, a polycarbonate derivative formed on the basis of 4,4 '- (3,3,5-trimethylcyclohexane-1,1-diol) diphenol, 4,4' - (3,3-dimethylcyclohexane-1, 1-diol) diphenol or 4.4 '- (2,4, trimethylcyclopentane-1,1-diol) diphenol.

In Examples 2, 16, 19, 23, 30, the polycarbonate derivative contains copolymers consisting of monomer units based on geminally substituted dihydroxydiphenyl cycloalkane, 4,4 '- (3,3,5-trimethylcyclohexane-1,1-diol) diphenol and monomer units based on bisphenol A, with their molar 0.2, 0.4, 0.5, 0.6, 0.8, respectively

In Examples fotooinitsiatorom used each of photoinitiators -IRGACURE ^®, CHEMCURE ^® TPO and LUCIRIN ^®.

In the Examples with stabilizer additives, each of the amine compound, ammonium compound, phosphorus compound, sulfur compound, and mixtures thereof were used alternately. The results are positive.

EXAMPLE 31-40.

Derivatives of ethyl acetate, butyl acetate, methoxypropyl acetate, diethyl ether, tetrahydrofuran, dioxane, methyl ethyl ketone, acetone, dimethylformamide, 1-methyl-2-pyrrolidone, hexane, heptane, to decane, benzene, toluene, xylene, chloro were also used as solvent. , carbon tetrachloride, acetonitrile and dimethyl sulfoxide.

A multilayer plastic card was made containing such a film image, which was obtained as described above.

Such a film image was fused with other layers of the product in the form of a monolithic compound.

Additionally used in other examples, sonication, and / or microwave processing, and / or high-frequency processing, and / or plasma processing, and / or processing by infrared radiation, and / or ultraviolet treatment.

In one example, a film image was applied in the form of a coating on a substrate.

A metal substrate was used (in other examples, glass, silicon wafer, ceramic, polyester, polyimide, oilcloth, fiber, wood and paper).

The film image was applied by dosing irrigation.

In other experiments, which showed the effectiveness of the proposed methodology, the film image was applied by inkjet printing, offset printing, screen printing, pad printing, gravure printing, flexography, rotator printing, embossing, xerography or lithography.

In the examples, a method for producing a multilayer polycarbonate product was used, where the film image was applied by dissolving the conductive ink composition in at least one solvent selected from the group consisting of glycol, ether, ester, ketone, aliphatic hydrocarbon, aromatic hydrocarbon, and halogenated hydrocarbon .

In addition, the solvent is at least one solvent selected from the group consisting of ethylhexyl alcohol, terpineol, ethylene glycol, ethyl acetate, butyl acetate, methoxypropyl acetate, carbitol acetate, etilkarbitolatsetata, methyl cellosolve, butyl cellosolve, diethyl ether, tetrahydrofuran, dioxane, methylethylketone, acetone , dimethylformamide, 1-methyl-2-pyrrolidone, hexane, heptane, dodecane, paraffin oil, white spirit, benzene, toluene, xylene, chloroform, methylene chloride, carbon tetrachloride, acetonite silt and dimethyl sulfoxide.

Claims (31)

1. A method of obtaining a film image based on a composition for conductive inks, comprising applying the composition and treating it with UV radiation so that the effect of UV radiation with the same emission spectrum of all UV LEDs corresponds to a region of the spectrum in which photoinitiators have maximum sensitization, wherein a series of current pulses are fed to UV LEDs, the frequency of which is in the range from 1 kHz to 10 MHz, and the composition contains nanoparticles of a metal complex compound obtained mutually Procedure according to at least one metal or metal compound represented by the formula

where y = 1, 2, 3 ... 10; M is a metal or metal compound; Z is selected from the group consisting of ammonium, oxygen, sulfur, halogen, cyano, carbonate, nitrate, sulfate, phosphate, acetylacetonate, alkoxide, carboxylate and their derivatives with at least one binder-based compound comprising a geminally polycarbonate derivative disubstituted dihydroxydiphenyl-cycloalkane represented by the formula

where R ¹ and R ² are hydrogen, halogen, chlorine or bromine, C ₁ -C ₈ alkyl, C ₅ -C ₆ cycloalkyl, C ₆ -C ₁₀ aryl, preferably phenyl, and C ₇ -C ₁₂ aralkyl preferably phenyl-C ₁ -C ₄ -alkyl, especially benzyl, m - 4, 5 ... 7, R ³ and R ⁴ are C ₁ -C ₆ alkyl, n is an integer greater than 20, X is geminal carbon, as well as at least one additive selected from the group consisting of an oxidizing agent, a photoinitiator, a stabilizer, a solvent, a dispersant, a surfactant, a wetting agent, a thixotropic agent, and a leveling agent. 2. The method of claim 1, wherein the metal nanoparticles or metal compound represented by formula (1) is at least one selected from the group consisting of Ag, Au, Cu, Zn, Ni, Co, Pd, Pt, Ti, V, Mn, Fe, Cr, Zr, Nb, Mo, W, Ru, Cd, Ta, Re, Os, Ir, Al, Ga, Ge, In, Sn, Sb, Pb, Bi, Sm, Eu, Ac, Th, copper oxide, zinc oxide, vanadium oxide, nickel sulfide, palladium chloride, copper carbonate, iron chloride, gold chloride, nickel chloride, cobalt chloride, bismuth nitrate, vanadium acetylacetonate, cobalt acetate, tin lactate, manganese oxalate, gold acetate, palladium oxalate, copper 2-ethylhexanoate, s earata iron, nickel formate, ammonium molybdate, zinc citrate, bismuth acetate, cobalt carbonate, platinum chloride, tetrabutoxytitanium, dimetoksitsirkoniya dichloride, aluminum isopropoxide, tantalum methoxide, and indium acetylacetonate. 3. The method of claim 1, wherein the polycarbonate derivative has an average molecular weight (average weight value) of at least 10,000, preferably from 20,000 to 300,000. 4. The method of claim 1, wherein the X atoms in the alpha position relative to the diphenyl substituted C (C1) atom are not disubstituted with alkyl. 5. The method according to claim 1, wherein the X atoms in the beta position relative to the diphenyl-substituted C (C1) atom are disubstituted with alkyls. 6. The method according to claim 1, where the polycarbonate derivative is formed on the basis of 4,4 '- (3,3,5-trimethylcyclohexane-1,1-diol) -diphenol, 4,4' - (3,3-dimethylcyclohexane-1 , 1-diol) diphenol or 4.4 '- (2,4,4-trimethylcyclopentane-1,1-diol) diphenol. 7. The method according to p. 1, where the polycarbonate derivative contains copolymers consisting of monomer units based on geminally substituted dihydroxydiphenyl-cycloalkane, preferably 4,4 '- (3,3,5-trimethylcyclohexane-1,1-diol) -diphenol and monomer units based on bisphenol A, with their molar ratio greater than 0.2-0.8, respectively 8. The method of claim 1, wherein the photoinitiator is selected from the group of IRGACURE®, CHEMCURE® and LUCIRIN® TPO. 9. The method of claim 1, wherein the stabilizer is at least one selected from an amine compound, an ammonium compound, a phosphorus compound, a sulfur compound, and a mixture thereof. 10. The method of claim 1, wherein the solvent is at least one selected from the group consisting of water, alcohol, glycol, acetate, ether, ketone, aromatic solvent, and a halogenated hydrocarbon. 11. The method according to claim 1, wherein the solvent is at least one solvent selected from the group consisting of water, methanol, ethanol, isopropanol, 1-methoxypropanol, butanol, ethylene glycol, glycerol, ethyl acetate, butyl acetate, methoxypropyl acetate, diethyl ether, tetrahydrofuran, dioxane, methyl ethyl ketone, acetone, dimethylformamide, 1-methyl-2-pyrrolidone, hexane, heptane, to decane, benzene, toluene, xylene, chloroform, methylene chloride, carbon tetrachloride, acetonitrile and dimethyl sulfoxide. 12. A multilayer polycarbonate product, such as a plastic card, a document characterized in that it contains a film image obtained by the method according to claim 1, wherein the film image is fused with other layers of the product in the form of a monolithic compound. 13. A multilayer polycarbonate product according to claim 12, in which the film image is fused with other layers of the product by heating, and / or cooling, and / or electrolysis, and / or sonication, and / or microwave processing, and / or high-frequency processing, and / or plasma processing and / or processing by infrared radiation and / or processing by ultraviolet radiation. 14. A method of producing a multilayer polycarbonate product according to claim 12, comprising applying a film image and processing with UV radiation. 15. A method of producing a multilayer polycarbonate product according to claim 12, in which a film image is formed by coating a substrate. 16. The method of producing a multilayer polycarbonate product according to claim 12, in which the substrate is at least one component selected from the group consisting of metal, glass, silicon wafer, ceramic, polyester, polyimide, oilcloth, fiber, wood and paper. 17. The method of producing a multilayer polycarbonate product according to claim 12, in which the film image is applied by irrigation with dosing, inkjet printing, offset printing, screen printing, pad printing, gravure printing, flexography, rotary printing, embossing, xerography or lithography. 18. The method of producing a multilayer polycarbonate product according to claim 12, in which the film image is applied by dissolving the conductive ink composition in at least one solvent by screen printing, pad printing, gravure printing, flexography, rotary printing, embossing, xerography or lithography. 19. The method of obtaining a multilayer polycarbonate product according to claim 12, in which the deposition of a film image is carried out by dissolving the composition for the conductive ink in at least one solvent selected from the group consisting of water, alcohol, glycol, acetate, ether, ketone, aliphatic hydrocarbon, aromatic hydrocarbon and halogenated hydrocarbon. 20. The method according to p. 19, where the solvent is at least one solvent selected from the group consisting of water, methanol, ethanol, isopropanol, 1-methoxypropanol, butanol, ethylhexyl alcohol, terpineol, ethylene glycol, glycerol, ethyl acetate, butyl acetate, methoxypropyl acetate, carbitol acetate, ethyl carbitol acetate, methyl cellosolve, butyl cellosolve, diethyl ether, tetrahydrofuran, dioxane, methyl ethyl ketone, acetone, dimethylformamide, 1-methyl-2-pyrrolidone, hexane, heptane, dodecane, paraffin, paraffin, paraffin benzene, toluene, xylene, chloroform, methylene chloride, carbon tetrachloride, acetonitrile and dimethyl sulfoxide.