RU2612628C2 - Волокнистая предварительно отформованная заготовка лопатки газотурбинного двигателя, выполненная из композитного материала и имеющая встроенную платформу, и способ ее выполнения - Google Patents
Волокнистая предварительно отформованная заготовка лопатки газотурбинного двигателя, выполненная из композитного материала и имеющая встроенную платформу, и способ ее выполнения Download PDFInfo
- Publication number
- RU2612628C2 RU2612628C2 RU2014132876A RU2014132876A RU2612628C2 RU 2612628 C2 RU2612628 C2 RU 2612628C2 RU 2014132876 A RU2014132876 A RU 2014132876A RU 2014132876 A RU2014132876 A RU 2014132876A RU 2612628 C2 RU2612628 C2 RU 2612628C2
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- Prior art keywords
- threads
- preform
- preformed
- fibrous
- group
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 29
- 239000002131 composite material Substances 0.000 title claims abstract description 11
- 239000000835 fiber Substances 0.000 claims abstract description 56
- 238000009941 weaving Methods 0.000 claims abstract description 26
- 210000003746 feather Anatomy 0.000 claims abstract description 22
- 230000008569 process Effects 0.000 claims abstract description 5
- 239000011159 matrix material Substances 0.000 claims description 13
- 238000007493 shaping process Methods 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 210000001991 scapula Anatomy 0.000 claims description 7
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 238000005520 cutting process Methods 0.000 claims description 6
- 230000009467 reduction Effects 0.000 claims description 5
- 239000000126 substance Substances 0.000 abstract description 4
- 239000004753 textile Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 239000007858 starting material Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 230000008595 infiltration Effects 0.000 description 3
- 238000001764 infiltration Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- XQUPVDVFXZDTLT-UHFFFAOYSA-N 1-[4-[[4-(2,5-dioxopyrrol-1-yl)phenyl]methyl]phenyl]pyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C(C=C1)=CC=C1CC1=CC=C(N2C(C=CC2=O)=O)C=C1 XQUPVDVFXZDTLT-UHFFFAOYSA-N 0.000 description 1
- 241000272525 Anas platyrhynchos Species 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
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- 238000005056 compaction Methods 0.000 description 1
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- 238000001746 injection moulding Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920003192 poly(bis maleimide) Polymers 0.000 description 1
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- 239000000243 solution Substances 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/28—Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
- F01D5/282—Selecting composite materials, e.g. blades with reinforcing filaments
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D25/00—Woven fabrics not otherwise provided for
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B11/00—Making preforms
- B29B11/14—Making preforms characterised by structure or composition
- B29B11/16—Making preforms characterised by structure or composition comprising fillers or reinforcement
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
- B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
- B29C70/16—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
- B29C70/22—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in at least two directions forming a two dimensional structure
- B29C70/222—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in at least two directions forming a two dimensional structure the structure being shaped to form a three dimensional configuration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
- B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
- B29C70/16—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
- B29C70/24—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in at least three directions forming a three dimensional structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D99/00—Subject matter not provided for in other groups of this subclass
- B29D99/0025—Producing blades or the like, e.g. blades for turbines, propellers, or wings
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D1/00—Woven fabrics designed to make specified articles
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D25/00—Woven fabrics not otherwise provided for
- D03D25/005—Three-dimensional woven fabrics
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D3/00—Woven fabrics characterised by their shape
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/08—Blades for rotors, stators, fans, turbines or the like, e.g. screw propellers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/08—Blades for rotors, stators, fans, turbines or the like, e.g. screw propellers
- B29L2031/082—Blades, e.g. for helicopters
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/60—Properties or characteristics given to material by treatment or manufacturing
- F05D2300/603—Composites; e.g. fibre-reinforced
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/60—Properties or characteristics given to material by treatment or manufacturing
- F05D2300/603—Composites; e.g. fibre-reinforced
- F05D2300/6034—Orientation of fibres, weaving, ply angle
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Woven Fabrics (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Reinforced Plastic Materials (AREA)
- Structures Of Non-Positive Displacement Pumps (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261584406P | 2012-01-09 | 2012-01-09 | |
| US61/584,406 | 2012-01-09 | ||
| PCT/FR2013/050026 WO2013104852A2 (fr) | 2012-01-09 | 2013-01-07 | Preforme fibreuse d'une aube de turbomachine en materiau composite a plate-forme integree, et son procede de realisation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2014132876A RU2014132876A (ru) | 2016-02-27 |
| RU2612628C2 true RU2612628C2 (ru) | 2017-03-09 |
Family
ID=47628361
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2014132876A RU2612628C2 (ru) | 2012-01-09 | 2013-01-07 | Волокнистая предварительно отформованная заготовка лопатки газотурбинного двигателя, выполненная из композитного материала и имеющая встроенную платформу, и способ ее выполнения |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9771810B2 (enExample) |
| EP (1) | EP2802701B1 (enExample) |
| JP (1) | JP6038178B2 (enExample) |
| CN (1) | CN104040056B (enExample) |
| BR (1) | BR112014016859B1 (enExample) |
| CA (1) | CA2862685C (enExample) |
| IN (1) | IN2014DN05637A (enExample) |
| RU (1) | RU2612628C2 (enExample) |
| WO (1) | WO2013104852A2 (enExample) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112015010844B1 (pt) * | 2012-11-13 | 2021-04-06 | Snecma | Preforma de fibra para uma pá de turbomáquina, pá para turbomáquina, invólucro intermediário para turbomáquina, ventilador para turbomáquina, e, turbomáquina |
| FR3011253B1 (fr) | 2013-10-01 | 2016-06-10 | Snecma | Structure fibreuse avec regroupement des flottes |
| FR3018473B1 (fr) | 2014-03-17 | 2016-04-08 | Snecma | Procede de fabrication d'une plate-forme d'aube en materiau composite a joints integres pour soufflante de turbomachine |
| FR3021349B1 (fr) * | 2014-05-22 | 2021-07-02 | Herakles | Procede de fabrication d'une aube de turbomachine en materiau composite, aube ainsi obtenue et turbomachine l'incorporant |
| FR3037097B1 (fr) * | 2015-06-03 | 2017-06-23 | Snecma | Aube composite comprenant une plateforme munie d'un raidisseur |
| FR3032462B1 (fr) | 2015-02-10 | 2017-03-10 | Aircelle Sa | Procede de fabrication d’une preforme de fibres de renfort tissee comprenant une section evolutive |
| FR3035678B1 (fr) * | 2015-04-29 | 2017-05-12 | Snecma | Aube munie de plateformes possedant une jambe de retenue |
| FR3035677B1 (fr) * | 2015-04-29 | 2017-05-12 | Snecma | Aube munie de plateformes possedant des portions d'accrochage |
| FR3035675B1 (fr) | 2015-04-29 | 2017-05-12 | Snecma | Aube munie de plateformes comportant des inserts |
| FR3035676B1 (fr) * | 2015-04-29 | 2017-05-12 | Snecma | Aube munie de plateformes possedant un raidisseur |
| CN105544060A (zh) * | 2016-01-29 | 2016-05-04 | 上海仪耐新材料科技有限公司 | 一种嵌入式缝合三维防弹织物 |
| US10436036B2 (en) * | 2016-07-05 | 2019-10-08 | Safran Aircraft Engines | Fitted platform for a turbine engine fan, and a method of fabricating it |
| US20180171806A1 (en) * | 2016-12-21 | 2018-06-21 | Rolls-Royce North American Technologies, Inc. | Three-dimensionally woven ceramic matrix composite turbine blade |
| FR3063448B1 (fr) * | 2017-03-01 | 2019-04-05 | Safran Aircraft Engines | Preforme et aube monobloc pour turbomachine |
| JP6790967B2 (ja) * | 2017-03-31 | 2020-11-25 | 株式会社豊田自動織機 | 繊維構造体及び繊維強化複合材 |
| JP6700615B2 (ja) * | 2017-03-31 | 2020-05-27 | 株式会社豊田自動織機 | 繊維構造体及び繊維強化複合材 |
| FR3066531B1 (fr) | 2017-05-19 | 2019-05-03 | Safran Aircraft Engines | Aube en materiau composite et a plateforme integree pour une turbomachine d'aeronef |
| WO2019097147A1 (fr) | 2017-11-14 | 2019-05-23 | Safran Ceramics | Structure fibreuse et piece en materiau composite incorporant une telle structure |
| FR3082854B1 (fr) * | 2018-06-25 | 2020-09-11 | Safran Ceram | Structure fibreuse et piece en materiau composite incorporant une telle structure |
| FR3076814B1 (fr) * | 2018-01-12 | 2020-01-31 | Safran Aircraft Engines | Aube ou pale d'helice composite avec longeron integre pour aeronef |
| US20190390555A1 (en) * | 2018-06-22 | 2019-12-26 | United Technologies Corporation | Composite airfoil with cleft in platform |
| FR3091723B1 (fr) * | 2019-01-15 | 2021-04-02 | Safran Aircraft Engines | Aube ou Pale d'hélice composite pour aéronef intégrant une pièce de conformation |
| FR3092034B1 (fr) * | 2019-01-30 | 2022-12-02 | Safran Aircraft Engines | Carter en matériau composite avec variation locale d’épaisseur |
| FR3093297B1 (fr) * | 2019-02-28 | 2022-08-12 | Safran Aircraft Engines | Procédé de réalisation d’une pièce en matériau tissé tenant compte du décadrage |
| CN109972271B (zh) * | 2019-03-27 | 2023-03-14 | 南京玻璃纤维研究设计院有限公司 | 一种变厚度预制体、一种复合部件以及一种变厚度预制体的减纱方法 |
| US11434177B2 (en) | 2019-05-13 | 2022-09-06 | Rolls-Royce Plc | Ceramic matrix composite vane with hybrid construction |
| US12099894B2 (en) * | 2019-09-20 | 2024-09-24 | Rtx Corporation | Composite material marking and identification |
| FR3102392B1 (fr) * | 2019-10-29 | 2021-10-08 | Safran | Préforme fibreuse tissée pour réaliser une aube de soufflante en matériau composite |
| CN111365079A (zh) * | 2020-04-01 | 2020-07-03 | 南京航空航天大学 | 陶瓷基复合材料涡轮转子叶片盘榫连接结构及涡轮盘 |
| FR3113647B1 (fr) | 2020-08-27 | 2023-04-14 | Safran Aircraft Engines | Helice non carenee a pales a calage variable comportant des plate-formes a pertubations reduites |
| FR3120910A1 (fr) * | 2021-03-17 | 2022-09-23 | Safran Aircraft Engines | Pièce de turbomachine composite formée d’une âme entourée par deux préformes fibreuses tissées 3D |
| FR3141094B1 (fr) * | 2022-10-25 | 2024-10-25 | Safran | Aube ou pale avec pied réalisé par croisement de trames |
| CN115949471B (zh) * | 2023-01-04 | 2023-12-22 | 北京航空航天大学 | 一种正交三维机织复合材料出口导向叶片及其制造方法 |
| US11846192B1 (en) | 2023-04-21 | 2023-12-19 | General Electric Company | Airfoil assembly with a trunnion and spar |
| CN119704716B (zh) * | 2023-09-27 | 2025-11-25 | 中国航发商用航空发动机有限责任公司 | 复合材料叶片制备方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030056847A1 (en) * | 2001-09-12 | 2003-03-27 | Schmidt Ronald P. | Woven preform for structural joints |
| RU2225902C1 (ru) * | 2001-07-05 | 2004-03-20 | Олбэни Интернэшнл Текниуив, Инк. | Плоская ткань для формирования структуры, имеющей трехмерную конфигурацию |
| US20100105269A1 (en) * | 2008-10-29 | 2010-04-29 | Jonathan Goering | Pi-Shaped Preform |
| FR2953885A1 (fr) * | 2009-12-14 | 2011-06-17 | Snecma | Aube de turbomachine en materiau composite et procede pour sa fabrication |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0772482B2 (ja) * | 1991-12-26 | 1995-08-02 | 工業技術院長 | ラジアルロータ及びその製造方法 |
| FR2861143B1 (fr) | 2003-10-20 | 2006-01-20 | Snecma Moteurs | Aube de turbomachine, notamment aube de soufflante et son procede de fabrication |
| DE10350917B3 (de) | 2003-10-31 | 2005-05-25 | Rle International Produktentwicklungsgesellschaft Mbh | Übertragungsunterbrechungsfreies Schaltgetriebe |
| FR2887601B1 (fr) | 2005-06-24 | 2007-10-05 | Snecma Moteurs Sa | Piece mecanique et procede de fabrication d'une telle piece |
| US7655581B2 (en) * | 2005-11-17 | 2010-02-02 | Albany Engineered Composites, Inc. | Hybrid three-dimensional woven/laminated struts for composite structural applications |
| FR2939153B1 (fr) * | 2008-11-28 | 2011-12-09 | Snecma Propulsion Solide | Realisation d'une structure fibreuse a epaisseur evolutive par tissage 3d |
| FR2939129B1 (fr) * | 2008-11-28 | 2014-08-22 | Snecma Propulsion Solide | Aube de turbomachine en materiau composite et procede pour sa fabrication. |
| FR2943942B1 (fr) | 2009-04-06 | 2016-01-29 | Snecma | Procede de fabrication d'une aube de turbomachine en materiau composite |
| FR2946999B1 (fr) * | 2009-06-18 | 2019-08-09 | Safran Aircraft Engines | Element de distributeur de turbine en cmc, procede pour sa fabrication, et distributeur et turbine a gaz l'incorporant. |
| FR2961846B1 (fr) * | 2010-06-28 | 2012-08-03 | Snecma Propulsion Solide | Aube de turbomachine a geometrie asymetrique complementaire |
| FR2961845B1 (fr) * | 2010-06-28 | 2013-06-28 | Snecma Propulsion Solide | Aube de turbomachine a geometrie complementaire paire/impaire et son procede de fabrication |
| US10280537B2 (en) * | 2011-12-14 | 2019-05-07 | Sanfran Aircraft Engines | Fiber structure woven as a single piece by 3D weaving and application to the manufacturing of composite material part |
-
2013
- 2013-01-07 CA CA2862685A patent/CA2862685C/fr active Active
- 2013-01-07 IN IN5637DEN2014 patent/IN2014DN05637A/en unknown
- 2013-01-07 US US14/371,220 patent/US9771810B2/en active Active
- 2013-01-07 JP JP2014550750A patent/JP6038178B2/ja active Active
- 2013-01-07 WO PCT/FR2013/050026 patent/WO2013104852A2/fr not_active Ceased
- 2013-01-07 BR BR112014016859-8A patent/BR112014016859B1/pt active IP Right Grant
- 2013-01-07 CN CN201380004969.XA patent/CN104040056B/zh active Active
- 2013-01-07 EP EP13701834.7A patent/EP2802701B1/fr active Active
- 2013-01-07 RU RU2014132876A patent/RU2612628C2/ru active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2225902C1 (ru) * | 2001-07-05 | 2004-03-20 | Олбэни Интернэшнл Текниуив, Инк. | Плоская ткань для формирования структуры, имеющей трехмерную конфигурацию |
| US20030056847A1 (en) * | 2001-09-12 | 2003-03-27 | Schmidt Ronald P. | Woven preform for structural joints |
| US20100105269A1 (en) * | 2008-10-29 | 2010-04-29 | Jonathan Goering | Pi-Shaped Preform |
| FR2953885A1 (fr) * | 2009-12-14 | 2011-06-17 | Snecma | Aube de turbomachine en materiau composite et procede pour sa fabrication |
Also Published As
| Publication number | Publication date |
|---|---|
| US20140369848A1 (en) | 2014-12-18 |
| JP6038178B2 (ja) | 2016-12-07 |
| BR112014016859B1 (pt) | 2021-02-09 |
| RU2014132876A (ru) | 2016-02-27 |
| CA2862685A1 (fr) | 2013-07-18 |
| CN104040056B (zh) | 2016-05-04 |
| IN2014DN05637A (enExample) | 2015-04-03 |
| BR112014016859A2 (pt) | 2017-06-13 |
| CA2862685C (fr) | 2020-03-10 |
| JP2015509159A (ja) | 2015-03-26 |
| BR112014016859A8 (pt) | 2017-07-04 |
| EP2802701B1 (fr) | 2016-11-16 |
| EP2802701A2 (fr) | 2014-11-19 |
| WO2013104852A2 (fr) | 2013-07-18 |
| CN104040056A (zh) | 2014-09-10 |
| US9771810B2 (en) | 2017-09-26 |
| WO2013104852A3 (fr) | 2014-02-20 |
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