RU2597315C1 - Method for producing solid deicing material based on table salt and calcined calcium chloride (versions) - Google Patents

Abstract

FIELD: chemistry.

SUBSTANCE: invention relates to chemical industry, namely to deicing materials with low corrosion activity. A method for producing a solid deicing material comprises a mechanical uniform mixing between a crystal of common salt stone Class I crystalline calcium chloride calcined first technical grade crystalline metal corrosion inhibitor elements, crystalline surfactant crystalline acidity regulator. During production of deicing material each element of corrosion inhibitor is saturated with heavy isotopes of carbon ¹³C so that ratio of carbon isotopes ¹³C to total amount of carbon in element makes from 0.005 to 0.75, and each element of corrosion inhibitor is saturated with heavy isotopes of nitrogen ¹⁵N so that ratio of nitrogen isotopes ¹⁵N to total amount of nitrogen in element makes from 0.0001 to 0.1375.

EFFECT: technical result consists in improvement of efficiency of corrosion inhibitor in obtained solid deicing material without deterioration of its anti-icing properties.

5 cl, 4 dwg, 69 tbl

Description

The technical field to which the invention relates.

The invention relates to the chemical industry, and in particular to deicing materials based on edible salt, calcined calcium chloride, corrosion inhibitors and can be used to obtain solid deicing materials with reduced corrosion activity.

The level of technology.

Most methods of dealing with winter slippery are aimed at removing the ice or snow layer from the road surface using chemical, mechanical, thermal and other methods, preventing the formation of a snow-ice layer or weakening its adhesion to the road surface.

To date, the most affordable deicing material (PGM) is sodium chloride / 1 /. Sodium chloride can reduce the temperature of ice formation on roads, as well as remove the formed ice, since the temperature of the eutectic of sodium chloride with ice is - 21.2 ° C 121. However, sodium chloride is highly corrosive to metals and, in particular, to metal structural materials of cars.

Famous PGM to prevent icing on the road, including a mixture of river sand and sodium chloride. Sodium chloride contained in such a sand-salt mixture is corrosive (Instructions for the protection of the environment in the construction of roads. BCN8-89 - Minavtodor, Moscow, 1989, p. 14). The method of application of this material refers to the combined, that is, the melting effect of the salt is complemented by the frictional property of sand.

Solid PGM is known, including a mixture of sodium chloride (sodium chloride) and calcium chloride (calcium chloride). The method of producing PGM is described in the source "ONE. Requirements for deicing materials. Rosavtodor of the Ministry of Transport of the Russian Federation, Moscow 2003 ”.

Due to the presence of calcium chloride in PGM, which generates heat during dissolution, a high melting rate of snow-ice deposits can be achieved, and the range of operating temperatures can be expanded up to -25 ° C. The high melting ability of a mixture of sodium and calcium chlorides causes a lower consumption of materials (reagents) in comparison, for example, with PGM based on only sodium chloride or a sand-salt mixture described above. Yielding to the melting ability of calcium chloride, its mixture with sodium chloride has a prolonged anti-icing effect. The duration of action of calcium chloride on the road surface in most cases does not exceed 3 hours. Sodium chloride, by contrast, acts on the pavement for up to 10 hours. The combination of sodium and calcium chlorides leads to a rational practical result.

The above-described PGM is also characterized by high corrosion activity with respect to metals. And in PGM there is no corrosion inhibitor (IR).

Increased modern requirements for the protection of road structures and cars from corrosion lead to the search for more effective technologies and means of combating snow and ice on all types of roads, including highways and city streets, as well as courtyards and sidewalks. Inorganic salts such as sodium, calcium, magnesium chlorides and metal corrosion inhibitors are widely used as such agents. Moreover, for the effective removal of ice, a high content of chlorides is required, and to weaken their corrosion activity, a high content of effective corrosion inhibitors is required. In modern PGM, the task of reducing corrosion activity is solved by reducing the deicing properties of materials and increasing the percentage of IR in PGM.

It will be shown below that in the invention, the task of reducing corrosion activity is achieved not by reducing chlorides in PHM, but by increasing the efficiency of IR.

Currently, in order to reduce the corrosive activity of PGM with respect to metals, they are introduced from fractions of percent to tens of percent of corrosion inhibitors. Currently, such corrosion inhibitors (or elements that are part of corrosion inhibitors) such as urea (NH ₂ ) ₂ CO, urotropin (CH ₂ ) ₆ N ₄ , 2-phosphonobutane-1,2,4-tricarboxylic acid tetrasodium acid have been widely used salt, sodium formate (sodium formate) HCO ₂ Na, potassium iron-hydrogen sulfide K ₃ [Fe (CN) ₆ ], sodium stearate NaC ₁₈ H ₃₅ O ₂ , potassium stearate KC ₁₈ H ₃₅ O ₂ , sodium nitrite NaNO ₂ , calcium nitrate Ca (NO ₃ ) ₂ and many others. Source / 3 / describes more than a thousand metal corrosion inhibitors.

An analogue to all variants of the invention is a method for producing PGM, described in RF patent 2285712, publ. 10/20/2006. In analogue, the problem of reducing the harmful corrosive effects of PGM is solved. This material is prepared by mixing sodium chloride, river sand, iron chloride and urea. Introduction to urea material in the amount of up to 4 wt. % allows to reduce the corrosive activity of PGM.

Signs that match the features of the invention: anti-icing material, urea, ... sodium chloride (which is part of the food table salt).

The disadvantage of the analogue is the relatively small decrease in the corrosivity of PGM.

Another analogue to all variants of the invention is a method for producing PGM described in RF patent 2521381, publ. 06/27/2014. The method involves mechanical mixing of the solid components of PGM: calcium chloride (calcium chloride), sodium chloride, ammonium chloride, sodium hydroxide and paraform. The analogue provides a decrease in the corrosive properties of PHM by using a corrosion inhibitor formed at the time of application of the composition.

Signs that match the features of the invention: a method for producing PGM, comprising mechanically mixing between themselves calcium chloride, sodium chloride (which is part of the food salt), ... corrosion inhibitor.

The disadvantage of the analogue is the relatively low efficiency of the corrosion inhibitor.

Also analogous to all variants of the invention is a method for producing anti-icing material described in RF patent 2259383, publ. August 27, 2005. In an analogue, calcium chloride (calcium chloride), sodium nitrite and urea are mixed. Urea (urea) and sodium nitrite are used as elements of a corrosion inhibitor. The content of calcium chloride in the solution depends on the ambient temperature for which it is designed.

Signs that match the features of the invention: a method of obtaining anti-icing material, mix calcium chloride, corrosion inhibitor, urea.

The disadvantage of the analogue is the relatively low efficiency of the corrosion inhibitor.

The prototype of all variants of the invention is a method for producing solid deicing material, including uniform mechanical mixing of crystalline food grade stone salt of the first grade, crystalline calcium chloride, technical calcined first grade, crystalline elements of a metal corrosion inhibitor, crystalline surfactant, crystalline acidity regulator (see http://newtechnolog.narod.ru/articles/52article.html).

These signs coincide with the signs of the restrictive parts of the claims of all variants of the invention.

As elements of IR in the prototype, disubstituted sodium phosphate and double superphosphate were used.

The disadvantage of the prototype is

The relatively low efficiency of the corrosion inhibitor in the composition of the solid anti-icing material obtained in the prototype is due to the fact that the elements of the corrosion inhibitor are not enriched with heavy isotopes of carbon ¹³ C and nitrogen ¹⁵ N.

Disclosure of the invention.

Terms and Definitions.

Deicing material (PGM) is a material for combating winter slippery on roads and sidewalks. Deicing material is also called deicing agent, anti-icing agent, anti-icing agent, anti-icing composition, anti-icing agent, anti-icing agent, ice and snow remover. The application deals with solid (crystalline) anti-icing materials used to combat winter slippery. The term "Deicing material" is disclosed in the Instruction to combat winter slippery / 4 /.

Deicing material consists of components. So in the patent of the Russian Federation 2521381, publ. 06/27/2014 Deicing material is described, the components of which are: calcium chloride, sodium chloride, ammonium chloride, sodium hydroxide and paraforms.

PGM containing carbon isotopes of ¹³ C and nitrogen ¹⁵ N is the material considered in the application Deicing material with a corrosion inhibitor containing carbon isotopes of ¹³ C and nitrogen ¹⁵ N. This is the shortened name considered in the invention of PGM.

PGM with isotopes of carbon ¹³ C and nitrogen ¹⁵ N is the same as PGM containing isotopes of carbon ¹³ C and nitrogen ¹⁵ N.

Base PGM - Deicing material obtained by methods 1-5 (see the claims) without saturation of corrosion inhibitors (IR elements) with heavy isotopes ¹³ C and ¹⁵ N. Another definition, basic PGM - Deicing material with a corrosion inhibitor (elements included in IR) contains ¹³ C and ¹⁴ N isotopes (there are no heavy ¹³ C and ¹⁵ N isotopes in IR).

Uniform mechanical mixing between each other is the mixing of components, for example, in a mixture, so that in any arbitrary volume of the mixture, the percentage of each component is the same. In addition, the term “Uniform mechanical mixing between each other” is the name of the operation in which the components of PGM are mixed together.

Food grade table salt of the first grade is a white crystalline substance. A component that is part of the PGM. Mass fraction of sodium chloride is not less than 97.7% / 5 /.

Calcium chloride technical calcined first grade - a white crystalline substance, a component that is part of PGM. Mass fraction of calcium chloride is not less than 90% / 6 /.

Metal Corrosion Inhibitor - A chemical or chemicals that inhibit metal corrosion. In the claimed embodiments of the invention use a corrosion inhibitor containing several chemicals - elements of a corrosion inhibitor. The term metal corrosion inhibitor can be written simply as a corrosion inhibitor or simply an inhibitor. The protective effect of the corrosion inhibitor is due to a change in the state of the metal surface and the formation of insoluble compounds on the metal surface.

An element of a metal corrosion inhibitor is a chemical substance that slows down metal corrosion and is a part of a corrosion inhibitor. In the text, an element of a metal corrosion inhibitor may simply be referred to as a “corrosion inhibitor element”, “an inhibitor element”, or simply an “element”.

Surfactant (surfactant) is a chemical compound that, when concentrated on the interface of thermodynamic phases, causes a decrease in surface tension.

The thermodynamic phase is a physically homogeneous part of the system, separated from other parts of the system by interface surfaces. At the interface, some properties of the system abruptly change. In a single-component system, different phases can be represented by different aggregate states or different polymorphic modifications of a substance. In a multicomponent system, the phases can have a different composition and structure.

Acidity regulator - a chemical substance for adjusting the acidity of a solution (pH value). In the claimed embodiments of the invention, ammonium chloride of the first grade is used as an acidity regulator.

In the application, the acidity regulator provides an aqueous solution of PHM pH = 8.5.

The eutectic temperature is the temperature at which the liquid and solid phases are in equilibrium. The eutectic composition is a liquid solution that crystallizes at the lowest temperature.

The St3ps steel used in the experiments contained: carbon - 0.20%, silicon - 0.08%, manganese - 0.45%, nickel, copper, chromium - up to 0.3%, arsenic up to 0.05%, sulfur up to 0 05, phosphorus up to 0.04%, respectively. To simplify, ST3ps steel can be called "Steel St3" or "St3".

Mass flow rate is the mass of a substance that passes through a given cross-sectional area of a stream per unit time.

The content of ¹³ C carbon isotopes in IR is from 0.5% to 75% - by the ratio of ¹³ C carbon isotopes to the total amount of carbon in IR from 0.005 to 0.75 (from 0.5% to 75%). The term “Content of ¹³ C carbon isotopes in IR from 0.5% to 75%” means that each IR element contains ¹³ C carbon isotopes from 0.5% to 75%.

The content of ¹⁵ N nitrogen isotopes in IR is from 0.01% to 13.75% - by the ratio of the amount of ¹⁵ N nitrogen isotopes to the total amount of nitrogen in IR from 0.0001 to 0.1375 (from 0.01 to 13.75%). The term “The content in nitrogen isotopes of N ¹⁵ N from 0.01% to 13.75%” means that each element of IR contains nitrogen isotopes of ¹⁵ N from 0.01% to 13.75%.

Channel cross-sectional area - the area of the internal cavity of the channel in the cross section of the channel.

A corrosion inhibitor without carbon isotopes ¹³ C and nitrogen ¹⁵ N is a corrosion inhibitor, all elements of which (and, consequently, the IR itself) are not saturated with heavy isotopes of carbon ¹³ C and nitrogen ¹⁵ N.

Five applications of the invention are described herein.

The objective of each of the variants of the invention is to develop a method for producing solid anti-icing material with low corrosion activity.

The first embodiment of the invention.

The problem is solved due to the fact that the method for producing solid deicing material includes uniform mechanical mixing between each other of crystalline salt of food grade stone first grade, crystalline calcium chloride technical calcined first grade, crystalline elements of a metal corrosion inhibitor, crystalline surfactant, crystalline acidity regulator, and differs from the prototype in that 2-et is used as a surfactant sodium ilhexyl iminodipropionate, technical grade ammonium chloride is used as an acidity regulator, first-grade technical grade ammonium chloride is used, granular carbamide of the first grade, 2-phosphonobutane-1,2,4-tricarboxylic acid tetrasodium salt, magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) are used ₂ , sodium benzoate C ₆ H ₅ COONa, caprolactam C ₆ H ₁₁ NO, in the following ratio, wt. % of the total number of components in the anti-icing material:

food grade table salt 51.0 calcium chloride technical calcined first grade 43.0 Sodium 2-ethylhexyliminodipropionate 0.10 first grade ammonium chloride 0.2 urea granular first grade 4.98 2-phosphonobutane-1,2,4-tricarboxylic acid tetrasodium salt 0.02 magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ 0.27 sodium benzoate C ₆ H ₅ COONa 0.33 caprolactam C ₆ H ₁₁ NO 0.10

wherein the metal corrosion inhibitor is prepared as follows:

- each of the above corrosion inhibitor element is dissolved in distilled water so that the resulting aqueous solution contains one weight part of the corrosion inhibitor element and three weight parts of distilled water;

- further, the resulting aqueous solution of each element of the corrosion inhibitor is subjected to cavitation treatment in a reactor installation, while the reactor installation contains a solution tank with a thermometer and a heat exchanger, an electric gear pump, a cavitation reactor, and the tank is connected by a pipeline to the pump inlet and the pump outlet by a pipeline connected to the inlet of the cavitation reactor, the outlet of the cavitation reactor by a pipeline connected to the tank, and at the entrance to the cavitation reactor and exit from the cavitation Pressure gauges for determining the pressure drop across the cavitation reactor are located, and the cavitation reactor contains a channel for the movement of the aqueous solution, and the channel, in the direction of the movement of the aqueous solution, contains three constrictions, the area of the passage section of the channel at each constriction is 8% of the maximum area the passage section of the channel, and before each narrowing of the channel there is a height-adjustable rod, turbulent flow before the narrowing of the channel, behind each narrowing in the cavitation reactor vessel false passage for supplying carbon dioxide or nitrogen to cavitation reactor;

- for cavitation treatment, the resulting aqueous solution of each element of the corrosion inhibitor is poured into the capacity of the reactor installation, heated to 60 ° C and pumped from 170 to 720 times through the cavitation reactor by means of a gear pump;

- during cavitation processing, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the location of the rod;

- in addition, in the process of cavitation treatment through the channel located behind the first, in the direction of movement of the solution by constriction, carbon dioxide is supplied with a mass flow rate equal to 2% of the mass flow rate of the aqueous solution, through the channel located behind the second, in the direction of movement of the solution by constriction carbon dioxide is supplied with a mass flow rate equal to 1% of the mass flow rate of an aqueous solution, carbon dioxide with a mass flow rate equal to 0 is supplied through a channel located behind the third one in the direction of movement of the solution by narrowing 5% of the mass flow rate of an aqueous solution;

- by means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment is increased from 60 ° C to 75 ° C;

- during the cavitation treatment, the corrosion inhibitor element in solution is saturated with ¹³ C heavy carbon isotopes so that the ratio of ¹³ C carbon isotopes to the total carbon in the element is from 0.005 to 0.75;

- control the number of carbon isotopes ¹³ C is carried out by high resolution mass spectroscopy;

- further, the resulting aqueous solution of the above-mentioned element of the corrosion inhibitor is subjected to repeated cavitation treatment in a reactor installation, for which the aqueous solution located in the tank is heated to 80 ° C and pumped from a cavitation reactor 50 to 390 times through a gear pump;

- during cavitation processing, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the location of the rod;

- in addition, in the process of cavitation treatment through the channel located after the first, in the direction of movement of the solution by constriction, gaseous nitrogen is supplied with a mass flow rate equal to 1% of the mass flow rate of the aqueous solution, through the channel located behind the second, in the direction of movement of the solution by constriction, nitrogen gas is supplied with a mass flow rate equal to 0.5% of the mass flow rate of an aqueous solution, nitrogen gas with a mass flow rate is fed through a channel located behind the third one in the direction of solution flow narrowing to 0.1% of the mass flow rate of the aqueous solution;

- by means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment is increased from 80 ° C to 85 ° C;

- during the cavitation treatment, the corrosion inhibitor element in solution is saturated with heavy nitrogen isotopes ¹⁵ N so that the ratio of the number of nitrogen isotopes ¹⁵ N to the total amount of nitrogen in the element is from 0.0001 to 0.1375;

- control the number of nitrogen isotopes ¹⁵ N carry out mass spectroscopy of high resolution;

- after repeated cavitation treatment of the solution, the element of the corrosion inhibitor is crystallized, for which 95.5% of water is evaporated from the aqueous solution;

- after cavitation treatment and crystallization of all the above elements of the corrosion inhibitor, they are mixed with the remaining components of the anti-icing material in the above percentage ratio;

- moreover, the cavitation treatment of the elements of the corrosion inhibitor is carried out in such a way that the percentage of carbon isotopes ¹³ C in each element of the corrosion inhibitor is the same and the percentage of nitrogen isotopes ¹⁵ N in each element of the corrosion inhibitor is the same.

The second variant of the invention.

The problem is solved due to the fact that the method for producing solid deicing material includes uniform mechanical mixing between each other of crystalline salt of food grade stone first grade, crystalline calcium chloride technical calcined first grade, crystalline elements of a metal corrosion inhibitor, crystalline surfactant, crystalline acidity regulator, and differs from the prototype in that 2-et is used as a surfactant sodium ilhexyliminodipropionate, technical grade ammonium chloride is used as an acidity regulator, technical grade ammonium chloride is used, granular carbamide of the first grade, urotropine, magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ , sodium benzoate C ₆ H ₅ COONa, caprolactam C ₆ are used as elements of a metal corrosion inhibitor H ₁₁ NO, in the following ratio, wt. % of the total number of components in the anti-icing material:

food grade table salt 51.0 calcium chloride technical calcined first grade 43.0 Sodium 2-ethylhexyliminodipropionate 0.10 first grade ammonium chloride 0.2 urea granular first grade 4.98 urotropin 0.02 magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ 0.27 sodium benzoate C ₆ H ₅ COONa 0.33 caprolactam C ₆ H ₁₁ NO 0.10

wherein the metal corrosion inhibitor is prepared as follows:

- each of the above corrosion inhibitor element is dissolved in distilled water so that the resulting aqueous solution contains one weight part of the corrosion inhibitor element and three weight parts of distilled water;

- further, the resulting aqueous solution of each element of the corrosion inhibitor is subjected to cavitation treatment in a reactor installation, while the reactor installation contains a solution tank with a thermometer and a heat exchanger, an electric gear pump, a cavitation reactor, and the tank is connected by a pipe to the pump inlet, the pump outlet is connected by a pipeline with the inlet of the cavitation reactor, the outlet of the cavitation reactor is connected by a pipeline to the tank, and at the entrance to the cavitation reactor and exit from the cavitation pressure gauges are located on the reactor to determine the pressure drop across the cavitation reactor, and the cavitation reactor contains a channel for the movement of the aqueous solution, and the channel, in the direction of the movement of the aqueous solution, contains three constrictions, the passage area of the channel at the site of each constriction is 8% of the maximum area the passage section of the channel, and before each narrowing of the channel, a height-adjustable rod is located, turbulent flow before the narrowing of the channel, behind each narrowing in the cavitation reactor vessel, a channel for supplying carbon dioxide or nitrogen to the cavitation area of the reactor is false;

- for cavitation treatment, the resulting aqueous solution of each element of the corrosion inhibitor is poured into the capacity of the reactor installation, heated to 60 ° C and pumped from 170 to 720 times through the cavitation reactor by means of a gear pump;

- during cavitation processing, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the location of the rod;

- in addition, in the process of cavitation treatment through the channel located behind the first, in the direction of movement of the solution by constriction, carbon dioxide is supplied with a mass flow rate equal to 2% of the mass flow rate of the aqueous solution, through the channel located behind the second, in the direction of movement of the solution by constriction carbon dioxide is supplied with a mass flow rate equal to 1% of the mass flow rate of an aqueous solution, carbon dioxide with a mass flow rate equal to 0 is supplied through a channel located behind the third one in the direction of movement of the solution by narrowing 5% of the mass flow rate of an aqueous solution;

- by means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment is increased from 60 ° C to 75 ° C;

- during the cavitation treatment, the corrosion inhibitor element in solution is saturated with ¹³ C heavy carbon isotopes so that the ratio of ¹³ C carbon isotopes to the total carbon in the element is from 0.005 to 0.75;

- control the number of carbon isotopes ¹³ C is carried out by high resolution mass spectroscopy;

- further, the obtained aqueous solution of the aforementioned element of the corrosion inhibitor is subjected to repeated cavitation treatment in a reactor installation, for which the aqueous solution located in the tank is heated to 80 ° C and pumped from a cavitation reactor 50 to 390 times through a gear pump;

- during cavitation processing, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the location of the rod;

- in addition, in the process of cavitation treatment through the channel located after the first, in the direction of movement of the solution by constriction, gaseous nitrogen is supplied with a mass flow rate equal to 1% of the mass flow rate of the aqueous solution, through the channel located behind the second, in the direction of movement of the solution by constriction, nitrogen gas is supplied with a mass flow rate equal to 0.5% of the mass flow rate of an aqueous solution, nitrogen gas with a mass flow rate is fed through a channel located behind the third one in the direction of solution flow narrowing to 0.1% of the mass flow rate of the aqueous solution;

- by means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment is increased from 80 ° C to 85 ° C;

- during the cavitation treatment, the corrosion inhibitor element in solution is saturated with heavy nitrogen isotopes ¹⁵ N so that the ratio of the number of nitrogen isotopes ¹⁵ N to the total amount of nitrogen in the element is from 0.0001 to 0.1375;

- control the number of nitrogen isotopes ¹⁵ N carry out mass spectroscopy of high resolution;

- after repeated cavitation treatment of the solution, the corrosion inhibitor element is crystallized, for which 95.5% of water is evaporated from the aqueous solution;

- after cavitation treatment and crystallization of all the above elements of the corrosion inhibitor, they are mixed with the remaining components of the anti-icing material in the above percentage ratio;

- moreover, the cavitation treatment of the elements of the corrosion inhibitor is carried out in such a way that the percentage of carbon isotopes ¹³ C in each element of the corrosion inhibitor is the same and the percentage of nitrogen isotopes ¹⁵ N in each element of the corrosion inhibitor is the same.

Third Embodiment

The problem is solved due to the fact that the method for producing solid deicing material includes uniform mechanical mixing between each other of crystalline salt of food grade stone first grade, crystalline calcium chloride technical calcined first grade, crystalline elements of a metal corrosion inhibitor, crystalline surfactant, crystalline acidity regulator, and differs from the prototype in that 2-et is used as a surfactant sodium ilhexyliminodipropionate, technical grade ammonium chloride is used as an acidity regulator, first-grade technical ammonium chloride is used, granular carbamide of the first grade, monosubstituted sodium phosphate NaH ₂ PO ₄ × 2H ₂ O, magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ , benzoate are used as elements of the corrosion inhibitor sodium C ₆ H ₅ COONa, caprolactam C ₆ H ₁₁ NO, in the following ratio, wt. % of the total number of components in the anti-icing material:

food grade table salt 51.0 calcium chloride technical calcined first grade 43.0 Sodium 2-ethylhexyliminodipropionate 0.10 first grade ammonium chloride 0.2 urea granular first grade 4.98 monosubstituted sodium phosphate NaH ₂ PO ₄ × 2H ₂ O 0.02 magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ 0.27 sodium benzoate C ₆ H ₅ COONa 0.33 caprolactam C ₆ H ₁₁ NO 0.10

wherein the metal corrosion inhibitor is prepared as follows:

- each of the above corrosion inhibitor element is dissolved in distilled water so that the resulting aqueous solution contains one weight part of the corrosion inhibitor element and three weight parts of distilled water;

- further, the resulting aqueous solution of each element of the corrosion inhibitor is subjected to cavitation treatment in a reactor installation, while the reactor installation contains a solution tank with a thermometer and a heat exchanger, an electric gear pump, a cavitation reactor, and the tank is connected by a pipeline to the pump inlet and the pump outlet by a pipeline connected to the inlet of the cavitation reactor, the outlet of the cavitation reactor by a pipeline connected to the tank, moreover, at the entrance to the cavitation reactor and the exit from the cavitation Pressure gauges for determining the pressure drop across the cavitation reactor are located, and the cavitation reactor contains a channel for the movement of the aqueous solution, and the channel, in the direction of the movement of the aqueous solution, contains three constrictions, the area of the passage section of the channel at each constriction is 8% of the maximum area the passage section of the channel, and before each narrowing of the channel there is a height-adjustable rod, turbulent flow before the narrowing of the channel, behind each narrowing in the cavitation reactor vessel a channel for supplying carbon dioxide or nitrogen to the cavitation area of the reactor is laid;

- for cavitation treatment, the resulting aqueous solution of each element of the corrosion inhibitor is poured into the capacity of the reactor installation, heated to 60 ° C and pumped 170 to 720 times through the cavitation reactor by means of a gear pump;

- during cavitation processing, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the location of the rod;

- in addition, in the process of cavitation treatment through the channel located behind the first, in the direction of movement of the solution by constriction, carbon dioxide is supplied with a mass flow rate equal to 2% of the mass flow rate of the aqueous solution, through the channel located behind the second, in the direction of movement of the solution by constriction carbon dioxide is supplied with a mass flow rate equal to 1% of the mass flow rate of an aqueous solution, carbon dioxide with a mass flow rate equal to 0 is supplied through a channel located behind the third one in the direction of movement of the solution by narrowing 5% of the mass flow rate of an aqueous solution;

- by means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment is increased from 60 ° C to 75 ° C;

- during the cavitation treatment, the corrosion inhibitor element in solution is saturated with ¹³ C heavy carbon isotopes so that the ratio of ¹³ C carbon isotopes to the total carbon in the element is from 0.005 to 0.75;

- control the number of carbon isotopes ¹³ C is carried out by high resolution mass spectroscopy;

- further, the resulting aqueous solution of the above-mentioned element of the corrosion inhibitor is subjected to repeated cavitation treatment in a reactor installation, for which the aqueous solution located in the tank is heated to 80 ° C and pumped from a cavitation reactor 50 to 390 times through a gear pump;

- during cavitation processing, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the location of the rod;

- in addition, in the process of cavitation treatment, nitrogen gas with a mass flow rate equal to 1% of the mass flow rate of the aqueous solution is fed through the channel located behind the first, in the direction of the solution’s narrowing, through the channel located behind the second, in the direction of the solution’s narrowing nitrogen gas is supplied with a mass flow rate equal to 0.5% of the mass flow rate of the aqueous solution, nitrogen gas with a mass flow rate is fed through a channel located behind the third one in the direction of solution flow narrowing m, of 0.1% of the mass flow rate of the aqueous solution;

- by means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment is increased from 80 ° C to 85 ° C;

- during the cavitation treatment, the corrosion inhibitor element in solution is saturated with heavy nitrogen isotopes ¹⁵ N so that the ratio of the number of nitrogen isotopes ¹⁵ N to the total amount of nitrogen in the element is from 0.0001 to 0.1375;

- control the number of nitrogen isotopes ¹⁵ N carry out mass spectroscopy of high resolution;

- after repeated cavitation treatment of the solution, the corrosion inhibitor element is crystallized, for which 95.5% of water is evaporated from the aqueous solution;

- after cavitation treatment and crystallization of all the above elements of the corrosion inhibitor, they are mixed with the remaining components of the anti-icing material in the above percentage ratio;

- moreover, the cavitation treatment of the elements of the corrosion inhibitor is carried out in such a way that the percentage of carbon isotopes ¹³ C in each element of the corrosion inhibitor is the same and the percentage of nitrogen isotopes ¹⁵ N in each element of the corrosion inhibitor is the same.

Fourth Embodiment

The problem is solved due to the fact that the method for producing solid deicing material includes uniform mechanical mixing between each other of crystalline salt of food grade stone first grade, crystalline calcium chloride technical calcined first grade, crystalline elements of a metal corrosion inhibitor, crystalline surfactant "crystalline acidity regulator, and differs from the prototype in that 2-e is used as a surfactant sodium ilgeksiliminodipropionat as an acidity regulator using ammonium chloride technical first grade, as elements of an inhibitor of metal corrosion using urea granular first grade, simple superphosphate Ca (H ₂ PO _{4) 2,} dihydrogen magnesium Mg (H ₂ PO _{4) 2,} sodium benzoate C ₆ H ₅ COONa, caprolactam C ₆ H ₁₁ NO, in the following ratio, wt. % of the total number of components in the anti-icing material:

food grade table salt 51.0 calcium chloride technical calcined first grade 43.0 Sodium 2-ethylhexyliminodipropionate 0.10 first grade ammonium chloride 0.2 urea granular first grade 4.98 simple superphosphate Ca (H ₂ PO ₄ ) ₂ 0.02 magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ 0.27 sodium benzoate C ₆ H ₅ COONa 0.33 caprolactam C ₆ H ₁₁ NO 0.10

wherein the metal corrosion inhibitor is prepared as follows:

- each of the above corrosion inhibitor element is dissolved in distilled water so that the resulting aqueous solution contains one weight part of the corrosion inhibitor element and three weight parts of distilled water;

- further, the resulting aqueous solution of each element of the corrosion inhibitor is subjected to cavitation treatment in a reactor installation, while the reactor installation contains a solution tank with a thermometer and a heat exchanger, an electric gear pump, a cavitation reactor, and the tank is connected by a pipeline to the pump inlet, the pump outlet is connected by a pipeline with the inlet of the cavitation reactor, the outlet of the cavitation reactor is connected by a pipeline to the tank, moreover, at the entrance to the cavitation reactor and the exit from the cavitation Pressure gauges for determining the pressure drop across the cavitation reactor are located, and the cavitation reactor contains a channel for the movement of the aqueous solution, and the channel, in the direction of movement of the aqueous solution, contains three constrictions, the area of the passage section of the channel at the site of each restriction is 8% of the maximum passage area the cross-section of the channel, and before each narrowing of the channel there is a height-adjustable rod, turbulent flow before the narrowing of the channel, behind each narrowing in the body of the cavitation reactor is located a channel for supplying carbon dioxide or nitrogen to the cavitation area of the reactor is false;

- for cavitation treatment, the resulting aqueous solution of each element of the corrosion inhibitor is poured into the capacity of the reactor installation, heated to 60 ° C and pumped from 170 to 720 times through the cavitation reactor by means of a gear pump;

- during cavitation processing, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the location of the rod;

- in addition, in the process of cavitation treatment through the channel located behind the first, in the direction of movement of the solution by constriction, carbon dioxide is supplied with a mass flow rate equal to 2% of the mass flow rate of the aqueous solution, through the channel located behind the second, in the direction of movement of the solution by constriction carbon dioxide is supplied with a mass flow rate equal to 1% of the mass flow rate of an aqueous solution, carbon dioxide with a mass flow rate equal to 0 is supplied through a channel located behind the third one in the direction of movement of the solution by narrowing 5% of the mass flow rate of an aqueous solution;

- by means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment is increased from 60 ° C to 75 ° C;

- during the cavitation treatment, the corrosion inhibitor element in solution is saturated with ¹³ C heavy carbon isotopes so that the ratio of ¹³ C carbon isotopes to the total carbon in the element is from 0.005 to 0.75;

- control the number of carbon isotopes ¹³ C is carried out by high resolution mass spectroscopy;

- further, the obtained aqueous solution of the aforementioned element of the corrosion inhibitor is subjected to repeated cavitation treatment in a reactor installation, for which the aqueous solution located in the tank is heated to 80 ° C and pumped from a cavitation reactor 50 to 390 times through a gear pump;

- during cavitation processing, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the location of the rod;

- in addition, in the process of cavitation treatment, nitrogen gas with a mass flow rate equal to 1% of the mass flow rate of the aqueous solution is fed through the channel located behind the first, in the direction of the solution’s narrowing, through the channel located behind the second, in the direction of the solution’s narrowing nitrogen gas is supplied with a mass flow rate equal to 0.5% of the mass flow rate of the aqueous solution, nitrogen gas with a mass flow rate is fed through a channel located behind the third one in the direction of solution flow narrowing m, of 0.1% of the mass flow rate of the aqueous solution;

- by means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment is increased from 80 ° C to 85 ° C;

- during the cavitation treatment, the corrosion inhibitor element in solution is saturated with heavy nitrogen isotopes ¹⁵ N so that the ratio of the number of nitrogen isotopes ¹⁵ N to the total amount of nitrogen in the element is from 0.0001 to 0.1375;

- control the number of nitrogen isotopes ¹⁵ N carry out mass spectroscopy of high resolution;

- after repeated cavitation treatment of the solution, the element of the corrosion inhibitor is crystallized, for which 95.5% of water is evaporated from the aqueous solution;

- after cavitation treatment and crystallization of all the above elements of the corrosion inhibitor, they are mixed with the remaining components of the anti-icing material in the above percentage ratio;

- moreover, the cavitation treatment of the elements of the corrosion inhibitor is carried out in such a way that the percentage of carbon isotopes ¹³ C in each element of the corrosion inhibitor is the same and the percentage of nitrogen isotopes ¹⁵ N in each element of the corrosion inhibitor is the same.

Fifth embodiment of the invention.

The problem is solved due to the fact that the method for producing solid deicing material includes uniform mechanical mixing between each other of crystalline salt of food grade stone first grade, crystalline calcium chloride technical calcined first grade, crystalline elements of a metal corrosion inhibitor, crystalline surfactant, crystalline acidity regulator, and differs from the prototype in that 2-et is used as a surfactant sodium ilhexyl iminodipropionate, technical grade ammonium chloride is used as an acidity regulator, first-grade technical ammonium chloride is used as corrosion inhibitor granular grade carbamide, calcium nitrate Ca (NO ₃ ) ₂ , magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ , sodium benzoate C ₆ H ₅ COONa, caprolactam C ₆ H ₁₁ NO, in the following ratio, wt. % of the total number of components in the anti-icing material:

food grade table salt 51.0 calcium chloride technical calcined first grade 43.0 Sodium 2-ethylhexyliminodipropionate 0.10 first grade ammonium chloride 0.2 urea granular first grade 4.98 calcium nitrate Ca (NO ₃ ) ₂ 0.02 magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ 0.27 sodium benzoate C ₆ H ₅ COONa 0.33 caprolactam C ₆ H ₁₁ NO 0.10

wherein the metal corrosion inhibitor is prepared as follows:

- each of the above corrosion inhibitor element is dissolved in distilled water so that the resulting aqueous solution contains one weight part of the corrosion inhibitor element and three weight parts of distilled water;

- further, the resulting aqueous solution of each element of the corrosion inhibitor is subjected to cavitation treatment in a reactor installation, while the reactor installation contains a solution tank with a thermometer and a heat exchanger, an electric gear pump, a cavitation reactor, and the tank is connected by a pipe to the pump inlet, the pump outlet is connected by a pipeline with the inlet of the cavitation reactor, the outlet of the cavitation reactor is connected by a pipeline to the tank, and at the entrance to the cavitation reactor and exit from the cavitation pressure gauges are located on the reactor to determine the pressure drop across the cavitation reactor, and the cavitation reactor contains a channel for the movement of the aqueous solution, and the channel, in the direction of the movement of the aqueous solution, contains three constrictions, the passage area of the channel at the site of each constriction is 8% of the maximum area the passage section of the channel, and before each narrowing of the channel, a height-adjustable rod is located, turbulent flow before the narrowing of the channel, behind each narrowing in the cavitation reactor vessel, a channel for supplying carbon dioxide or nitrogen to the cavitation area of the reactor is false;

- for cavitation treatment, the resulting aqueous solution of each element of the corrosion inhibitor is poured into the capacity of the reactor installation, heated to 60 ° C and pumped from 170 to 720 times through the cavitation reactor by means of a gear pump;

- during cavitation processing, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the location of the rod;

- in addition, in the process of cavitation treatment through the channel located behind the first, in the direction of movement of the solution by constriction, carbon dioxide is supplied with a mass flow rate equal to 2% of the mass flow rate of the aqueous solution, through the channel located behind the second, in the direction of movement of the solution by constriction carbon dioxide is supplied with a mass flow rate equal to 1% of the mass flow rate of an aqueous solution, carbon dioxide with a mass flow rate equal to 0 is supplied through a channel located behind the third one in the direction of movement of the solution by narrowing 5% of the mass flow rate of an aqueous solution;

- by means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment is increased from 60 ° C to 75 ° C;

- during the cavitation treatment, the corrosion inhibitor element in solution is saturated with ¹³ C heavy carbon isotopes so that the ratio of ¹³ C carbon isotopes to the total carbon in the element is from 0.005 to 0.75;

- control the number of carbon isotopes ¹³ C is carried out by high resolution mass spectroscopy;

- further, the obtained aqueous solution of the aforementioned element of the corrosion inhibitor is subjected to repeated cavitation treatment in a reactor installation, for which the aqueous solution located in the tank is heated to 80 ° C and pumped from a cavitation reactor 50 to 390 times through a gear pump;

- during cavitation processing, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the location of the rod;

- in addition, in the process of cavitation treatment, nitrogen gas with a mass flow rate equal to 1% of the mass flow rate of the aqueous solution is fed through the channel located behind the first, in the direction of the solution’s narrowing, through the channel located behind the second, in the direction of the solution’s narrowing nitrogen gas is supplied with a mass flow rate equal to 0.5% of the mass flow rate of the aqueous solution, nitrogen gas with a mass flow rate is fed through a channel located behind the third one in the direction of solution flow narrowing m, of 0.1% of the mass flow rate of the aqueous solution;

- by means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment is increased from 80 ° C to 85 ° C;

- during the cavitation treatment, the corrosion inhibitor element in solution is saturated with heavy nitrogen isotopes ¹⁵ N so that the ratio of the number of nitrogen isotopes ¹⁵ N to the total amount of nitrogen in the element is from 0.0001 to 0.1375;

- control the number of nitrogen isotopes ¹⁵ N carry out mass spectroscopy of high resolution;

- after repeated cavitation treatment of the solution, the element of the corrosion inhibitor is crystallized, for which 95.5% of water is evaporated from the aqueous solution;

- after cavitation treatment and crystallization of all the above elements of the corrosion inhibitor, they are mixed with the remaining components of the anti-icing material in the above percentage ratio;

- moreover, the cavitation treatment of the elements of the corrosion inhibitor is carried out in such a way that the percentage of carbon isotopes ¹³ C in each element of the corrosion inhibitor is the same and the percentage of nitrogen isotopes ¹⁵ N in each element of the corrosion inhibitor is the same.

Each of the above-described variants of the invention is aimed at achieving a technical result consisting in increasing the effectiveness of a corrosion inhibitor in the composition of the obtained anti-icing material by effectively enriching the corrosion inhibitor with heavy carbon isotopes ¹³ C and nitrogen ¹⁵ N in a reactor installation with a cavitation reactor, without compromising the anti-icing properties of PGM.

It was experimentally proved that with the increase in the content of heavy carbon isotopes ¹³ C and nitrogen ¹⁵ N in the IR, which is part of the PHM, the corrosivity of the PHM significantly decreases. At the same time, the capabilities of the Mining and Smelting Complex to eliminate snow and ice formations are not decreasing. In addition, the effect of the reagent on plant life did not increase.

The achievement of the technical result will be described in detail in the section "Implementation of the invention".

It should be noted that the inclusion of stable heavy isotope atoms ( ³ H, ¹⁴ C, ¹³ C, ¹⁵ N, ¹⁸ O) in the molecules of various hydrocarbon substances is known from the prior art. In particular, in medical practice, rare stable heavy isotopes ³ C, ¹⁴ C, ¹³ C are used in medical diagnostics.

The EAPO patents described in Sources 11-18 present the results of studies on the effect of carbon isotopes ¹³ C and nitrogen ¹⁵ N on the effectiveness of dosage forms. In the process of experimental verification of dosage forms enriched with heavy isotopes of carbon ¹³ C and nitrogen ¹⁵ N, it was found that these dosage forms have increased therapeutic efficacy and stability, compared with dosage forms in which there are no carbon isotopes of ¹³ C.

Currently, methods for producing ¹³ C carbon isotopes by gas diffusion through porous walls, diffusion in a steam stream, thermal diffusion, as well as by distillation, isotope exchange, centrifugation, electrolysis, genetic engineering, and others are well developed. A brief description of these methods is given in / 19/.

At the Moscow State Academy of Fine Chemical Technology. M.V. Lomonosov’s work out modern nanotechnologies for the production and incorporation of atoms of stable ¹³ C carbon isotopes into molecules of various structures. At the academy, molecules of isotopically labeled compounds with various levels of isotope enrichment are obtained - from fractions of a percent to one hundred percent of isotopes in a substance. The work is in the interests of medical diagnosis.

The source / 20 / provides links (a total of 165 links) to foreign sources of information on the isotopic enrichment of various substances, as well as modern methods for incorporating stable isotope atoms into molecules of various substances (hydrocarbons).

The author of the present invention conducts his own research on the isotopic enrichment of hydrocarbons, namely, IR elements. The elements were enriched with IR isotopes of carbon ¹³ C (substitution of carbon isotopes ¹³ C for carbon isotopes ¹³ C) and nitrogen ¹⁵ N (substitution of nitrogen isotopes ¹⁴ N for nitrogen isotopes ¹⁵ N) was carried out in a cavitation reactor. The principle of operation of the reactor is similar to the principles of operation of cavitation reactors designed by Professor V. Kormilitsyn. (Moscow Energy Institute - Technical University).

A brief description of the drawings.

In FIG. 1 is a diagram of a reactor installation containing a solution tank, a gear pump, a cavitation reactor, as well as manometers and cranes.

In FIG. 2 shows a longitudinal section of the channel of a cavitation reactor with three constrictions, three height-adjustable rods, three channels for supplying carbon dioxide or nitrogen to the cavitation region of the reactor.

In FIG. 3 shows a flow diagram in the channel of a cavitation reactor. The diagram shows three cavitation areas located in areas of narrowing.

In FIG. Figure 4 shows a photograph of a laboratory reactor installation, on which experimental studies were carried out. The photo gives an idea of the layout and size of the installation.

The implementation of the invention.

In each embodiment of the invention, a method for producing solid PGM is contemplated. Solid PGM based on calcium and sodium chlorides have a high melting ability than liquid, due to the released heat of hydration of the salt, which is exhausted in liquid compositions during their manufacture (dissolution in water). The temperature of the solutions when mixing PGM with ice at negative temperatures is higher on solid materials than when using aqueous solutions having an ambient temperature.

The thermal effect due to the dissolution of calcium chloride (included in the PGM) is about - 21.75 kcal / mol, that is, it comes with the release of heat. The heat of dissolution of sodium chloride (included in PGM) has a positive value of +1.02 kcal / mol and, therefore, will come with a small heat consumption.

The freezing temperature of a 20% aqueous solution of CaCl ₂ -18 ° C,

freezing temperature of a 29.87% aqueous solution of CaCl ₂ -55 ° C,

freezing temperature of a 30% aqueous solution of CaCl ₂ -46 ° C

(http://www.angara.com.ua/22_teplonositeli.html).

The freezing temperature of a 20% aqueous solution of NaCl -16.8 ° C,

the freezing temperature of a 23% aqueous solution of NaCl -21.1 ° C,

freezing temperature of 25% aqueous NaCl -8.8 ° C

(http://www.angara.com.ua/22_teplonositeli.html).

With the combined use of NaCl and CaCl _{2, the} minimum freezing point is reached at 54.3% NaCl and 45.7% CaCl ₂ . In PGM obtained by the claimed methods, chlorides make up 94%, the remaining 6% - surfactants, IR and acidity regulator. Therefore, PGM obtained by the claimed methods 51% NaCl and 43% CaCl ₂ and 6% surfactant, IR and acidity regulator. For each PGM claimed in the invention, the freezing temperature of a 20% aqueous solution is 32 ° C. At the same time, the time of action of PGM on the road surface is 8-10 hours.

When implementing the methods claimed in the invention, deicing materials with reduced corrosion activity are obtained.

Embodiments of the invention differ among themselves in the composition of the corrosion inhibitor (elements of the corrosion inhibitor).

A method of producing a solid anti-icing material according to any one of the variants of the invention includes uniform mechanical mixing between each other of the crystalline salt of food grade stone first grade, crystalline calcium chloride technical calcined first grade, crystalline elements of a metal corrosion inhibitor, crystalline surfactant, crystalline acidity regulator.

Sodium 2-ethylhexyliminodipropionate is used as a surfactant. Its characteristics are presented in the source / 8 /. Ammonium chloride of the first grade is used as an acidity regulator. Its characteristics are presented in the source / 9 /.

In the first embodiment, as a corrosion inhibitor elements metals are granulated carbamide first grade, 2-phosphonobutane-1,2,4-tricarboxylic acid tetrasodium salt, monomagnesium phosphate Mg (H ₂ PO _{4) 2,} sodium benzoate, C ₆ H ₅ COONa, caprolactam C ₆ H ₁₁ NO.

In the second embodiment of the invention, granular carbamide of the first grade, urotropin, magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ , sodium benzoate C ₆ H ₅ COONa, caprolactam C ₆ H ₁₁ NO are used as elements of a metal corrosion inhibitor.

In a third embodiment of the invention, granular carbamide of the first grade, monosubstituted sodium phosphate NaH ₂ PO ₄ × 2H ₂ O, magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ , sodium benzoate C ₆ H ₅ COONa, caprolactam C ₆ are used as elements of a metal corrosion inhibitor H ₁₁ NO.

In a fourth embodiment of the invention, granular carbamide of the first grade, simple superphosphate Ca (H ₂ PO ₄ ) ₂ , magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ , sodium benzoate C ₆ H ₅ COONa, caprolactam C ₆ H are used as elements of a metal corrosion inhibitor ₁₁ NO.

In a fifth embodiment of the invention, granular carbamide of the first grade, calcium nitrate Ca (NO ₃ ) ₂ , magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ , sodium benzoate C ₆ H ₅ COONa, caprolactam C ₆ H ₁₁ NO are used as elements of a metal corrosion inhibitor .

The ratio of the components of PGM is given in the section "Disclosure of the invention."

The above elements of the corrosion inhibitor are selected because when saturated with ¹³ C and ¹⁵ N isotopes, they significantly increase their effectiveness.

It should be noted that during the research, a number of elements of the corrosion inhibitor were revealed, which even with the maximum saturation with ¹³ C and ¹⁵ N isotopes, they do not change their properties.

Before mixing the PGM components, a metal corrosion inhibitor is obtained.

A metal corrosion inhibitor is prepared as follows. Each of the above corrosion inhibitor elements is dissolved in distilled water so that the resulting aqueous solution contains one weight part of the corrosion inhibitor element and three weight parts of distilled water. Mixing is carried out at a positive temperature. Next, the resulting aqueous solution is subjected to cavitation treatment in a reactor installation.

The reactor facility used for the experiments was made using the materials given in the sources / 10-18 /.

Structurally, the reactor installation contains a tank 1 for the solution (see Fig. 1), a gear pump 5 with an electric drive (not shown in the figure), a cavitation reactor 8. In the reactor installation, the tank 1 is connected by a pipeline to the inlet to the pump 5, the outlet of the pump 5 is connected by a pipeline with the inlet of the cavitation reactor 8, the outlet of the cavitation reactor 8 is connected by a pipe 20 to the tank 1. At the inlet of the cavitation reactor 8 and the outlet of the cavitation reactor, manometers 9 and 6 are located to determine the pressure drop across the cavitation reactor. For technological needs, bypassing the cavitation reactor, a line 10 with a crane 7 is located. This line serves to bypass at least part of the solution bypassing the cavitation reactor when it is started and the regulations. A thermometer 2 and a heat exchanger 4 are located in the tank 1 for heating or cooling the solution 3. The device 4 comprises a heat exchanger located in the tank 1. If necessary, hot or cold water is passed through the heat exchanger, respectively, for heating or cooling the solution.

The cavitation reactor 8 is made as shown in figure 2, and contains a channel 23 for the movement of an aqueous solution. This channel, in the direction of movement of the aqueous solution (left to right in the figure), contains three constrictions 24, 25 and 26, before each narrowing of the channel there is a height-adjustable rod 27, 28 and 29. The rods turbulent the flow moving along channel 23. Turbulization necessary to establish a cavitation mode at the lowest possible flow rates. If there were no rods, then the speed at which cavitation is established would increase by 15-17%.

As mentioned above, a height-adjustable rod is located before each narrowing of the channel. It is advisable that the rod 27 in front of the first, in the direction of movement of the solution constriction 24, is located at a distance equal to 2.1 diameters of the passage section in the place of restriction 24, the rod 28 in front of the second, in the direction of movement of the solution constriction 25, is located at a distance equal to 1.4 diameters of the passage section in place narrowing 25, the rod 29 before the third, in the direction of movement of the solution by narrowing 26, is located at a distance equal to 1.4 diameters of the bore at the point of narrowing 26.

Behind each narrowing in the cavitation reactor vessel there is a channel for supplying carbon dioxide or nitrogen to the cavitation region of the reactor. So, channel 30 is located behind narrowing 24, channel 31 is located behind narrowing 25, channel 32 is located behind narrowing 26.

In the course of testing the designs of the reactor installation and the cavitation reactor, and conducting experiments, recommendations were developed on the structural implementation of the elements of the installation and the cavitation reactor. So, the area of the passage section of the channel at the narrowing point is 8% of the maximum passage area of the channel. The maximum area of the passage section of the channel is equal to the area of the passage section of the pipeline located between the output of the gear pump and the inlet of the cavitation reactor. It is advisable that the area of the flow cross-sections of all pipelines and line 10 were the same. The shapes of the flow sections of the pipelines and the cavitation reactor can be any, it is convenient to carry them round. Although we conducted tests of cavitation reactors with rectangular shapes of passage sections of the channel, with oval shapes of passage sections, etc.

Each narrowing of the channel is made in the form of a nozzle (see Fig. 2) and has:

- the tapering part of the nozzle (in the direction of flow) is the part of the nozzle in front of the minimum flow area;

- minimum bore - section with a minimum bore;

- the expanding part of the nozzle is the part of the nozzle located behind the minimum flow area.

In the reactor installation used for the experiments, the shapes of the flow sections along the channel length of the cavitation reactor are made round, so the inner surfaces of the tapering and expanding parts are made in the form of a side surface of a truncated cone.

In the initial state, all valves 7, 48, 14, 49, 15, 50, 16 (see Fig. 1) of the reactor installation are closed.

For cavitation treatment, the resulting aqueous solution of the element of the corrosion inhibitor is poured into the tank 1 of the reactor installation. After which the solution 3, located in the tank 1, by means of the heat exchanger 4 is heated to 60 ° C. Then the solution 3 through the gear pump 5 is pumped from 170 to 720 times through the cavitation reactor. After the start of pumping, taps 14, 15 and 16 are opened. Carbon dioxide is supplied from the cylinders 17, 18 and 19 to the cavitation reactor. The gas supply is controlled on the basis of the readings of pressure gauges 9, 6, 11, 12 and 13 and is regulated using taps 14, 15 and 16.

The number of pumpings of solution 3 through a cavitation reactor 8 depends on the required content of heavy ¹³ C isotopes in the corrosion inhibitor element. Table 1.1 presents the dependence of the content of heavy carbon isotopes ¹³ C in the element of the corrosion inhibitor on the number of pumpings "n" of the aqueous solution of the element of the corrosion inhibitor through the cavitation reactor by means of a gear pump. The table shows that the more ¹³ C isotopes are required in the corrosion inhibitor element, the more times it is necessary to pump the solution through a cavitation reactor.

During cavitation processing, the height of each of the adjustable rods 27, 28 and 29 is set so that the rod covers 4-5% of the cross-sectional area of the channel at the location of the rod. During the operation of the installation, the rods interact with the flow, turbulence it, thereby ensuring the establishment of a cavitation mode at a minimum flow velocity in sections 14, 25 and 26.

In the process of cavitation treatment through the channel 30, located behind the first, by the movement of the solution by constriction, carbon dioxide is supplied from the cylinder 17 with the tap 14 open with a mass flow rate equal to 2% of the mass flow rate of the aqueous solution.

Through the channel 31, located behind the second, by the movement of the solution by constriction, carbon dioxide is supplied from the cylinder 18 with the open valve 15 with a mass flow rate equal to 1% of the mass flow rate of the aqueous solution.

Through the channel 32, located behind the third, by the movement of the solution by constriction, carbon dioxide is supplied from the cylinder 19 with the open valve 16 with a mass flow rate equal to 0.5% of the mass flow rate of the aqueous solution.

By means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment by means of the heat exchanger 4 is increased from 60 ° C to 75 ° C. Hot water is supplied through a heat exchanger, the temperature of which is controlled by thermometer 2.

In FIG. 3 shows a longitudinal section of a cavitation reactor 8. The direction of flow (movement of the solution) is indicated by arrow 33. Arrows 34, 35, 36, 37 show the movement of the stream along the channel of the cavitation reactor and behind the rods 27, 28, 29. The stream moving through the channel enters first narrowing. The cross-sectional area decreases, the flow rate increases. In the region of the minimum flow cross section 24, the flow rate increases so that the pressure in the flow becomes less than the saturated vapor pressure. The stream "boils" in this place - steam bubbles 38 are formed. Then the stream (liquid and steam bubbles) moving along the channel enters the expanding part, where the passage section of the channel increases and the speed decreases. The pressure in the stream becomes greater than the pressure of saturated steam, the vapor bubbles collapse. The collapse points of steam bubbles are shown at 39. Moreover, in the collapse region (in the region of the collapse point) of the cavitation bubble, an increase in pressure to several thousand atmospheres and an increase in temperature to a thousand or more degrees Celsius are observed.

The area in which the bubbles form and cools is called the cavitation area. As mentioned above, the rod 27 turbulizes the flow, and thereby facilitates the establishment of the cavitation flow regime at the lowest possible flow velocity.

In the same way, bubbles 40 arise and slam 41 in the region of the passage section 25, and bubbles 42 are formed and collapse 43 in the region of the passage section 26.

Carbon dioxide is supplied through channels 30, 31 and 32 in the flow region behind the minimum flow sections 24, 25 and 26, saturated with steam bubbles. When steam bubbles collapse, a powerful dynamic effect on the environment surrounding the bubbles occurs. It is at the point of collapse that the element of the corrosion inhibitor is enriched with heavy carbon isotopes.

In figure 3, arrows 44 show the direction of gas movement through channels 30, 31 and 32.

During cavitation treatment, the corrosion inhibitor element in solution is saturated with ¹³ C heavy carbon isotopes so that the ratio of ¹³ C carbon isotopes to the total carbon in the element is between 0.005 and 0.75. The amount of ¹³ C carbon isotopes is controlled by high resolution mass spectroscopy. Samples for this are taken from tank 1. Gas entering the tank is removed from the tank through the neck 21. Removal of gas from the tank is shown by arrow 22.

Then close the taps 14, 15 and 16. The pump installation is turned off.

After that, the resulting aqueous solution of the above-mentioned element of the corrosion inhibitor is subjected to repeated cavitation treatment in the reactor installation, for which the aqueous solution located in the tank is heated by means of a heat exchanger to 80 ° C. The pump installation is turned on, valves 48, 49 and 50 are opened and the solution is pumped 50 to 390 times through a cavitation reactor 8 through a gear pump.

The number of pumpings of solution 3 through a cavitation reactor 8 depends on the required content of heavy isotopes ¹⁵ N in the element of the corrosion inhibitor.

Table 1.2 shows the dependence of the content of heavy nitrogen isotopes ¹⁵ N in the element of the corrosion inhibitor on the number of pumpings "n" of the aqueous solution of the element of the corrosion inhibitor through the cavitation reactor by means of a gear pump.

The table shows that the more ¹⁵ N isotopes are required in the corrosion inhibitor element, the more times it is necessary to pump the solution through a cavitation reactor.

In the process of repeated cavitation treatment, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the installation site of the rod. In the particular case, the adjustment of the rods is left the same.

In the process of cavitation processing through the channel 30, located behind the first, by the movement of the solution by constriction, nitrogen gas is supplied from the cylinder 45 with the tap 48 open with a mass flow rate equal to 1% of the mass flow rate of the aqueous solution.

Through the channel 31, located behind the second, by the movement of the solution by constriction, gaseous nitrogen is supplied from the cylinder 46 with the open valve 49 with a mass flow rate equal to 0.5% of the mass flow rate of the aqueous solution.

Through the channel 32, located behind the third, by the movement of the solution by constriction, gaseous nitrogen is supplied from the cylinder 47 with the open valve 50 with a mass flow rate equal to 0.1% of the mass flow rate of the aqueous solution.

The gas supply is controlled based on the readings of pressure gauges 9, 6, 11, 12 and 13.

By means of gear pump 5, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of solution 3 in the tank 1 during the cavitation treatment by means of the heat exchanger 4 is increased from 80 ° C to 85 ° C.

As indicated previously, in FIG. 3 shows a longitudinal section of a cavitation reactor 8. The direction of flow (solution movement) is shown by arrow 33. Arrows 34, 35, 36, 37 show the movement of the stream along the reactor channel and behind the rods 27, 28, 29. The stream moving along the channel enters the first narrowing . The cross-sectional area decreases, the flow rate increases. In the region of the minimum flow cross section 24, the flow rate increases so that the pressure in the flow becomes less than the saturated vapor pressure. The flow in this place “boils” - steam bubbles 38 are formed. Further, the flow (liquid and steam bubbles) moving along the channel enters the expanding part, where the passage section of the channel increases and the speed decreases. The pressure in the stream becomes greater than the pressure of saturated steam, the vapor bubbles collapse 39. At the same time, in the area (in place) of the collapse of the cavitation bubble, an increase in pressure to several thousand atmospheres and an increase in temperature to a thousand or more degrees Celsius are observed.

The area in which the bubbles form and cools is called the area of cavitation. As mentioned above, the rod 27 turbulizes the flow, and thereby facilitates the establishment of the cavitation flow regime at the lowest possible flow velocity.

In the same way, bubbles 40 arise and slam 41 in the region of the passage section 25, and bubbles 42 are formed and collapse 43 in the region of the passage section 26.

Nitrogen gas is supplied through channels 30, 31, and 32 in the flow region saturated with vapor bubbles, for minimum passage sections 24, 25, and 26. When the vapor bubbles collapse, a powerful dynamic effect on the environment surrounding the bubbles occurs. It is at the point of collapse that the element of the corrosion inhibitor is enriched with heavy nitrogen isotopes.

During the cavitation treatment, the corrosion inhibitor element in solution is saturated with heavy nitrogen isotopes ¹⁵ N so that the ratio of the number of nitrogen isotopes ¹⁵ N to the total amount of nitrogen in the element is from 0.0001 to 0.1375. Control of the amount of nitrogen isotopes ¹⁵ N perform mass spectroscopy High resolution. Samples for this are taken from tank 1. Gas entering the tank is removed from the tank through the neck 21. Removal of gas from the tank is shown by arrow 22.

Next, the valves 48, 49 and 50 are closed. The installation is turned off.

After repeated cavitation treatment of the solution, crystallization of this element of the corrosion inhibitor is carried out, for which the solution is poured from the tank 1 into a device for evaporating water. 95.5% of water is evaporated from the aqueous solution. Crystallization is carried out by evaporation.

After cavitation treatment and crystallization of all the above elements of the corrosion inhibitor, they are mixed with the remaining components of the anti-icing material in the percentage indicated in the section “Disclosure of the invention”.

The cavitation treatment of the elements of the corrosion inhibitor is carried out in such a way that the percentage of carbon isotopes ¹³ C in each element of the corrosion inhibitor is the same and the percentage of nitrogen isotopes ¹⁵ N in each element of the corrosion inhibitor is the same.

The processes of cavitation treatment and crystallization of the elements of the corrosion inhibitor, as well as mixing the crystalline components of the PGM for all variants of the invention are identical.

Crane 7 and highway 10 are used for technological purposes. The reactor installation is flushed with water with open valve 7, and closed valves 48, 14, 49, 15, 50 and 16. Line 10 with open valve 7 can be used to mix the corrosion inhibitor element with water.

The appearance of the reactor installation is shown in the photograph (see Fig. 4).

An example of calculating the cavitation treatment time is given below.

During cavitation treatment, the solution is pumped n times through a cavitation reactor by means of a gear pump, while the operating time t of the reactor installation is determined by the formula:

t = nV / Q,

where n is the number of pumpings of an aqueous solution through a cavitation reactor by means of a gear pump;

V is the volume occupied by the solution in the tank;

Q is the volumetric flow rate of the gear pump.

In the experimental reactor installation, a gear pump NMSh 5-25-4.0 / 10 was used. At a pump with a gear speed of 1450 rpm, the flow rate Q = 4 m ³ / h. The pressure is provided equal to 10 · 10 ⁵ Pa, and the power consumption is 1.8 kW. The pump is driven by an asynchronous electric motor AIR100S4UZ. The volume of the tank is 0.01 m ³ , the volume occupied by the solution is 0.008 m ³ .

We give an example of calculating the operating time of a reactor installation.

170 pumping a solution through a cavitation reactor will require 0.34 hours (or 1224 seconds).

Another example, 400 pumping a solution through a cavitation reactor will require 0.8 hours (or 2880 seconds).

And 1110 pumping (this is the maximum number of pumping provided for the implementation of the invention) through a cavitation reactor will require 2.22 hours (or 7992 seconds).

In the sources / 11-18 / a reactor installation for the isotope enrichment of drugs is described. At the beginning of the experimental work, this setup was used for cavitation treatment of corrosion inhibitor elements. However, the large energy and time costs involved in the processing of solutions required the development and manufacture of a new reactor installation (see Fig. 1-4).

The old reactor installation / 11-18 / has a power consumption of 75 kW; it uses a 6NK-6X1 centrifugal pump with a flow rate of 90 m ³ / h and a feed of 125 m, as well as an 18 liter solution tank (of which 16 liters are for solution )

The new reactor installation used to implement all variants of the invention has a power consumption of 1.8 kW. A NMSh 5-25-4.0 / 10 gear pump was used in the installation, with a flow rate of 4 m ³ / h, a feed of 100 m, a capacity for a solution of 10 liters (of which 8 liters for a solution).

In the new installation, compared with the old installation described in the sources / 10-18 /, the power consumption of the pump is reduced by more than 40 times, the flow rate is reduced by 22 times.

When working on an old installation, the corrosion inhibitor element was saturated with ¹³ C isotopes to a content of 75% for several days (up to 65 hours). For working with medicines, such costs are acceptable, but for working with PGM, the costs are excessive. Therefore, a new reactor installation was developed and experimentally tested.

When working on a new installation, the saturation of the corrosion inhibitor element with ¹³ C isotopes to a content of 75% and ¹⁵ N isotopes to 13.75% was carried out for 2.22 hours (with a solution volume of 8 liters). Another 8 liters was also processed for 2.22 hours. Thus, in a new installation for processing 16 liters of solution, 4.44 hours will be required (with a power consumption of 1.8 kW). In this case, 8 kW · hour of electricity will be consumed.

On an old installation, the processing time of 16 liters was 65 hours with a power consumption of 75 kW. Energy costs will amount to 4800 kW · hour of electricity.

Energy saving - up to 600 times, time saving - up to 14 times. This is a significant saving in energy and uptime.

It is the claimed design of the reactor installation and the cavitation reactor that provides effective enrichment of the corrosion inhibitor with heavy isotopes of carbon ¹³ C and nitrogen ¹⁵ N. At present, there is no more efficient installation for these purposes.

As mentioned above, each of the above-described variants of the invention is aimed at achieving a technical result consisting in increasing the efficiency of a corrosion inhibitor in the composition of the obtained solid anti-icing material by enriching the corrosion inhibitor with heavy isotopes of carbon ¹³ C and nitrogen ¹⁵ N in a cavitation reactor of a new design.

When developing an application for an invention, it was experimentally proved that to increase the effectiveness of a corrosion inhibitor in the composition of the obtained solid deicing material, it is required that the ratio of the number of carbon isotopes ¹³ C to the total amount of carbon in the element of the corrosion inhibitor be from 0.005 to 0.75 (from 0.5% to 75%), as well as the ratio of the amount of nitrogen isotopes ¹⁵ N to the total amount of nitrogen in the element of the corrosion inhibitor, ranged from 0.0001 to 0.1375 (from 0.01% to 13.75%).

It was proved that a lower content of carbon isotopes ¹³ C and nitrogen isotopes ¹⁵ N (below the left border of the range) does not lead to the achievement of a technical result. A higher content of the above isotopes (above the right border of the range) does not lead to an increase in efficiency, but leads only to an increase in the cost of the corrosion inhibitor and, in general, PGM.

Experimental studies of the corrosive activity of PGM were carried out in 3 stages.

Stage 1. Conducting studies with PGM obtained by methods 1-5 (see the claims), without saturation of corrosion inhibitors with heavy isotopes ¹³ C and ¹⁵ N.

2 stage. Conducting studies with PGM obtained by methods 1-5 (see the claims), with saturation of corrosion inhibitors only with heavy isotopes ¹³ C or only heavy isotopes ¹⁵ N.

3 stage. Conducting studies with PGM obtained by methods 1-5 (see the claims), with saturation of corrosion inhibitors with heavy isotopes ¹³ C and ¹⁵ N.

Stage 1.

Conducting research with PGM obtained by the methods

1-5 (see paragraphs 1-5 of the claims), without saturation of corrosion inhibitors with heavy isotopes ¹³ C and ¹⁵ N.

PGM was prepared by the methods described in paragraphs 1-5 of the claims, but without saturation of the corrosion inhibitors with heavy isotopes ¹³ C and ¹⁵ N. The components of PGM were only mechanically mixed.

Tables 2-4 present experimental data on the corrosion activity of St3ps steel on solutions of anti-icing materials ( ¹³ C and ¹⁵ N isotopes are absent). These solutions in the tables are called basic anti-icing materials. In table 2, a 5% solution of basic PGM is considered, in table 3, a 10% solution of PGM is considered, in table 4, a 20% solution of PGM is considered.

In tables 2-4 in the left column (in the first column) are the serial numbers of deicing materials. Number 1 corresponds to PGM obtained by the method described in paragraph 1 of the claims (without saturation of corrosion inhibitors with heavy isotopes ¹³ C and ¹⁵ N). Number 2 corresponds to PGM obtained by the method described in paragraph 2 of the claims (without saturation of corrosion inhibitors with heavy isotopes ¹³ C and ¹⁵ N). Number 3 corresponds to PGM obtained by the method described in paragraph 3 of the claims (without saturation of corrosion inhibitors with heavy isotopes ¹³ C and ¹⁵ N). Number 4 corresponds to PGM obtained by the method described in paragraph 4 of the claims (without saturation of corrosion inhibitors with heavy isotopes ¹³ C and ¹⁵ N). Number 5 corresponds to PGM obtained by the method described in paragraph 5 of the claims (without saturation of corrosion inhibitors with heavy isotopes ¹³ C and ¹⁵ N).

The St3ps steel used in the experiments (GOST 14637) contained: carbon - 0.20%, silicon - 0.08%, manganese - 0.45%, nickel, copper, chromium - up to 0.3%, arsenic up to 0.05% sulfur to 0.05, phosphorus to 0.04%, respectively. From sheet steel 4 mm thick, plates 20 × 30 mm in size were cut. Experimental studies of PGM with corrosion inhibitors were carried out according to GOST 9.514-99. The corrosion rate was determined by the polarization resistance device P5126. In the device, the measured value of the polarization resistance was automatically converted to the corrosion rate in mm / year.

Analysis of tables 2, 3 and 4 shows that the corrosion rate decreases with decreasing solution temperature.

A comparative analysis of tables 2, 3 and 4 also shows that with an increase in the PGM content in the solution, the corrosion rate increases.

2 stage. Conducting studies with PGM obtained by methods 1-5 (see paragraphs 1-5 of the claims), with saturation of corrosion inhibitors only with heavy isotopes ¹³ C.

PGM was prepared by the methods described in paragraphs 1-5 of the claims, but without saturation of corrosion inhibitors with heavy isotopes of ¹⁵ N. In each method, corrosion inhibitors were saturated only with heavy isotopes of ¹³ C.

Table 6 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. The composition of PGM includes a corrosion inhibitor containing from 0.4% to 80% of carbon isotopes ¹³ C.

The temperature of anti-icing materials is -5 ° C. A 5% PGM solution in distilled water was used in the experiments.

The table shows that when the content of ¹³ C carbon isotopes in corrosion inhibitors is 0.4%, the corrosive activity of PGM with serial numbers 1, 2, 3, 4, and 5 is almost equal to the corrosivity of PGM described in table 2 (column No. 2 at deicing temperature materials -5 ° C). This means that an increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor to 0.4% does not lead to a decrease in the corrosivity of PHM.

But when the content of ¹³ C carbon isotopes in IR is 0.5%, the corrosive activity of PHM with serial numbers 1, 2, 3, 4 and 5 becomes less than the corrosivity of PHM described in table 2 (column No. 2 at anti-icing materials temperature -5 ° C). It can be seen that the corrosion rate is lower. This means that an increase in the content of ¹³ C in IR carbon to a value of 0.5% leads to a decrease in the corrosivity of PHM by about 15%.

With a further increase in the ¹³ C carbon isotope content in IR, the corrosive activity of PGM decreases. Moreover, when the content of ¹³ C carbon isotopes in the IR is 75%, the minimum corrosion rate is achieved. With a further increase in the content of ¹³ C carbon isotopes in IR, the corrosion rate no longer decreases, but the energy and time costs for manufacturing IR increase.

A comparative analysis of the corrosivity of PGM with corrosion inhibitors not containing carbon isotopes of ¹³ C and nitrogen ¹⁵ N with the corrosion activity of PGM with corrosion inhibitors enriched only with carbon isotopes of ¹³ C (at a content of ¹³ C isotopes of 75%) showed that a decrease in the corrosion rate can reach 70%.

Table 7 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. The composition of PGM includes a corrosion inhibitor containing from 0.4% to 80% of carbon isotopes ¹³ C.

The temperature of anti-icing materials is -5 ° C. In the experiments, a 10% solution of PGM in distilled water was used.

The table shows that when the content of ¹³ C carbon isotopes in corrosion inhibitors is 0.4%, the corrosive activity of PGM with serial numbers 1, 2, 3, 4 and 5 is almost equal to the corrosivity of PGM described in table 3 (column No. 2 at anti-icing temperature materials -5 ° C). It can be seen that the results are almost identical (the difference in values does not exceed 0.003). This means that an increase in the content of ¹³ C in the corrosion inhibitor to a value of 0.4% does not lead to a decrease in the corrosivity of PGM.

But when the content of carbon in the IR isotopes ¹³ C, equal to 0.5%, corrosivity PGM with sequence numbers 1, 2, 3, 4 and 5 becomes smaller corrosiveness PGM described in Table 3 (column №2 at icing materials -5 ° C). It can be seen that the corrosion rate is lower. This means that an increase in the ¹³ C content in IR carbon to a value of 0.5% leads to a decrease in the corrosivity of PHM by about 16%.

With a further increase in the ¹³ C carbon isotope content in IR, the corrosive activity of PGM decreases. Moreover, when the content of ¹³ C carbon isotopes in the IR is 75%, the minimum corrosion rate is achieved. With a further increase in the content of ¹³ C carbon isotopes in IR, the corrosion rate no longer decreases, but the energy and time costs for manufacturing IR increase.

A comparative analysis of the corrosivity of PGM with corrosion inhibitors not containing carbon isotopes of ¹³ C and nitrogen ¹⁵ N with the corrosion activity of PGM with corrosion inhibitors enriched only with carbon isotopes of ¹³ C (when the content of ¹³ C isotopes is 75%) showed that the corrosion rate may decrease by 70%.

Table 8 presents the data on the corrosion activity on St3ps steel anti-icing materials obtained by the methods described in paragraphs 1-5 of the claims. The composition of PGM includes a corrosion inhibitor containing from 0.4% to 80% of carbon isotopes ¹³ C.

The temperature of anti-icing materials is -5 ° C. A 20% solution of PGM in distilled water was used in the experiments.

The table shows that when the content of ¹³ C carbon isotopes in corrosion inhibitors is 0.4%, the corrosive activity of PGM with serial numbers 1, 2, 3, 4 and 5 is almost equal to the corrosivity of PGM described in table 4 (column No. 2 at deicing temperature materials -5 ° C). It can be seen that the results are almost identical (the difference in values does not exceed 0.003). This means that an increase in the content of ¹³ C in the corrosion inhibitor to a value of 0.4% does not lead to a decrease in the corrosivity of PGM.

But when the content of ¹³ C carbon isotopes in IR is 0.5%, the corrosive activity of PHM with serial numbers 1, 2, 3, 4, and 5 becomes less than the corrosivity of PHM described in Table 4 (column No. 2 at anti-icing materials -5 ° C). It can be seen that the corrosion rate is lower. This means that an increase in the ¹³ C content in IR carbon to a value of 0.5% leads to a decrease in the corrosivity of PHM by about 16%.

With a further increase in the ¹³ C carbon isotope content in IR, the corrosive activity of PGM decreases. Moreover, when the content of ¹³ C carbon isotopes in the IR is 75%, the minimum corrosion rate is achieved. With a further increase in the content of ¹³ C carbon isotopes in IR, the corrosion rate no longer decreases, but the energy and time costs for manufacturing IR increase.

A comparative analysis of the corrosivity of PGM with corrosion inhibitors not containing carbon isotopes of ¹³ C and nitrogen ¹⁵ N with the corrosion activity of PGM with corrosion inhibitors enriched only with carbon isotopes of ¹³ C (when the content of ¹³ C isotopes is 75%) showed that the corrosion rate may decrease by 70%.

Table 9 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. The composition of PGM includes a corrosion inhibitor containing from 0.4% to 80% of carbon isotopes ¹³ C.

The temperature of anti-icing materials is -10 ° C. A 5% PGM solution in distilled water was used in the experiments.

The table shows that when the content of ¹³ C carbon isotopes in corrosion inhibitors is 0.4%, the corrosive activity of PGM with serial numbers 1, 2, 3, 4, and 5 is almost equal to the corrosivity of PGM described in table 2 (column No. 3 at deicing temperature -10 ° C). It can be seen that the results are almost the same. This means that an increase in the content of ¹³ C in the corrosion inhibitor to a value of 0.4% does not lead to a decrease in the corrosivity of PGM.

But when the content of ¹³ C carbon isotopes in IR is 0.5%, the corrosive activity of PHM with serial numbers 1, 2, 3, 4, and 5 becomes less than the corrosivity of PHM described in Table 2 (column No. 3 at a temperature of anti-icing materials -10 ° C). It can be seen that the corrosion rate is lower. This means that an increase in the content of ¹³ C in IR carbon to a value of 0.5% leads to a decrease in the corrosivity of PHM (by about 16%).

With a further increase in the ¹³ C carbon isotope content in IR, the corrosive activity of PGM decreases. Moreover, when the content of ¹³ C carbon isotopes in the IR is 75%, the minimum corrosion rate is achieved. With a further increase in the content of ¹³ C carbon isotopes in IR, the corrosion rate no longer decreases, but the energy and time costs for manufacturing IR increase.

A comparative analysis of the corrosivity of PGM with corrosion inhibitors not containing carbon isotopes of ¹³ C and nitrogen ¹⁵ N with the corrosion activity of PGM with corrosion inhibitors enriched only with carbon isotopes of ¹³ C (at a content of ¹³ C isotopes of 75%) showed that a decrease in the corrosion rate can reach 73%.

Table 10 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. The composition of PGM includes a corrosion inhibitor containing from 0.4% to 80% of carbon isotopes ¹³ C.

The temperature of anti-icing materials is -10 ° C. In the experiments, a 10% solution of PGM in distilled water was used.

The table shows that when the content of ¹³ C carbon isotopes in corrosion inhibitors is 0.4%, the corrosive activity of PGM with serial numbers 1, 2, 3, 4 and 5 is almost equal to the corrosivity of PGM described in table 3 (column No. 3 at deicing temperature -10 ° C). It can be seen that the results are almost identical (the difference in values does not exceed 0.003). This means that an increase in the content of ¹³ C in the corrosion inhibitor to a value of 0.4% does not lead to a decrease in the corrosivity of PGM.

But when the content of ¹³ C carbon isotopes in IR is 0.5%, the corrosive activity of PHM with serial numbers 1, 2, 3, 4 and 5 becomes less than the corrosivity of PHM described in table 3 (column No. 3 at -10 anti-icing materials ° C). It can be seen that the corrosion rate is lower. This means that an increase in the content of ¹³ C in IR carbon to a value of 0.5% leads to a decrease in the corrosivity of PHM (by about 15%).

With a further increase in the ¹³ C carbon isotope content in IR, the corrosive activity of PGM decreases. Moreover, when the content of ¹³ C carbon isotopes in the IR is 75%, the minimum corrosion rate is achieved. With a further increase in the content of ¹³ C carbon isotopes in IR, the corrosion rate no longer decreases, but the energy and time costs for manufacturing IR increase.

A comparative analysis of the corrosivity of PGM with corrosion inhibitors not containing carbon isotopes of ¹³ C and nitrogen ¹⁵ N with the corrosion activity of PGM with corrosion inhibitors enriched only with carbon isotopes of ¹³ C (at a content of ¹³ C isotopes of 75%) showed that a decrease in the corrosion rate can reach 73%.

Table 11 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. The composition of PGM includes a corrosion inhibitor containing from 0.4% to 80% of carbon isotopes ¹³ C.

The temperature of anti-icing materials is -10 ° C. A 20% solution of PGM in distilled water was used in the experiments.

The table shows that when the content of ¹³ C carbon isotopes in corrosion inhibitors is 0.4%, the corrosive activity of PGM with serial numbers 1,2, 3,4, and 5 is almost equal to the corrosion activity of PHM described in table 4 (column No. 3 at deicing temperature -10 ° C). It can be seen that the results are almost identical (the difference in values does not exceed 0.003). This means that an increase in the content of ¹³ C in the corrosion inhibitor to a value of 0.4% does not lead to a decrease in the corrosivity of PGM.

But when the content of ¹³ C carbon isotopes in IR is 0.5%, the corrosive activity of the PHM with serial numbers 1, 2, 3, 4, and 5 becomes less than the corrosivity of the PHM described in table 4 (column No. 3 at a temperature of anti-icing materials -10 ° C). It can be seen that the corrosion rate is lower. This means that an increase in the content of ¹³ C in IR carbon to a value of 0.5% leads to a decrease in the corrosivity of PHM (by about 16%).

With a further increase in the ¹³ C carbon isotope content in IR, the corrosive activity of PGM decreases. Moreover, when the content of ¹³ C carbon isotopes in the IR is 75%, the minimum corrosion rate is achieved. With a further increase in the content of ¹³ C carbon isotopes in IR, the corrosion rate no longer decreases, but the energy and time costs for manufacturing IR increase.

A comparative analysis of the corrosivity of PGM with corrosion inhibitors not containing carbon isotopes of ¹³ C and nitrogen ¹⁵ N with the corrosion activity of PGM with corrosion inhibitors enriched only with carbon isotopes of ¹³ C (at a content of ¹³ C isotopes of 75%) showed that a decrease in the corrosion rate can reach 73%.

Table 12 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. The composition of PGM includes a corrosion inhibitor containing from 0.4% to 80% of carbon isotopes ¹³ C.

The temperature of anti-icing materials is -20 ° C. A 5% PGM solution in distilled water was used in the experiments.

The table shows that when the content of ¹³ C carbon isotopes in corrosion inhibitors is 0.4%, the corrosive activity of PGM with serial numbers 1, 2, 3, 4, and 5 is almost equal to the corrosivity of PGM described in table 2 (column No. 4 at deicing temperature materials -20 ° C). It can be seen that the results are almost the same. This means that an increase in the content of ¹³ C in the corrosion inhibitor to a value of 0.4% does not lead to a decrease in the corrosivity of PGM.

But when the content of ¹³ C carbon isotopes in IR is 0.5%, the corrosive activity of PHM with serial numbers 1, 2, 3, 4, and 5 becomes less than the corrosivity of PHM described in Table 2 (column No. 4 at a temperature of anti-icing materials -20 ° C). It can be seen that the corrosion rate is lower. This means that an increase in the content of ¹³ C in IR carbon to a value of 0.5% leads to a decrease in the corrosivity of PHM (by about 16%).

With a further increase in the ¹³ C carbon isotope content in IR, the corrosive activity of PGM decreases. Moreover, when the content of ¹³ C carbon isotopes in the IR is 75%, the minimum corrosion rate is achieved. With a further increase in the content of ¹³ C carbon isotopes in IR, the corrosion rate no longer decreases, but the energy and time costs for manufacturing IR increase.

A comparative analysis of the corrosivity of PGM with corrosion inhibitors not containing carbon isotopes of ¹³ C and nitrogen ¹⁵ N with the corrosion activity of PGM with corrosion inhibitors enriched only with carbon isotopes of ¹³ C (at a content of ¹³ C isotopes of 75%) showed that a decrease in the corrosion rate can reach 73%.

Table 13 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. The composition of PGM includes a corrosion inhibitor containing from 0.4% to 80% of carbon isotopes ¹³ C.

The temperature of anti-icing materials is -20 ° C. In the experiments, a 10% solution of PGM in distilled water was used.

The table shows that when the content of ¹³ C carbon isotopes in corrosion inhibitors is 0.4%, the corrosive activity of PGM with serial numbers 1, 2, 3, 4 and 5 is almost equal to the corrosivity of PGM described in table 3 (column No. 4 at anti-icing temperature materials -20 ° C). It can be seen that the results are almost identical (the difference in values does not exceed 0.003). This means that an increase in the content of ¹³ C in the corrosion inhibitor to a value of 0.4% does not lead to a decrease in the corrosivity of PGM.

But when the content of ¹³ C carbon isotopes in IR is 0.5%, the corrosive activity of PHM with serial numbers 1, 2, 3, 4, and 5 becomes less than the corrosivity of PHM described in table 3 (column No. 4 at a temperature of anti-icing materials -20 ° C). It can be seen that the corrosion rate is lower. This means that an increase in the content of ¹³ C in IR carbon to a value of 0.5% leads to a decrease in the corrosivity of PHM (by about 16%).

With a further increase in the ¹³ C carbon isotope content in IR, the corrosive activity of PGM decreases. Moreover, when the content of ¹³ C carbon isotopes in the IR is 75%, the minimum corrosion rate is achieved. With a further increase in the content of ¹³ C carbon isotopes in IR, the corrosion rate no longer decreases, but the energy and time costs for manufacturing IR increase.

A comparative analysis of the corrosivity of PGM with corrosion inhibitors not containing carbon isotopes of ¹³ C and nitrogen ¹⁵ N with the corrosion activity of PGM with corrosion inhibitors enriched only with carbon isotopes of ¹³ C (at a content of ¹³ C isotopes of 75%) showed that a decrease in the corrosion rate can reach 73%.

Table 14 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. The composition of PGM includes a corrosion inhibitor containing from 0.4% to 80% of carbon isotopes ¹³ C.

The temperature of anti-icing materials is -20 ° C. A 20% solution of PGM in distilled water was used in the experiments.

The table shows that when the content of ¹³ C carbon isotopes in corrosion inhibitors is 0.4%, the corrosive activity of PGM with serial numbers 1, 2, 3, 4, and 5 is almost equal to the corrosivity of PGM described in table 4 (column No. 4 at deicing temperature materials -20 ° C). It can be seen that the results are almost identical (the difference in values does not exceed 0.003). This means that an increase in the content of ¹³ C in the corrosion inhibitor to a value of 0.4% does not lead to a decrease in the corrosivity of PGM.

But when the content of ¹³ C carbon isotopes in IR is 0.5%, the corrosive activity of PHM with serial numbers 1, 2, 3, 4 and 5 becomes less than the corrosivity of PHM described in table 4 (column No. 4 at a temperature of anti-icing materials -20 ° C). It can be seen that the corrosion rate is lower. This means that an increase in the content of ¹³ C in IR carbon to a value of 0.5% leads to a decrease in the corrosivity of PHM (by about 16%).

With a further increase in the ¹³ C carbon isotope content in IR, the corrosive activity of PGM decreases. Moreover, when the content of ¹³ C carbon isotopes in the IR is 75%, the minimum corrosion rate is achieved. With a further increase in the content of ¹³ C carbon isotopes in IR, the corrosion rate no longer decreases, but the energy and time costs for manufacturing IR increase.

A comparative analysis of the corrosivity of PGM with corrosion inhibitors not containing carbon isotopes of ° C and nitrogen ¹⁵ N with the corrosion activity of PGM with corrosion inhibitors enriched only with ¹³ C carbon isotopes (with a ¹³ C isotope content of 75%) showed that a decrease in the corrosion rate can reach 72%.

Table 15 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. The composition includes a corrosion inhibitor PGM containing from 0.005% to 14% nitrogen isotope ¹⁵ N. Temperature icing materials -5 ° C. A 5% PGM solution in distilled water was used in the experiments.

A comparative analysis of table 15 (column 2) and table 2 (column 2) shows that with a 0.005% content of ¹⁵ N nitrogen isotopes in the corrosion inhibitor, there is no effect of reducing corrosion activity. The effect occurs at a concentration of nitrogen isotopes of ¹⁵ N in the corrosion inhibitor at 0.01% (column 5 of Table 15) a further decrease in corrosion activity is observed to 13.75% (column 5 of table 15) of the nitrogen isotopes in the corrosion inhibitor ¹⁵ N. With a further increase in the content in the corrosion inhibitor isotopes of nitrogen ¹⁵ N reduction in corrosion activity is not observed.

At 0.01% corrosion inhibitor content in the nitrogen isotopes ¹⁵ N effect is approximately 20%.

With a 13.75% content of ¹⁵ N nitrogen isotopes in the corrosion inhibitor, the effect is about 80%.

Table 16 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. The composition includes a corrosion inhibitor PGM containing from 0.005% to 14% nitrogen isotope ¹⁵ N. Temperature icing materials -5 ° C. In the experiments, a 10% solution of PGM in distilled water was used.

A comparative analysis of table 16 (column 2) and table 3 (column 2) shows that at a concentration of ¹⁵ N nitrogen isotopes in a corrosion inhibitor, there is no effect of a decrease in corrosion activity. The effect occurs at a concentration of nitrogen isotopes of ¹⁵ N in the corrosion inhibitor at 0.01% (column 5 of table 16) a further decrease in corrosion activity is observed to 13.75% (column 5 of table 16) of the content of nitrogen isotopes in the corrosion inhibitor ¹⁵ N. With a further increase in the content in the corrosion inhibitor isotopes of nitrogen ¹⁵ N reduction in corrosion activity is not observed.

At 0.01% corrosion inhibitor content in the nitrogen isotopes ¹⁵ N effect is approximately 20%.

With a 13.75% content of ¹⁵ N nitrogen isotopes in the corrosion inhibitor, the effect is about 80%.

Table 17 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. The composition includes a corrosion inhibitor PGM containing from 0.005% to 14% nitrogen isotope ¹⁵ N. Temperature icing materials -5 ° C. In the experiments, a 20% solution of PGM in distilled water was used.

A comparative analysis of table 17 (column 2) and table 4 (column 2) shows that with a 0.005% content of ¹⁵ N nitrogen isotopes in the corrosion inhibitor, there is no effect of reducing corrosion activity. The effect occurs at a concentration of nitrogen isotopes of ¹⁵ N in the corrosion inhibitor at 0.01% (column 5 of Table 17) a further decrease in corrosion activity is observed to 13.75% (column 5 of table 17) of the nitrogen isotopes in the corrosion inhibitor ¹⁵ N. With a further increase in the content in the corrosion inhibitor isotopes of nitrogen ¹⁵ N reduction in corrosion activity is not observed.

At 0.01% corrosion inhibitor content in the nitrogen isotopes ¹⁵ N effect is approximately 20%.

With a 13.75% content of ¹⁵ N nitrogen isotopes in the corrosion inhibitor, the effect is about 80%.

Table 18 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. The composition includes a corrosion inhibitor PGM containing from 0.005% to 14% nitrogen isotope ¹⁵ N. Temperature icing materials -10 ° C. A 5% PGM solution in distilled water was used in the experiments.

A comparative analysis of table 18 (column 2) and table 2 (column 3) shows that with a 0.005% content of ¹⁵ N nitrogen isotopes in the corrosion inhibitor, there is no effect of reducing corrosion activity. The effect occurs at a concentration of nitrogen isotopes of ¹⁵ N in the corrosion inhibitor at 0.01% (column 5 of table 18) a further decrease in corrosion activity is observed to 13.75% (column 5 of table 18) of the content of nitrogen isotopes in the corrosion inhibitor ¹⁵ N. With a further increase in the content in the corrosion inhibitor isotopes of nitrogen ¹⁵ N reduction in corrosion activity is not observed.

At 0.01% corrosion inhibitor content in the nitrogen isotopes ¹⁵ N effect is approximately 20%.

With a 13.75% content of ¹⁵ N nitrogen isotopes in the corrosion inhibitor, the effect is about 80%.

Table 19 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. The composition includes a corrosion inhibitor PGM containing from 0.005% to 14% nitrogen isotope ¹⁵ N. Temperature icing materials -10 ° C. In the experiments, a 10% solution of PGM in distilled water was used.

A comparative analysis of table 19 (column 2) and table 3 (column 3) shows that with a 0.005% content of ¹⁵ N nitrogen isotopes in the corrosion inhibitor, there is no effect of a decrease in corrosion activity. The effect occurs at a concentration of nitrogen isotopes of ¹⁵ N in the corrosion inhibitor at 0.01% (column 5 of table 19) a further decrease in corrosion activity is observed to 13.75% (column 5 of table 19) of the content of nitrogen isotopes in the corrosion inhibitor ¹⁵ N. With a further increase in the content in the corrosion inhibitor isotopes of nitrogen ¹⁵ N reduction in corrosion activity is not observed.

With a 0.01% content of ¹⁵ N nitrogen isotopes in the corrosion inhibitor, the effect is about 19%.

With a 13.75% content of ¹⁵ N nitrogen isotopes in the corrosion inhibitor, the effect is about 80%.

Table 20 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. The composition includes a corrosion inhibitor PGM containing from 0.005% to 14% nitrogen isotope ¹⁵ N. Temperature icing materials -10 ° C. In the experiments, a 20% solution of PGM in distilled water was used.

A comparative analysis of table 20 (column 2) and table 4 (column 3) shows that at 0.005% content of ¹⁵ N nitrogen isotopes in the corrosion inhibitor, there is no effect of a decrease in corrosion activity. The effect occurs at a concentration of nitrogen isotopes of ¹⁵ N in the corrosion inhibitor at 0.01% (column 5 of Table 20) a further decrease in corrosion activity is observed up to 13.75% (column 5 of table 20) of the nitrogen isotopes in the corrosion inhibitor ¹⁵ N. With a further increase in the content in the corrosion inhibitor isotopes of nitrogen ¹⁵ N reduction in corrosion activity is not observed.

At 0.01% corrosion inhibitor content in the nitrogen isotopes ¹⁵ N effect is approximately 20%.

With a 13.75% content of ¹⁵ N nitrogen isotopes in the corrosion inhibitor, the effect is about 80%.

Table 21 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. The composition of PGM includes a corrosion inhibitor containing from 0.005% to 14% of nitrogen isotopes ¹⁵ N. The temperature of anti-icing materials is -20 ° C. A 5% PGM solution in distilled water was used in the experiments.

A comparative analysis of table 21 (column 2) and table 4 (column 4) shows that with a 0.005% content of ¹⁵ N nitrogen isotopes in the corrosion inhibitor, there is no effect of reducing corrosion activity. The effect occurs at a concentration of nitrogen isotopes of ¹⁵ N in the corrosion inhibitor at 0.01% (column 5 of table 21) a further decrease in corrosion activity is observed to 13.75% (column 5 of table 21) of the content of nitrogen isotopes in the corrosion inhibitor ¹⁵ N. With a further increase in the content in the corrosion inhibitor isotopes of nitrogen ¹⁵ N reduction in corrosion activity is not observed.

At 0.01% corrosion inhibitor content in the nitrogen isotopes ¹⁵ N effect is approximately 20%.

With a 13.75% content of ¹⁵ N nitrogen isotopes in the corrosion inhibitor, the effect is about 80%.

Table 22 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. The composition of PGM includes a corrosion inhibitor containing from 0.005% to 14% of nitrogen isotopes ¹⁵ N. The temperature of anti-icing materials is -20 ° C. In the experiments, a 10% solution of PGM in distilled water was used.

A comparative analysis of table 22 (column 2) and table 3 (column 4) shows that at a 0.005% content of ¹⁵ N nitrogen isotopes in the corrosion inhibitor, there is no effect of reducing corrosion activity. The effect occurs at a concentration of nitrogen isotopes of ¹⁵ N in the corrosion inhibitor at 0.01% (column 5 of table 22) a further decrease in corrosion activity is observed to 13.75% (column 5 of table 22) of the content of nitrogen isotopes in the corrosion inhibitor ¹⁵ N. With a further increase in the content in the corrosion inhibitor isotopes of nitrogen ¹⁵ N reduction in corrosion activity is not observed.

At 0.01% corrosion inhibitor content in the nitrogen isotopes ¹⁵ N effect is approximately 20%.

With a 13.75% content of ¹⁵ N nitrogen isotopes in the corrosion inhibitor, the effect is about 80%.

Table 23 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. The composition of PGM includes a corrosion inhibitor containing from 0.005% to 14% of nitrogen isotopes ¹⁵ N. The temperature of anti-icing materials is -20 ° C. In the experiments, a 20% solution of PGM in distilled water was used.

A comparative analysis of table 23 (column 2) and table 4 (column 4) shows that with a 0.005% content of ¹⁵ N nitrogen isotopes in the corrosion inhibitor, there is no effect of reducing corrosion activity. The effect occurs at a concentration of nitrogen isotopes of ¹⁵ N in the corrosion inhibitor at 0.01% (column 5 of table 23) a further decrease in corrosion activity is observed to 13.75% (column 5 of table 23) of the content of nitrogen isotopes in the corrosion inhibitor ¹⁵ N. With a further increase in the content in the corrosion inhibitor isotopes of nitrogen ¹⁵ N reduction in corrosion activity is not observed.

At 0.01% corrosion inhibitor content in the nitrogen isotopes ¹⁵ N effect is approximately 20%.

With a 13.75% content of ¹⁵ N nitrogen isotopes in the corrosion inhibitor, the effect is about 80%.

Tables 6-23 show that saturation of corrosion inhibitors with carbon isotopes ¹³ C or nitrogen ¹⁵ N can lead to a decrease in the corrosivity of PHM under various conditions of use.

In tables 24-68 below, it will be shown that saturation of corrosion inhibitors with carbon isotopes ¹³ C and nitrogen ¹⁵ N can lead to a more significant decrease in the corrosivity of PHM under various conditions of use.

3 stage.

Conducting studies with PGM obtained by methods 1-5 (see paragraphs 1-5 of the claims), with saturation of corrosion inhibitors with heavy isotopes ¹³ C and ¹⁵ N.

PGM was prepared by the methods described in paragraphs 1-5 of the claims.

In stage 3, comparative analyzes of the corrosivity of PGMs that do not contain carbon isotopes of ¹³ C and nitrogen ¹⁵ N and the corrosion activity of PGMs enriched with isotopes of carbon ¹³ C and nitrogen of ¹⁵ N.

Table 24 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 0.005% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and carbon isotopes from ¹³ C 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -5 ° C.

A 5% PGM solution in distilled water was used in the experiments.

A comparative analysis of table 24 (column 2) and table 2 (column 2) shows that at 0.005% content of ¹⁵ N nitrogen isotopes in IR and 0.4% ¹³ C content in IR isotopes, there is no effect of reducing corrosion activity. The effect occurs at 0.5% (column 3 of table 24) of ¹³ C. carbon isotopes in IR.

A further decrease in corrosion activity is observed up to 75% (column 5 of table 24) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, at a 0.5% content of ¹³ C carbon isotopes in IR and a 0.005% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 15%.

With a 75% content of ¹³ C carbon isotopes in IR and a 0.005% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 72%.

Table 25 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM contains a corrosion inhibitor containing 0.005% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes of 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -5 ° C.

In the experiments, a 10% solution of PGM in distilled water was used.

A comparative analysis of table 25 (column 2) and table 3 (column 2) shows that at 0.005% content of nitrogen isotopes ¹⁵ N in IR and 0.4% content of ¹³ C carbon isotopes in IR, there is no effect of reducing corrosion activity. The effect occurs at 0.5% (column 3 of table 25) of ¹³ C carbon isotopes in IR.

A further decrease in corrosion activity is observed up to 75% (column 5 of table 25) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, at a 0.5% content of ¹³ C carbon isotopes in IR and a 0.005% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 16%.

With a 75% content of ¹³ C carbon isotopes in IR and a 0.005% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 73%.

Table 26 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM contains a corrosion inhibitor containing 0.005% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes of 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -5 ° C.

A 20% solution of PGM in distilled water was used in the experiments.

A comparative analysis of table 26 (column 2) and table 4 (column 2) shows that at 0.005% content of ¹⁵ N nitrogen isotopes in IR and 0.4% ¹³ C carbon isotopes in IR, there is no effect of a decrease in corrosion activity. The effect occurs when 0.5% (column 3 of table 26) contains ¹³ C carbon isotopes in IR.

A further decrease in corrosion activity is observed up to 75% (column 5 of table 26) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, at a 0.5% content of ¹³ C carbon isotopes in IR and a 0.005% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 16%.

With a 75% content of ¹³ C carbon isotopes in IR and a 0.005% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 72%.

Table 27 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM contains a corrosion inhibitor containing 0.005% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes of 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -10 ° C.

A 5% PGM solution in distilled water was used in the experiments.

A comparative analysis of Table 27 (column 2) and Table 2 (column 3) shows that at 0.005% content of ¹⁵ N nitrogen isotopes in IR and 0.4% ¹³ C content in IR isotopes, there is no effect of reducing corrosion activity. The effect occurs at 0.5% (column 3 of table 27) content of ¹³ C. carbon isotopes in IR

A further decrease in corrosion activity is observed up to 75% (column 5 of Table 27) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, at a 0.5% content of ¹³ C carbon isotopes in IR and a 0.005% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 16%.

With a 75% content of ¹³ C carbon isotopes in IR and a 0.005% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 73%.

Table 28 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM contains a corrosion inhibitor containing 0.005% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes of 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -10 ° C.

In the experiments, a 10% solution of PGM in distilled water was used.

A comparative analysis of Table 28 (column 2) and Table 3 (column 3) shows that at 0.005% content of ¹⁵ N nitrogen isotopes in IR and 0.4% ¹³ C carbon isotopes in IR, there is no effect of reducing corrosion activity. The effect occurs at 0.5% (column 3 of table 28) content of ¹³ C. carbon isotopes in IR

A further decrease in corrosion activity is observed up to 75% (column 5 of table 28) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, at a 0.5% content of ¹³ C carbon isotopes in IR and a 0.005% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 15%.

With a 75% content of ¹³ C carbon isotopes in IR and a 0.005% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 73%.

Table 29 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM contains a corrosion inhibitor containing 0.005% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes of 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -10 ° C.

A 20% solution of PGM in distilled water was used in the experiments.

A comparative analysis of table 29 (column 2) and table 4 (column 3) shows that at 0.005% content of ¹⁵ N nitrogen isotopes in IR and 0.4% ¹³ C carbon isotopes in IR, there is no effect of reducing corrosion activity. The effect occurs at 0.5% (column 3 of table 29) with ¹³ C carbon isotopes in IR.

A further decrease in corrosion activity is observed up to 75% (column 5 of table 29) of the ¹³ C carbon isotope content in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in the corrosion activity is observed.

Thus, at a 0.5% content of ¹³ C carbon isotopes in IR and a 0.005% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 16%.

With a 75% content of ¹³ C carbon isotopes in IR and a 0.005% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 73%.

Table 30 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM contains a corrosion inhibitor containing 0.005% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes of 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -20 ° C.

A 5% PGM solution in distilled water was used in the experiments.

A comparative analysis of table 30 (column 2) and table 2 (column 4) shows that at 0.005% content of nitrogen isotopes ¹⁵ N in IR and 0.4% content of ¹³ C carbon isotopes in IR, there is no effect of reducing corrosion activity. The effect occurs at 0.5% (column 3 of table 30) of ¹³ C carbon isotopes in the IR.

A further decrease in corrosion activity is observed up to 75% (column 5 of table 30) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, at a 0.5% content of ¹³ C carbon isotopes in IR and a 0.005% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 16%.

With a 75% content of ¹³ C carbon isotopes in IR and a 0.005% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 73%.

Table 31 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM contains a corrosion inhibitor containing 0.005% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes of 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -20 ° C.

In the experiments, a 10% solution of PGM in distilled water was used.

A comparative analysis of table 31 (column 2) and table 3 (column 4) shows that at 0.005% content of ¹⁵ N nitrogen isotopes in IR and 0.4% ¹³ C carbon isotopes in IR, there is no effect of reducing corrosion activity. The effect occurs at 0.5% (column 3 of table 31) of ¹³ C carbon isotopes in IR.

A further decrease in corrosion activity is observed up to 75% (column 5 of Table 31) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, at a 0.5% content of ¹³ C carbon isotopes in IR and a 0.005% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 16%.

With a 75% content of ¹³ C carbon isotopes in IR and a 0.005% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 73%.

Table 32 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM contains a corrosion inhibitor containing 0.005% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes of 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -20 ° C.

A 20% solution of PGM in distilled water was used in the experiments.

A comparative analysis of table 32 (column 2) and table 4 (column 4) shows that at 0.005% content of ¹⁵ N nitrogen isotopes in IR and 0.4% ¹³ C content in IR isotopes, there is no effect of reducing corrosion activity. The effect occurs at 0.5% (column 3 of table 32) of ¹³ C carbon isotopes in IR.

A further decrease in corrosion activity is observed up to 75% (column 5 of table 32) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, at a 0.5% content of ¹³ C carbon isotopes in IR and a 0.005% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 16%.

With a 75% content of ¹³ C carbon isotopes in IR and a 0.005% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 73%.

Table 33 presents the data on the corrosion activity on St3ps steel deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 0.01% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -5 ° C.

A 5% PGM solution in distilled water was used in the experiments.

A comparative analysis of table 33 (column 2) and table 2 (column 2) shows that with 0.01% content of ¹⁵ N nitrogen isotopes in IR and 0.4% ¹³ C content in IR isotopes, there is an effect of reducing corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of table 33) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, there is no decrease in corrosion activity.

Thus, with a 0.4% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 20%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 41%.

With a 75% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 100%.

Table 34 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 0.01% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -5 ° C.

In the experiments, a 10% solution of PGM in distilled water was used.

A comparative analysis of table 34 (column 2) and table 3 (column 2) shows that with 0.01% content of ¹⁵ N nitrogen isotopes in IR and 0.4% ¹³ C content in IR isotopes, there is an effect of reducing corrosion activity. Further reduction in corrosivity is observed up to 75% (column 5 of Table 34) IR content in the carbon isotope ¹³ C. A further increase corrosion inhibitor content in the carbon isotopes ¹³ C reduction in corrosivity is not observed.

Thus, with a 0.4% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 19%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 41%.

With a 75% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 109%.

Table 35 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 0.01% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -5 ° C.

A 20% solution of PGM in distilled water was used in the experiments.

A comparative analysis of table 35 (column 2) and table 4 (column 2) shows that at 0.01% content of ¹⁵ N nitrogen isotopes in IR and 0.4% ¹³ C content in IR isotopes, there is an effect of reducing corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of table 35) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, with a 0.4% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 20%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 41%.

With a 75% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 110%.

Table 36 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 0.01% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -10 ° C.

A 5% PGM solution in distilled water was used in the experiments.

A comparative analysis of table 36 (column 2) and table 2 (column 3) shows that with 0.01% content of ¹⁵ N nitrogen isotopes in IR and 0.4% ¹³ C content in IR isotopes, there is an effect of reducing corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of table 36) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, with a 0.4% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 20%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 41%.

With a 75% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 112%.

Table 37 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 0.01% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -10 ° C.

In the experiments, a 10% solution of PGM in distilled water was used.

Comparative analysis of the table 37 (column 2) and Table 3 (column 3) shows that when the content of 0.01% Infrared nitrogen isotopes ¹⁵ N and 0.4% Content in IR carbon isotopes ¹³ C, the effect of reducing the corrosiveness is. A further decrease in corrosion activity is observed up to 75% (column 5 of table 37) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, at 0.4% of the ¹³ C carbon isotopes in the IR and 0.01% of the ¹⁵ N nitrogen isotopes in the IR, the effect is about 18%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 40%.

With a 75% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 110%.

Table 38 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 0.01% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -10 ° C.

A 20% solution of PGM in distilled water was used in the experiments.

A comparative analysis of table 38 (column 2) and table 4 (column 3) shows that with 0.01% content of ¹⁵ N nitrogen isotopes in IR and 0.4% ¹³ C content in IR isotopes, there is an effect of reducing corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of table 38) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, with a 0.4% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 20%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 41%.

With a 75% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 111%.

Table 39 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 0.01% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -20 ° C.

A 5% PGM solution in distilled water was used in the experiments.

A comparative analysis of table 39 (column 2) and table 2 (column 4) shows that with 0.01% content of ¹⁵ N nitrogen isotopes in IR and 0.4% ¹³ C content in IR isotopes, there is an effect of reducing corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of table 39) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, there is no decrease in corrosion activity.

Thus, with a 0.4% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 20%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 43%.

With a 75% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 114%.

Table 40 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 0.01% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -20 ° C.

In the experiments, a 10% solution of PGM in distilled water was used.

A comparative analysis of table 40 (column 2) and table 3 (column 4) shows that with 0.01% content of ¹⁵ N nitrogen isotopes in IR and 0.4% ¹³ C carbon isotopes in IR, there is an effect of a decrease in corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of Table 40) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, with a 0.4% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 19%.

At 0.5% content of ¹³ C carbon isotopes in IR and 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 42%.

With a 75% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 112%.

Table 41 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 0.01% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -20 ° C.

A 20% solution of PGM in distilled water was used in the experiments.

A comparative analysis of table 41 (column 2) and table 4 (column 4) shows that with 0.01% content of ¹⁵ N nitrogen isotopes in IR and 0.4% ¹³ C content in IR isotopes, there is an effect of reducing corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of Table 41) of the ¹³ C carbon isotope content in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, there is no decrease in corrosion activity.

Thus, with a 0.4% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 20%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 43%.

With a 75% content of ¹³ C carbon isotopes in IR and a 0.01% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 115%.

Table 42 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 3% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -5 ° C.

A 5% PGM solution in distilled water was used in the experiments.

A comparative analysis of table 42 (column 2) and table 2 (column 2) shows that with a 3% content of ¹⁵ N nitrogen isotopes in IR and a 0.4% ¹³ C content in IR isotopes, there is an effect of a decrease in corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of table 42) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, with a 0.4% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 50%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 79%.

With a 75% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 167%.

Table 43 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 3% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -5 ° C.

In the experiments, a 10% solution of PGM in distilled water was used.

A comparative analysis of table 43 (column 2) and table 3 (column 2) shows that with a 3% content of ¹⁵ N nitrogen isotopes in IR and a 0.4% content of ¹³ C carbon isotopes in IR, there is an effect of reducing corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of table 43) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, with a 0.4% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 50%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 78%.

With a 75% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 166%.

Table 44 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 3% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -5 ° C.

A 20% solution of PGM in distilled water was used in the experiments.

A comparative analysis of table 44 (column 2) and table 4 (column 2) shows that with a 3% content of ¹⁵ N nitrogen isotopes in IR and a 0.4% content of ¹³ C carbon isotopes in IR, there is an effect of reducing corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of table 44) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, with a 0.4% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 51%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 79%.

With a 75% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 168%.

Table 45 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 3% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -10 ° C.

A 5% PGM solution in distilled water was used in the experiments.

A comparative analysis of table 45 (column 2) and table 4 (column 2) shows that with a 3% content of ¹⁵ N nitrogen isotopes in IR and a 0.4% ¹³ C content in IR isotopes, there is an effect of a decrease in corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of table 45) of the ¹³ C carbon isotope content in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in the corrosion activity is observed.

Thus, with a 0.4% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 51%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 79%.

With a 75% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 168%.

Table 46 presents the data on the corrosion activity on St3ps steel anti-icing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 3% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -10 ° C.

In the experiments, a 10% solution of PGM in distilled water was used.

A comparative analysis of table 46 (column 2) and table 3 (column 2) shows that with a 3% content of ¹⁵ N nitrogen isotopes in IR and a 0.4% ¹³ C content of ¹³ C carbon isotopes, there is an effect of reducing corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of table 46) of the ¹³ C carbon isotope content in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, there is no decrease in corrosion activity.

Thus, with a 0.4% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 49%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 77%.

With a 75% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 165%.

Table 47 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 3% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -10 ° C.

A 20% solution of PGM in distilled water was used in the experiments.

A comparative analysis of table 47 (column 2) and table 4 (column 2) shows that with a 3% content of ¹⁵ N nitrogen isotopes in IR and a 0.4% content of ¹³ C carbon isotopes in IR, there is an effect of reducing corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of table 47) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, there is no decrease in corrosion activity.

Thus, with a 0.4% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 50%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 78%.

With a 75% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 169%.

Table 48 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 3% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -20 ° C.

A 5% PGM solution in distilled water was used in the experiments.

A comparative analysis of table 48 (column 2) and table 2 (column 2) shows that with a 3% content of nitrogen isotopes ¹⁵ N in IR and a 0.4% content of ¹³ C carbon isotopes in IR, there is an effect of reducing corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of table 48) of the ¹³ C carbon isotope content in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, there is no decrease in corrosion activity.

Thus, with a 0.4% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 51%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 82%.

With a 75% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 172%.

Table 49 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 3% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -20 ° C.

In the experiments, a 10% solution of PGM in distilled water was used.

A comparative analysis of table 49 (column 2) and table 3 (column 4) shows that with a 3% content of ¹⁵ N nitrogen isotopes in IR and a 0.4% content of ¹³ C carbon isotopes in IR, there is an effect of reducing corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of Table 49) of the ¹³ C carbon isotope content in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in the corrosion activity is observed.

Thus, with a 0.4% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 50%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 82%.

With a 75% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 171%.

Table 50 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 3% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -20 ° C.

A 20% solution of PGM in distilled water was used in the experiments.

A comparative analysis of table 50 (column 2) and table 4 (column 4) shows that with a 3% content of ¹⁵ N nitrogen isotopes in IR and a 0.4% content of ¹³ C carbon isotopes in IR, there is an effect of reducing corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of table 50) of the ¹³ C carbon isotope content in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, there is no decrease in corrosion activity.

Thus, with a 0.4% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 50%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 84%.

With a 75% content of ¹³ C carbon isotopes in IR and a 3% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 172%.

Table 51 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 13.75% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -5 ° C.

A 5% PGM solution in distilled water was used in the experiments.

A comparative analysis of table 51 (column 2) and table 2 (column 2) shows that at 13.75% of the nitrogen isotopes ¹⁵ N in the IR and 0.4% of the ¹³ C carbon isotopes in the IR, there is an effect of reducing corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of Table 51) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, at 0.4% of the ¹³ C carbon isotopes in the IR and 13.75% of the ¹⁵ N nitrogen isotopes in the IR, the effect is about 80%.

With 0.5% content of ¹³ C carbon isotopes in IR and 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 120%.

With 75% content of ¹³ C carbon isotopes in IR and 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 229%.

Table 52 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 13.75% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -5 ° C.

In the experiments, a 10% solution of PGM in distilled water was used.

A comparative analysis of table 52 (column 2) and table 3 (column 2) shows that at 13.75% of the nitrogen isotopes ¹⁵ N in the IR and 0.4% of the ¹³ C carbon isotopes in the IR, there is an effect of reducing corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of table 52) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, at 0.4% content of ¹³ C carbon isotopes in IR and 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 79%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 117%.

With 75% content of ¹³ C carbon isotopes in IR and 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 227%.

Table 53 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 13.75% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -5 ° C.

A 20% solution of PGM in distilled water was used in the experiments.

A comparative analysis of table 53 (column 2) and table 4 (column 2) shows that at 13.75% content of ¹⁵ N nitrogen isotopes in IR and 0.4% ¹³ C carbon isotopes in IR, there is an effect of reducing corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of table 53) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, at 0.4% of the ¹³ C carbon isotopes in the IR and 13.75% of the ¹⁵ N nitrogen isotopes in the IR, the effect is about 80%.

With 0.5% content of ¹³ C carbon isotopes in IR and 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 119%.

With 75% content of ¹³ C carbon isotopes in IR and 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 230%.

Table 54 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 13.75% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -10 ° C.

A 5% PGM solution in distilled water was used in the experiments.

A comparative analysis of table 54 (column 2) and table 2 (column 3) shows that at 13.75% of the nitrogen isotopes ¹⁵ N in the IR and 0.4% of the ¹³ C carbon isotopes in the IR, there is an effect of a decrease in corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of Table 54) of the ¹³ C carbon isotope content in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, there is no decrease in corrosion activity.

Thus, at 0.4% of the ¹³ C carbon isotopes in the IR and 13.75% of the ¹⁵ N nitrogen isotopes in the IR, the effect is about 80%.

With 0.5% content of ¹³ C carbon isotopes in IR and 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 119%.

With 75% content of ¹³ C carbon isotopes in IR and 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 229%.

Table 55 presents data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 13.75% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -10 ° C.

In the experiments, a 10% solution of PGM in distilled water was used.

A comparative analysis of table 55 (column 2) and table 3 (column 3) shows that at 13.75% of the nitrogen isotopes ¹⁵ N in the IR and 0.4% of the ¹³ C carbon isotopes in the IR, there is an effect of reducing corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of table 55) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, at 0.4% content of ¹³ C carbon isotopes in IR and 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 79%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 117%.

With 75% content of ¹³ C carbon isotopes in IR and 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 223%.

Table 56 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 13.75% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -10 ° C.

A 20% solution of PGM in distilled water was used in the experiments.

A comparative analysis of table 56 (column 2) and table 4 (column 3) shows that at 13.75% of the nitrogen isotopes ¹⁵ N in the IR and 0.4% of the ¹³ C carbon isotopes in the IR, there is an effect of reducing corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of table 56) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, with a 0.4% content of ¹³ C carbon isotopes in IR and a 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 81%.

With 0.5% content of ¹³ C carbon isotopes in IR and 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 118%.

With 75% content of ¹³ C carbon isotopes in IR and 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 225%.

Table 57 presents the data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 13.75% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -20 ° C.

A 5% PGM solution in distilled water was used in the experiments.

A comparative analysis of table 57 (column 2) and table 2 (column 4) shows that at 13.75% of the nitrogen isotopes ¹⁵ N in the IR and 0.4% of the ¹³ C carbon isotopes in the IR, there is an effect of a decrease in corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of table 57) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, with a 0.4% content of ¹³ C carbon isotopes in IR and a 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 81%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 122%.

With 75% content of ¹³ C carbon isotopes in IR and 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 229%.

Table 58 presents data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 13.75% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -20 ° C.

In the experiments, a 10% solution of PGM in distilled water was used.

A comparative analysis of Table 58 (column 2) and Table 3 (column 4) shows that at 13.75% of the nitrogen isotopes ¹⁵ N in the IR and 0.4% of the ¹³ C carbon isotopes in the IR, there is an effect of a decrease in corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of table 58) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, at 0.4% of the ¹³ C carbon isotopes in the IR and 13.75% of the ¹⁵ N nitrogen isotopes in the IR, the effect is about 80%.

With 0.5% content of ¹³ C carbon isotopes in IR and 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 121%.

With 75% content of ¹³ C carbon isotopes in IR and 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 226%.

Table 59 presents data on the corrosion activity on St3ps steel of deicing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 13.75% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR.

The temperature of anti-icing materials is -20 ° C.

A 20% solution of PGM in distilled water was used in the experiments.

A comparative analysis of table 59 (column 2) and table 4 (column 4) shows that at 13.75% of the nitrogen isotopes ¹⁵ N in the IR and 0.4% of the ¹³ C carbon isotopes in the IR, there is an effect of a decrease in corrosion activity. A further decrease in corrosion activity is observed up to 75% (column 5 of table 59) of ¹³ C carbon isotopes in IR. With a further increase in the content of ¹³ C carbon isotopes in the corrosion inhibitor, no decrease in corrosion activity is observed.

Thus, at 0.4% of the ¹³ C carbon isotopes in the IR and 13.75% of the ¹⁵ N nitrogen isotopes in the IR, the effect is about 82%.

With a 0.5% content of ¹³ C carbon isotopes in IR and a 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 122%.

With 75% content of ¹³ C carbon isotopes in IR and 13.75% content of ¹⁵ N nitrogen isotopes in IR, the effect is approximately 229%.

As mentioned earlier, an increase in the content of ¹⁵ N nitrogen isotopes in IR from 13.75% to 14% practically does not lead to a further decrease in corrosion activity. This is experimentally confirmed. Tables 60-68 show the data on the corrosion activity of St3ps steel anti-icing materials obtained by the methods described in paragraphs 1-5 of the claims. PGM includes a corrosion inhibitor containing 14% of ¹⁵ N nitrogen isotopes of the total nitrogen in IR and ¹³ C carbon isotopes from 0.4% to 80% of the total carbon in IR. The data in the tables practically coincide with the data in tables 51-59.

A joint analysis of tables 2-68 shows that it is advisable to produce PGM by the methods described in paragraphs 1-5 of the claims, so that the corrosion inhibitors included in the PGM contain ¹³ C carbon isotopes and ¹⁵ N nitrogen isotopes, moreover, the ratio of the amount carbon isotopes ¹³ C to the total amount of carbon in the IR element should be from 0.005 to 0.75 (from 0.5% to 75%) and the ratio of the number of nitrogen isotopes ¹⁵ N to the total amount of nitrogen in the IR element should be from 0.0001 to 0, 1375 (from 0.01 to 13.75%).

Above, experimental studies of the corrosive activity of PGM obtained by the claimed methods on St3ps steel are described. It has been experimentally established that the corrosive activity of PGM obtained by the claimed methods (for any content of ¹³ C and ¹⁵ N isotopes in IR) is lower for St45 steel than for St3ps steel by about 2-2.5 times. And the corrosive activity of PGM obtained by the claimed methods (for any content of ¹³ C and ¹⁵ N isotopes in IR) is lower for St60 steel than for St3ps steel by about 1.9-2 times. The corrosive activity of PGM obtained by the claimed methods was tested on other materials and alloys. In all cases, the introduction of ¹³ C and ¹⁵ N isotopes into IR, which is part of the PHM, leads to a significant decrease in the corrosivity of the PHM.

When developing an application for an invention, assessments were made of the melting ability of PGM obtained by methods 1-5 (see the claims) for loose snow, rolling and ice. Also, estimates were made of the melting ability of the basic PGM obtained by methods 1-5 (see the claims) on snow, coast and ice without saturation of corrosion inhibitors with heavy isotopes ¹³ C and ¹⁵ N.

Table 5 presents the dependence of the melting ability of the five basic PGM on snow and coast from the temperature of the outside air. The floating ability of the base PGM is measured in "g / g" (shows how many grams of loose snow or runoff can melt 1 gram of PGM). For ice, the melting capacity values given in Table 5 should be reduced by five times. The table shows that with a decrease in the temperature of snow or coast, the melting ability of PGM decreases.

Deicing materials obtained for studies of corrosion activity were used to assess the melting ability of PGM. It turned out that the saturation of corrosion inhibitors with heavy ¹³ C and ¹⁵ N isotopes has practically no effect on the ability of PGM to melt snow, ice and ice. Thus, the data shown in table 5 can be attributed to PGM obtained by methods 1-5 (see the claims).

In practice, to combat slippage, PGM obtained by any of the methods claimed in the invention is applied to snow, rolling or ice located on the road, mechanically or manually. To determine the weight of the PGM necessary to combat, for example, coasting on the road, the thickness of rolling on the road is determined, then the weight of rolling on 1 m ^{2 of the} road is determined, then the obtained weight (in grams) of rolling is divided by the value of the melting ability from table 5 and get the result is how much PGM is needed in grams to process 1 m ^{2 of the} road to completely melt the run.

In this case, for all embodiments of the invention ensures the achievement of technical result consisting in increasing the effectiveness of the corrosion inhibitor in the composition of the resulting solid deicing material through the effective concentration of the corrosion inhibitor heavy carbon isotopes ¹³ C and nitrogen ¹⁵ N in a reactor installation with a cavitation reactor without deteriorating anti-icing properties PGM.

Also, when developing an application for an invention, experiments were conducted to assess the impact of PGM obtained by the claimed methods on plant life. The negative effect of PGM on the vital activity of a plant consists of the negative effects of chlorides, a corrosion inhibitor, a surfactant, and an acidity regulator on plants. The experiments compared the effect on the vital activity of PGM plants containing IR with isotopes of carbon ¹³ C and nitrogen ¹⁵ N with the effect on the vital activity of PGM plants containing IR without isotopes of carbon ¹³ C and nitrogen ¹⁵ N.

Three beds were prepared for research, on which seeds of Butterhead lettuce, First Class and Alphabet cucumbers were planted, grass for roadside lawns (Road mix containing annual ryegrass - 20%, plantain - 15%, timothy meadow - 35%, hedgehog team - 30%).

The first garden was watered with water for irrigation from an open source.

The second garden was watered with a 5% solution of PGM (with IR without carbon isotopes ¹³ C and nitrogen ¹⁵ N) with water for irrigation from an open source.

The third garden was divided into 3 parts.

The first part of the third garden was watered with a 5% solution of PHM (with IR containing 0.5% carbon isotopes ¹³ C and 0.01% nitrogen ¹⁵ N) with water for irrigation from an open source.

The second part of the third garden was watered with a 5% solution of PGM (with IR containing 15% of carbon isotopes ¹³ C and 3% nitrogen ¹⁵ N) with water for irrigation from an open source.

The third part of the third garden was watered with a 5% solution of PGM (with IR containing 75% of carbon isotopes ¹³ C and 13.75% nitrogen ¹⁵ N) with water for irrigation from an open source.

Seed germination and plant growth was observed for 4 weeks from 05/12/2014 to 06/13/2014. Place of experiments - Moscow region.

After 4 weeks of observation, there was practically no difference in the germination and growth of plants in the first and second beds. There was no difference in the germination and growth of plants in the second garden and the first part of the third garden.

The difference in the germination and growth of plants in the second garden and the second part of the third garden was noticed. In the second part of the third bed, seedlings were observed 2 days earlier than seedlings in the second bed. Subsequently, the growth and appearance of plants on the second bed and the second part of the third bed did not practically differ.

The difference in the germination and growth of plants in the second bed and the third part of the third bed was also noticed. In the third part of the third bed, seedlings were observed 3 days earlier than seedlings in the second bed. Subsequently, in the third part of the third garden, more intensive plant growth was observed than the growth of plants in the second garden. By the end of the observation period, the dynamics of plant growth in the third part of the third garden and the growth dynamics of plants in the second garden were leveled. This allowed us to conclude that the presence of a corrosion inhibitor with carbon isotopes ¹³ C and nitrogen ¹⁵ N in PGM does not adversely affect plants.

In addition, comparative tests were conducted on watering plants of 10% aqueous solutions of PHM with carbon isotopes ¹³ C and nitrogen ¹⁵ N and without carbon isotopes ¹³ C and nitrogen ¹⁵ N. There was no difference in germination and growth of plants.

Literature

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2. Handbook of a chemist, t.z. M .: Chemistry, 1964, p. 213.

3. A.I. Altsybeev, S.Z. Levin. Metal corrosion inhibitors. Edited by L.I. Antropov, Chemistry Publishing House, Leningrad Branch, 1968.

4. Instructions for dealing with winter slippery on roads. BCH 20-87. Minavtodor of the RSFSR. Moscow "Transport", 1988.

5. GOST R 51574-2000. Edible salt. Technical conditions

6. GOST 450-77. Technical calcium chloride. Technical conditions

7. Handbook of a chemist, vol. 3, p. 613, 628, publishing house Chemistry, M.-L., 1964.

8. Description of sodium 2-ethylhexyliminodipropionate, http://ruswind.ru/katalog/spetsialnye-ingredienty-dlya-avtohimii/amphotensid-eh.html.

9. GOST 2210-73. Ammonium chloride technical. Technical conditions

10. R.F. Ganiev, V.I. Kormilitsyn, L.I. Ukrainian. Wave technology for the preparation of alternative fuels and the efficiency of their combustion. - M .: Scientific and Publishing Center “Regular and Chaotic Dynamics”, 2008. - 116 p. /.

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Claims (5)

1. A method of obtaining a solid anti-icing material, including uniform mechanical mixing between a crystalline salt of a food grade stone of first grade, crystalline calcium chloride, technical calcined first grade, crystalline elements of a metal corrosion inhibitor, crystalline surfactant, crystalline acidity regulator, characterized in that sodium 2-ethylhexyliminodipropionate is used as a surfactant, as Your acidity regulator uses technical grade ammonium chloride, granular carbamide of the first grade, 2-phosphonobutane-1,2,4-tricarboxylic acid tetrasodium salt, magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ , sodium benzoate are used as elements of a metal corrosion inhibitor C ₆ H ₅ COONa, caprolactam C ₆ H ₁₁ NO, in the following ratio of components, wt.% Of the total number of components in the anti-icing material:
food grade table salt 51.0 calcium chloride technical calcined first grade 43.0 Sodium 2-ethylhexyliminodipropionate 0.10 first grade ammonium chloride 0.2 urea granular first grade 4.98 2-phosphonobutane-1,2,4-tricarboxylic acid tetrasodium salt 0.02 magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ 0.27 sodium benzoate C ₆ H ₅ COONa 0.33 caprolactam C ₆ H ₁₁ NO 0.10
wherein the metal corrosion inhibitor is prepared as follows:
- each of the above corrosion inhibitor element is dissolved in distilled water so that the resulting aqueous solution contains one weight part of the corrosion inhibitor element and three weight parts of distilled water;
- further, the resulting aqueous solution of each element of the corrosion inhibitor is subjected to cavitation treatment in a reactor installation, while the reactor installation contains a solution tank with a thermometer and a heat exchanger, an electric gear pump, a cavitation reactor, and the tank is connected by a pipe to the pump inlet, the pump outlet is connected by a pipeline with the inlet of the cavitation reactor, the outlet of the cavitation reactor is connected by a pipeline to the tank, and at the entrance to the cavitation reactor and exit from the cavitation pressure gauges are located on the reactor to determine the pressure drop across the cavitation reactor, and the cavitation reactor contains a channel for the movement of the aqueous solution, and the channel, in the direction of movement of the aqueous solution, contains three constrictions, the area of the passage section of the channel at the site of each restriction is 8% of the maximum passage area the cross-section of the channel, and before each narrowing of the channel there is a height-adjustable rod, turbulent flow before the narrowing of the channel, behind each narrowing in the body of the cavitation reactor is located dix passage for supplying carbon dioxide or nitrogen to cavitation reactor;
- for cavitation treatment, the resulting aqueous solution of each element of the corrosion inhibitor is poured into the capacity of the reactor installation, heated to 60 ° C and pumped from 170 to 720 times through the cavitation reactor by means of a gear pump;
- during cavitation processing, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the location of the rod;
- in addition, in the process of cavitation treatment through the channel located behind the first, in the direction of movement of the solution by constriction, carbon dioxide is supplied with a mass flow rate equal to 2% of the mass flow rate of the aqueous solution, through the channel located behind the second, in the direction of movement of the solution by constriction carbon dioxide is supplied with a mass flow rate equal to 1% of the mass flow rate of an aqueous solution, carbon dioxide with a mass flow rate equal to 0 is supplied through a channel located behind the third one in the direction of movement of the solution by constriction. 5% of the mass flow rate of an aqueous solution;
- by means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment is increased from 60 ° C to 75 ° C;
- during cavitation treatment, the corrosion inhibitor element in solution is saturated with ¹³ C heavy isotopes so that the ratio of ¹³ C carbon isotopes to the total amount of carbon in the element is from 0.005 to 0.75;
- control of the amount of carbon isotopes ¹³ C is carried out by high resolution mass spectroscopy;
- further, the resulting aqueous solution of the above-mentioned element of the corrosion inhibitor is subjected to repeated cavitation treatment in a reactor installation, for which the aqueous solution located in the tank is heated to 80 ° C and pumped from a cavitation reactor 50 to 390 times through a gear pump;
- during cavitation processing, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the location of the rod;
- in addition, in the process of cavitation treatment, nitrogen gas with a mass flow rate equal to 1% of the mass flow rate of the aqueous solution is fed through the channel located behind the first, in the direction of the solution’s narrowing, through the channel located behind the second, in the direction of the solution’s narrowing nitrogen gas is supplied with a mass flow rate equal to 0.5% of the mass flow rate of the aqueous solution, nitrogen gas with a mass flow rate is fed through a channel located behind the third one in the direction of solution flow narrowing m, of 0.1% of the mass flow rate of the aqueous solution;
- by means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment is increased from 80 ° C to 85 ° C;
- during the cavitation treatment, the corrosion inhibitor element in solution is saturated with heavy nitrogen isotopes ¹⁵ N so that the ratio of the number of nitrogen isotopes ¹⁵ N to the total amount of nitrogen in the element is from 0.0001 to 0.1375;
- control, the amount of ¹⁵ N nitrogen isotopes is carried out by high resolution mass spectroscopy;
- after repeated cavitation treatment of the solution, the element of the corrosion inhibitor is crystallized, for which 95.5% of water is evaporated from the aqueous solution;
- after cavitation treatment and crystallization of all the above elements of the corrosion inhibitor, they are mixed with the remaining components of the anti-icing material in the above percentage ratio;
- moreover, the cavitation treatment of the elements of the corrosion inhibitor is carried out in such a way that the percentage of carbon isotopes ¹³ C in each element of the corrosion inhibitor is the same and the percentage of nitrogen isotopes ¹⁵ N in each element of the corrosion inhibitor is the same. 2. A method of obtaining a solid anti-icing material, including uniform mechanical mixing between themselves of crystalline salt of food grade stone first grade, crystalline calcium chloride technical calcined first grade, crystalline elements of a metal corrosion inhibitor, crystalline surfactant, crystalline acidity regulator, characterized in that sodium 2-ethylhexyliminodipropionate is used as a surfactant, as Your acidity regulator uses ammonium chloride of the first grade, granular carbamide of the first grade, urotropine, magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ , sodium benzoate C ₆ H ₅ COONa, caprolactam C ₆ H ₁₁ NO, are used as elements of a metal corrosion inhibitor in the following ratio of components, wt.% of the total number of components in the anti-icing material:
food grade table salt 51.0 calcium chloride technical calcined first grade 43.0 Sodium 2-ethylhexyliminodipropionate 0.10 first grade ammonium chloride 0.2 urea granular first grade 4.98 urotropin 0.02 magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ 0.27 sodium benzoate C ₆ H ₅ COONa 0.33 caprolactam C ₆ H ₁₁ NO 0.10
wherein the metal corrosion inhibitor is prepared as follows:
- each of the above corrosion inhibitor element is dissolved in distilled water so that the resulting aqueous solution contains one weight part of the corrosion inhibitor element and three weight parts of distilled water;
- further, the resulting aqueous solution of each element of the corrosion inhibitor is subjected to cavitation treatment in a reactor installation, while the reactor installation contains a solution tank with a thermometer and a heat exchanger, an electric gear pump, a cavitation reactor, and the tank is connected by a pipe to the pump inlet, the pump outlet is connected by a pipeline with the inlet of the cavitation reactor, the outlet of the cavitation reactor is connected by a pipeline to the tank, and at the entrance to the cavitation reactor and exit from the cavitation a reactor disposed pressure gauges to determine the pressure drop across the cavitation reactor,
and the cavitation reactor contains a channel for the movement of the aqueous solution, and the channel, in the direction of movement of the aqueous solution, contains three constrictions, the area of the passage section of the channel at the point of each narrowing is 8% of the maximum passage area of the channel, and an adjustable height is located before each narrowing of the channel a rod, turbulent flow before the narrowing of the channel, behind each narrowing in the body of the cavitation reactor there is a channel for supplying carbon dioxide or nitrogen to the region of cavitation of the reactor;
- for cavitation treatment, the resulting aqueous solution of each element of the corrosion inhibitor is poured into the capacity of the reactor installation, heated to 60 ° C and pumped from 170 to 720 times through the cavitation reactor by means of a gear pump;
- during cavitation processing, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the location of the rod;
- in addition, in the process of cavitation treatment through the channel located behind the first, in the direction of movement of the solution by constriction, carbon dioxide is supplied with a mass flow rate equal to 2% of the mass flow rate of the aqueous solution, through the channel located behind the second, in the direction of movement of the solution by constriction carbon dioxide is supplied with a mass flow rate equal to 1% of the mass flow rate of an aqueous solution, carbon dioxide with a mass flow rate equal to 0 is supplied through a channel located behind the third one in the direction of movement of the solution by constriction. 5% of the mass flow rate of an aqueous solution;
- by means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment is increased from 60 ° C to 75 ° C;
- during cavitation treatment, the corrosion inhibitor element in solution is saturated with ¹³ C heavy isotopes so that the ratio of ¹³ C carbon isotopes to the total amount of carbon in the element is from 0.005 to 0.75;
- control of the amount of carbon isotopes ¹³ C is carried out by high resolution mass spectroscopy;
- further, the resulting aqueous solution of the above-mentioned element of the corrosion inhibitor is subjected to repeated cavitation treatment in a reactor installation, for which the aqueous solution located in the tank is heated to 80 ° C and pumped from a cavitation reactor 50 to 390 times through a gear pump;
- during cavitation processing, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the location of the rod;
- in addition, in the process of cavitation treatment, nitrogen gas with a mass flow rate equal to 1% of the mass flow rate of the aqueous solution is fed through the channel located behind the first, in the direction of the solution’s narrowing, through the channel located behind the second, in the direction of the solution’s narrowing nitrogen gas is supplied with a mass flow rate equal to 0.5% of the mass flow rate of the aqueous solution, nitrogen gas with a mass flow rate is fed through a channel located behind the third one in the direction of solution flow narrowing m, of 0.1% of the mass flow rate of the aqueous solution;
- by means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment is increased from 80 ° C to 85 ° C;
- during the cavitation treatment, the corrosion inhibitor element in solution is saturated with heavy nitrogen isotopes ¹⁵ N so that the ratio of the number of nitrogen isotopes ¹⁵ N to the total amount of nitrogen in the element is from 0.0001 to 0.1375;
- control the number of nitrogen isotopes ¹⁵ N carry out mass spectroscopy of high resolution;
- after repeated cavitation treatment of the solution, the element of the corrosion inhibitor is crystallized, for which 95.5% of water is evaporated from the aqueous solution;
- after cavitation treatment and crystallization of all the above elements of the corrosion inhibitor, they are mixed with the remaining components of the anti-icing material in the above percentage ratio;
- moreover, the cavitation treatment of the elements of the corrosion inhibitor is carried out in such a way that the percentage of carbon isotopes ¹³ C in each element of the corrosion inhibitor is the same and the percentage of nitrogen isotopes ¹⁵ N in each element of the corrosion inhibitor is the same. 3. A method of obtaining a solid anti-icing material, including uniform mechanical mixing between a crystalline salt of a food grade stone of first grade, crystalline calcium chloride technical calcined first grade, crystalline elements of a metal corrosion inhibitor, crystalline surfactant, crystalline acidity regulator, characterized in that sodium 2-ethylhexyliminodipropionate is used as a surfactant, as Your acidity regulator uses ammonium chloride of the first grade, carbamide granulated first grade, monosubstituted sodium phosphate NaH ₂ PO ₄ × 2H ₂ O, magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ , sodium benzoate C ₆ H are used as elements of a metal corrosion inhibitor ₅ COONa, caprolactam C ₆ H ₁₁ NO,
in the following ratio of components, wt.% of the total number of components in the anti-icing material:
food grade table salt 51.0 calcium chloride technical calcined first grade 43.0 Sodium 2-ethylhexyliminodipropionate 0.10 first grade ammonium chloride 0.2 urea granular first grade 4.98 monosubstituted sodium phosphate NaH ₂ PO ₄ × 2H ₂ O 0.02 magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ 0.27 sodium benzoate C ₆ H ₅ COONa 0.33 caprolactam C ₆ H ₁₁ NO 0.10
wherein the metal corrosion inhibitor is prepared as follows:
- each of the above corrosion inhibitor element is dissolved in distilled water so that the resulting aqueous solution contains one weight part of the corrosion inhibitor element and three weight parts of distilled water;
- further, the resulting aqueous solution of each element of the corrosion inhibitor is subjected to cavitation treatment in a reactor installation, while the reactor installation contains a solution tank with a thermometer and a heat exchanger, an electric gear pump, a cavitation reactor, and the tank is connected by a pipe to the pump inlet, the pump outlet is connected by a pipeline with the inlet of the cavitation reactor, the outlet of the cavitation reactor is connected by a pipeline to the tank, and at the entrance to the cavitation reactor and exit from the cavitation a reactor disposed pressure gauges to determine the pressure drop across the cavitation reactor,
and the cavitation reactor contains a channel for the movement of the aqueous solution, and the channel, in the direction of movement of the aqueous solution, contains three constrictions, the area of the passage section of the channel at the point of each narrowing is 8% of the maximum passage area of the channel, and an adjustable height is located before each narrowing of the channel a rod, turbulent flow before the narrowing of the channel, behind each narrowing in the body of the cavitation reactor there is a channel for supplying carbon dioxide or nitrogen to the region of cavitation of the reactor;
- for cavitation treatment, the resulting aqueous solution of each element of the corrosion inhibitor is poured into the capacity of the reactor installation, heated to 60 ° C and pumped from 170 to 720 times through the cavitation reactor by means of a gear pump;
- during cavitation processing, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the location of the rod;
- in addition, in the process of cavitation treatment through the channel located behind the first, in the direction of movement of the solution by constriction, carbon dioxide is supplied with a mass flow rate equal to 2% of the mass flow rate of the aqueous solution, through the channel located behind the second, in the direction of movement of the solution by constriction carbon dioxide is supplied with a mass flow rate equal to 1% of the mass flow rate of an aqueous solution, carbon dioxide with a mass flow rate equal to 0 is supplied through a channel located behind the third one in the direction of movement of the solution by constriction. 5% of the mass flow rate of an aqueous solution;
- by means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment is increased from 60 ° C to 75 ° C;
- during cavitation treatment, the corrosion inhibitor element in solution is saturated with ¹³ C heavy isotopes so that the ratio of ¹³ C carbon isotopes to the total amount of carbon in the element is from 0.005 to 0.75;
- control of the amount of carbon isotopes ¹³ C is carried out by high resolution mass spectroscopy;
- further, the resulting aqueous solution of the above-mentioned element of the corrosion inhibitor is subjected to repeated cavitation treatment in a reactor installation, for which the aqueous solution located in the tank is heated to 80 ° C and pumped from a cavitation reactor 50 to 390 times through a gear pump;
- during cavitation processing, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the location of the rod;
- in addition, in the process of cavitation treatment, nitrogen gas with a mass flow rate equal to 1% of the mass flow rate of the aqueous solution is fed through the channel located behind the first, in the direction of the solution’s narrowing, through the channel located behind the second, in the direction of the solution’s narrowing nitrogen gas is supplied with a mass flow rate equal to 0.5% of the mass flow rate of the aqueous solution, nitrogen gas with a mass flow rate is fed through a channel located behind the third one in the direction of solution flow narrowing m, of 0.1% of the mass flow rate of the aqueous solution;
- by means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment is increased from 80 ° C to 85 ° C;
- during the cavitation treatment, the corrosion inhibitor element in solution is saturated with heavy nitrogen isotopes ¹⁵ N so that the ratio of the number of nitrogen isotopes ¹⁵ N to the total amount of nitrogen in the element is from 0.0001 to 0.1375;
- control the number of nitrogen isotopes ¹⁵ N carry out mass spectroscopy of high resolution;
- after repeated cavitation treatment of the solution, the corrosion inhibitor element is crystallized, for which 95.5% of water is evaporated from the aqueous solution;
- after cavitation treatment and crystallization of all the above elements of the corrosion inhibitor, they are mixed with the remaining components of the anti-icing material in the above percentage ratio;
- moreover, the cavitation treatment of the elements of the corrosion inhibitor is carried out in such a way that the percentage of carbon isotopes ¹³ C in each element of the corrosion inhibitor is the same and the percentage of nitrogen isotopes ¹⁵ N in each element of the corrosion inhibitor is the same. 4. A method of obtaining a solid anti-icing material, including uniform mechanical mixing between a crystalline salt of a food grade stone of first grade, crystalline calcium chloride technical calcined first grade, crystalline elements of a metal corrosion inhibitor, crystalline surfactant, crystalline acidity regulator, characterized in that sodium 2-ethylhexyliminodipropionate is used as a surfactant, as Your acidity regulator uses technical grade ammonium chloride, granular carbamide of the first grade, simple superphosphate Ca (H ₂ PO ₄ ) ₂ , magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ , sodium benzoate C ₆ H ₅ are used as elements of a metal corrosion inhibitor COONa, caprolactam C ₆ H ₁₁ NO, in the following ratio of components, wt.% Of the total number of components in the anti-icing material:
food grade table salt 51.0; calcium chloride technical calcined first grade 43.0 Sodium 2-ethylhexyliminodipropionate 0.10 first grade ammonium chloride 0.2 urea granular first grade 4.98 simple superphosphate Ca (H ₂ PO ₄ ) ₂ 0.02 magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ 0.27 sodium benzoate C ₆ H ₅ COONa 0.33 caprolactam C ₆ H ₁₁ NO 0.10
wherein the metal corrosion inhibitor is prepared as follows:
- each of the above corrosion inhibitor element is dissolved in distilled water so that the resulting aqueous solution contains one weight part of the corrosion inhibitor element and three weight parts of distilled water;
- further, the resulting aqueous solution of each element of the corrosion inhibitor is subjected to cavitation treatment in a reactor installation, while the reactor installation contains a solution tank with a thermometer and a heat exchanger, an electric gear pump, a cavitation reactor, and the tank is connected by a pipe to the pump inlet, the pump outlet is connected by a pipeline with the inlet of the cavitation reactor, the outlet of the cavitation reactor is connected by a pipeline to the tank, and at the entrance to the cavitation reactor and exit from the cavitation a reactor disposed pressure gauges to determine the pressure drop across the cavitation reactor,
and the cavitation reactor contains a channel for the movement of the aqueous solution, and the channel, in the direction of movement of the aqueous solution, contains three constrictions, the area of the passage section of the channel at the point of each narrowing is 8% of the maximum passage area of the channel, and an adjustable height is located before each narrowing of the channel a rod, turbulent flow before the narrowing of the channel, behind each narrowing in the body of the cavitation reactor there is a channel for supplying carbon dioxide or nitrogen to the region of cavitation of the reactor;
- for cavitation treatment, the resulting aqueous solution of each element of the corrosion inhibitor is poured into the capacity of the reactor installation, heated to 60 ° C and pumped from 170 to 720 times through the cavitation reactor by means of a gear pump;
- during cavitation processing, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the location of the rod;
- in addition, in the process of cavitation treatment through the channel located behind the first, in the direction of movement of the solution by constriction, carbon dioxide is supplied with a mass flow rate equal to 2% of the mass flow rate of the aqueous solution, through the channel located behind the second, in the direction of movement of the solution by constriction carbon dioxide is supplied with a mass flow rate equal to 1% of the mass flow rate of an aqueous solution, carbon dioxide with a mass flow rate equal to 0 is supplied through a channel located behind the third one in the direction of movement of the solution by constriction. 5% of the mass flow rate of an aqueous solution;
- by means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment is increased from 60 ° C to 75 ° C;
- during cavitation treatment, the corrosion inhibitor element in solution is saturated with ¹³ C heavy isotopes so that the ratio of ¹³ C carbon isotopes to the total amount of carbon in the element is from 0.005 to 0.75;
- control of the amount of carbon isotopes ¹³ C is carried out by high resolution mass spectroscopy;
- further, the resulting aqueous solution of the above-mentioned element of the corrosion inhibitor is subjected to repeated cavitation treatment in a reactor installation, for which the aqueous solution located in the tank is heated to 80 ° C and pumped from a cavitation reactor 50 to 390 times through a gear pump;
- during cavitation processing, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the location of the rod;
- in addition, in the process of cavitation treatment through the channel located after the first, in the direction of movement of the solution by constriction, gaseous nitrogen is supplied with a mass flow rate equal to 1% of the mass flow rate of the aqueous solution, through the channel located behind the second, in the direction of movement of the solution by constriction, nitrogen gas is supplied with a mass flow rate equal to 0.5% of the mass flow rate of an aqueous solution, nitrogen gas with a mass flow rate is fed through a channel located behind the third one in the direction of solution flow narrowing to 0.1% of the mass flow rate of the aqueous solution;
- by means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment is increased from 80 ° C to 85 ° C;
- during the cavitation treatment, the corrosion inhibitor element in solution is saturated with heavy nitrogen isotopes ¹⁵ N so that the ratio of the number of nitrogen isotopes ¹⁵ N to the total amount of nitrogen in the element is from 0.0001 to 0.1375;
- control the number of nitrogen isotopes ¹⁵ N carry out mass spectroscopy of high resolution;
- after repeated cavitation treatment of the solution, the corrosion inhibitor element is crystallized, for which 95.5% of water is evaporated from the aqueous solution;
- after cavitation treatment and crystallization of all the above elements of the corrosion inhibitor, they are mixed with the remaining components of the anti-icing material in the above percentage ratio;
- moreover, the cavitation treatment of the elements of the corrosion inhibitor is carried out in such a way that the percentage of carbon isotopes ¹³ C in each element of the corrosion inhibitor is the same and the percentage of nitrogen isotopes ¹⁵ N in each element of the corrosion inhibitor is the same. 5. A method of obtaining a solid anti-icing material, comprising uniform mechanical mixing between each other of crystalline salt of food grade stone first grade, crystalline calcium chloride technical calcined first grade, crystalline elements of a metal corrosion inhibitor, crystalline surfactant, crystalline acidity regulator, characterized in that sodium 2-ethylhexyliminodipropionate is used as a surfactant, as Your acidity regulator uses first-class technical ammonium chloride, granular urea first grade, calcium nitrate Ca (NO ₃ ) ₂ , magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ , sodium benzoate C ₆ H ₅ COONa, caprolactam are used as elements of a corrosion inhibitor C ₆ H ₁₁ NO, in the following ratio of components, wt.% Of the total number of components in the anti-icing material:
food grade table salt 51.0 calcium chloride technical calcined first grade 43.0 Sodium 2-ethylhexyliminodipropionate 0.10 first grade ammonium chloride 0.2 urea granular first grade 4.98 calcium nitrate Ca (NO ₃ ) ₂ 0.02 magnesium dihydroorthophosphate Mg (H ₂ PO ₄ ) ₂ 0.27 sodium benzoate C ₆ H ₅ COONa 0.33 caprolactam C ₆ H ₁₁ NO 0.10
wherein the metal corrosion inhibitor is prepared as follows:
- each of the above corrosion inhibitor element is dissolved in distilled water so that the resulting aqueous solution contains one weight part of the corrosion inhibitor element and three weight parts of distilled water;
- further, the resulting aqueous solution of each element of the corrosion inhibitor is subjected to cavitation treatment in a reactor installation, while the reactor installation contains a solution tank with a thermometer and a heat exchanger, an electric gear pump, a cavitation reactor, and the tank is connected by a pipe to the pump inlet, the pump outlet is connected by a pipeline with the inlet of the cavitation reactor, the outlet of the cavitation reactor is connected by a pipeline to the tank, and at the entrance to the cavitation reactor and exit from the cavitation a reactor disposed pressure gauges to determine the pressure drop across the cavitation reactor,
and, the cavitation reactor contains a channel for the movement of the aqueous solution, and the channel, in the direction of movement of the aqueous solution, contains three constrictions, the area of the passage section of the channel at the point of each narrowing is 8% of the maximum passage area of the channel, and before each channel narrowing is located adjustable the height of the rod, turbulent flow before the narrowing of the channel, behind each narrowing in the body of the cavitation reactor there is a channel for supplying carbon dioxide or nitrogen to the cavitation area of the reactor;
- for cavitation treatment, the resulting aqueous solution of each element of the corrosion inhibitor is poured into the capacity of the reactor installation, heated to 60 ° C and pumped from 170 to 720 times through the cavitation reactor by means of a gear pump;
- during cavitation processing, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the location of the rod;
- in addition, in the process of cavitation treatment through the channel located behind the first, in the direction of movement of the solution by constriction, carbon dioxide is supplied with a mass flow rate equal to 2% of the mass flow rate of the aqueous solution, through the channel located behind the second, in the direction of movement of the solution by constriction carbon dioxide is supplied with a mass flow rate equal to 1% of the mass flow rate of an aqueous solution, carbon dioxide with a mass flow rate equal to 0 is supplied through a channel located behind the third one in the direction of movement of the solution by constriction. 5% of the mass flow rate of an aqueous solution;
- by means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment is increased from 60 ° C to 75 ° C;
- during cavitation treatment, the corrosion inhibitor element in solution is saturated with ¹³ C heavy isotopes so that the ratio of ¹³ C carbon isotopes to the total amount of carbon in the element is from 0.005 to 0.75;
- control of the amount of carbon isotopes ¹³ C is carried out by high resolution mass spectroscopy;
- further, the resulting aqueous solution of the above-mentioned element of the corrosion inhibitor is subjected to repeated cavitation treatment in a reactor installation, for which the aqueous solution located in the tank is heated to 80 ° C and pumped from a cavitation reactor 50 to 390 times through a gear pump;
- during cavitation processing, the height of each of the adjustable rods is set so that it covers 4-5% of the cross-sectional area of the channel at the location of the rod;
- in addition, in the process of cavitation treatment, nitrogen gas with a mass flow rate equal to 1% of the mass flow rate of the aqueous solution is fed through the channel located behind the first, in the direction of the solution’s narrowing, through the channel located behind the second, in the direction of the solution’s narrowing nitrogen gas is supplied with a mass flow rate equal to 0.5% of the mass flow rate of the aqueous solution, nitrogen gas with a mass flow rate is fed through a channel located behind the third one in the direction of solution flow narrowing m, of 0.1% of the mass flow rate of the aqueous solution;
- by means of a gear pump, the pressure drop across the cavitation reactor is maintained in the range from 7.5 ⁵ Pa to 8 · 10 ⁵ Pa, the temperature of the solution in the tank during cavitation treatment is increased from 80 ° C to 85 ° C;
- during the cavitation treatment, the corrosion inhibitor element in solution is saturated with heavy nitrogen isotopes ¹⁵ N so that the ratio of the number of nitrogen isotopes ¹⁵ N to the total amount of nitrogen in the element is from 0.0001 to 0.1375;
- control the number of nitrogen isotopes ¹⁵ N carry out mass spectroscopy of high resolution;
- after repeated cavitation treatment of the solution, the corrosion inhibitor element is crystallized, for which 95.5% of water is evaporated from the aqueous solution;
- after cavitation treatment and crystallization of all the above elements of the corrosion inhibitor, they are mixed with the remaining components of the anti-icing material in the above percentage ratio;
- moreover, the cavitation treatment of the elements of the corrosion inhibitor is carried out in such a way that the percentage of carbon isotopes ¹³ C in each element of the corrosion inhibitor is the same and the percentage of nitrogen isotopes ¹⁵ N in each element of the corrosion inhibitor is the same.

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