RU2576267C1 - Method for combined effect on formations containing hydrocarbons and/or solid organic substances and device for implementing said method - Google Patents

Abstract

FIELD: oil and gas industry.

SUBSTANCE: group of inventions relates to oil and gas industry. Method for action on productive formations containing hydrocarbons and/or solid organic substance involves formation of working agent represented by water, which is mainly in supercritical state (SC-water), and subsequent spontaneous injecting working agent in productive formations. Working agent is formed on surface of well in ground generator of SC-water containing unit for enrichment of formed SC-water with exothermal oxidation catalyst. Working agent enriched with said catalyst is supplied via product with insulation in well and/or downhole zone of exothermic oxidation reactions in SC-water, wherein well and/or downhole fed by separate product lines reactants - organic compounds and organic compounds oxidising agent, providing additional heating and additional pressure increase above pre-formed working fluid due to exothermic oxidation reactions in SC-water to produce carbon dioxide (CO₂), in a supercritical state, then finally formed spontaneous working agent is injected into formation.

EFFECT: technical result of intensification of production of deep natural bitumen and heavy oil and oil low-permeable rocks, as well as for in-bed generation synthetic hydrocarbons from solid organic substance - kerogen.

11 cl, 2 dwg

Description

The invention relates to the oil and gas industry and can be used to intensify the production of deep-lying natural bitumen, heavy oils and low-permeability oil due to their in-situ molecular modification, increase in internal energy and permeability of productive formations, and can also be used for in-situ generation of synthetic hydrocarbons from solid organic substances - kerogen.

In recent years, systematic studies of the behavior of water simultaneously at high temperatures and pressures (supercritical water - SC-water) have begun to attract attention in connection with the actualization of the possibility of significant practical applications of SC-water. First of all, interest in SK-water is caused by the possibility of efficiently carrying out high-temperature exothermic oxidation reactions of organic compounds, for example, hydrocarbons in SK-water. This is the so-called process of supercritical water oxidation (SCWO). And, indeed, upon the transition of water to a supercritical state (temperature T> 374 ° C, pressure P> 22.1 MPa), hydrogen bonds are destroyed, the ionic product of water decreases by orders of magnitude, and the dielectric constant decreases from 80 to 10 ÷ 2. This leads to the fact that the solubility of many organic substances and gases in SC water becomes unlimited, and the solubility of inorganic salts and acids, on the contrary, is negligible. In a significant range of supercritical temperature values, the density of SC water can also be changed, in fact, from the density of the gas to the density of liquid water. Today, there are already existing industrial plants for generating SK-water, in the reactors of which chemical warfare agents, poisons, industrial and household organic waste are destroyed. Also, the identified properties of SC water are already used in the energy sector of the economy, in particular, in the oil and gas industry, for example, to generate electrical energy in the process of utilizing oil sludge in SK water.

It is known to use the properties of SK water in a method of coal gasification to produce hydrogen and synthesis gas, which consists in opening a coal seam with boreholes and forming an underground gas generator, igniting an underground gas of a generator, gasing a coal seam, monitoring the main technological and hydrological parameters, and controlling them discharge from the underground gas generator of the outgoing gases, while the prepared suspension of powdered aluminum is fed into the combustion zone of the underground gas generator in aqueous medium with a ratio of Al: H ₂ O = 1: 4-5 weight. hours with water in a ratio of 1: 50-100 weight. including under pressure P, which provides conditions for the supercritical state of water in the combustion zone, taking into account the depth H of the underground gas generator (RF patent No. 2354820, IPC EV 43/295, 2009 publication).

The known method cannot be used to intensify oil production and / or in-situ generation of synthetic oil from solid organic substances for the following reasons.

Hydrocarbon-bearing productive formations located at a depth of more than 2000 meters, the in-situ pressure of which can exceed 22.1 MPa, which is one of the necessary conditions for the existence of SC water, is usually characterized by very low permeability. So, for example, the bulk of the hydrocarbons of the Bazhenov formation are concentrated in a reservoir with an average pore radius of 8-25 nm (A. Khavkin. Nanotechnologies in gas oil production / edited by Corresponding Member of the Russian Academy of Sciences G.K.Safaraliev // M., Oil and gas, 2008, 171 pp.). That is why, due to their large sizes, aluminum particles (more than 40 microns) used in the known method cannot penetrate into the pore space and / or the space of fluid-conducting channels of productive formations. If this happens, sooner or later, they (particles of aluminum and / or alumina) will collect / clog the near-bore fluid-conducting channels of the reservoir, which will cause the flow of hydrocarbons from the reservoir to stop flowing into the well. The use of aluminum nanoparticles (less than 25 nm) is not economically feasible due to the very high cost of aluminum nanopowder.

In addition, based on the fact that the calorific value of aluminum is 3900 kcal / kg, for the generation of thermal energy in the well and / or downhole of the well, for example, equal to 5 MW / h, which are minimally necessary for effective heat treatment of hydrocarbon-containing reservoirs , it will be required every hour to oxidize 1103 kg of aluminum powder in SK-water in the well and / or at the bottom of the well, which is technically practically impossible, but from an economic point of view, it is also impractical.

A known method and device for drilling deep geothermal wells using SK water in solid crystalline rocks, for example, in granite. The method consists in using the exothermic reaction of the oxidation of organic compounds in SK water at the bottom of the well (more than 2500 meters) for drilling a well by hydrothermal peeling of solid crystalline rocks (US patent No. 2011303460, IPC ЕВВ 7/14, publication 2011).

The construction of the known device is shown in FIG. 1, which is a cited illustration (Fig. 3A), given in US patent document No. 2011303460, explaining the design and principle of operation of the known device.

The known device includes a product pipeline (104) for feeding reactant No. 1 to a well bottom, a product pipeline (105) for supplying reactant No. 2 to a well bottom, an electric cable (107), a preheating unit (109) of reacting substances No. 1 and No. 2 to the temperature of initiation of the exothermic oxidation reaction of organic compounds in SK-water, a mixing unit for preheated reactants No. 1 and No. 2 for the exothermic reaction of oxidation of organic compounds in SK-water.

The principle of operation of the known device is as follows:

- reacting substances No. 1 and No. 2 are supplied to the known device through product pipelines (104) and (105);

- passing through the preheating unit (109), the reacting substances No. 1 and No. 2 are heated to the temperature of the initiation of the exothermic oxidation of organic compounds in SC water;

- further, preheated reactants No. 1 and No. 2 enter the mixing unit (112);

- from the mixing unit, the high-temperature mixture, consisting of reactants No. 1 and No. 2, then enters the zone (102) of the high-temperature exothermic oxidation of organic compounds in SC water, where the exothermic hydro-flame oxidation reaction (combustion with the formation of a flame) of the organic compound takes place (in this case, methanol) in SK-water.

Thus, a high temperature is generated at the bottom of the well, which is a prerequisite for the implementation of the drilling process of solid crystalline rocks by hydrothermal peeling.

The known invention, intended for drilling deep geothermal wells in solid crystalline rocks, does not have the necessary power to generate thermal energy in the well and / or in the bottom of the well in an amount sufficient to effectively affect formations containing hydrocarbons and / or solid organic matter, in connection with which it cannot be used to affect formations containing hydrocarbons and / or solid organic substances.

A known method of developing an oil deposit by placing injection and production wells, injecting into the injection wells air, water, combustion gases extracted from the production of production wells, and selecting oil, combustion gases and associated petroleum gases from the production wells, is preliminarily injected into injection wells coolant to warm the formation to a temperature of at least 65 ° C in the vicinity of the well with a radius of 5-20 m, a portion of hot water is pumped in alternation with an oil solvent weighing 5-150 tons per 1 m of power of the productive interval, they pump air with a mass of 0.01-0.2 of the total weight of the injected water and pump the heated air-water mixture, and the water-air ratio at a reservoir pressure of less than 22.064 MPa is determined from the given ratio (RF patent No. 2403383, MPKE 21 V 43 / 24, 2010 publication - closest equivalent).

The known method has the following disadvantages:

1. The burning of some valuable hydrocarbons (HC). To heat the reservoir, oxidation / burning of some part of the in-situ oil contained in it is of high cost, and for the extraction of which, in fact, the production process is organized. So, to heat 1 m ^{3 of the} reservoir to a temperature of 400 ° C, an energy of approximately 850 thousand kJ is required. It is known that the heat of combustion of an average viscosity oil is approximately 45 thousand kJ / kg.

Therefore, to heat 1 m ^{3 of the} reservoir to a temperature of 400 ° C, it is necessary to oxidize / burn 18.9 kg of in-situ oil. It is also known that, as a result of thermal exposure to the productive formations of the Bazhenov Formation, it is possible to extract from 1 m ³ from 50 to 80 kg of both low-permeability oil and synthetic oil generated from kerogen. Thus, as a result of using the known method, the volume of total recoverable oil is reduced by 24-38%, respectively, from 32 to 62 kg / m ³ .

2. Coke formation. The temperature of the formation in the zone of in-situ oxidative reactions can reach 650 ° C. At this temperature, active coke formation occurs in the reservoir. Coke clogs fluid-conducting channels, which leads to a decrease in the efficiency of the known method.

3. Low predictability and manageability. In reservoir conditions, it is difficult to predict exactly what the temperature in the zone of oxidative reactions is at a given time. This complicates the process of deciding when to start pumping warm water or a water-air mixture to form SK-water in the formation. Given the high heterogeneity of the productive formations of the Bazhenov Formation and the undetermined zonal concentrations of oil and kerogen in them, an accurate calculation of the temperature in the formation and determining the start of the injection of water or a water-air mixture into the formation is practically impossible. The result of low predictability and low controllability of the known method is that at some points in time the reservoir can either overheat or not reheat, which, in general, leads to a decrease in the efficiency of the known method.

4. Displacement and oil production through an area with unchanged low natural permeability. In the known method, two wells are used - injection and production. From the current level of technology it is known that as a result of heat exposure, the permeability of the reservoir increases. But this effect is not used in the known method, since oil is displaced from the injection well into the side of the producing well through the reservoir zone with unchanged low natural permeability. This method of organizing oil production - thermal flooding - is ineffective in low-permeable productive formations of the Bazhenov formation.

5. The use of two or more wells. In the known method, several wells are used - one injection and at least one producer. This leads to an increase in capital investment and, accordingly, to an increase in the cost of oil production.

6. Use of hydrocarbon solvents. The use of hydrocarbon solvents, especially such as diesel fuel, oil distillate or a wide fraction of light hydrocarbons increases the cost of oil production and leads to a decrease in the economic efficiency of the known method, since some of the hydrocarbon solvents injected into the reservoir (up to 50%) become non-recoverable and remain in the reservoir.

The aim of the invention is to develop a method of combined exposure to productive formations containing hydrocarbons and / or solid organic substances, including a method of forming a working agent of impact on productive formations by using the high-temperature exothermic oxidation reaction of organic compounds in SC water, as well as creating a device for implementing this combined method.

The technical result obtained by carrying out the invention consists in generating additional thermal energy in the well and / or in the bottom of the well necessary for the final formation of the working agent, further used as for intensifying hydrocarbon production, in-situ generation of synthetic hydrocarbons from solid organic matter, for example, kerogen, and to increase the permeability of productive formations at the macro, meso and micro levels, including through the implementation of thermohydrogasocatalite rupture of reservoirs.

The essence of the proposed technical solution is as follows.

The method of exposure to productive formations containing hydrocarbons and / or solid organic substances includes the formation of a working agent, which is used as water, which is mainly in a supercritical state (SK-water), and subsequent spontaneous injection of the working agent into productive formations, while working the agent is preliminarily formed on the day surface of the well in a surface SK-water generator containing an enrichment unit for the generated SK-water with an exothermic oxidation catalyst then the working agent enriched with the indicated catalyst is fed through the product pipeline with thermal insulation to the well and / or to the bottom of the well into the zone of the exothermic oxidation reaction in SK-water. Reactants — organic compounds and an oxidizing agent of organic compounds — are supplied to the well and / or to the bottom of the well, providing additional heating and an additional pressure increase of the above preformed working agent due to the exothermic oxidation reaction in SC water with the formation of carbon dioxide (CO ₂ ), which is in a supercritical state, then the finally formed working agent is spontaneously injected into the formation.

The catalyst can be made either in the form of ultra-sized particles (more than 100 nanometers (nm)) of metals and / or their oxides, or in the form of nanosized particles (less than 100 nm) of metals and / or their oxides, either in molecular form or in ionic form or in atomic ion form.

The catalyst may be in the form of a composition comprising catalysts in the form of ultra-sized particles of metals and / or their oxides, and / or in the form of nanosized particles of metals and / or their oxides, and / or in molecular form, and / or in ionic form, and / or in atomic ion form, or in any combination thereof.

Hydrocarbons, for example, methanol (CH ₃ OH), are used as organic compounds.

As an oxidizing agent of organic compounds, air or oxygen O ₂ or hydrogen peroxide H ₂ O _{2 is used} .

The essence of the proposed technical solution also lies in creating a device for forming a working agent for acting on formations containing hydrocarbons and / or solid organic substances. The device comprises a surface generator for generating a working agent in the form of water, which is mainly in a supercritical state (SK-water), a high-temperature packer, a product pipeline with thermal insulation for delivery to the well and / or bottom hole of a worker previously formed on the day surface of the well with a ground generator of SK-water working agent, and product pipelines for delivery to the well and / or downhole of the reacting substances in the form of organic compounds and an oxidizing agent of organic compounds, while SC-water generator node features enrichment formed on the surface of the well working fluid catalytic exothermic oxidation reaction.

To generate a working agent in a ground-based SK-water generator, heat-generating devices operating on various types of fuel are used, including nuclear fuel, for example, thorium reactors.

As a thermal insulation for the product delivery pipeline to the well and / or to the bottom of the well, the working agent preformed on the day surface of the well by the ground water generator SK-water uses ultra-thin liquid thermal insulation based on aluminosilicate and / or ceramic ultra-thin microspheres that can work for a long time in the presence of high temperatures ( up to 600 ° C).

The heat-insulated product pipeline is an assembly of tubing made of heat-resistant and corrosion-resistant steels, equipped with thermal insulation and connected by couplings.

Product pipelines for supplying reactive substances in the form of organic compounds and an oxidizing agent of organic compounds to the well and / or to the bottom of the well are assembled from separate pipe segments made of corrosion-resistant stainless steel, connected by couplings, or made of a long clutchless pipe.

To form a low-temperature sub-packer zone, a Rank-Hillsch tube is used, which is connected to a heat-insulated product pipeline and delivers a cooled working agent preformed on the day surface of the well to the sub-packer zone.

The claimed invention provides:

- the temperature of the finally formed working agent in the well and / or at the bottom of the well from 374 to 600 ° C.

- the pressure of the finally formed working agent for the implementation of thermohydrogasocatalytic effects on formations containing hydrocarbons and / or solid organic substances, from 22.1 to 50 MPa;

- the pressure of the finally formed working agent for the implementation of the physical thermohydro-gas-catalytic effects on the reservoir (fracturing) from 50 to 150 MPa;

- the high-temperature high-pressure working agent finally formed in the well and / or at the bottom of the well contains a catalyst and carbon dioxide;

- the temperature range of the thermal insulation used for the product pipeline with thermal insulation is from 500 to 600 ° C;

- the thermal conductivity coefficient of the thermal insulation used for the product pipeline with thermal insulation can vary from 0.0012 W / (m ∙ K) to 0.05 W / (m ∙ K);

- the total thermal power generated by the claimed device, both on the day surface of the well, and in the well and / or on the bottom of the well - based on one well from 1 to 100 MW;

- the temperature in the under-packer zone is less than 350 ° C. The attached figures show:

in FIG. 1 - presents a known device according to US patent document No. 2011303460;

in FIG. 2 - presents the claimed device; The device shown schematically in FIG. 2 includes:

- ground generator 1 SK-water, equipped with an enrichment unit (not shown), a catalyst of a preformed working agent 2 in the form of SK-water;

- a feed device 3 into the well and / or downhole of the well of organic compounds (reactant 4), in the preferred embodiment, hydrocarbons, for example methanol;

- a feed device 5 into the well and / or to the bottom of the well of the oxidizing agent (reactant 6), preferably air, oxygen or hydrogen peroxide;

- a product pipeline 7 with thermal insulation for delivery to the well and / or to the bottom of the well of the working agent 2 previously formed by the ground generator 1 of SK water in the form of SK water enriched with a catalyst;

- product pipeline 8 for delivery to the well and / or downhole of the reactant 4;

- product pipeline 9 for delivery to the well and / or to the bottom of the well of the reactant 6;

- special high-temperature packer 10;

- a Rank-Hilsch tube 11 for local cooling of the under-packer zone 12. The tube 11 is connected to the product pipe 7 with thermal insulation for delivery to the well and / or bottom hole of the working agent 2 previously formed by the ground generator 1 SK-water in the form of SK-enriched catalyst ;

- a locking device 13 for reducing the penetration rate of the high-temperature preformed working agent 2 and the ultra-high-temperature preformed working agent 14 or their mixture 2, 14 from the borehole and / or bottomhole zone 15 of the exothermic oxidation of organic compounds in SK water into the low-temperature sub-packer zone 12 .

The claimed method of forming a working agent is carried out through the use of the claimed device, which operates as follows (Fig. 2).

1. The ground generator 1 of SK-water pre-generates a working agent - SK-water, for example, with the following characteristics: T = 500 ° C, P = 30 MPa and ρ = 115.07 kg / m ³ .

2. In the enrichment unit of the ground-based generator 1 SK-water, a preformed working agent is enriched with a catalyst for an exothermic oxidation reaction.

3. The working agent 2, enriched with the catalyst, is fed through the product pipeline 7 with thermal insulation to the well and / or to the bottom of the well into the zone 15 for the exothermic oxidation of organic compounds in SK water.

4. The device 3 through the product pipeline 8 delivers into the well and / or bottomhole reactant 4.

5. The device 5 through the product pipeline 9 delivers a reactive substance 6 into the well and / or to the bottom of the well.

6. Due to heat losses, which in the case of the use of a heat-insulated product pipeline reach approximately 10% for every 1000 running meters of transportation of the working agent, and some loss of friction pressure, the working agent 2, preformed by the ground water generator 1 of SK-water, is enriched the catalyst and delivered through the product pipeline 7 with thermal insulation to the borehole and / or bottomhole zone 15 of the well to a depth of 2300 meters, has, for example, the following design characteristics: T = 400 ° C, P = 25 MPa and ρ = 166.54 kg / m ³ . These thermobaric characteristics of the working agent 2 correspond to the required and necessary conditions for the implementation of the exothermic oxidation reaction of organic compounds in SC water.

7. Then, in the zone 15 for the exothermal reaction of the oxidation of organic compounds in SC water from product pipelines 8 and 9 at the same time (one of the possible options), reactants 4 and 6 come in, which are mixed in SK water and are the main participants in the exothermic reaction of organic compounds in SK-water, enter into an exothermic oxidation reaction of organic compounds in SK-water - in the environment of a preformed working agent 2. The trajectory of the oxidation reaction, for example, methanol, in SK-water is schematic but it looks like this:

8. The presence of catalysts and / or any possible compositions in SC water promotes the efficiency of the exothermic oxidation reaction, which mainly involves organic compounds and an oxidizing agent of organic compounds, and, under favorable thermobaric conditions, can also take part as a reacting substance SK water itself.

9. As a result of the exothermic reaction of the oxidation of organic compounds in SK water, which is both a working agent preformed on the day surface of the well, carbon dioxide (CO ₂ ) is formed, which, enriching the working agent with its presence, under the considered pressure and pressure characteristics of the working agent ( the pressure is equal to or greater than 22.064 MPa and the temperature is equal to or greater than 373.95 ° C) is in a supercritical state.

10. As a result of the exothermic reaction of the oxidation of organic compounds in SC water, of which reactants 4 and 6 were participants, heat is generated (for methanol, for example, at T = 400 ° C, P = 25 MPa and a methanol concentration of 0.55 mol / liter of water - 474 kJ / mol), and the reaction products are mainly water (H ₂ O) and carbon dioxide (CO ₂ ).

11. Thus, as a result of the exothermic reaction of the oxidation of organic compounds in SC water, the preformed working agent 2 is additionally enriched with carbon dioxide, and its temperature and pressure increase to 500 ° C and 30 MPa, respectively. The process of the final formation of the working agent 16 is completed.

12. The finally formed working agent 16 from the zone 17 of the final formation of the working agent through the perforated holes in the casing or the downhole filter 18 is spontaneously injected into the reservoir 19.

13. To form a low-temperature sub-packer zone 12, the claimed device uses a Rank-Hillsha tube 11, which delivers a cooled preformed working agent 20 to the sub-packer zone 12, and, through a clogging device 13, delivers an ultrahigh-temperature to the zone of the exothermic oxidation of organic compounds in SK water preformed working agent 14.

14. To reduce the penetration rate of the preformed working agent 2 and the ultra-high temperature preformed working agent 14 or their mixture 2, 14 into the low-temperature under-packer zone 12, the inventive device uses a clogging device 13, which is preferably made of high-temperature heat-resistant silica dense insulating material .

15. Qualitative and quantitative characteristics of the implementation of a particular exothermic oxidation reaction of organic substances in SC-water (kinetics of oxidation reactions), in the most general form, are determined by the thermobaric characteristics of SC-water, the volume of reactants 4 and 6 in SC-water, their physico-chemical properties, as well as a stoichiometric ratio of reactants 4 and 6 in SK water.

The result of using the inventive method of combined exposure (including thermal exposure, chemical exposure and physical exposure) on a reservoir containing hydrocarbons and / or solid organic substances, is: (a) increased mobility and drainage ability of liquid hydrocarbons; (b) molecular modification of liquid hydrocarbons — an irreversible decrease in their viscosity and density; (c) in-situ generation of synthetic hydrocarbons from solid organic matter, for example, kerogen; (c) substantial re-energization of the reservoir, and (e) increased permeability of the reservoir at the macro, meso and micro levels, including through the implementation of thermohydro-gas-catalytic fracture of the reservoir, which, as a whole, results in a significant increase in the recovery coefficient hydrocarbons.

Despite the fact that the present invention is described by the presented example, various modifications are possible, including modifications of the product piping configurations in the well, not contradicting the basic principles of the invention. Therefore, the present invention should be construed as relating to any such modifications within the spirit of the invention.

Claims (11)

1. The method of exposure to productive formations containing hydrocarbons and / or solid organic substances, including the formation of a working agent, which is used as water, which is mainly in a supercritical state (SC-water), and subsequent spontaneous injection of a working agent into productive formations, characterized the fact that the working agent is preliminarily formed on the day surface of the well in a surface SK-water generator containing an enrichment unit for the generated SK-water with an exothermic catalyst oxidation reaction, after which the working agent enriched by the specified catalyst is fed through the product pipeline with thermal insulation to the well and / or to the bottom of the well into the zone of the exothermic oxidation reaction in SK-water, while reacting to the well and / or bottom of the well through separate product pipelines substances - organic compounds and an oxidizing agent of organic compounds, providing additional heating and an additional increase in pressure of the above preformed working agent due to exothermic oxidation reaction in SC water with the formation of carbon dioxide (CO ₂ ) in a supercritical state, then the finally formed working agent is spontaneously injected into the formation. 2. The method according to p. 1, characterized in that the catalyst is made either in the form of ultra-sized particles (more than 100 nanometers (nm)) of metals and / or their oxides, or in the form of nanoscale particles (less than 100 nm) of metals and / or their oxides either in molecular form, or in ionic form, or in atomic-ionic form. 3. The method according to p. 1, characterized in that the catalyst is made in the form of a composition comprising catalysts in the form of ultra-sized particles of metals and / or their oxides, and / or in the form of nanosized particles of metals and / or their oxides, and / or in molecular form, and / or in ionic form, and / or in atomic-ionic form, or in any combination thereof. 4. The method according to p. 1, characterized in that the organic compounds used are hydrocarbons, for example, methanol (CH ₃ OH). 5. The method according to p. 1, characterized in that as the oxidizing agent of organic compounds use air or oxygen O ₂ , or hydrogen peroxide H ₂ O ₂ . 6. A device for forming a working agent for acting on formations containing hydrocarbons and / or solid organic substances, characterized in that it contains a surface generator for forming a working agent in the form of water, which is mainly in a supercritical state (SK-water), a high-temperature packer, heat-insulated product pipeline for delivery to the well and / or to the bottom of the well of the working agent preformed on the day surface of the well with the ground water generator SK-water, and product pipelines for delivering reactive substances in the form of organic compounds and an oxidizing agent of organic compounds to the well and / or to the bottom of the well, the ground-based SK-water generator is equipped with an enrichment unit for the exothermic oxidation catalyst formed on the day surface of the working agent well. 7. The device according to claim 6, characterized in that for generating a working agent in the ground SK-water generator, heat-generating devices operating on various types of fuel are used, including nuclear fuel, for example, thorium reactors. 8. The device according to claim 6, characterized in that an ultrathin liquid thermal insulation based on aluminosilicate and / or ceramic is used as thermal insulation for the product delivery line to the well and / or to the bottom of the well pre-formed on the day surface of the well by the surface agent of the SK-water of the working agent ultrafine microspheres, capable of working for a long time in the presence of high temperatures (up to 600 ° C). 9. The device according to p. 6, characterized in that the product pipeline with thermal insulation is an assembly of tubing made of heat-resistant and corrosion-resistant steels equipped with thermal insulation and connected by couplings. 10. The device according to claim 6, characterized in that the product pipelines for supplying reactive substances in the form of organic compounds and an oxidizing agent of organic compounds to the well and / or to the bottom of the well are assembled from separate pipe segments made of corrosion-resistant stainless steel connected by couplings or made of long sleeveless pipe. 11. The device according to claim 6, characterized in that for the formation of a low-temperature sub-packer zone, a Rank-Hills tube is used, which is connected to the product pipe with thermal insulation and delivers a cooled working agent preformed on the day surface of the well to the sub-packer zone.

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