RU2375042C1 - Perfume composition, containing combination of filter of hydroxyaminobenzophenone type, filter b of cinnamate type, and compound c of piperidinol, benzotriazole or dibenzoylmethane type - Google Patents

Abstract

FIELD: cosmetology.

SUBSTANCE: invention is related to perfume-cosmetic field, namely to perfume composition, which includes the following components in cosmetically acceptable medium: a) at least 2 wt % of fragrant substance of the overall mass of composition; b) at least one filter A of hydroxyaminobenzophenone type; c) at least one filter B of cinnamate type; d) at least one compound C selected from the following: i) compound of piperidinol type; ii) at least one compound of benzotriazole type; iii) UV-filter of dibenzoylmethane type.

EFFECT: invention makes it possible to produce perfume products, which have organoleptic properties, such as smell and colour, that remain stable with course of time and under action of light or temperature difference.

15 cl, 13 ex

Description

The invention relates to a perfume composition comprising in a cosmetically acceptable medium:

a) at least 2 wt.% fragrance of the total weight of the composition;

b) at least one hydroxyaminobenzophenone type filter A of formula (I), which is described in more detail below;

c) at least one cinnamate type filter B;

d) at least one compound C selected from:

i) a piperidinol type compound of formula (II), which is described in more detail below;

ii) at least one benzotriazole type compound of formula (III), which is described in more detail below;

iii) a dibenzoylmethane type UV filter.

It is known that perfumes are a combination of various odorous substances that evaporate at different periods of time. Each perfume has what is called a “head note”, the smell of which spreads first when the perfume is applied or when the container containing the perfume is opened, a “middle or main note” that corresponds to the smell of whole perfumes (odor spreads within a few hours after the “head note” ”) And a“ final note ”, which has the most persistent odor (odor spreads within a few hours after the“ middle note ”). The persistence of the final note corresponds to the residual aromatic substance.

A person constantly strives to use perfume products and aromatizes the objects around him or his place of residence in order to eliminate strong and / or unpleasant odors and create a pleasant aroma.

It is known to introduce perfumes into certain types of products or compositions, in particular into cosmetic or dermatological compositions, such as refreshing water, eau de toilette, perfume water, aftershave lotions, skin care water.

Perfume or perfume composition should have a pleasant smell and a constant color while the consumer is using this product. They must be resistant to certain aggressive influences, such as light and temperature differences.

Typically, a filtering and / or antioxidant system is also added. However, some filter systems are ineffective and / or tend to lose the desired color and / or smell.

Most perfumes contain stabilizers, such as UVA filters or UVB filters, and antioxidants.

Stabilizers are designed to preserve the organoleptic properties of products that are stable to various aggressive conditions, such as UV radiation and thermal shock. Stabilizing agents are known in the art as agents that improve the stability of these products with respect to said aggressive effects.

From the international application WO2005 / 123013, a combination of diethylaminohydroxybenzoylhexylbenzoate and ethylhexylmethoxycinnamate is known, marketed under the name Uvinul A + B, as a color stabilizer in perfume compositions.

From the international patent application WO2000 / 25730, it is also known to use Tinogard AS or “Bumetrizole” to eliminate the photolytic decomposition of cosmetic products, in particular fragrances.

From the international patent application WO2003 / 103622, it is also known to use Tinogard Q or “Tris (tetramethylhydroxypiperidinol) a” to stabilize fragrances, in particular toilet water.

International patent application WO 2005/042828 describes the combination of Tinogard Q with certain filters in order to stabilize fragrances and eliminate the decomposition of toilet water in the light.

Unfortunately, the UV filters or stabilizers proposed in the patent applications of the prior art are not completely satisfactory, especially with regard to unstable fragrances enriched with natural substances. Most often, there is a modification of organoleptic properties, such as, for example, smell and color, over time (which are assessed using sensory analysis such as a “sniff test” to determine odor, and using a visual test with the naked eye or using a spectrometer to quantitative assessment of color changes according to various parameters of color change depending on the effect of different light intensities). In particular, changes observed visually manifest themselves in mild yellowness or in a pinkish tint, which are associated with the decomposition of chemicals. It is also possible to note changes in the transparency of liquids, if they were initially transparent, changes that are expressed in fluctuations and precipitation of substances or in turbidity, which interfere with the appearance of products and can impair the effectiveness of nebulizers if the product is available in aerosol containers.

Thus, there is a need to develop new perfume products that would not have the disadvantages of prior art products, i.e. in the production of perfumes that have organoleptic properties, such as smell and color, would remain stable over time and under the influence of light or temperature difference.

The applicant unexpectedly discovered that this problem can be solved by using a perfume composition containing in a cosmetically acceptable medium:

a) at least 2 wt.% fragrance of the total weight of the composition;

b) at least one hydroxyaminobenzophenone type filter A of the specific formula (I), which is described in more detail below;

c) at least one cinnamate type filter B;

d) at least one compound C selected from:

i) a piperidinol type compound of the specific formula (II), which is described in more detail below;

ii) at least one benzotriazole type compound of the specific formula (III), which is described in more detail below;

iii) a dibenzoylmethane type UV filter.

This discovery was the basis of the invention.

The invention also relates to the use in cosmetics of a combination of at least one hydroxyaminobenzophenone type A filter of the specific formula (I), which is described in more detail below, at least one cinnamate type filter B and at least one compound C selected from:

i) a piperidinol type compound of the specific formula (II), which is described in more detail below;

ii) at least one benzotriazole type compound of the specific formula (III), which is described in more detail below;

iii) a dibenzoylmethane type UV filter;

in the composition of the perfume composition containing in a cosmetically acceptable medium, at least 2 wt.% fragrance; as a stabilizer of organoleptic properties, in particular the color and / or smell of the specified composition, in relation to external aggressive influences, such as light or temperature difference.

The invention also relates to a cosmetic method for the aromatization of human keratin substances, in particular the skin, lips, hair, scalp, lips, nails, comprising applying to the keratin substances the composition described above.

A perfume composition is understood to mean any composition that, after application to keratinous substances, leaves a scent.

By "fragrant substance" is meant any fragrance and aromatic substance capable of adding flavor to the skin and the keratinous substance of a person in general, including skin, hair, scalp, lips, nails.

The amount of aromatic substance (s) is preferably 3-50 wt.%, Better 5-30, even better 10-20 wt.%, Of the total weight of the composition.

By a cosmetically acceptable medium in a composition according to the invention is meant a non-toxic medium capable of being applied to human keratin substances, including skin, face, lips, nails, hair, scalp.

Fragrances and aromatic substances of natural or synthetic origin and mixtures thereof can be used as aromatic substances in the composition according to the invention. As fragrances and aromatic substances of natural origin can be called as an example, extracts of flowers (lily, lavender, rose, jasmine, ylang-ylang), stems and leaves (pichuli, geranium, petigrene), fruits (coriander, anise, cumin, juniper ), peel of fruits (bergamot, lemon, orange), roots (angelica, celery, cardamom, iris, calamus), wood (pine, sandalwood, guaiac wood, pink cedar), herbs and cereals (tarragon, lemongrass, sage, thyme ), needles and branches (spruce, fir, pine, dwarf pine), resins and ball amov (galbanum, elemi, benzoin tree, myrrh, olibana, opopanaksa).

As aromatic substances of synthetic origin, for example, compounds related to esters, ethers, aldehydes, ketones, aromatic alcohols and hydrocarbon compounds can be mentioned.

As the esters may be mentioned in particular, benzyl acetate, benzyl benzoate, fenoksietilizobutirat, p-tert-butiltsiklogeksilatsetat, tsitronellilatsetat, tsitronellilformiat, geranyl, linalyl acetate, dimetilbenzilkarbinilatsetat, feniletilatsetat, linalilbenzoat, benzilformiat, etilmetilfenilglitsinat, alkiltsiklogeksilpropionat, stiralilpropionat and benzyl salicylate.

As ethers, benzyl ethyl ether can be mentioned.

As aldehydes, mention may be made, for example, of linear alkanaldehydes containing 8-18 carbon atoms, citral, citronellal, citronyloxyacetaldehyde, cyclamenaldehyde, hydroxycytronellal, lilial and kidney aldehyde.

As ketones, mention may be made, for example, of ionones, such as alpha-isomethylionone and methylcetyl ketone.

Among the aromatic alcohols, in particular terpene alcohols, anethole, citronellol, eugenol, isoeugenol, geraniol, linalol, phenylethyl alcohol and terpineol can be mentioned.

As hydrocarbons, terpenes can be mentioned in particular. These compounds are often in the form of mixtures of two or more of these fragrance substances.

In addition, you can also use essential oils, components of aromatic substances, such as, for example, essential oils of sage, chamomile, pharmacy, clove, lemon balm, peppermint, oil from cinnamon leaves, linden, juniper, vetiver, oliban, galbanum, labolanum and lavender.

It is preferable to use, as an aromatic substance, individually or as a mixture, bergamot essential oil, dihydromyrceneol, lilial, lyral, citronellol, phenylethyl alcohol, alpha-hexylcinnamaldehyde, geraniol, besilacetone, cyclamenaldehyde, linalol, ambroxan, indole, gedol, lemon, mandarin and orange, allylamine glycolate, cyclovertal, lavender oil, sage oil, beta-adamascone, geranium oil, cyclohexyl salicylate, phenylacetic acid, geranyl acetate, benzyl acetate, rose oxide.

According to a preferred embodiment of the invention, a mixture of various aromatic substances is used, which together create a pleasant note for the user.

Famous olfactory notes include, for example, citrus scents, aromas of fragrances, floral scents, musky aromas, fruit scents, spicy scents, “oriental” scents, sea breeze notes, watery notes, chypre scents, woody scents, fern scents and their mixtures.

Compounds A of the hydroxyaminobenzophenone type corresponding to the invention correspond to the following general formula (I):

wherein:

R ₁ and R ₂ , the same or different, represent a hydrogen atom, C ₁ -C ₂₀ alkyl; C ₃ -C ₁₀ cycloalkyl or C ₃ -C ₁₀ cycloalkenyl, or form, together with the nitrogen atom to which they are connected, a 5 or 6 membered ring;

R ₃ is C ₁ -C ₂₀ alkyl.

As C ₁ -C ₂₀ alkyl radicals, for example, methyl, ethyl, n-propyl, 1-methylethyl, n-butyl, 1-methylpropyl, 2-methylpropyl, 1,1-dimethylethyl, n-pentyl, 1- methylbutyl, 2-methylbutyl, 3-methylbutyl, 2,2-dimethylpropyl, 1-ethylpropyl, n-hexyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4- methylpentyl, 1,1-dimethylbutyl, 1,2-dimethylbutyl, 1,3-dimethylbutyl, 2,2-dimethylbutyl, 2,3-dimethylbutyl, 3,3-dimethylbutyl, 1- tilbutyl, 2-ethylbutyl, 1,2,2-trimethylpropyl, 1-ethyl-1-methylpropyl, 1-ethyl-2-methylpropyl, n-heptyl, n-octyl, n-nonyl, n-decyl, n-undecyl, n-dodecyl, n-tridecyl, n-tetradecyl, n-pentadecyl, n-hexadecyl, n-heptadecyl, n-octadecyl, n-nonadecyl or n-eicosyl.

As C ₃ -C ₁₀ cycloalkyl radicals, for example, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, 1-methylcyclopropyl, 1-ethylcyclopropyl, 1-propylcyclopropyl, 1-butylcyclopropyl, 1-pentylcyclopropyl, 1-methyl-1-butyl , 1,2-dimethylcyclopropyl, 1-methyl-2-ethylcyclopropyl, cyclooctyl, cyclononyl or cyclodecyl.

As C ₃ -C ₁₀ cycloalkenyl radicals containing one or more double bonds, mention may be made of cyclopropenyl, cyclobutenyl, cyclopentenyl, cyclopentadienyl, cyclohexenyl, 1,3-cyclohexadienyl, 1,4-cyclohexadienyl, cycloheptenyl, cycloheptatrienyl, cyclooctenyl β-cyclooctadienyl, cyclooctatetraenyl, cyclononenyl or cyclodecenyl.

As examples of 5 or 6 membered rings formed by the radicals R ₁ and R ₂ with a nitrogen atom, mention may in particular be made of pyrrolidine or piperidine.

A particularly preferred compound A of formula (I) is n-hexyl-2- (4-diethylamino-2-hydroxybenzoyl) benzoate of formula (A):

such as a product sold under the trade name “UVINUL A +” by BASF.

Compounds A of formula (I) described above are known products, their structure and synthesis are described in patent applications EP-A-1046391, EP 1133980 and DE 100 12 408.

Preferably, compound A of the hydroxyaminobenzophenone type of formula (I) is present in the composition of the invention in an amount of 0.01-1.5 wt.%, More specifically 0.1-0.8 wt.%. by weight of the entire composition.

Among the filters B, the cinnamate type according to the invention can be called, in particular, without limitation:

Ethylhexylmethoxycinnamate, sold, for example, under the trade name “PARSOL MCX” by HOFFMANN LA ROCHE,

Isopropylmethoxycinnamate,

Isoamylmethoxycinnamate sold under the trade name “NEO HELIOPAN E 1000” by HAARMANN and REIMER,

Zinoxate

DEA methoxy cinnamate,

Diisopropyl methyl cinnamate,

Glyceryl ethyl hexanoate dimethoxy cinnamate.

Among the cinnamate type B filters mentioned above, ethylhexylmethoxycinnamate sold under the trade name “PARSOL MCX” by DSM should be especially used; this filter corresponds to the following formula (B):

Preferably, compound B of cinnamate is present in the compositions of the invention in an amount of 0.01-1.5% by weight, more particularly 0.1-0.8% by weight, of the total weight of the composition.

According to a particular embodiment of the invention, a combination of n-hexyl-2- (4-diethylamino-2-hydroxybenzoyl) benzoate / ethylhexylmethoxycinnamate is used in a weight ratio of 35/65 wt.%, Which is represented by the product sold under the trade name “UVINAL A + B” by the company BASF.

This combination is in the compositions according to the invention in an amount of 0.01-2 wt.%, More specifically 0.1-1 wt.%, Even more specifically 0.3-1 wt.% Of the total weight of the composition.

Compound C according to the invention is selected from:

(i) a piperidinol type compound of the specific formula (II), which is described in more detail below,

(ii) at least one benzotriazole type compound of the specific formula (III), which is described in more detail below,

(iii) a dibenzoylmethane type UV filter.

The piperidinol type compounds of the invention correspond to the following formula (II):

wherein

R is hydrogen or methyl,

x is 1 or 2, wherein

1) when x is 1,

then R ¹ is hydrogen; C ₁ -C ₁₈ alkyl; C ₂ -C ₁₈ alkenyl; propargyl; glycidyl group; C ₂ -C ₅₀ alkyl interrupted by 1-20 oxygen atoms; wherein said alkyl is substituted with 1-10 hydroxyl groups or is simultaneously interrupted by said oxygen atoms and substituted by said hydroxyl groups; C ₁ -C ₄ alkyl substituted with a carboxyl group or a -COOZ group, where Z is hydrogen, C ₁ -C ₄ alkyl, phenyl, C ₁ -C ₄ alkyl substituted with a group

(COO ^- ) _p M ^{p +} , where p is an integer from 1 to 3 and M is a metal ion of groups 1, 2 and 3 of the periodic table or Zn, Cu, Ni or Co, or M is a group N ^{p +} (R ² ) ₄ , where R ² is C ₁ -C ₈ alkyl or benzyl;

2) when x is 2

then R ¹ is C ₁ -C ₁₂ alkylene; C ₄ -C ₁₂ alkenylene; xylylene group; C ₁ -C ₅₀ alkylene interrupted by 1-20 oxygen atoms, wherein said alkyl is substituted by 1-10 hydroxyl groups or is simultaneously interrupted by said oxygen atoms and substituted by said hydroxyl groups;

X is an organic or inorganic anion;

moreover, the total charge of cations y is equal to the total charge of anions j.

Among the anions of X we can name the anion of phosphate, phosphonate, carbonate, bicarbonate, nitrate, chloride, bromide, bisulfite, sulfite, bisulfate, sulfate, borate, formate, acetate, benzoate, citrate, oxalate, tartrate, acrylate, polyacrylate, fumarate, maleate, itaconate, glycolate, gluconate, malate, mandelate, crucible, ascorbate, polymethacrylate, nitrile triacetic acid carboxylate, hydroxyethylene diaminotriacetic acid residue, ethylenediaminetetraacetic acid residue, diethylenediaminopentaacetic acid residue, diethylene inopentametilenfosfonata, alkyl sulfonate, or aryl sulfonate.

Piperidinol type compounds of formula (II) are per se known compounds and are described in WO03 / 103622.

In particular, compounds of the formula (II) are used in which R and R ¹ are hydrogen, x = 1 and X is a citrate anion, more specifically the compound Tris- (tetramethylhydroxypiperidinol) citrate of the formula

where y = 3, which is represented by a commercial product sold under the name TINOGUARD Q or TINOGUARD S-FX by CIBA-GEIGY.

Compounds of the benzotriazole type according to the invention correspond to the following formula:

wherein:

R ₁ is C ₁ -C ₁₂ alkyl, C ₁ -C ₅ alkoxy, C ₁ -C ₅ alkoxycarbonyl, C ₅ -C ₇ cycloalkyl, C ₆ -C ₁₀ aryl, aralkyl, SO ₃ M, a radical of formula (IIIa)

wherein

R ₄ and R ₅ , identical or different, are C ₁ -C ₅ alkyl or hydrogen;

R ₃ is hydrogen, C ₁ -C ₁₂ alkyl, C ₁ -C ₅ alkoxy, halogen, preferably Cl, or a hydroxyl group;

M denotes a cation of an alkali, alkaline earth metal or ammonium, preferably Na +,

m is 1 or 2

n is 0 or 1,

if m = 1, then R ₂ is hydrogen, C ₁ -C ₁₂ alkyl, unsubstituted or substituted by phenyl; C ₆ -C ₁₀ aryl;

if m = 2, then R ₂ is a direct bond, the radical is (CH ₂ ) _p- , where p is an integer from 1 to 3.

Alkyl radicals are linear or branched and are selected, for example, from methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, tert-butyl, amyl, isoamyl, heptyl, octyl, isooctyl, nonyl, decyl, dodecyl radicals .

The following radicals can be mentioned as C ₁ -C ₅ alkoxy: methoxy, ethoxy, n-propoxy, n-butoxy, n-pentoxy, 1-methylpropoxy, 3-methylbutoxy, 2,2-dimethylpropoxy.

C ₅ -C ₇ cycloalkyls are, for example, cyclopentyl, cycloheptyl or preferably cyclohexyl.

Alkylphenyls are, for example, phenylpropyl, phenylethyl and preferably benzyl.

Compounds of the benzotriazole type of formula (II) are, per se, known compounds, their structures are described in WO 00/25730.

Among the compounds of formula (III), mention may in particular be made of the following compounds:

(i) Sodium benzotriazolylbutylphenol sulfonate of the formula (1)

such as a product sold under the name “TINOGUARD HS” by CIBA-GEIGY.

(ii) Benzotriazolyl dodecyl-para-cresol of formula (2)

such as a product sold under the name “TINOGUARD TL” by CIBA-GEIGY.

(iii) Benzotriazolylbutylphenol sulfonate of the formula (3)

such as a product sold under the trade name “CIBAFAST H LIQUID” by CIBA-GEIGY.

(iv) Bumetrizole of formula (4)

such as a product sold under the name “TINOGUARD AS” by CIBA-GEIGY.

The compound Bumetrizole of formula (4) is especially used.

The piperidinol type compound or compounds C, as well as the benzotriazole type compounds of the invention, are preferably present in the compositions of the invention in an amount of 0.01-0.1 wt.% Of the final composition, more preferably 0.01-0.05 wt.% , even more preferably 0.01-0.03 wt.% of the total weight of the composition.

Among the filters of the dibenzoylmethane type corresponding to the invention, it is possible to name, in particular, but not limited to, the following:

- 2-methyldibenzoylmethane,

- 4-methyldibenzoylmethane,

- 4-isopropyl dibenzoylmethane,

- 4-tert-butyldibenzoylmethane,

- 2,4-dimethyldibenzoylmethane,

- 2,5-dimethyldibenzoylmethane,

- 4,4'-diisopropyl dibenzoylmethane,

- 4,4'-dimethoxybenzoylmethane,

- 4-tert-butyl-4'-methoxydibenzoylmethane,

- 2-methyl-5-isopropyl-4'-methoxydibenzoylmethane,

- 2-methyl-5-tert-butyl-4'-methoxydibenzoylmethane,

- 2,4-dimethyl-4'-methoxydibenzoylmethane,

- 2,6-dimethyl-4-tert-butyl-4'-methoxydibenzoylmethane.

Among the dibenzoylmethanes listed above, 4-tert-butyl-4′-methoxydibenzoylmethane or butylmethoxybenzoylmethane sold under the trade name “PARSOL 1789” by DSM should be especially used; this filter corresponds to the following formula (IV):

The dibenzoylmethane filter or filters of the invention are preferably present in the compositions of the invention in an amount of 0.01-1.5% by weight, preferably 0.1-0.5% by weight, more preferably 0.1-0.8 wt.% of the total weight of the composition.

According to a preferred form of the invention, the perfume composition contains in a cosmetically suitable medium:

a) at least 2 wt.% fragrance of the total weight of the composition;

b) at least one hydroxyaminobenzophenone type A filter of formula (I) described above;

c) at least one cinnamate type filter B described above;

d) at least one dibenzoylmethane type filter C described above and

e) at least one salicylate type filter D.

Of the salicylate type filters D according to the invention, it is possible to name, in particular, for example:

Homosalate sold under the name “Eusolex HMS” by Rona / EM Industries,

Ethylhexyl salicylate sold under the name “NEO HELIOPAN OS” by SYMRISE,

Dipropylene glycol salicylate sold under the name “DIPSAL” by SCHER,

TEM Salicylate, marketed under the name “NEO HELIOPAN TS” by SYMRISE.

Among the salicylates D mentioned above, ethylhexyl salicylate, sold under the name “NEO HELIOPAN OS” by SYMRISE, of the following formula (V), should especially be used:

The salicylate type filter or filters D of the invention are preferably present in the compositions of the invention in an amount of 0.01-1.5 wt.%, Preferably 0.1-0.5 wt.%, More preferably 0.1-0.8 wt.% of the total weight of the composition.

According to a particular form of the invention, the cosmetically acceptable medium according to the invention contains at least one volatile alcohol and / or one volatile silicone oil and, optionally, water. Preferably, this composition medium contains water in an amount of preferably 0.01-50 wt.%, More preferably 0.5-25 wt.% Of the total weight of the composition.

By “volatile alcohol” is meant any compound containing at least one alcohol group and having a vapor pressure at 20 ° C. above 17.5 mm Hg.

By “oil” is meant, according to the invention, a fatty substance insoluble in water and liquid at room temperature and atmospheric pressure.

By “volatile silicone oil” is meant, according to the invention, any silicone compound capable of evaporating upon contact with skin or keratin fiber for at least 1 hour at room temperature and atmospheric pressure. The volatile compound is a cosmetic volatile compound, liquid at room temperature, having, in particular, a vapor pressure not equal to zero at room temperature and atmospheric pressure, in particular having a vapor pressure of 0.13-40000 Pa (10 ^-3 -300 mm Hg ), in particular 1.3-13000 Pa (0.01-100 mm Hg), more specifically 1.3-1300 Pa (0.01-10 mm Hg).

The volatile alcohols of the invention are preferably selected from C ₁ -C ₅ lower mono alcohols, which may be selected from methanol, ethanol, propanol, isopropanol, n-butanol, isobutanol, tert-butanol, preferably ethanol.

Volatile alcohol or volatile alcohols are preferably in an amount of 40-80 wt.%, More preferably in an amount of 55-80 wt.% Of the total weight of the composition.

Suitable volatile silicone oils are, for example, linear-chain volatile silicone oils or cyclic silicone oils, in particular those having a viscosity of ≤ 6 centistokes (6 · 10 ^-6 m ² / s) and, in particular, of 2-10 atoms silicon, and these silicones optionally contain alkyl or alkoxyl groups having 1-22 carbon atoms. As the volatile silicone oil used according to the invention, mention may in particular be made of octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, heptamethylhexyltrisiloxane, heptamethyloctyltrisiloxane, hexamethyldisiloxane, decamethoxyl methane dimethyl methane dimethyl methane dimethyl methane dimethyl methane dimethyl methane decantoxyl.

Volatile silicone oil or oils are preferably in an amount of 40-98.5 wt.%, Preferably in a concentration of 10-80 wt.% Of the total weight of the composition.

The composition according to the invention may additionally contain any additive commonly used in the field of perfumery, selected in particular from antioxidants, cosmetically or dermatologically active substances, such as moisturizing agents or emollients, for example sweet almond oil, stone apricot oil; hydrating agents such as glycerin; sedative agents such as α-bisabolol, allantoin, aloe vera; vitamins, volatile fatty acids, insect repellents, propellants, dispersants, colorants, pearlescent pigments, flowering flakes and mixtures thereof. The composition according to the invention may also contain auxiliary substances commonly used in the field of cosmetics and dermatology, such as gelling hydrophilic or lipophilic substances, preservatives (for example, phenoxyethanol and parabens), solvents, fillers, bactericides. The amount of these various auxiliary agents is classical used in this field, for example, 0.01-20% of the total weight of the composition.

Among the antioxidants, for example, BHA (tert-butyl-4-hydroxyanisole), BHT (2,6-ditret-butyl-p-cresol), tocopherols, such as vitamin E and its derivatives, such as tocopherol acetate, can be mentioned.

The composition according to the invention may contain, in particular, at least one coloring matter, such as powdered substances, fat-soluble dyes, water-soluble dyes.

Coloring powdery substances can be selected from pigments and pearlescent pigments.

The pigments may be white or colored, mineral and / or organic, coated or uncoated. Mineral pigments may include titanium dioxide, optionally surface-treated, zirconium, zinc or cerium oxides, as well as iron or chromium oxides, manganese violet, ultramarine blue, chromium hydrate and ferrous blue. Organic pigments include soot, D&C pigments and varnishes based on cochineal carmine, barium, strontium, calcium, aluminum.

Pearlescent pigments can be selected from white pearlescent pigments, such as mica coated with titanium or bismuth oxychloride, colored pearlescent pigments such as titanium mica with iron oxides, titanium mica, in particular with ferrous blue or chromium oxide, titanium mica with organic pigment of the above type, as well as pearlescent pigments based on bismuth oxychloride.

Soluble dyes are, for example: caramel, Yellow 5, Acid Blue 9 / Blue 1, Green 5, Green 3 / Fast Green FCF 3, Orange 4, Red 4 / Food Red 1, Yellow 6, Acid Red 33 / Food Red 12, Red 40, cochineal carmine (CI 15850, CI 75470), Ext. Violet 2, Red 6-7, Ferric Ferrocyanide, Ultramarines, Acid Yellow 3 / Yellow 10, Acid Blue 3, Yellow 10.

Fat-soluble dyes are, for example, red Sudan, D&C Red 17, D&C Green 6, β-carotene, soybean oil, brown Sudan, D&C Yellow 11, D&C Violet 2, D&C Orange 5, quinoline yellow, Orleans.

The invention relates not only to perfumery products, but also to care products for treating the body, skin, face, lips, nails, including hair and scalp containing fragrant substance. Thus, the composition according to the invention can be a composition for flavoring, skin care, for treating keratin fibers, in particular it can be produced in the form of refreshing water, toilet water, fragrant water, aftershave, skin care lotion, silicone or hydrosilicone oil for skin care, hygiene products such as shower gels, bath products, shampoos, scrubs. It can also be produced as a fragrant two- or three-phase lotion (toilet water phase / hydrocarbon oil and / or silicone oil and / or fluorinated oil phase).

The invention also relates to a cosmetic method for flavoring keratin substances of a person, in particular skin, lips and skin appendages, comprising applying to the keratin substances the composition described above.

The composition according to the invention can be obtained by known methods commonly used in the field of perfume compositions.

Compositions according to the invention can be packaged in vials. They can be applied in the form of small particles by means of an extrusion device. The devices of the invention are well known to those skilled in the art and comprise atomizers for non-aerosol packaging or “nebulizers”, aerosol cans containing propellant, and aerosol nebulizers using compressed air as a propellant. These devices are described in US Pat. No. 4,077,441 and US Pat. No. 4,850,517 (this description is part of the content of this description).

Aerosolized compositions according to the invention typically contain conventional propellants, such as, for example, hydrofluoric compounds, dichlorodifluoromethane, difluoroethane, dimethyl ether, isobutane, n-butane, propane, trichlorofluoromethane.

The perfume compositions according to the invention are presented in all possible galenic forms, classically used for topical application, in particular in the form of an aqueous or aqueous-alcoholic solution, an oil-in-water emulsion (N / E) or water-in-oil emulsion (E / N) or a multiphase emulsion (three-phase: E / H / E or H / E / H), aqueous gels, anhydrous dehydrating products, such as fragrant talc in free or compact form, or in the form of dispersions of the oil phase in the aqueous phase with lipid visuals ionic type (liposomes) and / or non-ionic type. These compositions are prepared according to known methods.

In addition, the compositions according to the invention can be more or less liquid and have the form of a cream, lipstick, milk, lotion, serum, paste, foam. They may also be in solid form, for example in the form of a pencil.

When the compositions according to the invention contain an oil phase, this phase preferably contains at least one oil, in particular a physiologically acceptable oil. It may additionally contain other fatty substances.

As the oils used in the composition according to the invention, for example, there may be mentioned:

- hydrocarbon oils of animal origin, such as perhydrosqualene;

- vegetable hydrocarbon oils, such as liquid triglycerides of fatty acids containing 4-10 carbon atoms, such as heptanoic or octanoic triglycerides, or, for example, sunflower oil, corn, soybean, pumpkin seed oil, grape seed oil, sesame oil, peanut butter, apricot oil, macadamia oil, Arara, sunflower, castor oil; caprylic / capric triglycerides, such as triglycerides sold by Stearineries Dubois or triglycerides sold under the names Myglyol 810, 812 and 818 by Dynamit Nobel, jojoba oil, shea butter;

- synthetic esters and ethers, in particular fatty acids, such as oils of the formula R ¹ COOR ² and R ₁ OR ₂ , in which R ¹ denotes the remainder of a fatty acid containing 8-29 carbon atoms, and R ² denotes a branched or unbranched a hydrocarbon chain containing 3-30 carbon atoms, such as, for example, purcellon oil, isononyl isononanoate, isopropyl myristate, ethyl 2-hexyl palmitate, octyl 2-dodecyl stearate, octyl 2-dodecyl steruate, isostearyl isosteart; hydroxylated esters such as isostearyl lactate, octyl hydroxy stearate, octyl dodecyl hydroxy stearate, diisostearyl malate, triisocetyl citrate, heptanoates, octanoates, fatty acid decanoates; polyhydric alcohol esters such as propylene glycol dioctanoate, neopentyl glycol diheptanoate and diethylene glycol diisononanoate; and pentaerythritol esters, such as pentaerythritol tetraisostearate;

- linear or branched hydrocarbons of mineral or synthetic origin, such as volatile or non-volatile paraffin oils and their derivatives, petroleum jelly, polydecene, hydrogenated polyisobutene, such as Parleam oil;

fatty alcohols with 8-26 carbon atoms, such as cetyl alcohol, stearyl alcohol and a mixture thereof (cetyl stearyl alcohol), octyldodecanol, 2-butyloctanol, 2-hexyldecanol, 2-undecylpentadecanol, olein alcohol or linole alcohol;

- partially fluorinated hydrocarbon and / or silicone oils, such as those described in JP-A-2-295912;

- volatile or non-volatile silicone oils, such as linear or cyclic silicone chain polymethylsiloxanes (PDMS), liquid or paste at room temperature, in particular cyclopolydimethylsiloxanes (cyclomethicones), such as cyclohexasiloxane; polydimethylsiloxanes containing alkyl, alkoxyl or phenyl groups, side or at the end of the silicone chain, groups with 2-24 carbon atoms; phenyl-containing silicones such as phenyltrimethicones, phenyldimethicones, phenyltrimethylsiloxyphenylsiloxanes, diphenyldimethicones, diphenylmethyl diphenyltrisiloxanes, 2-phenylethyltrimethylsiloxysiloxanes and polymethylphenylsiloxanes;

- mixtures thereof.

By “hydrocarbon oil” is meant in this list of oils any oil containing mainly carbon and hydrogen atoms and, optionally, ester, ether, fluorine, carboxyl and / or alcohol groups.

Other fatty substances that may be present in the oil phase are, for example, fatty acids containing 8-30 carbon atoms, such as stearic acid, lauric acid, palmitic acid and oleic acid; waxes such as lanolin, beeswax, carnauba wax, candelilla wax, paraffin, lignite waxes or microcrystalline waxes, ceresin or ozokerite, synthetic waxes such as polyethylene waxes, Fischer-Tropsch waxes; silicone resins such as trifluoromethyl-C _1-4 alkyl dimethicone and trifluoropropyl dimethicone; silicone elastomers, such as products marketed under the name “KSG” by Shin-Etsu, under the names “Trefil”, “BY29” or “EPSX” by Dow Corning or under the names “Gransil” by Grant Industries.

These fatty substances can be selected by a specialist in various ways in order to obtain a composition with certain properties, for example with the desired consistency or texture.

Emulsions usually contain at least one emulsifier selected from amphoteric, anionic, cationic or nonionic emulsifiers used individually or in admixture. Emulsifiers are selected appropriately depending on the continuous phase of the emulsion obtained (E / H or H / E). If the emulsion is multiphase, then it usually contains one emulsifier in the primary emulsion and one emulsifier in the external phase into which the primary emulsion is introduced.

As emulsifiers used to obtain emulsions of type E / H, mention may be made, for example, of complex or simple alkyl monoesters of sorbitan, glycerol or sugars; silicone surfactants, such as dimethicone copolyols, such as cyclomethicone-dimethicone-copolyol mixtures sold under the names DC 5225 C and DC 3225 C by Dow Corning, or such as alkyl dimethicone copolyols such as the laurylmethicone copolyol sold under the name “Dow Corning 5200 Formulation Aid ”by Dow Corning, a cetyl dimethicone copolyol sold under the name Abil EM 90R by Goldschmidt and a polyglyceryl 4-isostearate / cetyl dimethicone / hexyl laurate copolyol sold under the name Abil WE 09R by Goldsm One or more co-emulsifiers can also be added to them, which can advantageously be selected from the group consisting of branched chain fatty acid esters and polyol, in particular branched chain fatty acid esters of glycerol and / or sorbitan, for example polyglyceryl isostearate, which is represented by the product marketed under the name Isolan Gl 34 by Goldschmidt, sorbitan isostearate, which is represented by a product marketed under the name Arlacel 987 by ICI, sorbitan isostearate and glyce ins, which is represented by the products sold on the market under the name Arlacel 986 by ICI, and mixtures thereof.

As emulsifiers used to obtain H / E type emulsions, for example, nonionic emulsifiers, such as esters of fatty acids and hydroxyalkylated polyols (more specifically polyoxyethylene), for example polyethylene glycol stearate, such as PEG-100-stearate, PEG- 50-stearate and PEG-40-stearate; and mixtures thereof, such as a mixture of glycerol monostearate and polyethylene glycol stearate (100 OU), sold under the name SIMULSOL 165 by SEPPIC; esters of fatty acids and oxyalkylated sorbitans containing, for example, 20-100 OE, for example, esters sold under the trade name Tween 20 or Tween 60 by Ubiqema; ethers of fatty hydroxyalkylated alcohols (hydroxyethylated and / or hydroxypropylated); sugar esters such as sucrose stearate; and mixtures thereof, such as, for example, a mixture of glycerol stearate and PEG-100 stearate, sold under the name Arlacel 165 by Uniqema.

Co-emulsifiers, such as, for example, fatty alcohols with 8-26 carbon atoms, such as cetyl alcohol, stearyl alcohol and a mixture thereof (cetearyl alcohol), octyldodecanol, 2-butyloctanol, 2-hexyldecanol, 2-undecanolant, can be added to these emulsifiers. oleic alcohol.

It is also possible to obtain emulsions without emulsifying surfactants or when their content is less than 0.5% of the total weight of the composition using appropriate compounds, for example polymers having emulsifying properties, such as polymers sold under the names Carbopol 1342 and Pemulen by Noveon; or polymers and copolymers of 2-acrylamido-2-methylpropanesulfonic acid, optionally crosslinked and / or neutralized, such as a polymer of 2-acrylamido-2-methylpropanesulfonic acid sold by CLARIANT under the name "Hostacerin AMPS" (CTFA name: polyacryldimethyl ammonium tauramide) an emulsion polymer sold under the name Sepigel 305 by Seppic (INCI name: Polyacrylamide / C ₁₃ -C ₁₄ -isoparaffin / laureth-7); particles of ionic or non-ionic polymers, more specifically particles of anionic polymers, such as in particular polymers of isophthalic or sulfoisophthalic acid, in particular copolymers of phthalate / sulfoisophthalate / glycol (e.g. diethylene glycol / phthalate / isophthalate / 1,4-cyclohexane dimethanol (INCI name: Diglycol / CHDM / Isophthalates / SIP copolymer), sold under the names Eastman AQ polymer (AQ35S, AQ38S, AQ55S, AQ48 Ultra) by Eastman Chemical.

It is also possible to obtain emulsions without emulsifiers by stabilizing the emulsions with silicone particles or particles from metal oxides such as TiO ₂ or others.

As fillers that can be used in the compositions according to the invention, mention may be made, for example, in addition to pigments, of silica powder; talc; particles of polyamide, in particular particles sold under the name ORGASOL by Atochem; polyethylene powders; powders from natural organic materials, such as powders from starch, in particular corn, wheat and rice starch, structured or unstructured, such as powders from starch, structured with octenyl succinate anhydride, sold under the name DRY-FLO by National Starch; acrylic copolymer microspheres, such as ethylene glycol dimethyl acrylate / lauryl methacrylate microspheres, sold by Dow Corning under the name POLYTRAP; hollow particle powders such as hollow microspheres, in particular microspheres sold under the name EXPANCEL by Kemanord Plast or under the name MICROPEARL F 80 ED by Matsumoto; silicone bead microspheres, such as those manufactured under the name TOSPEARL by Toshiba Silicone; and mixtures thereof. These excipients may be present in amounts of from 0 to 20 wt.%, Preferably from 1 to 10 wt.% Of the total weight of the composition.

The invention is described below with reference to the following examples, given to illustrate the invention and do not limit it. In these examples, unless otherwise indicated, the amounts are expressed in mass percent. In the preparation of the following compositions, amounts are indicated in weight percent.

Examples

COMPARATIVE TESTS FOR STABILITY OF ODOR AND COLOR

Principle of operation

The principle of these tests is that the test products are exposed to a light source whose spectrum is strictly defined and the amount of radiated energy is precisely dosed.

Widely used light sources are xenon lamps that emit light through:

- a quartz platinum filter that deflects infrared rays and cuts them off at the top of the device

- a glass filter, which, absorbing short-wave ultraviolet radiation, allows you to simulate the radiation received in the exposure zone.

Equipment

Use the CPS Sun-test device:

- Lighting is provided by a xenon lamp in the wavelength range of 300-800 nm with an irradiation density of 765 W / m ² (the value is set by the manufacturer)

- Optical filtering is provided by a quartz filter with IR coating and a special window glass)

Observe with the naked eye the color of each vial before and after light irradiation with the Sun Test instrument after 16 hours of treatment at room temperature.

The sniff test olfactory test is also carried out by a group of experts of 5 people on samples at time point T ₀ and after 2 months of exposure at room temperature and at 45 ° C.

Examples 1a, 1b and 1c

Composition 1a (*) 1b (*) 1c (invention) Fragrant Concentrate
substance x fifteen% fifteen% fifteen% Ethanol 65% 65% 65% Dyes n.k. n.k. n.k. A mixture of n-hexyl-2- (4-diethylamino-2-hydroxybenzoyl) -benzoate and ethylhexylmethoxycinnamate 35/65 (Uvinul A + B) one 0% one Tris- (tetramethylhydroxypiperidinol)
citrate - (TINOGUARD Q) 0 0,03 0,03 Water up to 100% up to 100% up to 100% (*) not in accordance with the invention
n.k. required amount

results

Test 1a:

Result at the moment T ₀ : obtaining a fragrance of golden yellow color with a pleasant smell.

Suntest result after 16 hours: color degradation = discoloration -

Observation after 2 months at 45 ° C: a very distinct change in smell, pungent odor, -

Test 1b:

Result at the moment T ₀ : obtaining a fragrance of golden yellow color with a pleasant smell.

Suntest result after 16 hours: color degradation = discoloration ---

Observation after 2 months at 45 ° C: odor reduction ---

Test 1c (according to the invention):

Result at the moment T ₀ : obtaining a fragrance of golden yellow color with a pleasant smell.

Suntest result after 16 hours: maintaining the original color

Observation after 2 months at 45 ° C: no change in smell

It is noted that the composition 1c according to the invention, containing a combination of n-hexyl-2- (4-diethylamino-2-hydroxybenzoyl) -benzoate / ethylhexylmethoxycinnamate / Tris- (tetramethylhydroxypiperidinol), has a stable odor and color when exposed to light and when stored at 45 ° C unlike compositions 1a and 1b (not corresponding to the invention).

Examples 2a, 2b and 2c

Composition 2a (*) 2b (*) 2c (invention) Fragrant Concentrate
substance x fifteen% fifteen% fifteen% Ethanol 65% 65% 65% Dyes n.k. n.k. n.k. A mixture of n-hexyl-2- (4-diethylamino-2-hydroxybenzoyl) -benzoate and ethylhexylmethoxycinnamate 35/65 (Uvinul A + B) one 0% one

Bumetrizole - Compound (4)
(TINOGUARD AS) 0 0,03 0,03 Water up to 100% up to 100% up to 100% (*) not in accordance with the invention

results

Test 2a:

Result at the moment T ₀ : obtaining a fragrance of golden yellow color with a pleasant smell.

Suntest result after 16 hours: color degradation = discoloration -

Observation after 2 months at 45 ° C: a very distinct change in smell, pungent odor, -

Test 2b:

Result at the moment T ₀ : obtaining a fragrance of golden yellow color with a pleasant smell.

Suntest result after 16 hours: color degradation = discoloration ---

Observation after 2 months at 45 ° C: odor reduction ---

Test 2c (according to the invention):

Result at the moment T ₀ : obtaining a fragrance of golden yellow color with a pleasant smell.

Suntest result after 16 hours: maintaining the original color

Observation after 2 months at 45 ° C: no change in smell.

It is noted that the composition 2c according to the invention, containing a combination of n-hexyl-2- (4-diethylamino-2-hydroxybenzoyl) -benzoate / ethylhexylmethoxycinnamate / Bumetrizole, has a stable odor and color when exposed to light and when stored at 45 ° C, in contrast compositions 2a and 2b (not corresponding to the invention).

Examples 3a, 3b, 3c and 3d

Composition 3a (*) 3b (*) 3s (*) 3d (invention) Fragrant Concentrate
substance x fifteen% fifteen% fifteen% fifteen% Ethanol 65% 65% 65% 65% Dyes n.k. n.k. n.k. n.k. n-hexyl-2- (4-diethylamino-2-hydroxybenzoyl) benzoate (Uvinul A +) one% 0 0 0 A mixture of n-hexyl-2- (4-diethylamino-2-hydroxybenzoyl) -benzoate and ethylhexylmethoxycinnamate 35/65 (Uvinul A + B) 0 one% 0 one Butylmethoxydibenzoylmethane (Parsol 1789) 0 0 0.3% 0.3 Water up to 100% up to 100% up to 100% up to 100% (*) not in accordance with the invention

results

Test 3a:

Result at the moment T ₀ : obtaining a fragrance of golden yellow color with a pleasant smell.

Suntest result after 16 hours: color degradation = discoloration ---

Observation after 2 months at 45 ° C: very sharp change in smell, pungent odor, ---

Test 3b:

Result at the moment T ₀ : obtaining a fragrance of golden yellow color with a pleasant smell.

Suntest result after 16 hours: color degradation = discoloration -

Observation after 2 months at 45 ° C: odor reduction -

Test 3s:

Result at the moment T ₀ : obtaining a fragrance of golden yellow color with a pleasant smell.

Suntest result after 16 hours: color degradation = discoloration (---)

Observation after 2 months at 45 ° C: a sharp decrease in odor (---)

Test 3d (according to the invention):

Result at the moment T ₀ : obtaining a fragrance of golden yellow color with a pleasant smell.

Suntest Result after 16 hours: Preservation of the original color.

Observation after 2 months at 45 ° C: very slight change in odor (-)

It is noted that the composition 3d according to the invention, containing a combination of n-hexyl-2- (4-diethylamino-2-hydroxybenzoyl) -benzoate / Ethylhexylmethoxycinnamate / Butylmethoxybenzoylmethane, has a stable odor and color when exposed to light and when stored at 45 ° C, in contrast compositions 3a, 3b and 3c (not corresponding to the invention).

Examples 4a, 4b and 4c

Composition 4a (*) 4b (*) 4c (invention) Fragrance Concentrate x fifteen% fifteen% fifteen% Ethanol 65% 65% 65% Dyes n.k. n.k. n.k. A mixture of n-hexyl-2- (4-diethylamino-2-hydroxybenzoyl) -benzoate and ethylhexylmethoxycinnamate 35/65 (Uvinul A + B) 0 one% 0.6 Ethylhexyl Salicylate (NEO HELIOPAN OS) 0.3% 0% 0.1 Butylmethoxydibenzoylmethane (Parsol 1789) 0% 0% 0.2 Water up to 100% up to 100% up to 100% (*) not in accordance with the invention

results

Test 4a:

Result at the moment T ₀ : obtaining a fragrance of golden yellow color with a pleasant smell.

Suntest result after 16 hours: color degradation = discoloration ---

Observation after 2 months at 45C: very sharp change in smell, pungent odor, ---

Test 4b:

Result at the moment T ₀ : obtaining a fragrance of golden yellow color with a pleasant smell.

Suntest result after 16 hours: color degradation = discoloration -

Observation after 2 months at 45 ° C: odor reduction -

Test 4c (according to the invention):

Result at the moment T ₀ : obtaining a fragrance of golden yellow color with a pleasant smell.

Suntest result after 16 hours: maintaining the original color

Observation after 2 months at 45 ° C: no change in smell.

It is noted that the composition 4c according to the invention, containing a combination of n-hexyl-2- (4-diethylamino-2-hydroxybenzoyl) -benzoate / Ethylhexylmethoxycinnamate / Butylmethoxybenzoylmethane /.

Ethylhexyl salicylate has a stable odor and color when exposed to light and when stored at 45 ° C, in contrast to compositions 4a and 4b (not corresponding to the invention).

Claims (15)

1. Perfume composition containing in a cosmetically acceptable medium:
a) at least 2% of a fragrance of the total weight of the composition;
b) at least one hydroxyaminobenzophenone type A filter of formula (I)

in which R ₁ and R ₂ , the same or different, represent a hydrogen atom, C ₁ -C ₂₀ alkyl;
C ₃ -C ₁₀ cycloalkyl or C ₃ -C ₁₀ cycloalkenyl or form, together with the nitrogen atom to which they are connected, a 5 or 6 membered ring;
R ₃ is C ₁ -C ₂₀ alkyl,
c) at least one cinnamate type filter B;
d) at least one compound C selected from:
(i) a piperidinol type compound of the following formula (II):

in which R is hydrogen or methyl,
x is 1 or 2, wherein
1) when x is 1,
then R ¹ is hydrogen; C ₁ -C ₁₈ alkyl; C ₂ -C ₁₈ alkenyl; propargyl; glycidyl group; C ₂ -C ₅₀ alkyl interrupted by 1-20 oxygen atoms; wherein said alkyl is substituted with 1-10 hydroxyl groups or is simultaneously interrupted by said oxygen atoms and substituted by said hydroxyl groups; C ₁ -C ₄ alkyl substituted with a carboxyl group or a -COOZ group, where Z is hydrogen, C ₁ -C ₄ alkyl, phenyl, C ₁ -C ₄ alkyl substituted with a group
(COO ^- ) _p M ^{p +} , where p is an integer from 1 to 3 and M is a metal ion of groups 1, 2 and 3 of the Periodic table or Zn, Cu, Ni or Co; or M represents a group N ^{p +} (R ² ) ₄ , where R ² is C ₁ -C ₈ alkyl or benzyl;
2) when x is 2,
then R ¹ is C ₁ -C ₁₂ alkylene; C ₄ -C ₁₂ alkenylene; xylylene group; C ₁ -C ₅₀ alkylene interrupted by 1-20 oxygen atoms, wherein said alkyl is substituted by 1-10 hydroxyl groups or is simultaneously interrupted by said oxygen atoms and substituted by said hydroxyl groups;
X is an organic or mineral anion;
moreover, the total charge of cations y is equal to the total charge of anions j;
(ii) at least one benzotriazole type compound of formula (III)

in which R ₁ denotes C ₁ -C ₁₂ alkyl, C ₁ -C ₅ alkoxy, C ₁ -C ₅ alkoxycarbonyl, C ₅ -C ₇ cycloalkyl, C ₆ -C ₁₀ aryl, aralkyl, SO ₃ M group, radical of the formula ( IIIa)

in which R ₄ and R ₅ , identical or different, are C ₁ -C ₅ alkyl or hydrogen;
R ₃ is hydrogen, C ₁ -C ₁₂ alkyl, C ₁ -C ₅ alkoxy, halogen, preferably C1, or a hydroxyl group;
M denotes a cation of an alkali, alkaline earth metal or ammonium, preferably Na ⁺ ,
m is 1 or 2,
n is 0 or 1,
if m = 1, then R ₂ is hydrogen, C ₁ -C ₁₂ alkyl, unsubstituted or substituted by phenyl; C ₆ -C ₁₀ aryl;
if m = 2, then R ₂ is a direct bond, the radical is (CH ₂ ) _p- , where p is an integer from 1 to 3.
(iii) a dibenzoylmethane type UV filter. 2. The composition according to claim 1, in which the amount of aromatic substance is 3-50%, preferably 5-30%, even better 10-20% of the total weight of the composition. 3. The composition according to claim 1, in which the compound A of formula (I) is n-hexyl-2- (4-diethylamino-2-hydroxybenzoyl) -benzoate of the following formula (A):

4. The composition according to claim 1, in which the compound of the cinnamate type is ethylhexylmethoxycinnamate of the following formula (B):

5. The composition according to claim 3 or 4, which contains a combination of n-hexyl-2- (4-diethylamino-2-hydroxybenzoyl) -benzoate / ethylhexylmethoxycinnamate in the ratio of 35/65 wt.%. 6. The composition according to claim 1, in which the compound C of the piperidinol type of formula (II) is tris- (tetramethylhydroxypiperidinol) citrate of the formula

where y = 3. 7. The composition according to claim 1, in which the compound C of the benzotriazole type of the formula (III) is selected from the following compounds:
(i) sodium benzotriazolylbutylphenol sulfonate of the formula (1)

(ii) benzotriazolyl dodecyl-paracresol of formula (2)

(iii) benzotriazolylbutylphenol sulfonate of the formula (H)

(iv) bumetrizole of the formula (4)

8. The composition according to claim 7, in which the compound C of the formula (III) is bumetrizole of the formula (4)

9. The composition according to claim 1, characterized in that it further comprises at least one salicylate type filter D. 10. The composition according to claim 1, in which the compound of the dibenzoylmethane type is 4- (tert-butyl) -4'-methoxybenzoylmethane or butylmethoxybenzoylmethane of the following formula (IV):

11. The composition of claim 10, in which the salicylate type filter D is ethylhexyl salicylate of the following formula (V):

12. The composition of claim 1, wherein the cosmetically acceptable medium comprises at least one volatile alcohol and / or volatile silicone oil and optionally water. 13. The composition according to item 12, in which the cosmetically acceptable medium contains water in an amount of, preferably, 0.01-50%, more preferably 0.5-25% of the total weight of the composition. 14. The use of a combination of at least one hydroxyaminobenzophenone type A filter of formula (I), at least one cinnamate type filter B and at least one compound C described in the preceding paragraphs, in a perfume composition containing in at least a cosmetically acceptable medium 2% of the fragrance of the total weight of the composition, as a stabilizer of the organoleptic properties of the composition with respect to external aggressive influences, such as light and temperature difference, in particular color and / or odor Azana composition. 15. A cosmetic method for flavoring keratin substances in humans, comprising applying to keratin substances the composition described in claims 1-13.