RU2017141731A - AVIATION GASOLINE CONTAINING BRANCHED AROMATIC CONNECTIONS WITH MANGANESE ADDITIVE INCREASING OCTANE NUMBER - Google Patents

AVIATION GASOLINE CONTAINING BRANCHED AROMATIC CONNECTIONS WITH MANGANESE ADDITIVE INCREASING OCTANE NUMBER Download PDF

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RU2017141731A
RU2017141731A RU2017141731A RU2017141731A RU2017141731A RU 2017141731 A RU2017141731 A RU 2017141731A RU 2017141731 A RU2017141731 A RU 2017141731A RU 2017141731 A RU2017141731 A RU 2017141731A RU 2017141731 A RU2017141731 A RU 2017141731A
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aviation gasoline
aromatic
aviation
manganese
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Захари Джон МАКАФИ
Третий Джозеф Энтони КАЛЬДЕРОН
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Эфтон Кемикал Корпорейшн
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/103—Liquid carbonaceous fuels containing additives stabilisation of anti-knock agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1608—Well defined compounds, e.g. hexane, benzene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/10—Use of additives to fuels or fires for particular purposes for improving the octane number
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/02—Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
    • C10L2200/0204—Metals or alloys
    • C10L2200/0236—Group VII metals: Mn, To, Re
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/02—Inorganic or organic compounds containing atoms other than C, H or O, e.g. organic compounds containing heteroatoms or metal organic complexes
    • C10L2200/0254—Oxygen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0407—Specifically defined hydrocarbon fractions as obtained from, e.g. a distillation column
    • C10L2200/0415—Light distillates, e.g. LPG, naphtha
    • C10L2200/0423—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0407—Specifically defined hydrocarbon fractions as obtained from, e.g. a distillation column
    • C10L2200/043—Kerosene, jet fuel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/08—Inhibitors
    • C10L2230/087—Inhibitors for inhibiting misting
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/14—Function and purpose of a components of a fuel or the composition as a whole for improving storage or transport of the fuel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2270/00—Specifically adapted fuels
    • C10L2270/04—Specifically adapted fuels for turbines, planes, power generation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/24—Mixing, stirring of fuel components

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Catalysts (AREA)

Claims (19)

1. Состав авиационного бензина, содержащий1. The composition of aviation gasoline containing по меньшей мере приблизительно 20 об.% композиции авиационного алкилата; at least about 20% by volume of an aviation alkylate composition; марганецсодержащее соединение; иmanganese-containing compound; and приблизительно от 1 до 50 об.% композиции ароматических соединений, причем композиция ароматических соединений включает композицию разветвленного ароматического соединения, представляющего собой ароматическую функциональную группу, ковалентно связанную с разветвленной алкильной группой.from about 1 to about 50% by volume of an aromatic composition, wherein the aromatic composition comprises a branched aromatic composition, which is an aromatic functional group covalently linked to a branched alkyl group. 2. Состав авиационного бензина по п. 1, где ароматическая функциональная группа выбрана из группы, состоящей из бензола, нафталина и антрацена.2. The composition of aviation gasoline according to claim 1, where the aromatic functional group is selected from the group consisting of benzene, naphthalene and anthracene. 3. Состав авиационного бензина по п. 1, где ароматическая функциональная группа представляет собой гетероароматическую группу, содержащую атом, выбранный из группы, состоящей из кислорода, азота и серы.3. The composition of aviation gasoline according to claim 1, where the aromatic functional group is a heteroaromatic group containing an atom selected from the group consisting of oxygen, nitrogen and sulfur. 4. Состав авиационного бензина по п. 1, где ароматическая функциональная группа представляет собой 5- или 6-членное ароматическое кольцо.4. The composition of aviation gasoline according to claim 1, where the aromatic functional group is a 5 - or 6-membered aromatic ring. 5. Состав авиационного бензина по п. 1, где разветвленная алкильная группа содержит от 3 до 15 атомов.5. The composition of aviation gasoline according to claim 1, where the branched alkyl group contains from 3 to 15 atoms. 6. Состав авиационного бензина по п. 5, где разветвленная алкильная группа полностью состоит из атомов углерода.6. The composition of aviation gasoline according to claim 5, where the branched alkyl group consists entirely of carbon atoms. 7. Состав авиационного бензина по п. 5, где разветвленная алкильная группа включает один или более гетероатомов, выбранных из группы, состоящей из кислорода, азота, серы, кремния, фосфора, бора, фтора, хлора, брома и йода.7. The composition of aviation gasoline according to claim 5, where the branched alkyl group includes one or more heteroatoms selected from the group consisting of oxygen, nitrogen, sulfur, silicon, phosphorus, boron, fluorine, chlorine, bromine and iodine. 8. Состав авиационного бензина по п. 1, где композиция разветвленного ароматического соединения составляет приблизительно от 1 до 25 об.% состава авиационного бензина.8. The composition of aviation gasoline according to claim 1, where the composition of the branched aromatic compound is from about 1 to 25% by volume of the composition of aviation gasoline. 9. Состав авиационного бензина по п. 1, где композиция разветвленного ароматического соединения содержит смесь различных композиций разветвленного ароматического соединения.9. The composition of aviation gasoline according to claim 1, where the composition of a branched aromatic compound contains a mixture of various compositions of branched aromatic compounds. 10. Состав авиационного бензина по п. 1, где композиция разветвленного ароматического соединения представляет собой трет-бутилбензол.10. The composition of aviation gasoline according to claim 1, where the composition of branched aromatic compounds is tert-butylbenzene. 11. Состав авиационного бензина по п. 1, где марганецсодержащее соединение присутствует в количестве 500 мг Mn/л или менее, и моторное октановое число (ОЧМ) авиационного бензина составляет по меньшей мере 99,6.11. The composition of aviation gasoline according to claim 1, where the manganese-containing compound is present in an amount of 500 mg Mn / l or less, and the motor octane number (OCM) of aviation gasoline is at least 99.6. 12. Состав авиационного бензина по п. 1, где композиция ароматического соединения присутствует в количестве 30 об.% относительно состава бензина или менее, и моторное октановое число (ОЧМ) авиационного бензина составляет по меньшей мере 99,6.12. The composition of aviation gasoline according to claim 1, where the aromatic compound composition is present in an amount of 30% by volume relative to the composition of gasoline or less, and the motor octane number (OCM) of aviation gasoline is at least 99.6. 13. Способ снижения количества марганецсодержащих отложений в двигателе, образованных при сгорании состава авиационного бензина, включающий следующие стадии:13. The method of reducing the amount of manganese-containing deposits in the engine, formed during the combustion of the composition of aviation gasoline, comprising the following stages: обеспечение первого состава авиационного бензина, содержащего по меньшей мере приблизительно 20 об.% композиции авиационного алкилата, первое количество марганецсодержащего соединения и приблизительно от 1 до 50 об.% неразветвленного ароматического соединения;providing the first composition of aviation gasoline containing at least about 20% by volume of the composition of aviation alkylate, the first amount of manganese-containing compound and from about 1 to 50% by volume of unbranched aromatic compound; перед смешиванием первого состава авиационного бензина получение второго состава авиационного бензина путем замены по меньшей мере приблизительно 25 об.% неразветвленного ароматического соединения на композицию разветвленного ароматического соединения, и в то же время включения только второго количества марганецсодержащего соединения, меньшего, чем первое количество марганецсодержащего соединения;before mixing the first composition of aviation gasoline, obtaining a second composition of aviation gasoline by replacing at least about 25% by volume of the unbranched aromatic compound with the branched aromatic composition and at the same time including only the second amount of manganese-containing compound smaller than the first amount of manganese-containing compound; причем сгорание второго состава авиационного бензина приводит к образованию меньшего количества марганецсодержащих отложений в двигателе, чем сгорание первого состава авиационного бензина.moreover, the combustion of the second composition of aviation gasoline leads to the formation of a smaller amount of manganese-containing deposits in the engine than the combustion of the first composition of aviation gasoline.
RU2017141731A 2016-12-01 2017-11-30 AVIATION GASOLINE CONTAINING BRANCHED AROMATIC CONNECTIONS WITH MANGANESE ADDITIVE INCREASING OCTANE NUMBER RU2017141731A (en)

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US15/366,346 2016-12-01
US15/366,346 US20180155648A1 (en) 2016-12-01 2016-12-01 Aviation Gasoline Containing Branched Aromatics with a Manganese Octane Enhancer

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US6187064B1 (en) * 1991-10-28 2001-02-13 Ethyl Petroleum Additives, Inc. Unleaded aviation gasoline
US6238446B1 (en) * 1991-10-28 2001-05-29 Ethyl Petroleum Additives, Inc. Unleaded aviation gasoline
US5851241A (en) * 1996-05-24 1998-12-22 Texaco Inc. High octane unleaded aviation gasolines
GB9922553D0 (en) * 1999-09-23 1999-11-24 Bp Oil Int Fuel compositions
US20020045785A1 (en) * 1996-11-18 2002-04-18 Bazzani Roberto Vittorio Fuel composition
US7462207B2 (en) * 1996-11-18 2008-12-09 Bp Oil International Limited Fuel composition
US7862629B2 (en) * 2004-04-15 2011-01-04 Exxonmobil Research And Engineering Company Leaded aviation gasoline
FR2894976B1 (en) * 2005-12-16 2012-05-18 Total France AVIATION GASOLINE WITHOUT LEAD
AU2014206202C1 (en) * 2013-10-31 2016-02-18 Shell Internationale Research Maatschappij B.V. High octane unleaded aviation gasoline
CN104711053A (en) * 2013-12-11 2015-06-17 张希顺 Clean fuel oil antiknock additive

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