RU2016111719A - Additive copolymer of 3,3,4-tris (trimethylsilyl) tricyclononene-7 and 3-trimethylsilyl tricyclononene-7, a method for its preparation and a method for the separation of gas mixtures with its use - Google Patents

Additive copolymer of 3,3,4-tris (trimethylsilyl) tricyclononene-7 and 3-trimethylsilyl tricyclononene-7, a method for its preparation and a method for the separation of gas mixtures with its use Download PDF

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RU2016111719A
RU2016111719A RU2016111719A RU2016111719A RU2016111719A RU 2016111719 A RU2016111719 A RU 2016111719A RU 2016111719 A RU2016111719 A RU 2016111719A RU 2016111719 A RU2016111719 A RU 2016111719A RU 2016111719 A RU2016111719 A RU 2016111719A
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tricyclononene
trimethylsilyl
tris
additive copolymer
gas mixtures
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RU2016111719A
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Russian (ru)
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RU2634724C2 (en
Inventor
Павел Петрович Чапала
Максим Владимирович Бермешев
Людмила Эриковна Старанникова
Юрий Павлович Ямпольский
Евгений Шмерович Финкельштейн
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Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН)
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/44—Polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, not provided for in a single one of groups B01D71/26-B01D71/42
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F232/00—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C08F232/02—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having no condensed rings
    • C08F232/04—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having no condensed rings having one carbon-to-carbon double bond

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  • Separation Using Semi-Permeable Membranes (AREA)

Claims (7)

1. Аддитивный сополимер (3,3,4-трис(триметилсилил)трициклононена-7 и 3-триметилсилилтрициклононена-7 общей структурной формулы:1. The additive copolymer of (3,3,4-tris (trimethylsilyl) tricyclononene-7 and 3-trimethylsilyl tricyclononene-7 of the General structural formula:
Figure 00000001
,
Figure 00000001
, где n, m - доля указанных мономерных звеньев,where n, m is the proportion of these monomer units, Me представляет собой метил,Me is methyl, характеризующийся тем, что величина средневесовой молекулярной массы составляет MW=(3.5-4.5)×105 г/моль и индекс полидисперсности MW/Mn=2.5-2.8, содержание звеньев 3,3,4-трис(триметилсилил)трициклононена-7 до 20 мол. %.characterized in that the weight average molecular weight is M W = (3.5-4.5) × 10 5 g / mol and the polydispersity index M W / M n = 2.5-2.8, the content of 3,3,4-tris (trimethylsilyl) tricyclononene units is 7 to 20 mol. % 2. Способ получения аддитивного сополимера (3,3,4-трис(триметилсилил)трициклононена-7 и 3-триметилсилилтрициклононена-7 по п. 1, характеризующий тем, что он включает растворение в толуоле 3,3,4-трис(триметилсилил)трициклононена-7 и ацетата палладия(II), добавление при перемешивании раствора в толуоле тритил тетракис(пентафторфенил)бората до образования каталитической системы ацетата палладия(II)/тритил тетракис(пентафторфенил)бората, добавление 3-триметилсилилтрициклононена-7 и сополимеризацию с ним (3,3,4-трис(триметилсилил)трициклононена-7 при комнатной температуре в присутствии полученной каталитической системы.2. A method of obtaining an additive copolymer of (3,3,4-tris (trimethylsilyl) tricyclononene-7 and 3-trimethylsilyl tricyclononene-7 according to claim 1, characterized in that it comprises dissolving 3,3,4-tris (trimethylsilyl) in toluene tricyclononene-7 and palladium (II) acetate, adding with stirring a solution in toluene of trityl tetrakis (pentafluorophenyl) borate to form the catalytic system of palladium (II) acetate / trityl tetrakis (pentafluorophenyl) borate, adding 3-trimethylsilyl tricyclonolonene-7-i 3,3,4-tris (trimethylsilyl) tricyclononene-7 at k mnatnoy temperature in the presence of the resulting catalyst system. 3. Способ разделения газовых смесей, включающий подачу разделяемой смеси с одной стороны селективно-проницаемой мембраны из материала на основе трициклононена и отбор проникающих через нее компонентов с другой стороны, отличающийся тем, что в качестве указанного материала мембраны используют аддитивный сополимер по п. 1.3. A method of separating gas mixtures, comprising supplying a separable mixture from one side of a selectively permeable membrane from a material based on tricyclononene and selecting components penetrating through it, on the other hand, characterized in that the additive copolymer according to claim 1 is used as said membrane material.
RU2016111719A 2016-03-30 2016-03-30 Additive copolymer 3,3,4-tris(trimethylsilyl)tricyclononene-7 and 3-trimethylsilyltricyclononene-7, method of its production and method for separating gas mixtures with its application RU2634724C2 (en)

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RU2522555C2 (en) * 2012-03-30 2014-07-20 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Additive poly(mono(trimethylgermyl)-substituted tricyclononene), monomer for obtaining thereof and method of separating gas mixtures based on additive poly(mono(trimethylgermyl)-substituted tricyclononene)

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