RU2016101224A - IMPAIRED RESIN COATED PRODUCT WITH IMPROVED AESTHETIC PROPERTIES - Google Patents

IMPAIRED RESIN COATED PRODUCT WITH IMPROVED AESTHETIC PROPERTIES Download PDF

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Publication number
RU2016101224A
RU2016101224A RU2016101224A RU2016101224A RU2016101224A RU 2016101224 A RU2016101224 A RU 2016101224A RU 2016101224 A RU2016101224 A RU 2016101224A RU 2016101224 A RU2016101224 A RU 2016101224A RU 2016101224 A RU2016101224 A RU 2016101224A
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Prior art keywords
reducing agent
acid
color index
paragraphs
base layer
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RU2016101224A
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Russian (ru)
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RU2671327C2 (en
RU2016101224A3 (en
Inventor
Ильпо Сильвентойнен
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Серфактор Джермани Гмбх
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Publication of RU2016101224A3 publication Critical patent/RU2016101224A3/ru
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/47—Condensation polymers of aldehydes or ketones
    • D21H17/48—Condensation polymers of aldehydes or ketones with phenols
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/54—Starch
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/80—Paper comprising more than one coating
    • D21H19/82—Paper comprising more than one coating superposed
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/28—Colorants ; Pigments or opacifying agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18—Paper- or board-based structures for surface covering
    • D21H27/22—Structures being applied on the surface by special manufacturing processes, e.g. in presses
    • D21H27/26—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Laminated Bodies (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paper (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Claims (24)

1. Покрытое изделие, которое содержит:1. A coated product that contains: a) основной слой, предпочтительно, бумагу;a) a base layer, preferably paper; b) слой покрытия, содержащий композицию смолы, в частности, фенольной смолы; иb) a coating layer containing a resin composition, in particular a phenolic resin; and с) слой ослабления, содержащий один или более восстановителей, способных, по меньшей мере, частично обесцвечивать композицию смолы,c) a weakening layer containing one or more reducing agents capable of at least partially decolorizing the resin composition, в котором указанный слой покрытия находится в контакте с указанным слоем ослабления.wherein said coating layer is in contact with said attenuation layer. 2. Покрытое изделие по п. 1, в котором слой ослабления содержит печатную краску, нанесенную на основной слой.2. The coated article of claim 1, wherein the attenuation layer comprises printing ink applied to a base layer. 3. Покрытое изделие по п. 1 или 2, в котором указанный восстановитель имеет стандартный электродный потенциал Е0 в интервале от -150 до -1500 мВ.3. The coated product according to claim 1 or 2, wherein said reducing agent has a standard electrode potential E 0 in the range from -150 to -1500 mV. 4. Покрытое изделие по любому из пп. 1-3, в котором указанный восстановитель выбран из группы, состоящей из восстановительных сахаров, гидридов, органических кислот и неорганических солей.4. The coated product according to any one of paragraphs. 1-3, in which said reducing agent is selected from the group consisting of reducing sugars, hydrides, organic acids and inorganic salts. 5. Покрытое изделие по любому из пп. 1-4, в котором указанный восстановитель выбран из группы, состоящей из дигидроксиацетона, гликолевого альдегида, глицеринового альдегида, эритрозы, треозы, рибозы, арабинозы, ксилозы, ликсозы, аллозы, альтрозы, глюкозы, маннозы, гулозы, идозы, галактозы, талозы, фруктозы, лактозы, мальтозы, целлобиозы, диборана, литий-алюмогидрида, натрийборгидрида, литийборгидрида, SnCl2, SnF2, Sn(ОH)2, натрийдитионита (восстановитель индекса цвета 1), тиомочевинадиоксида (восстановитель индекса цвета 11), натрийгидроксиметансульфината (восстановитель индекса цвета 2), цинкформальдегидсульфоксилата (восстановитель индекса цвета 6), кальцийформальдегидкарбоксилата (восстановитель индекса цвета 12), натрийсульфита, натрийбисульфита, диизобутилалюминийгидрида, шавелевой кислоты, муравьиной кислоты, аскорбиновой кислоты, (NH4)2HPO3, CuHPO3, SnHPO3 и Al2(HPO3)3, калийгипофосфита, FeCl2, FeCO3, FeSO4.5. Covered product according to any one of paragraphs. 1-4, wherein said reducing agent is selected from the group consisting of dihydroxyacetone, glycolaldehyde, glycerol aldehyde, erythrose, threose, ribose, arabinose, xylose, lyxose, allose, altrose, glucose, mannose, gulose, idose, galactose, thalose, fructose, lactose, maltose, cellobiose, diborane, lithium aluminum hydride, sodium borohydride, lithium borohydride, SnCl 2 , SnF 2 , Sn (OH) 2 , sodium dithionite (reducing agent of color index 1), thiourea dioxide (reducing agent of color index 11), sodium sulfate color 2), zinc formaldehyde sulfoxylate (color index reducing agent 6), calcium formaldehyde carboxylate (color index reducing agent 12), sodium sulfite, sodium bisulfite, diisobutylaluminium hydride, oxalic acid, formic acid, ascorbic acid, (NH 4 ) 2 HPO 3 , CuHPO 3 , CuHPO 3 , CuHPO 2 (HPO 3 ) 3 , potassium hypophosphite, FeCl 2 , FeCO 3 , FeSO 4 . 6. Покрытое изделие по любому из пп. 1-5, в котором смола выбрана из группы, состоящей из фенольных смол, таких как фенолоформальдегидные смолы, мочевиноформальдегидные смолы, меламиноформальдегидные смолы, эпоксидных смол, винилсложноэфирных смол и сложнополиэфирных смол или их смеси, предпочтительно, фенольной смолы.6. Covered product according to any one of paragraphs. 1-5, in which the resin is selected from the group consisting of phenolic resins, such as phenol-formaldehyde resins, urea-formaldehyde resins, melamine-formaldehyde resins, epoxy resins, vinyl ester resins and polyester resins, or mixtures thereof, preferably phenolic resins. 7. Покрытое изделие по любому из пп. 1-6, в котором композиция смолы содержит краситель.7. Covered product according to any one of paragraphs. 1-6, in which the resin composition contains a dye. 8. Покрытое изделие по п. 7, в котором указанный краситель выбран из группы, состоящей из кислотного желтого 23, кислотного красного 18, кислотного желтого 36, кислотного черного 194, прямого красного 239, реактивного красного 120, кислотного голубого 9, кислотного красного 27, кислотного красного 51, прямого голубого 199, прямого красного 254, реактивного красного 195, кислотного красного 14, кислотного желтого 17, кислотного черного 1, прямого желтого 86, прямого черного 168 и пищевого черного 2.8. The coated product of claim 7, wherein said dye is selected from the group consisting of acid yellow 23, acid red 18, acid yellow 36, acid black 194, direct red 239, reactive red 120, acid blue 9, acid red 27 acid red 51, direct blue 199, direct red 254, reactive red 195, acid red 14, acid yellow 17, acid black 1, direct yellow 86, direct black 168 and food black 2. 9. Покрытое изделие по любому из пп. 1-8, которое дополнительно содержит слой подложки, предпочтительно, выбранный из группы, состоящей из картона, фанеры, древесно-стружечной плиты, древесно-волокнистой плиты, плиты из ориентированных cтренг ((ПОС)(OSB)), клееной древесины, ламинированного шпонового пиломатериала ((ЛШПМ)(LVL)), пиломатериала из параллельных стренг ((ПМПС)(PSL)) и пиломатериала из ориентированных стренг ((ПМОС)(OSL)), предпочтительно, фанеры.9. The coated product according to any one of paragraphs. 1-8, which further comprises a substrate layer, preferably selected from the group consisting of cardboard, plywood, chipboard, fiberboard, oriented strand board (OSB), glued wood, laminated veneer lumber ((LSLM) (LVL)), parallel strand lumber ((PHL) (PSL)) and oriented strand lumber ((EML) (OSL)), preferably plywood. 10. Композиция краски для нанесения печати на подложку, предпочтительно, бумагу, которая композиция содержит связующее, восстановитель и краситель или пигмент, в которой восстановитель имеет стандартный электродный потенциал Е0 от -150 мВ до - 1500 мВ.10. The ink composition for printing on a substrate, preferably paper, which composition contains a binder, a reducing agent and a dye or pigment, in which the reducing agent has a standard electrode potential E 0 from -150 mV to - 1500 mV. 11. Композиция краски по п. 10, в которой указанный восстановитель выбран из группы, состоящей из восстанавливающих сахаров, гидридов, органических кислот и неорганических солей.11. The paint composition of claim 10, wherein said reducing agent is selected from the group consisting of reducing sugars, hydrides, organic acids, and inorganic salts. 12. Композиция краски по п. 11, в которой восстановитель выбран из группы, состоящей из дигидроксиацетона, гликолевого альдегида, глицеринового альдегида, эритрозы, треозы, рибозы, арабинозы, ксилозы, ликсозы, аллозы, альтрозы, глюкозы, маннозы, гулозы, идозы, галактозы, талозы, фруктозы, лактозы, мальтозы, целлобиозы, диборана, литийалюминийгидрида, натрийборогидрида, литийборогидрида, SnCl2, SnF2, Sn(OH)2, натрийдитионита (восстановитель индекса цвета 1), диоксида тиомочевины (восстановитель индекса цвета 11), натрийгидроксиметан-сульфината (восстановитель индекса цвета 2), цинкформальдегидсульфоксилата (восстановитель индекса цвета 6), кальцийформальдегидкарбоксилата (восстановитель индекса цвета 12), сульфита натрия, бисульфита натрия, диизобутилалюминийгидрида, щавелевой кислоты, муравьиной кислоты, аскорбиновой кислоты, (NH4)2HPO3, CuHPO3, SnHPO3 и Al2(HPO3)3, калийгипофосфита, FeCl2, FeCO3, FeSO4.12. The paint composition according to claim 11, wherein the reducing agent is selected from the group consisting of dihydroxyacetone, glycolaldehyde, glycerol aldehyde, erythrose, threose, ribose, arabinose, xylose, lyxose, allose, altrose, glucose, mannose, gulose, idose, galactose, thalose, fructose, lactose, maltose, cellobiose, diborane, lithium aluminum hydride, sodium borohydride, lithium borohydride, SnCl 2 , SnF 2 , Sn (OH) 2 , sodium dithionite (reductant color index 1), thiourea dioxide 11 -sulfinate (rebound ovitel color index 2) tsinkformaldegidsulfoksilata (reductant color index 6) kaltsiyformaldegidkarboksilata (reductant Color Index 12), sodium sulfite, sodium bisulfite, diisobutylaluminum hydride, oxalic acid, formic acid, ascorbic acid, (NH 4) 2 HPO 3, CuHPO 3 SnHPO 3 and Al 2 (HPO 3 ) 3 , potassium hypophosphite, FeCl 2 , FeCO 3 , FeSO 4 . 13. Композиция краски по любому из пп. 10-12, в которой связующим является казеин, а восстановителем, предпочтительно, является фруктоза.13. The paint composition according to any one of paragraphs. 10-12, in which casein is a binder, and fructose is preferably a reducing agent. 14. Композиция краски по любому из пп. 11-13, которая содержит 0,5-20 мас.% восстановителя в расчете на сумму всех компонентов композиции.14. The paint composition according to any one of paragraphs. 11-13, which contains 0.5-20 wt.% Reducing agent calculated on the sum of all components of the composition. 15. Применение композиции краски, содержащей восстановитель, для обесцвечивания, по меньшей мере, частично композиции смолы, нанесенной на основной слой.15. The use of a paint composition containing a reducing agent to discolour at least partially the resin composition applied to the base layer. 16. Способ получения покрытого изделия, который содержит следующие стадии:16. A method of obtaining a coated product, which contains the following stages: а) обеспечение основного слоя, предпочтительно, бумаги,a) providing a base layer, preferably paper, b) нанесение композиции краски на основной слой, причем указанная композиция краски содержит один или более восстановителей,b) applying a paint composition to a base layer, said paint composition containing one or more reducing agents, с) пропитка основного слоя b) композицией смолы, иc) impregnation of the base layer b) a resin composition, and d) необязательно, ламинирование основного слоя с) на слой подложки.d) optionally, laminating the base layer c) onto a substrate layer.
RU2016101224A 2013-06-19 2014-06-18 Resin impregnated coated article with improved aesthetic properties RU2671327C2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13172877.6 2013-06-19
EP20130172877 EP2816154A1 (en) 2013-06-19 2013-06-19 Resin impregnated coated article with improved aesthetic properties
PCT/EP2014/001654 WO2014202216A1 (en) 2013-06-19 2014-06-18 Resin impregnated coated article with improved aesthetic properties

Publications (3)

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RU2016101224A true RU2016101224A (en) 2017-07-24
RU2016101224A3 RU2016101224A3 (en) 2018-04-03
RU2671327C2 RU2671327C2 (en) 2018-10-30

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WO (1) WO2014202216A1 (en)

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Publication number Priority date Publication date Assignee Title
CN109322211B (en) * 2018-09-28 2021-07-30 东莞市贝辉装饰材料有限公司 Silicon sheet amine-aldehyde resin glue, odorless adhesive film paper and preparation method
EP4155340A1 (en) * 2021-09-23 2023-03-29 Borealis AG Decoloration of polyolefins in the melt state

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US3952119A (en) * 1972-07-12 1976-04-20 Th. Goldschmidt Ag Process for coloring absorptive, rough surface paper
US5110320A (en) 1990-02-13 1992-05-05 Minnesota Mining And Manufacturing Company Abrasive products bonded with color stabilized base catalyzed phenolic resin
EP1194647A1 (en) * 1998-10-14 2002-04-10 The Mead Corporation Colorant application on the wet end of a paper machine
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RU2671327C2 (en) 2018-10-30
WO2014202216A1 (en) 2014-12-24
RU2016101224A3 (en) 2018-04-03
EP2816154A1 (en) 2014-12-24

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