RU2015125563A - PEROXIDE UTERINE MIXTURE BASED ON BIOSYNTHESE - Google Patents

PEROXIDE UTERINE MIXTURE BASED ON BIOSYNTHESE Download PDF

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RU2015125563A
RU2015125563A RU2015125563A RU2015125563A RU2015125563A RU 2015125563 A RU2015125563 A RU 2015125563A RU 2015125563 A RU2015125563 A RU 2015125563A RU 2015125563 A RU2015125563 A RU 2015125563A RU 2015125563 A RU2015125563 A RU 2015125563A
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masterbatch
paragraphs
polymer matrix
masterbatch according
peroxides
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RU2015125563A
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RU2654025C2 (en
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Пол Альберт ЯКОБУЧЧИ
Вилхелм Клас ФРЕЙЛИНК
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Акцо Нобель Кемикалз Интернэшнл Б.В.
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Priority claimed from PCT/EP2013/075192 external-priority patent/WO2014086693A1/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/005—Processes for mixing polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/203—Solid polymers with solid and/or liquid additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/20—Compounding polymers with additives, e.g. colouring
    • C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/36—After-treatment
    • C08J9/40—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/14—Peroxides

Claims (17)

1. Маточная смесь, содержащая один или более органических пероксидов в жидком виде, распределенных в полимерной матрице, содержащей, по меньшей мере, 50 мас.% биосмолы, где полимерная матрица имеет пористость, выраженную в виде процентной доли пустот в объеме матрицы, составляющую от 2,5 до 70 об.%, и концентрация воды в маточной смеси поддерживается на уровне 2000 ч./млн. или менее в расчете на суммарную массу маточной смеси.1. The masterbatch containing one or more organic peroxides in liquid form, distributed in a polymer matrix containing at least 50 wt.% Biosin, where the polymer matrix has a porosity expressed as a percentage of voids in the matrix volume, comprising 2.5 to 70 vol.%, And the concentration of water in the masterbatch is maintained at 2000 ppm. or less, based on the total weight of the masterbatch. 2. Маточная смесь по п. 1, в которой биосмола представляет собой полимер, который встречается в составе или производится живым организмом, или производится из мономеров или олигомеров, полученных из растений и/или животных.2. The masterbatch according to claim 1, in which the biosin is a polymer that is found in the composition or is produced by a living organism, or is made from monomers or oligomers obtained from plants and / or animals. 3. Маточная смесь по п. 2, в которой биосмола является полилактидом.3. The masterbatch of claim 2, wherein the biosin is a polylactide. 4. Маточная смесь по любому из предыдущих пунктов, в которой, по меньшей мере, один из одного или нескольких органических пероксидов выбирают из органических пероксидов, имеющих период полуразложения, равный одному часу при температуре 77°C или более.4. The masterbatch according to any one of the preceding paragraphs, in which at least one of the one or more organic peroxides is selected from organic peroxides having a half-life of one hour at a temperature of 77 ° C or more. 5. Маточная смесь по п. 4, в которой, по меньшей мере, один из одного или нескольких органических пероксидов выбирают из группы, состоящей из трет-бутилперокси-2-этилгексилкарбоната, 2,5-диметил-2,5-ди(трет-бутилперокси)гексана и циклических пероксидов кетонов, имеющих строение согласно любой из следующих формул:5. The masterbatch of claim 4, wherein at least one of the one or more organic peroxides is selected from the group consisting of tert-butyl peroxy-2-ethylhexyl carbonate, 2,5-dimethyl-2,5-di (tert β-butyl peroxy) hexane and cyclic ketone peroxides having a structure according to any of the following formulas:
Figure 00000001
,
Figure 00000001
, в которых R1-R6 независимо выбирают из группы, состоящей из водорода, C1-C20 алкильных, C3-C20 циклоалкильных, C6-C20 арильных, C7-C20 аралкильных и C7-C20 алкарильных групп, которые могут включать линейные или разветвленные алкильные фрагменты; и каждый из R1-R6 может необязательно быть замещен одной или более группами, выбираемыми из гидрокси-, алкокси-, линейных или разветвленных алкильных, арилокси-, сложноэфирных, карбокси-, нитрильных и амидогрупп.in which R 1 -R 6 independently selected from the group consisting of hydrogen, C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl, C 6 -C 20 aryl, C 7 -C 20 aralkyl and C 7 -C 20 alkaryl groups which may include linear or branched alkyl moieties; and each of R 1 -R 6 may optionally be substituted with one or more groups selected from hydroxy, alkoxy, linear or branched alkyl, aryloxy, ester, carboxy, nitrile and amido groups. 6. Маточная смесь по п. 5, в которой циклический пероксид кетона представляет собой 3,6,9-триэтил-3,6,9-триметил-1,4,7-трипероксонан.6. The masterbatch of claim 5, wherein the cyclic ketone peroxide is 3,6,9-triethyl-3,6,9-trimethyl-1,4,7-triperoxonan. 7. Маточная смесь по любому из пп. 1-3, содержащая от 4 до 40 мас.% органического пероксида.7. The masterbatch according to any one of paragraphs. 1-3, containing from 4 to 40 wt.% Organic peroxide. 8. Маточная смесь по любому из пп. 1-3, в которой полимерная матрица имеет пористость от 10 до 65 об.%.8. The masterbatch according to any one of paragraphs. 1-3, in which the polymer matrix has a porosity of from 10 to 65 vol.%. 9. Маточная смесь по любому из пп. 1-3, дополнительно содержащая растворитель.9. The masterbatch according to any one of paragraphs. 1-3, additionally containing a solvent. 10. Применение маточной смеси по любому из предыдущих пунктов для модификации полимеров.10. The use of the masterbatch according to any one of the preceding paragraphs for the modification of polymers. 11. Применение маточной смеси по п. 10 для повышения прочности расплава полилактида.11. The use of the masterbatch according to claim 10 to increase the strength of the polylactide melt. 12. Способ получения маточной смеси по любому из пп. 1-9, включающий стадии: 12. The method of obtaining the masterbatch according to any one of paragraphs. 1-9, including the stages: (i) обеспечения полимерной матрицы, содержащей, по меньшей мере, 50 мас.% биосмолы, и имеющей пористость, выраженную в виде процентной доли пустот в объеме матрицы, составляющую от 2,5 до 70 об.%, и содержание воды менее или равное 2000 ч./млн.;(i) providing a polymer matrix containing at least 50 wt.% bio resin, and having a porosity expressed as a percentage of voids in the matrix, ranging from 2.5 to 70 vol.%, and a water content of less than or equal to 2000 ppm; (ii) пропитки указанной полимерной матрицы одним или более пероксидами в жидком виде.(ii) impregnating said polymer matrix with one or more peroxides in liquid form. 13. Способ по п. 12, в котором содержание воды в биосмоле имеет значение, менее или равное 1000 ч./млн.13. The method according to p. 12, in which the water content in the bio-resin has a value less than or equal to 1000 ppm.
RU2015125563A 2012-12-05 2013-12-02 Peroxide masterbatch based on bioresin RU2654025C2 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201261733564P 2012-12-05 2012-12-05
US61/733,564 2012-12-05
EP13150135 2013-01-03
EP13150135.5 2013-01-03
PCT/EP2013/075192 WO2014086693A1 (en) 2012-12-05 2013-12-02 Peroxide masterbatch based on bioresin

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RU2654025C2 RU2654025C2 (en) 2018-05-15

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BR (1) BR112015011737A2 (en)
ES (1) ES2709724T3 (en)
IN (1) IN2015DN03935A (en)
MY (1) MY178296A (en)
PH (1) PH12015501206A1 (en)
RU (1) RU2654025C2 (en)
TR (1) TR201900799T4 (en)

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4225650A (en) * 1975-10-22 1980-09-30 Exxon Research & Engineering Co. Crosslinkable polymer powder and laminate
CA2022349C (en) * 1989-10-13 2001-07-17 Daryl L. Stein Peroxide masterbatches using polycaprolactone as the carrier
IT1260495B (en) * 1992-05-29 1996-04-09 Himont Inc CONCENTRATES SUITABLE FOR THE PREPARATION OF FUNCTIONALIZED POLYOLEFINS AND FUNCTIONALIZATION PROCESS THROUGH THOSE CONCENTRATES
AU686466B2 (en) * 1994-07-21 1998-02-05 Akzo Nobel N.V. Cyclic ketone peroxide formulations
RU2002117429A (en) * 2000-09-15 2003-12-20 Бэйселлтек Ю Эс Эй Инк. (Us) NON-EXTRUDED DISPERSIONS AND CONCENTRATES OF ADDITIVES IN OLEFIN POLYMERS
RU2304598C2 (en) * 2002-03-12 2007-08-20 Базелль Полиолефин Италия С.П.А. Composition of the mother batch for production of the polyolefin products by the injection molding
DE10220606A1 (en) * 2002-05-08 2003-11-20 Peroxid Chemie Gmbh & Co Kg Preparation for organic peroxides
US20060258796A1 (en) * 2005-05-13 2006-11-16 General Electric Company Crosslinked polyethylene compositions

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PH12015501206A1 (en) 2015-08-17
MY178296A (en) 2020-10-07
TR201900799T4 (en) 2019-02-21
IN2015DN03935A (en) 2015-10-02
RU2654025C2 (en) 2018-05-15
BR112015011737A2 (en) 2017-07-11

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Effective date: 20191203