RU2015117543A - LUBRICANT COMPOSITIONS CONTAINING BOROXINS TO IMPROVE COMPATIBILITY WITH FLUOROPOLYMER SEAL - Google Patents
LUBRICANT COMPOSITIONS CONTAINING BOROXINS TO IMPROVE COMPATIBILITY WITH FLUOROPOLYMER SEAL Download PDFInfo
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- RU2015117543A RU2015117543A RU2015117543A RU2015117543A RU2015117543A RU 2015117543 A RU2015117543 A RU 2015117543A RU 2015117543 A RU2015117543 A RU 2015117543A RU 2015117543 A RU2015117543 A RU 2015117543A RU 2015117543 A RU2015117543 A RU 2015117543A
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- lubricating composition
- group
- carbon atoms
- composition according
- boroxin
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M161/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a non-macromolecular compound, each of these compounds being essential
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/10—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/12—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic compound containing atoms of elements not provided for in groups C10M141/02 - C10M141/10
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/102—Aliphatic fractions
- C10M2203/1025—Aliphatic fractions used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
- C10M2205/0285—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/221—Six-membered rings containing nitrogen and carbon only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/26—Amines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
- C10M2223/045—Metal containing thio derivatives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/061—Esters derived from boron
- C10M2227/062—Cyclic esters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/36—Seal compatibility, e.g. with rubber
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/52—Base number [TBN]
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/08—Hydraulic fluids, e.g. brake-fluids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/12—Gas-turbines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/135—Steam engines or turbines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
1. Смазывающая композиция, содержащая:базовое масло;содержащее бороксин соединение, описывающееся общей формулой (I):в которой каждый Rнезависимо означает алкильную группу, содержащую от 1 до 7 атомов углерода; истерически затрудненный амин, включенный в количестве, находящемся в диапазоне от 0,5 до 5 мас. % в пересчете на полную массу указанной смазывающей композиции.2. Смазывающая композиция по п. 1 в которой каждый Rнезависимо означает алкильную группу, содержащую от 1 до 5 атомов углерода.3. Смазывающая композиция по п. 1 в которой каждый Rозначает метальную группу.4. Смазывающая композиция по п. 1, в которой указанное содержащее бороксин соединение включено в количестве, находящемся в диапазоне от 0,1 до 5 мас. %, в пересчете на указанную полную массу указанной смазывающей композиции.5. Смазывающая композиция по п. 1, в которой по меньшей мере 50% указанного содержащего бороксин соединения остается непрореагировавшим в указанной смазывающей композиции в пересчете на полную массу указанного содержащего бороксин соединения, применяющегося для получения указанной смазывающей композиции, до протекания какой-либо реакции в указанной смазывающей композиции.6. Смазывающая композиция по п. 1, отличающаяся тем, что она обладает совместимостью с фторполимером, такой, что фторполимерное уплотнение, погруженное в указанную смазывающую композицию, характеризуется изменением прочности на разрыв, составляющим менее 45% по данным тестирования в соответствии со стандартом СЕС L-39-T96; или отличающаяся тем, что она обладает совместимостью с фторполимером, такой, что фторполимерное уплотнение, погруженное в указанную смазывающую композицию, характеризуется изменением1. A lubricating composition comprising: a base oil, a boroxin-containing compound of the general formula (I): in which each R is independently an alkyl group containing from 1 to 7 carbon atoms; hysterically hindered amine, included in an amount in the range from 0.5 to 5 wt. % in terms of the total weight of the specified lubricating composition. 2. A lubricating composition according to claim 1, wherein each R independently means an alkyl group containing from 1 to 5 carbon atoms. A lubricating composition according to claim 1, wherein each R is a methyl group. A lubricating composition according to claim 1, wherein said boroxin-containing compound is included in an amount ranging from 0.1 to 5 wt. %, calculated on the specified total weight of the specified lubricating composition. 5. A lubricating composition according to claim 1, wherein at least 50% of said boroxin-containing compound remains unreacted in said lubricating composition, based on the total weight of said boroxin-containing compound used to prepare said lubricating composition, before any reaction occurs in said lubricating composition composition. 6. A lubricating composition according to claim 1, characterized in that it is compatible with a fluoropolymer, such that the fluoropolymer seal immersed in said lubricating composition is characterized by a change in tensile strength of less than 45% according to testing in accordance with CEC L-39 -T96; or characterized in that it is compatible with the fluoropolymer, such that the fluoropolymer seal immersed in said lubricating composition is characterized by a change
Claims (20)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
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US201261713088P | 2012-10-12 | 2012-10-12 | |
US201261713103P | 2012-10-12 | 2012-10-12 | |
US61/713,088 | 2012-10-12 | ||
US61/713,103 | 2012-10-12 | ||
PCT/US2013/064539 WO2014059277A1 (en) | 2012-10-12 | 2013-10-11 | Lubricant compositions comprising boroxines to improve fluoropolymer seal compatibility |
Publications (1)
Publication Number | Publication Date |
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RU2015117543A true RU2015117543A (en) | 2016-12-10 |
Family
ID=50475855
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2015117542A RU2015117542A (en) | 2012-10-12 | 2013-10-11 | LUBRICANT COMPOSITIONS CONTAINING BOROXINS AND AMINES TO IMPROVE COMPATIBILITY WITH FLUOROPOLYMER SEAL |
RU2015117543A RU2015117543A (en) | 2012-10-12 | 2013-10-11 | LUBRICANT COMPOSITIONS CONTAINING BOROXINS TO IMPROVE COMPATIBILITY WITH FLUOROPOLYMER SEAL |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2015117542A RU2015117542A (en) | 2012-10-12 | 2013-10-11 | LUBRICANT COMPOSITIONS CONTAINING BOROXINS AND AMINES TO IMPROVE COMPATIBILITY WITH FLUOROPOLYMER SEAL |
Country Status (12)
Country | Link |
---|---|
US (5) | US20150344806A1 (en) |
EP (2) | EP2906669A4 (en) |
JP (3) | JP5883200B2 (en) |
KR (2) | KR101576783B1 (en) |
CN (2) | CN104812878A (en) |
AU (2) | AU2013329021B2 (en) |
BR (2) | BR112015008110A2 (en) |
CA (2) | CA2894187A1 (en) |
MX (2) | MX2015004550A (en) |
RU (2) | RU2015117542A (en) |
WO (2) | WO2014059277A1 (en) |
ZA (2) | ZA201503231B (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20150344806A1 (en) * | 2012-10-12 | 2015-12-03 | Basf Se | Lubricant Compositions Comprising Trimethoxyboroxines and Sterically Hindered Amines To Improve Fluoropolymer Seal Compatibilty |
US9677023B2 (en) | 2014-04-09 | 2017-06-13 | Basf Se | Lubricating oil compositions containing seal compatibility additives and sterically hindered amines |
US9828566B2 (en) * | 2015-07-06 | 2017-11-28 | Afton Checmical Corporation | Boron free corrosion inhibitors for metalworking fluids |
US10550350B2 (en) | 2015-11-11 | 2020-02-04 | Afton Chemical Corporation | Boroxine based seal compatibility agents |
US10414999B2 (en) | 2016-01-22 | 2019-09-17 | Chevron Oronite Company Llc | Synergistic lubricating oil composition containing a mixture of olefin copolymer dispersant-type viscosity improver and amine compound |
US20190322958A1 (en) * | 2016-11-08 | 2019-10-24 | Basf Se | Lubricant Composition |
US10662391B2 (en) | 2017-02-21 | 2020-05-26 | Chevron Oronite Company Llc | Lubricating oil compositions containing borated dispersants and amine compounds and methods of making and using same |
US10435643B2 (en) * | 2017-03-06 | 2019-10-08 | Chevron Oronite Company Llc | Lubricating oil compositions containing amine compounds having improved seal performance |
WO2018203144A2 (en) * | 2017-05-04 | 2018-11-08 | Basf Se | Lubricant composition |
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IN169147B (en) * | 1986-04-04 | 1991-09-07 | Lubrizol Corp | |
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GB9705766D0 (en) * | 1997-03-20 | 1997-05-07 | Pilkington Plc | Boroxine compositions |
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WO2002062930A2 (en) * | 2001-02-07 | 2002-08-15 | The Lubrizol Corporation | Boron containing lubricating oil composition containing a low level of sulfur and phosphorus |
WO2004037959A1 (en) | 2002-10-25 | 2004-05-06 | University Of Chicago | Improved metalworking and machining fluids |
US20080020952A1 (en) * | 2004-10-19 | 2008-01-24 | Kazuhiro Yagishita | Lubricant Composition |
JP4663288B2 (en) * | 2004-10-19 | 2011-04-06 | Jx日鉱日石エネルギー株式会社 | Lubricating oil composition in contact with lead-containing metal material |
JP4461000B2 (en) * | 2004-11-25 | 2010-05-12 | 本田技研工業株式会社 | Grease composition for constant velocity joint and constant velocity joint |
AU2006259086B2 (en) * | 2005-06-13 | 2011-05-26 | Basf Se | Process for synthesis of dialkoxyorganoboranes |
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US7932218B2 (en) * | 2006-07-31 | 2011-04-26 | Ciba Corporation | Lubricant composition |
RU2493243C2 (en) * | 2009-02-02 | 2013-09-20 | Ар.Ти. ВАНДЕРБИЛТ КОМПАНИ, ИНК. | Ash-free lubricating composition |
CA2750650A1 (en) * | 2009-02-09 | 2010-08-12 | The Lubrizol Corporation | Method for improved performance of a functional fluid |
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US20150344806A1 (en) * | 2012-10-12 | 2015-12-03 | Basf Se | Lubricant Compositions Comprising Trimethoxyboroxines and Sterically Hindered Amines To Improve Fluoropolymer Seal Compatibilty |
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2013
- 2013-10-11 US US14/051,689 patent/US20150344806A1/en not_active Abandoned
- 2013-10-11 WO PCT/US2013/064539 patent/WO2014059277A1/en active Application Filing
- 2013-10-11 AU AU2013329021A patent/AU2013329021B2/en not_active Ceased
- 2013-10-11 BR BR112015008110A patent/BR112015008110A2/en not_active IP Right Cessation
- 2013-10-11 US US14/051,953 patent/US20150045262A1/en not_active Abandoned
- 2013-10-11 BR BR112015008109A patent/BR112015008109A2/en not_active Application Discontinuation
- 2013-10-11 MX MX2015004550A patent/MX2015004550A/en unknown
- 2013-10-11 US US14/051,742 patent/US20140106997A1/en not_active Abandoned
- 2013-10-11 RU RU2015117542A patent/RU2015117542A/en unknown
- 2013-10-11 KR KR1020157012372A patent/KR101576783B1/en not_active IP Right Cessation
- 2013-10-11 AU AU2013329028A patent/AU2013329028B2/en not_active Ceased
- 2013-10-11 EP EP13845613.2A patent/EP2906669A4/en not_active Withdrawn
- 2013-10-11 CA CA2894187A patent/CA2894187A1/en not_active Abandoned
- 2013-10-11 WO PCT/US2013/064531 patent/WO2014059270A1/en active Application Filing
- 2013-10-11 CN CN201380061256.7A patent/CN104812878A/en active Pending
- 2013-10-11 MX MX2015004548A patent/MX2015004548A/en unknown
- 2013-10-11 KR KR1020157012371A patent/KR101576782B1/en not_active IP Right Cessation
- 2013-10-11 US US14/051,931 patent/US20150045261A1/en not_active Abandoned
- 2013-10-11 CN CN201380061253.3A patent/CN104822810B/en not_active Expired - Fee Related
- 2013-10-11 JP JP2015536932A patent/JP5883200B2/en not_active Expired - Fee Related
- 2013-10-11 CA CA2894186A patent/CA2894186A1/en not_active Abandoned
- 2013-10-11 US US14/051,644 patent/US20140106996A1/en not_active Abandoned
- 2013-10-11 JP JP2015536936A patent/JP5882548B2/en not_active Expired - Fee Related
- 2013-10-11 RU RU2015117543A patent/RU2015117543A/en unknown
- 2013-10-11 EP EP13845754.4A patent/EP2906670A4/en not_active Withdrawn
-
2015
- 2015-05-11 ZA ZA2015/03231A patent/ZA201503231B/en unknown
- 2015-05-11 ZA ZA2015/03230A patent/ZA201503230B/en unknown
-
2016
- 2016-02-04 JP JP2016019812A patent/JP2016135872A/en not_active Withdrawn
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