CN104822810A

CN104822810A - Lubricant compositions comprising boroxines and amine compounds to improve fluoropolymer seal compatibility

Info

Publication number: CN104822810A
Application number: CN201380061253.3A
Authority: CN
Inventors: K·J·德山提斯; M·D·霍伊; A·阿特莱赛; R·L·库尔曼; D·查森; P·拉巴特
Original assignee: BASF SE
Current assignee: BASF SE
Priority date: 2012-10-12
Filing date: 2013-10-11
Publication date: 2015-08-05
Anticipated expiration: 2033-10-11
Also published as: CA2894187A1; WO2014059270A1; CN104822810B; BR112015008110A2; MX2015004550A; JP2015531428A; RU2015117543A; RU2015117542A; KR101576783B1; US20140106997A1; KR101576782B1; BR112015008109A2; JP2015531429A; EP2906669A4; EP2906670A4; EP2906669A1; AU2013329028A1; US20150045261A1; KR20150060996A; AU2013329021B2

Abstract

A lubricant composition including a boroxine compound is disclosed. An additive package including the boroxine compound is also disclosed. The lubricant composition and the additive package may additionally include an amine compound. The boroxine compound of the lubricant composition acts to improve compatibility of the lubricant composition with a fluoropolymer seal.

Description

Comprise boroxin and amine compound to improve the lubricant compositions of fluoropolymer seal part consistency

Invention field

The present invention relates generally to lubricant compositions, it comprises base oil, boroxin compound and amine compound.The invention still further relates to the additive-package for lubricant compositions.

Background of invention

Known with routine is joined by stablizer in the lubricant compositions based on mineral oil or synthetic oil, improves their performance.The amine compound of some routines is the effective stablizers for lubricant.During the amine compound of these routines can help and the acid formed in combustion method.But the amine compound of these routines is not used in oil engine usually, this is owing to they deleterious effects for fluoropolymer seal part.

An object of the present invention is to provide new lubricant composition, it has the fluoropolymer seal part consistency of improvement.

Summary of the invention

The invention provides lubricant compositions, it comprises base oil, boroxin compound and amine compound, and this amine compound, when testing according to ASTM D4739, has the total basicnumber of at least 80mg KOH/g.This boroxin compound has general formula (I):

Wherein each R ¹the alkyl with 1-7 carbon atom independently.The present invention also provides lubricant compositions, and it comprises base oil, the boroxin compound of general formula (I), and is selected from amine compound below: the stereo hindered amine compound of general formula (VI) or (VII):

Wherein each R ⁵hydrogen atom or the alkyl with 1-17 carbon atom independently, and wherein R ⁵at least two represented groups are alkyl; Wherein each R ⁶hydrogen atom or the alkyl with 1-17 carbon atom independently; Wherein each R ⁷hydrogen atom or the alkyl with 1-17 carbon atom independently, and wherein R ⁷at least two represented groups are alkyl; Wherein each R ⁸hydrogen atom or the alkyl with 1-17 carbon atom independently, and wherein R ⁵, R ⁶, R ⁷and R ⁸represented described alkyl is each is alcohol radical independently, alkyl, amide group, ether or ester group; The amine compound acyclic with monomer, its weight-average molecular weight is less than 500 and be made up of covalent linkage; With monomeric circular amine compound, its weight-average molecular weight is less than 500 and is not more than 2 nitrogen-atoms with comprising.

The invention still further relates to additive-package, it comprises the boroxin compound of general formula (I), and amine compound, and this amine compound, when testing according to ASTM D4739, has the total basicnumber of at least 80mg KOH/g.

The lubricant compositions comprising this boroxin compound shows the consistency improved with fluoropolymer seal part, and this is confirmed by CEC L-39-T96.

Detailed Description Of The Invention

As described below, boroxin compound can be included in lubricant compositions or in the additive-package of lubricant compositions, improve the sealing member consistency of this lubricant compositions.This boroxin compound can merge with one or more amine compound in lubricant compositions.It is believed that when being present in lubricant compositions together with amine compound, this boroxin compound and amine compound interact, when disturbing lubricant compositions to contact with fluoropolymer seal part, these amine compound and the disadvantageous interactional tendency of fluoropolymer seal part, and do not affect the stabilization effect of this amine compound.

This boroxin compound has general formula (I):

In general formula (I), each R ¹that there is the alkyl being equal to or less than 7 carbon atoms independently.Such as each R ¹can be that there is 1-7 independently, the alkyl of 1-6,1-5,1-4,1-3 or 1-2 carbon atom.Each R ¹can be straight chain or side chain independently.In one is specifically filled a prescription, each R ¹it can be methyl.Exemplary R ¹group can comprise methyl independently, ethyl, n-propyl, sec.-propyl, normal-butyl, sec-butyl, the tertiary butyl and n-hexyl.

This boroxin compound can example be trimethoxy boroxin, tripropoxy boroxin, three isopropoxy boroxins, three butoxy boroxins, three pentyloxy boroxins, three hexyloxy boroxins and three heptan oxygen boroxines.As an example, trimethoxy boroxin following formula carrys out example:

In certain embodiments, each R in formula (I) ¹different alkyl can be represented.Such as, this boroxin compound can carry out example with following formula:

Here R in formula (I) ¹a represented group is methyl, R in formula (I) ¹a represented group is ethyl, and R in formula (I) ¹a represented group is propyl group.Still selectively, R ¹represented group can be identical, and R ¹a represented group can be different in formula (I).

This boroxin compound can be comprised in such amount in this lubricant compositions and/or additive-package, and this amount is enough to the boron concentration providing expectation in this lubricant compositions and/or additive-package.Such as, this boroxin compound can be enough to provide the amount of 1-5000ppm boron involved in this lubricant compositions, based on the gross weight of this lubricant compositions.Selectively, this boroxin compound can amount with such in this lubricant compositions or additive-package involved, it is enough to provide 100-5000,300-3000 in this lubricant compositions, the boron of 500-1500 or 700-1200ppm, based on the gross weight of this lubricant compositions.Still selectively, this boroxin compound can be enough to provide 1-100 in this lubricant compositions, and the amount of 1-40,1-20 or 10-20ppm boron provides, based on the gross weight of this lubricant compositions.

Selectively, the amount of this boroxin compound in this lubricant compositions can be 0.1-10,0.1-5,0.1-1,0.3-0.7,0.5-3 or 0.5-1.5wt%, based on the gross weight of this lubricant compositions.In other embodiments, this boroxin compound is greater than 1wt%, but the amount being less than 5wt% is involved, based on the gross weight of this lubricant compositions.The mixture of different rings boroxane compound also may be used for this lubricant compositions or additive-package combined.

If be formulated as additive-package, then the amount of this boroxin compound can be 0.1-75wt%, based on the gross weight of this additive-package.This boroxin compound also can exist with the amount of 0.1-50,0.1-33 or 0.1-25wt% in this additive-package, based on the gross weight of this additive-package.

This boroxin compound can be prepared via numerous methods.But as an example, this boroxin compound can by the orthoboric acid (H of 2mol ₃bO ₃) prepare with the trialkylborates of 1mol.This boron alkyl acid esters can have 1-7 carbon atom, and this depends on R in general formula (I) ¹the carbonatoms expected in represented group.This reaction can be carried out the temperature of 50-150 DEG C, to remove the H of 1mol ₂o.

The normal usage of conventional boron compound is included in forming reactions product between conventional amine compound and the boron compound of routine.The boron compound of this routine can example be reactive boric acid ester and boric acid.In the application of these routines, conventional boron compound is consumed by chemical reaction, can the boron compound of routine of the amount of measuring to make the final lubricant compositions formed not comprise.In addition, in such applications, the amine compound of this routine reacts to form salt with conventional boron compound.The formation of this salt is confirmed by the electron bombardment when boron compound of routine and the reaction of conventional amine compound, and it is visible as chemical shift in NMR spectrum.Also there is the physics instruction of reacting and carrying out, such as, release heat and solution retrogradation (being cross-linked).

In the application that the boron compound of routine is such, before reactions, the boron compound being greater than the routine of 50wt% can react with the amine compound of routine, or hydrolysis, based on the gross weight of the boron compound of this routine.On the contrary, lubricant compositions of the present invention, additive-package and practical methods can comprise a large amount of boroxin compound being in unreacted state.In addition, actual lubricant compositions, actual additive-package and practical methods do not relate to the formation of the salt of a large amount of boroxin compounds.Therefore, this lubricant compositions can not containing the salt formed by the reaction of boroxin compound, or can comprise and be less than 10, be less than 5 or be less than the salt formed by the reaction of this boroxin compound of 1wt%, based on the gross weight of this lubricant compositions after any reaction.

In certain embodiments, in this lubricant compositions before any reaction, at least 50, at least 60, at least 70, at least 80 or this boroxin compound of at least 90wt% remain unreacted in lubricant compositions, based on being used for the gross weight of the boroxin compound forming this lubricant compositions.Selectively, in this lubricant compositions before any reaction, at least 95, at least 96, at least 97, at least 98 or this boroxin compound of at least 99wt% remain unreacted in lubricant compositions, based on the gross weight of boroxin compound.

Term " unreacted " refers to such fact, that is, the amine compound that the boroxin compound of amount shown is such as not conventional with any component in this lubricant compositions or water react.Therefore, before this lubricant compositions is for terminal applies such as oil engine, when being present in this lubricant compositions, the boroxin compound of unreacted amount maintains its health state.

Wording " in this lubricant compositions before any reaction " refers to the amount based on boroxin compound in this lubricant compositions.This specification sheets does not need other component reaction in boroxin compound and lubricant compositions, namely, in lubricant compositions before any reaction, in this lubricant compositions, the boroxin compound of 100wt% can remain unreacted, based on the gross weight of this boroxin compound.

In one embodiment, the per-cent remaining unreacted boroxin compound is that whole components existing in this lubricant compositions reach measuring afterwards of balancing each other.The time reached in this lubricant compositions needed for balance can extensively change.Such as, the time quantum reached needed for balance can be several minutes to a couple of days, or even several weeks.In certain embodiments, the per-cent remaining unreacted boroxin compound in this lubricant compositions is at 1 minute, 1 hour, 5 hours, 12 hours, 1 day, 2 days, 3 days, 1 week, January, measures after June or 1 year.Usually, the per-cent remaining unreacted boroxin compound in this lubricant compositions measures before the final use.

In certain embodiments, this lubricant compositions comprises and is less than 0.1, is less than 0.01, and the compound reacted with boroxin compound being less than 0.001 or being less than 0.0001wt%, based on the gross weight of this lubricant compositions.In certain embodiments, this lubricant compositions can comprise entire amount and be less than the acid of the 0.1wt% of lubricant compositions gross weight, acid anhydrides, triazole and/or oxide compound.Selectively, this lubricant compositions can comprise that entire amount is less than lubricant compositions gross weight 0.01, be less than 0.001 or be less than the acid of 0.0001wt%, acid anhydrides, triazole and/or oxide compound.Still selectively, this lubricant compositions can not contain acid, acid anhydrides, triazole and/or oxide compound.

Term " acid " comprises both traditional acid and Lewis acid.Such as acid comprises carboxylic acid such as lactic acid and hydroxy-propionic acid; Alkylated succinic acid; Alkyl aromatic sulfonic acid; And lipid acid.Exemplary Lewis acid comprises aluminic acid alkyl ester (salt); Alkyl titanate (salt); Molybdate such as thiocarbamate molybdenum and carboxylamine molybdenum; And moly-sulfide.

" acid anhydrides " example is alkylating succinyl oxide and acrylate.Triazole can example be benzotriazole and derivative thereof; Tolytriazole and derivative thereof; 2-mercaptobenzothiazole, 2,5-dimercaptothiodiazole, 4,4'-methylene radical-bis--benzotriazole, 4,5,6,7-tetrahydrochysene-benzotriazole and salt thereof.Oxide compound can example be oxirane, such as oxyethane and propylene oxide; Metal oxide; Alcohol alcoxylates; Or alkoxylation ester.

This lubricant compositions can comprise and be less than 100, is less than 50, is less than 10 or be less than the B (OH) of 5ppm ₃ ^-ion, based on this lubricant compositions gross weight.Conventional boroxin compound can be hydrolyzed, to make the B (OH) being greater than 100ppm before they merge with conventional lubricant compositions ₃ ^-ion is present in conventional lubricant compositions.In such hydrolysis state, present inventor recognizes that the boroxin compound of formed routine is not provided in the effect that sealing member consistency is expected surprisingly.In other words, at least 50, at least 60, at least 70, at least 80, at least 90, at least 95 or the boroxin compound of at least 99wt% in lubricant compositions, be in non-hydrolyzed state, based on this boroxin compound gross weight.When measuring the amount of the unreacted boroxin compound of above-mentioned maintenance, the amount of the boroxin compound be hydrolyzed be considered, as above.

In addition, this boroxin compound does not have a negative impact to the total basicnumber (TBN) of lubricant compositions.The TBN value of this lubricant compositions can measure according to ASTM D2896 as described below and ASTM D4739.

As mentioned above, this boroxin compound can merge with at least one amine compound.Should be appreciated that the mixture of different amine compound also can merge with this boroxin compound.If comprised, then this lubricant compositions comprises 0.1-25, and the amine compound of 0.1-20,0.1-15 or 0.1-10wt% amount, based on this lubricant compositions gross weight.Selectively, this lubricant compositions can comprise 0.5-5, and the amine compound of 1-3,1-2wt% amount, based on this lubricant compositions gross weight.

This amine compound does not react to form salt with boroxin compound substantially.The formation that there is not salt is that the chemical potential in-migration do not existed in NMR spectrum proves by this boroxin compound and amine compound when they are incorporated in lubricant compositions and/or additive-package.In other words, after this lubricant compositions and/or additive-package reach balance, at least 50,60,70,80,90,95 or the amine compound of 99wt% remain unreacted.

The basicity of this amine compound can be measured by acidometric titration.The neutralization number obtained is expressed as TBN, and diverse ways can be used to measure.ASTM D4739 is a kind of electromotive force HCI.ASTM D4739 method is favourable in Engine Block Test, and measures TBN loss/maintenance together with used oil.When the engine lubricant of test, be to be understood that some weak base is the result used, but not gather in oil.This testing method may be used for representing under oxidisability or other working conditionss, the relative change in use occurred in lubricant compositions, is no matter the color of formed lubricant compositions, or other performances.

When testing according to ASTM D4739, the TBN value of this amine compound can be at least 80mgKOH/g.Selectively, when testing according to ASTM D4739, the TBN value of this amine compound can be at least 90, at least 100, at least 110, at least 120, at least 130, at least 140, at least 150 or at least 160mg KOH/g.

If comprise this amine compound in additive-package, then this additive-package comprises the amine compound of 0.1-50wt% amount, based on this additive-package gross weight.Selectively, this additive-package can comprise 1-25, the amine compound of the amount of 0.1-15,1-10,0.1-8 or 1-5wt%, based on this additive-package gross weight.The combination of different amine compound also it is expected to.

In some embodiments, this amine compound comprises at least one nitrogen-atoms.In other embodiments, this amine compound does not comprise triazole, triazine or similar compound, here existence 3 or more nitrogen in the ring body of Cheng Huan.

In some embodiments, this amine compound can by or substantially by hydrogen, carbon, nitrogen and oxygen composition.Selectively, this amine compound by or substantially by hydrogen, carbon and nitrogen composition.In the context of amine compound, wording " substantially by ... composition " refer to such compound, at least the amine compound of 95mol% is described atom (that is, hydrogen, carbon, nitrogen and oxygen here; Or hydrogen, carbon and nitrogen).If such as this amine compound hydrogen substantially, carbon, nitrogen and oxygen composition, then at least this amine compound of 95mol% is hydrogen, carbon, nitrogen and oxygen.In some configurations, at least 96, at least 97, at least 98, at least 99 or this amine compound of at least 99.9mol% be hydrogen, carbon, nitrogen and oxygen, or be carbon, nitrogen and hydrogen in other embodiments.

This amine compound can be made up of covalent linkage.Wording " is made up of " object covalent linkage be get rid of those compounds, and it is bonded on amine compound by the ion relevant to one or more ionic atoms or compound.That is, in the structure that amine compound is made up of covalent linkage wherein, this amine compound eliminates the salt of amine compound, such as phosphate amine salt and amine salt.Therefore, in certain embodiments, this lubricant compositions does not have the salt of amine compound.More specifically, this lubricant compositions can not phosphoric acid amine salt, amine salt and/or sulfuric acid amine salt.

In other embodiments, this amine compound can be the acyclic amine compound of monomer that weight-average molecular weight is less than 500.Selectively, the weight-average molecular weight of the amine compound that this monomer is acyclic can be less than 450, is less than 400, is less than 350, be less than 300, be less than 250, is less than 200 or be less than 150.

Term " monomer " object represents that described compound does not comprise to be greater than 3, is greater than 2 or be greater than 1 repeated monomer unit bonded together.Selectively, term monomer can refer to the compound not comprising any repeated monomer unit.In other words, term " monomer " object gets rid of such compound, and it is oligopolymer or polymkeric substance.But compound such as diethylamide do not got rid of in term " monomer ".

Term " acyclic " object represents such compound, and it is without any ring structure and get rid of aromatic structure.Such as, the acyclic amine compound of this monomer does not comprise such compound, and it has the ring of at least 3 atoms be bonded together in ring structure, and comprises benzyl, those compounds of phenyl or triazolyl.

The acyclic amine compound of this monomer can example be general formula (II):

Here each R ²hydrogen atom or alkyl independently.Each R ²can be alcohol radical independently, amino, alkyl, amide group, ether or ester group.In the amine compound that this monomer is acyclic, R ²1-50 can be had independently, 1-25,1-17,1-15,1-12,1-8,1-6 or 1-4 carbon atom.R ²represented each group can be straight chain or side chain independently.The acyclic amine of this monomer comprises monoamine, diamines and polyamines.Such as each R ²can be the alcohol radical with 1-50 carbon atom, amino, alkyl, amide group, ether or ester group, and described functional group (alcohol radical etc.) is bonded on the different positions in carbochain.

In certain embodiments, R ²at least one represented group is unsubstituted.Selectively, R ²two or three represented groups are unsubstituted.Still selectively, it is expected to R ²1,2 or 3 represented group replaces." unsubstituted " is meant to shown group not such as, containing Pendant functional groups, hydroxyl, carboxyl, oxygen base, sulfenyl and thiol group, and shown group does not contain without ring hetero atom, such as oxygen, sulphur and nitrogen heteroatom.Shown in term " replacement " represents, group comprises at least one Pendant functional groups, or shown group comprises at least one without ring hetero atom.

Exemplary alkyl R ²can independently selected from methyl, ethyl, n-propyl, normal-butyl, sec-butyl, the tertiary butyl, n-hexyl, n-octyl, 2-ethylhexyl, n-nonyl, positive decyl, n-undecane base, dodecyl, n-tridecane base, n-tetradecane base, n-hexadecyl or Octadecane base.

The acyclic amine compound of exemplary monomer includes but not limited to primary, secondary and tertiary amine, such as:

Methylamine:

Thanomin:

Dimethyl amine:

Mono Methyl Ethanol Amine:

Trimethylamine:

Two (2-ethylhexyl) amine:

Two (tridecyl) amine:

The acyclic amine compound of this monomer can be selectively one or more other primary amine such as ethylamines, n-propyl amine, isopropylamine, n-butylamine, isobutylamine, sec-butylamine, tert-butylamine, amylamine, and hexyl amine; The primary amine of following formula: CH ₃-O-C ₂h ₄-NH ₂, C ₂h ₅-O-C ₂h ₄-NH ₂, CH ₃-O-C ₃h ₆-NH ₂, C ₂h ₅-O-C ₃h ₆-NH ₂, C ₄h ₉-O-C ₄h ₈-NH ₂, HO-C ₂h ₄-NH ₂, HO-C ₃h ₆-NH ₂with HO-C ₄h ₈-NH ₂; Secondary amine is diethylamide such as, methylethyl amine, di-n-propyl amine, diisopropylamine, diisobutyl amine, di-sec-butyl amine, di-t-butyl amine, diamyl amine, dihexyl amine; And the secondary amine of following formula: (CH ₃-O-C ₂h ₄) ₂nH, (C ₂h ₅-O-C ₂h ₄) ₂nH, (CH ₃-O-C ₃h ₆) ₂nH, (C ₂h ₅-O-C ₃h ₆) ₂nH, (n-C ₄h ₉-O-C ₄h ₈) ₂nH, (HO-C ₂h ₄) ₂nH, (HO-C ₃h ₆) ₂nH and (HO-C ₄h ₈) ₂nH; With polyamines such as positive Pn, Isosorbide-5-Nitrae-butane diamine, 1,6-hexane diamine, diethylenetriamine, triethylene tetramine, tetraethylene pentamine, and their alkylate, such as 3-(dimethylamino)-n-propyl amine, N, N-dimethylvinylsiloxy diamines, N, N-diethyl ethylene diamine and N, N, N ', N '-tetramethyl-diethylenetriamine.

Selectively, this amine compound can be monomeric circular amine compound.The weight-average molecular weight of this monomeric circular amine compound can be 100-1200,200-800 or 200-600.Selectively, the weight-average molecular weight of this monomeric circular amine compound can be less than 500.

Term " ring " is intended to represent the compound comprising any such molecule, and this molecule has the atom that at least 3 are bonded together to be formed ring.In some embodiments, term " ring " does not comprise aromatic substance.Therefore in some embodiments, monomeric circular amine compound does not have aromatic group, such as phenyl and benzyl rings.

This monomeric circular amine compound can comprise 2 or less nitrogen-atoms/molecule.Selectively, this monomeric circular amine compound can comprise only 1 nitrogen/molecule.Wording " nitrogen/molecule " refers to the nitrogen-atoms sum in whole molecule, comprises molecular bulk and any side joint substituting group.In certain embodiments, this monomeric circular amine compound comprises 1 or 2 nitrogen-atoms at the loop section of this monomeric circular amine compound.

This monomeric circular amine compound can example be general formula (III):

or

General formula (IV)

Here Z has represented into the necessary atom of ring ring.Ring represented by Z can comprise 2-20,3-15,5-15 carbon atom.Ring represented by Z can use alkyl, hydroxyl, amino, amide group, carboxyl, ether, oxygen base, and sulfenyl and mercaptan side base replace, and can comprise oxygen and sulfur heteroatom.In certain embodiments, the nonnitrogenous heteroatoms of the ring represented by Z.

In formula (III), R ³hydrogen atom or alkyl.If R ³alkyl, then R ³can be alcohol radical, amino, alkyl, amide group, ether or ester group.R ³can 1-50 be had, 1-25,1-17,1-15,1-12,1-8,1-6, or 1-4 carbon atom.R ³can be straight chain or side chain.Such as each R ³can be the alcohol groups with 1-50 carbon atom, amino, alkyl, amide group, ether or ester group, and described group (amino etc.) be bonded on the different positions of carbochain.

In a more particular embodiment, this monomeric circular amine compound can example be logical formula V:

In logical formula V, each R ⁴hydrogen atom or the alkyl with 1-17 carbon atom independently.Each R ⁴can be alcohol radical independently, amino, alkyl, amide group, ether or ester group.Each R ⁴1-17 can be had independently, 1-15,1-12,1-8,1-6 or 1-4 carbon atom.R ⁴represented each group can be straight chain or side chain independently.In certain embodiments, R ⁴at least one represented group is unsubstituted.Selectively, R ⁴represented at least two, three, four, five or six groups are unsubstituted.Still selectively, it is expected to R ⁴represented one, two, three, four, five or six groups replace.Such as each R ⁴can be the alcohol groups with 1-17 carbon atom, amino, alkyl, amide group, ether or ester group, and described functional group is bonded on the different positions of carbochain.

Exemplary monomer cyclic amine compound comprises:

Cyclopentyl amine:

Cyclo-hexylamine:

Ethylenimine:

Piperidines:

N-methyl piperidine:

In some embodiments, the amine compound that this monomer is acyclic or monomeric circular amine compound can be stereo hindered amine compounds.In one or more embodiments, the weight-average molecular weight of this stereo hindered amine compound can be 100-1200.Selectively, the weight-average molecular weight of this stereo hindered amine compound can be 200-800, or 200-600.Still selectively, the weight-average molecular weight of this stereo hindered amine compound can be less than 500.

As used herein, term " stereo hindered amine compound " represents such organic molecule, and it has and is bonded to relative at least one alpha-carbon of secondary or tertiary N atom is less than two hydrogen atoms.In other embodiments, term " stereo hindered amine compound " represents such organic molecule, and it does not have the hydrogen atom be bonded to relative at least one alpha-carbon of secondary or tertiary N atom.In other embodiments still, term " stereo hindered amine compound " represents such organic molecule, its do not have be bonded to relative to secondary or tertiary N atom at least two alpha-carbon each on hydrogen atom.

This stereo hindered amine compound can have general formula (VI) or (VII):

In general formula (VI), each R ⁵hydrogen atom or the alkyl with 1-17 carbon atom independently, at least two R in one of them molecule ⁵it is alkyl; And R ⁶hydrogen atom or the alkyl with 1-17 carbon atom independently.In general formula (VII), each R ⁷hydrogen atom or the alkyl with 1-17 carbon atom, wherein at least two R independently ⁷alkyl, and each R ⁸hydrogen atom or the alkyl with 1-17 carbon atom independently.

Each R ⁵, R ⁶, R ⁷and R ⁸can be alcohol radical independently, alkyl, amide group, ether or ester group.Each R ⁵, R ⁶, R ⁷and R ⁸1-17 can be had independently, 1-15,1-12,1-8,1-6 or 1-4 carbon atom.R ⁵, R ⁶, R ⁷and R ⁸represented each group can be straight chain or side chain independently.Such as each R ⁵, R ⁶, R ⁷and R ⁸can be the alcohol groups with 1-17 carbon atom, amino, alkyl, amide group, ether or ester group, and described functional group is bonded on the different positions of carbochain.

In certain embodiments, R ⁵, R ⁶, R ⁷and R ⁸at least one represented group is unsubstituted.Selectively, R ⁵, R ⁶, R ⁷and R ⁸represented at least two, three, four, five or six groups are unsubstituted.In other embodiments, R ⁵, R ⁶, R ⁷and R ⁸represented each group is unsubstituted.Still selectively, it is expected to R ⁵, R ⁶, R ⁷and R ⁸represented one, two, three, four, five or six groups replace.

Exemplary R ⁵, R ⁶, R ⁷and R ⁸group can independently selected from methyl, ethyl, n-propyl, normal-butyl, sec-butyl, the tertiary butyl, n-hexyl, n-octyl, 2-ethylhexyl, n-nonyl, positive decyl, n-undecane base, dodecyl, n-tridecane base, n-tetradecane base, n-hexadecyl or Octadecane base.

In general formula (VI), R ⁵represented at least two, at least three or whole four groups are alkyl independently.Similarly, in general formula (VII), R ⁷at least two represented groups are alkyl.Selectively, R ⁷represented at least three or whole four groups are alkyl.

The stereo hindered amine compound of general formula (VI) can example be compound below:

2,2,6,6-tetramethyl--4-octyl group piperidines:

2,2,6,6-tetramethyl--4-decyl piperidines:

2,2,6,6-tetramethyl--4-butyl piperidine:

2,2,6,6-tetramethyl--4-hexadecyl piperidines:

The stereo hindered amine compound of general formula (VII) is acyclic.Term " acyclic " object represents that the stereo hindered amine compound of general formula (VII) is without any ring structure and aromatic structure.The stereo hindered amine compound of general formula (VII) can example be:

The N-tertiary butyl-2-ethyl-N-methyl-own-1-amine:

Tert .-amyl-tert .-butyl amine:

The N-tertiary butyl-2-in heptan amine:

This stereo hindered amine compound can example be selectively general formula (VIII):

In general formula (VIII), each R ⁵and R ⁶as mentioned above, wherein at least three R ⁵alkyl independently.The stereo hindered amine compound of general formula (VIII) can example be compound below:

(1,2,2,6,6-pentamethyl--4-piperidyl) octanoate:

(1,2,2,6,6-pentamethyl--4-piperidyl) decylate:

(1,2,2,6,6-pentamethyl--4-piperidyl) dodecylate:

(2,2,6,6-tetramethyl--4-piperidyl) dodecylate

This stereo hindered amine compound can comprise monoesters group.But this stereo hindered amine compound can selectively containing ester group.In certain embodiments, this stereo hindered amine compound can comprise at least one or an only piperidine ring.

This boroxin compound and amine compound can provide with such amount, to make in lubricant compositions, the boron of 1 part are supplied to every 1-20 part nitrogen of this amine compound.Selectively, this boroxin compound and amine compound can provide with such amount, to make in lubricant compositions, the boron of 1 part are supplied to every 1-15,1-10 or 1-5 part nitrogen of this amine compound.

In another embodiment still, this lubricant compositions can by or substantially by base oil, boroxin compound and amine compound composition.It is also contemplated that except one or more additives (it produces substantial effect to the function of this boroxin compound or performance), this lubricant compositions by or substantially by base oil, boroxin compound and amine compound composition.Such as, the compound of the overall performance of this lubricant compositions of substantial effect can comprise such compound, its TBN to this lubricant compositions promotion property, oilness, fluoropolymer seal part consistency, corrosion-inhibiting or acidity create disadvantageous effect.

In other embodiments, this additive-package can by or be substantially made up of boroxin compound and amine compound.It is also contemplated that except one or more additives (it does not jeopardize function or the performance of this boroxin compound), this additive-package can also by or be substantially made up of boroxin compound and amine compound.When for mentioning additive-package, term " substantially by ... composition " describes this additive-package produces substantial effect compound to the overall performance of this lubricant compositions.Such as, the compound bag overall performance of this additive being produced to substantial effect can comprise such compound, and its TBN to additive-package promotion property, oilness, fluoropolymer seal part consistency, corrosion-inhibiting or acidity create disadvantageous effect.

In some respects, this lubricant compositions comprises base oil.Base oil is classified according to American Petroleum Institute (API) base oil interchangeability guide.In other words, base oil can further describe is one or more of five type base oils: Group I (sulphur content >0.03wt%, and/or <90wt%, saturates, viscosity index 80-119); Group II (sulphur content is less than or equal to 0.03wt%, and is greater than or equal to 90wt%, saturates, viscosity index 80-119); Group III (sulphur content is less than or equal to 0.03wt%, and is more than or equal to 90wt%, saturates, and viscosity index is more than or equal to 119); Group IV (being all polyalphaolefin (PAO)); With Group V (other base oils whole not included in I, II, III or IV group).

This base oil is selected from API Group I base oil; API Group II base oil; API Group III base oil; API Group IV base oil; API Group V base oil; And combination.In a concrete formula, this base oil comprises API Group II base oil.

When according to ASTM D445 100 DEG C test time, this base oil viscosity can be 1-20cSt.Selectively, when according to ASTM D445 100 DEG C test time, this base oil viscosity can be 3-17 or 5-14cSt.

This base oil can be further defined as the crankcase oil for spark ignition and compression-ignition engine, comprises automobile and truck engine, two-cycle engine, aviation piston engine, ship engine and rail diesel engine.Selectively, this base oil can be further defined as gas blowing engine, diesel motor, the oil in constant power engine and turbine.This base oil can be further defined as heavy type or light duty engine oil.

In other embodiments still, this base oil can be further defined as synthetic oil, and it comprises one or more alkylene oxide polymers and interpretation and derivative thereof.The terminal hydroxy group of this alkylene oxide polymer can pass through esterification, and etherificate or similar reaction carry out modification.These synthetic oils can be prepared as follows: form polyoxyalkylene polymers by the polymerization of oxyethane or propylene oxide, and it can react to form synthetic oil further.Such as can use alkyl and the aryl ethers of these polyoxyalkylene polymers.Such as, the methyl of molecular-weight average 1000 gathers Isopropanediol ether; The diphenyl ether of the polyoxyethylene glycol of molecular weight 500-1000; Or the Anaesthetie Ether of the polypropylene glycol of molecular weight 1000-1500 and/or its list-and polycarboxylate, such as acetic ester, the C of mixing ₃-C ₈fatty acid ester, and the C of Tetraglycol 99 ₁₃oxoacid diester also can be used as base oil.

In one embodiment, be mixed in additive-package by one or more components described herein, it is mixed into subsequently in base oil and manufactures lubricant compositions.This additive-package can prepare the base oil of working as additive-package and predetermined amount when merging, and provides the concentration of expectation in lubricant compositions.Should be appreciated that great majority mention that the content of lubricant compositions is also applicable to describe this additive-package in entirety of the present invention.Such as, be to be understood that this additive-package can comprise or get rid of the component identical with lubricant compositions, although be in different amounts.

The amount of this base oil in lubricant compositions can be 50-99.9,60-99.9,70-99.9,80-99.9,90-99.9,75-95,80-90 or 85-95wt%, based on this lubricant compositions gross weight.Selectively, the amount of this base oil in this lubricant compositions can be greater than 50,60,70,75,80,85,90,95, and 98 or 99wt%, based on this lubricant compositions gross weight.In different embodiments, base oil is 50-99,60-90,80-99.5,85-96 or 90-95wt% in the amount of the lubricant compositions prepared completely (comprising the situation of thinner or carrier oil existence), based on this lubricant compositions gross weight.In different embodiments, if comprised, then the amount of base oil in additive-package (comprising the situation of thinner or carrier oil existence) is 0.1-50,1-25 or 1-15wt%, based on additive-package gross weight.

In one or more embodiments, this lubricant compositions can be categorized as low SAPS lubricant, and its sulphating ash content is not more than 3,2, and 1 or 0.5wt%, based on this lubricant compositions gross weight.Term " SAPS " refers to vitriol ashing, p and s.

The TBN value of this lubricant compositions can be at least 1mg KOH/g lubricant compositions.Selectively, when testing according to ASTM D2896, the TBN value of this lubricant compositions is 1-15,5-15 or 9-12mg KOH/g lubricant compositions.

Except boroxin compound and/or amine compound, this lubricant compositions or additive-package can also comprise dispersion agent further.This dispersion agent can polyalkene amines.This polyalkene amines comprises polyethylene fraction.This polyethylene fraction is identical or different, the C of straight chain or side chain _2-6the polymerisate of olefinic monomer.The example of suitable olefinic monomer is ethene, propylene, 1-butylene, iso-butylene, 1-amylene, 2-methyl butene, 1-hexene, 2-methylpentene, 3-methylpentene and 4-methylpentene.The weight-average molecular weight of this polyethylene fraction is 200-10000,500-10000 or 800-5000.

In one embodiment, this polyalkene amines is derived from polyisobutene.Specially suitable polyisobutene is referred to as " hyperergy " polyisobutene, it is characterized in that the terminal double bond of high-content.Terminal double bond is the alpha-olefin double bond of general formula (IX) shown type:

Key shown in general formula (IX) is referred to as vinylidene double bond.Suitable highly reactive polyisobutenes is such as such polyisobutene, and its vinylidene double bond mark is greater than 70,80,85mol%.Preferably particularly such polyisobutene, it has uniform polymer backbone.Uniform polymeric skeleton is those polyisobutene particularly, and it comprises the isobutene units of at least 85,90 or 95wt%.The preferred number-average molecular weight of such highly reactive polyisobutenes is in above-mentioned scope.In addition, the polydispersity of this highly reactive polyisobutenes can be 1.05-7, or 1.1-2.5.The polydispersity of this highly reactive polyisobutenes can be less than 1.9 or be less than 1.5.Polydispersity refers to the business of weight-average molecular weight Mw divided by number-average molecular weight Mn.

This amine dispersion agent can comprise derived from succinyl oxide, and has hydroxyl and/or amino and/or amide group and/or imide part.Such as this dispersion agent can derived from polyisobutenyl succinic anhydride, its can by the routine of weight-average molecular weight 500-5000 or highly reactive polyisobutenes and maleic anhydride react to obtain by hot route reaction or via the polyisobutene of chlorination.Such as, can use and there is aliphatic polyamine such as ethylene diamine, diethylenetriamine, the derivative of triethylene tetramine or tetraethylene pentamine.

In order to prepare this polyalkene amines, this polyolefin component can carry out amination by known way.Illustrative methods prepares oxa-intermediate through hydroformylation, and under suitable nitrogen compound exists, reductive amination carries out subsequently.

This dispersion agent can be poly-(oxyalkyl) group or the polyalkylene polyamine group of general formula (X):

R ⁹-NH-(C ₁-C ₆-alkylidene group-NH) _m-C ₁-C ₆-alkylidene group (X)

Here m is integer 1-5, R ⁹hydrogen atom or the alkyl with 1-6 carbon atom, and C ₁-C ₆alkylidene group represents the corresponding bridging analogue of alkyl.This dispersion agent also can be polyalkyleneimine group, and it comprises 1-10 C ₁-C ₄alkylene imine group; Or be bonded to them together with the nitrogen-atoms on it, be optional 5-to the 7-unit heterocyclic ring replaced, it is optionally by 1-3 C ₁-C ₄alkyl replaces, and optionally with other ring hetero atom such as an oxygen or nitrogen.

The example of suitable thiazolinyl comprises the list-of the alkyl with 2-18 carbon atom or polyunsaturated, preferably single-or two undersaturated analogues, and wherein double bond can be in any position of hydrocarbon chain.

C ₄-C ₁₈the example of cycloalkyl comprises cyclobutyl, cyclopentyl and cyclohexyl, and by 1-3 C ₁-C ₄the analogue that alkyl replaces.This C ₁-C ₄alkyl is such as selected from methyl, ethyl, different or n-propyl, just, different, the secondary or tertiary butyl.

The example of arylalkyl comprises C ₁-C ₁₈alkyl and aryl, it is derived from monocycle or 4-to 7-unit that is bicyclic condensed or non-condensed, particularly 6 yuan of aromatics or heteroaromatic group, such as phenyl, pyridyl, naphthyl and xenyl.

If use the other dispersion agent of non-above-mentioned dispersion agent, then these dispersion agents can be dissimilar.The example that dispersion agent is suitable comprises polybutenylsuccinic acid amides or-imide, polybutylene-based phosphonate derivative and alkaline magnesium, calcium and barium sulfonate and phenates, succinate and alkylphenol amine (the strange alkali of Manny), and combination.

If used, this dispersion agent can use with different amounts.The amount of this dispersion agent in lubricant compositions can be 0.01-15,0.1-12,0.5-10 or 1-8wt%, based on this lubricant compositions gross weight.Selectively, the amount of this dispersion agent can be less than 15, is less than 12, is less than 10, is less than 5 or be less than 1wt%, each gross weight based on this lubricant compositions.

In this additive-package, the gross weight of dispersion agent and boroxin compound can be additive-package be less than 50, be less than 45, be less than 40, be less than 35 or be less than 30wt%, based on the gross weight of this additive-package.Surprisingly, have been found that if the total excessive concentration of dispersion agent and boroxin compound in additive-package, then reaction will occur between dispersion agent and boroxin compound, this causes thickening and forms throw out, reduces the fluoropolymer seal part consistency of this lubricant compositions simultaneously.

This lubricant compositions or additive-package can comprise dialkyl dithiophosphate further.This dialkyl dithiophosphate can represent with general formula below: [R ¹⁰o (R ¹¹o) PS (S)] ₂m, here R ¹⁰and R ¹¹each is the alkyl with 1-20 carbon atom, and wherein M is atoms metal or ammonium.Such as R ¹⁰and R ¹¹can eachly be C independently _1-20alkyl, C _2-20thiazolinyl, C _3-20cycloalkyl, C _1-20aralkyl or C _3-20aryl.R ¹⁰and R ¹¹represented group can be to replace or unsubstituted.This atoms metal can be selected from aluminium, plumbous, tin, manganese, cobalt, nickel or zinc.This ammonium can derived from ammonia or primary, secondary or tertiary amine.This ammonium can be formula R ¹²r ¹³r ¹⁴r ¹⁵n ⁺, wherein R ¹², R ¹³, R ¹⁴and R ¹⁵each alkyl representing hydrogen atom independently or there is 1-150 carbon atom.In certain embodiments, R ¹², R ¹³, R ¹⁴and R ¹⁵can eachly be the alkyl with 4-30 carbon atom independently.In a kind of specific embodiment, this dialkyl dithiophosphate is zinc dialkyl dithiophosphate.

The amount of this dialkyl dithiophosphate in lubricant compositions can be 0.1-20,0.5-15,1-10,0.1-5,0.1-1,0.1-0.5 or 0.1-1.5wt%, each based on this lubricant compositions gross weight.Selectively, the amount of this dialkyl dithiophosphate can be less than 20, is less than 10, is less than 5, be less than 1, is less than 0.5 or be less than 0.1wt%, each based on this lubricant compositions gross weight.This additive-package also can comprise the dialkyl dithiophosphate of following amounts: 0.1-20,0.5-15,1-10,0.1-5,0.1-1,0.1-0.5 or 0.1-1.5wt%, each based on this additive-package gross weight.

This lubricant compositions or additive-package can comprise one or more additives in addition to improve the various chemistry of this lubricant compositions and/or physicals.These additives can join boroxin compound or join in the composition of boroxin compound and amine compound.The concrete example of these one or more additives comprises antiwear additive, antioxidant, metal passivator (or passivator), rust-preventive agent, viscosity index improver, pour point depressant, dispersion agent, sanitising agent and wear-preventive additive.Each additive may be used singly or in combin.These one or more additives in use consumption can be different.This lubricant compositions can add several assisted group and assign to prepare, to realize some performance objective for some application.Such as this lubricant compositions can be corrosion and oxidation lubricant batching, and waterpower lubricant is prepared burden, turbine lubricants oil and internal combustion engine lubricant batching.Therefore, it is expected to base oil can prepare to realize these targets, as described below.

In use, antiwear additive can be dissimilar.This antiwear additive can comprise sulfur-bearing-and/or phosphorus-and/or halogen-compound, such as olefine sulfide and vegetables oil, alkylating triphenyl, tricresyl phosphate (triolyl phosphate), tricresyl phosphate (tricresyl phosphate), clorafin, alkyl and aryl two-and trithio, the amine salt of list-and dialkyl phosphate, the amine salt of methyl-phosphorous acid, diethanolamino methyl toluene base triazole, two (2-ethylhexyl) amino methyl tolyl-triazole, 2, 5-dimercapto-1, 3, the derivative of 4-thiadiazoles, 3-[(diisopropoxy phosphinothioyl) sulfo-] ethyl propionate, triphenylphosphorothionate (triphenyl phosphorus sulfonyl), three (alkyl phenyl) phosphorothioate and composition thereof, phenylbenzene list nonyl phenyl phosphorothioate, isobutyl phenenyl diphenylphosphine sulfonyl, 3-hydroxyl-1, the dodecyl amine salt of 3-sulphur phosphorus heterocycle butane 3-oxide compound, trithio phosphoric acid 5, 5, 5-tri-[iso-octyl 2-acetic ester], 2-mercaptobenzothiazole derivative is 1-[N such as, two (2-ethylhexyl) amino methyl of N-]-2-sulfydryl-1H-1, 3-benzothiazole, ethoxy carbonyl-5-octyl group dithiocarbamate and/or its combination.

In use, in addition or replace above-mentioned dialkyl dithiophosphate, this antiwear additive can use with different amounts.The amount of this antiwear additive in this lubricant compositions can be 0.1-20,0.5-15,1-10,0.1-1,0.1-0.5 or 0.1-1.5wt%, each based on this lubricant compositions gross weight.Selectively, the amount of this antiwear additive can be less than 20, is less than 10, is less than 5, be less than 1, is less than 0.5 or be less than 0.1wt%, each gross weight based on this lubricant compositions.

In use, this antioxidant can be dissimilar.Suitable antioxidant comprises alkylating single phenol, such as 2, 6-di-t-butyl-4-sylvan, the 2-tertiary butyl-4, 6-dimethyl phenol, 2, 6-di-t-butyl-4-ethyl phenol, 2, 6-di-t-butyl-4-normal-butyl phenol, 2, 6-di-t-butyl-4-isobutyl-phenol, 2, 6-bicyclopentyl-4-sylvan, 2-(Alpha-Methyl cyclohexyl)-4, 6-dimethyl phenol, 2, 6-bis-(octadecyl)-4-sylvan, 2, 4, 6-thricyclohexyl phenol, 2, 6-di-t-butyl-4-methoxymethyl phenol, 2, 6-dinonyl-4-sylvan, 2, 4-dimethyl-6 (1'-methylundecane-1'-base) phenol, 2, 4-dimethyl-6-(1'-methyl heptadecane-1'-base) phenol, 2, 4-dimethyl-6-(1'-methyltridec-1'-base) phenol and combination thereof.

The other example of suitable antioxidant comprises alkylthiomethyl phenol, such as 2,4-dioctyl thiomethyl-6-tert-butyl phenols, 2,4-dioctyl thiomethyl-6-sylvan, 2,4-dioctyl thiomethyl-6-ethyl phenol, 2,6-docosyl sulphomethyl-4-nonyl phenol and combination thereof.Also Resorcinol and alkylating Resorcinol can be used, such as 2,6-di-t-butyl-4-methoxyl group phenol, 2,5-di-tert-butyl hydroquinone, 2,5-bis-tert-pentyl Resorcinol, 2,6-phenylbenzene-4-octadecyl oxygen phenol, 2,6-di-tert-butyl hydroquinone, 2,5-di-t-butyl-4-hydroxyanisol, 3,5-di-t-butyl-4-hydroxyanisol, 3,5-di-tert-butyl-hydroxy phenyl stearate, two-(3,5-di-tert-butyl-hydroxy phenyl) adipic acid ester and combination thereof.

In addition, also hydroxylated thiodiphenyl ethers can be used, such as 2,2'-thiobis (the 6-tertiary butyl-4-sylvan), 2,2'-thiobis (4-octyl phenol), 4,4'-thiobis (the 6-tertiary butyl-3-sylvan), 4,4'-thiobis (the 6-tertiary butyl-2-sylvan), 4,4'-thiobis-(3,6-di-sec-amyl phenol), 4,4'-pair-(2,6-dimethyl-4-hydroxy phenyl) disulphide and combination thereof.

Can also be expected that alkylidene bisphenols, such as 2, 2'-methylene-bis (the 6-tertiary butyl-4-sylvan), 2, 2'-methylene-bis (the 6-tertiary butyl-4-ethyl phenol), 2, 2'-methylene-bis [4-methyl-6-(Alpha-Methyl cyclohexyl) phenol], 2, 2'-methylene-bis (4-methyl-6-cyclohexyl phenol), 2, 2'-methylene-bis (6-nonyl-4-sylvan), 2, 2'-methylene-bis (4, 6-di-tert-butylphenol), 2, 2'-ethylenebis (4, 6-di-tert-butylphenol), 2, 2'-ethylenebis (the 6-tertiary butyl-4-isobutyl-phenol), 2, 2'-methylene-bis [6-(α-methylbenzyl)-4-nonyl phenol], 2, 2'-methylene-bis [6-(α, α-dimethylbenzyl)-4-nonyl phenol], 4, 4'-methylene-bis (2, 6-di-tert-butylphenol), 4, 4'-methylene-bis (the 6-tertiary butyl-2-sylvan), 1, two (5-tertiary butyl-4-hydroxy-2-aminomethyl phenyl) butane of 1-, 2, two (the 3-tertiary butyl-5-methyl-2-the hydroxybenzyl)-4-sylvan of 6-, 1, 1, 3-tri-(5-tertiary butyl-4-hydroxy-2-aminomethyl phenyl) butane, 1, two (5-tertiary butyl-4-hydroxy-2-the methylphenyl)-3-dodecyl sulfydryl butane of 1-, ethylene glycol bis [3, two (the 3'-tertiary butyl-4'-hydroxy phenyl) butyric ester of 3-], two (3-tertiary butyl-4-hydroxy-5-methylphenyl) Dicyclopentadiene (DCPD), two [2-(the 3'-tertiary butyl-2'-hydroxyl-5'-the methyl-benzyl)-6-tertiary butyl-4-aminomethyl phenyl] terephthalate, 1, 1-two-(3, 5-dimethyl-2-hydroxy phenyl) butane, 2, 2-two-(3, 5-di-tert-butyl-hydroxy phenyl) propane, 2, 2-pair-(5-tertiary butyl-4-hydroxy-2-aminomethyl phenyl)-4-dodecyl sulfydryl butane, 1, 1, 5, 5-tetra--(5-tertiary butyl-4-hydroxy-2-aminomethyl phenyl) pentane and combination thereof can be used in this lubricant compositions as antioxidant.

Also O-, N-and S-benzyl compounds such as 3 can be used, 5,3', 5'-tetra-tert-4,4'-dihydroxyl dibenzyl ether, 4-hydroxyl-3,5-dimethyl benzyl Thiovanic acid stearyl, three-(3,5-di-tert-butyl-4-hydroxyl benzyl) amine, two (the 4-tertiary butyl-3-hydroxyl-2,6-dimethyl benzyl) two mercaptan terephthalate, two (3,5-di-tert-butyl-4-hydroxyl benzyl) sulfide, 3,5-di-tert-butyl-4-hydroxyl benzyl Thiovanic acid isooctyl acrylate and combination thereof.

Hvdroxvbenzvlated malonates, such as 2,2-two-(3,5-di-t-butyl-2-hydroxybenzyl)-propanedioic acid two (octadecyl) ester, 2-(3-tertiary butyl-4-hydroxy-5-methyl-benzyl)-propanedioic acid two (octadecyl) ester, mercaptoethyl-2,2-two-(3,5-di-tert-butyl-4-hydroxyl benzyl) propanedioic acid two (dodecyl) ester, two [4-(1,1,3,3-tetramethyl butyl) phenyl]-2,2-two (3,5-di-tert-butyl-4-hydroxyl benzyl) malonic esters and combination thereof be also suitable for use as antioxidant.

Also triaizine compounds such as 2 can be used, two (the octylmercapto)-6-(3 of 4-, 5-di-t-butyl-4-hydroxybenzene amido)-1, 3, 5-triazine, 2-octylmercapto-4, 6-two (3, 5-di-t-butyl-4-hydroxybenzene amido)-1, 3, 5-triazine, 2-octylmercapto-4, 6-two (3, 5-di-t-butyl-4-hydroxyphenoxy)-1, 3, 5-triazine, 2, 4, 6-tri-(3, 5-di-t-butyl-4-hydroxyphenoxy)-1, 2, 3-triazine, 1, 3, 5-tri-(3, 5-di-tert-butyl-4-hydroxyl benzyl) chlorinated isocyanurates, 1, 3, 5-tri-(the 4-tertiary butyl-3-hydroxyl-2, 6-dimethyl benzyl 2, 4, 6-tri-(3, 5-di-tert-butyl-hydroxy phenyl ethyl)-1, 3, 5-triazine, 1, 3, 5-tri-(3, 5-di-tert-butyl-hydroxy phenyl propionyl)-six hydrogen-1, 3, 5-triazine, 1, 3, 5-tri--(3, 5-dicyclohexyl-4-hydroxybenzyl)-chlorinated isocyanurates and combination thereof.

The other example of antioxidant comprises Aromatic hydroxybenzyl compound, such as 1,3,5-tri--(3,5-di-tert-butyl-4-hydroxyl benzyl)-2,4,6-Three methyl Benzene, Isosorbide-5-Nitrae-bis-(3,5-di-tert-butyl-4-hydroxyl benzyl)-2,3,5,6-tetramethyl-benzene, 2,4,6-tri-(3,5-di-tert-butyl-4-hydroxyl benzyl) phenol and combination thereof.Also benzylphosphonic acid ester can be used, such as 2,5-di-tert-butyl-4-hydroxyl benzyl dimethyl phosphonate, 3,5-di-tert-butyl-4-hydroxyl benzyl diethyl phosphonate, 3,5-di-tert-butyl-4-hydroxyl benzyl phosphonic acids two (octadecyl) ester, 5-tertiary butyl-4-hydroxy 3-methylbenzylphosphonic acid two (octadecyl) ester, the calcium salt of single ethyl ester of 3,5-di-tert-butyl-4-hydroxyl benzyl phosphonic acids and combination thereof.In addition, acyl amino phenol such as 4-hydroxylauric aniline is also had, 4-hydroxy stearate aniline, and N-(3,5-di-tert-butyl-hydroxy phenyl) carboxylamine octyl group ester.

[3-(3 can also be used, 5-di-tert-butyl-hydroxy phenyl) propionic acid and single-or the ester of polyhydroxy-alcohol, such as with methyl alcohol, ethanol, Stearyl alcohol, 1, 6-hexylene glycol, 1, 9-nonanediol, ethylene glycol, 1, 2-propylene glycol, neopentyl glycol, Thiodiglycol, glycol ether, triglycol, tetramethylolmethane, three (hydroxyethyl) chlorinated isocyanurates, N, two (hydroxyethyl) oxamide of N'-, 3-thiaundecanol, 3-thiapentadecanol, trimethylammonium hexylene glycol, TriMethylolPropane(TMP), 4-methylol-1-phosphorus-2, 6, the ester of 7-trioxa-l-phosphabicyclo [2.2.2] octane and combination thereof.It is expected to the ester that can use β-(5-tertiary butyl-4-hydroxy-3-aminomethyl phenyl)-propionic acid and list-or polyhydroxy-alcohol further, such as with methyl alcohol, ethanol, Stearyl alcohol, 1, 6-hexylene glycol, 1, 9-nonanediol, ethylene glycol, 1, 2-propylene glycol, neopentyl glycol, Thiodiglycol, glycol ether, triglycol, tetramethylolmethane, three (hydroxyethyl) chlorinated isocyanurates, N, two (hydroxyethyl) oxamide of N'-, 3-thiaundecanol, 3-thiapentadecanol, trimethylammonium hexylene glycol, TriMethylolPropane(TMP), 4-methylol-1-phosphorus-2, 6, the ester of 7-trioxa-l-phosphabicyclo [2.2.2] octane and combination thereof.

The other example of suitable antioxidant comprises nitrogenous those; the acid amides of such as β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid, such as N; N'-two (3; 5-di-tert-butyl-hydroxy phenyl propionyl) hexamethylene-diamine, N, N'-two (3; 5-di-tert-butyl-hydroxy phenyl-propionyl) trimethylene diamine; two (3, the 5-di-tert-butyl-hydroxy phenyl propionyl) hydrazine of N, N'-.Other suitable examples of antioxidant comprise amine antioxidant such as N, N'-di-isopropyl-P-pHENYLENE dI AMINE, N, N'-di-sec-butyl-P-pHENYLENE dI AMINE, N, N'-two (1, 4-dimethyl amyl group)-P-pHENYLENE dI AMINE, N, two (1-ethyl-3-the methyl amyl)-P-pHENYLENE dI AMINE of N'-, N, two (1-the methylheptyl)-P-pHENYLENE dI AMINE of N'-, N, N'-dicyclohexyl-P-pHENYLENE dI AMINE, N, N'-diphenyl-p-phenylene diamines, N, two (2-the naphthyl)-P-pHENYLENE dI AMINE of N'-, N-sec.-propyl-N'-phenyl-p-phenylene diamine, N-(1, 3-dimethyl-butyl)-N'-phenyl-p-phenylene diamine, N-(1-methylheptyl)-N'-phenyl-p-phenylene diamine, N-cyclohexyl-N'-phenyl-p-phenylene diamine, 4-(paratoluenesulfonic acid acyl) diphenylamine, N, N'-dimethyl-N, N'-di-sec-butyl-P-pHENYLENE dI AMINE, diphenylamine, N-allyl group diphenylamine, 4-isopropoxydiphenylamine, N-phenyl-1-naphthylamine, N-phenyl-2-ALPHA-NAPHTHYL AMINE, octylatcd diphenylamine, such as p, the tertiary octyldiphenylamine of p'-bis-, 4-n-butylamino phenol, 4-butyryl radicals amino phenol, 4-nonanoyl amino phenol, 4-lauroyl amino phenol, 4-octadecanoyl amino phenol, two (4-p-methoxy-phenyl) amine, 2, 6-di-t-butyl-4-dimethylaminomethyl phenol, 2, 4'-diaminodiphenyl-methane, 4, 4'-diaminodiphenyl-methane, N, N, N', N'-tetramethyl--4, 4'-diaminodiphenyl-methane, 1, 2-two [(2-methylphenyl) is amino] ethane, 1, two (phenyl amino) propane of 2-, (o-tolyl) biguanides, two [4-(1', 3'-dimethylbutyl) phenyl] amine, tertiary octylatcd N-phenyl-1-naphthylamine, the mixture of the tertiary butyl/tertiary octyldiphenylamine of list-and di, the mixture of the sec.-propyl/isohexyl diphenylamine of list-and di, the mixture of the tert-butyl diphenyl amine of list-and di, 2, 3-dihydro-3, 3-dimethyl-4H-1, 4-benzothiazine, thiodiphenylamine, N-allyl group thiodiphenylamine, N, N, N', N'-tetraphenyl-1, 4-diamino but-2-ene and combination thereof.

The even other example of suitable antioxidant comprises aliphatics or aromatic phosphite, the ester of thio-2 acid or thiodiglycolic acid, or the salt of dithiocarbamic acid or phosphorodithioic acid, 2,2,12,12-tetramethyl--5,9-dihydroxyl-3,7,1 trithio tridecane and 2,2,15,15-tetramethyl--5,12-dihydroxyl-3,7,10,14-tetrathio n-Hexadecane and combination thereof.In addition, the fatty ester of sulfuration can be used, sulfurized fatty and olefine sulfide and combination thereof.

In use, this antioxidant can use with different amounts.The amount of this antioxidant in this lubricant compositions can be 0.01-5,0.1-3 or 0.5-2wt%, based on the gross weight of this lubricant compositions.Selectively, the amount of this antioxidant can be less than 5, is less than 3 or be less than 2wt%, based on the gross weight of this lubricant compositions.

In use, this metal passivator can be dissimilar.Suitable metal passivator comprises benzotriazole and derivative thereof, such as 4-or 5 alkyl benzotriazole (such as tolytriazole) and derivatives thereof, 4,5,6,7-tetrahydro benzo triazole and 5,5'-methylene-bis benzotriazole; The strange alkali of Manny of benzotriazole or tolytriazole, such as 1-[two (2-ethylhexyl) amino methyl) tolytriazole and 1-[two (2-ethylhexyl) amino methyl) benzotriazole; With alkoxyalkyl benzotriazole such as 1-(yloxymethyl in the ninth of the ten Heavenly Stems) benzotriazole, 1-(1-butoxyethyl group) benzotriazole and 1-(1-cyclohexyl oxygen-butyl) tolytriazole and combination thereof.

The other example of suitable metal passivator comprises 1,2,4-triazole and derivative thereof, and the strange alkali of the Manny of 1,2,4-triazole, such as 1-[two (2-ethylhexyl) aminomethyl-1,2,2,4-triazole; Alkoxyalkyl-1,2,4-triazole is 1-(1-butoxyethyl group)-1,2,4-triazoles such as; With the 3-amino-1,2,4-triazole of acidylate, imdazole derivatives such as 4,4'-methylene-biss (2-undecyl-5-Methylimidazole) and two [(N-methyl) imidazoles-2-base] methyl alcohol Octyl Ether and combination thereof.The other example of suitable metal passivator comprises sulfur heterocyclic ring compound such as 2-mercaptobenzothiazole, 2,5-dimercapto-1,3,4-thiadiazole and derivative thereof; [two (2-ethylhexyl) amino methyl]-1,3,4-Thiadiazoline-2-ketone and combinations thereof two with 3,5-.The even other example of metal passivator comprises aminocompound, such as salicylidene Pn, salicylaminoguanidine and salt thereof, and combination.

In use, this metal passivator can use with different amounts.The amount of this metal passivator in this lubricant compositions can be 0.01-0.1,0.05-0.01 or 0.07-0.1wt%, based on the gross weight of this lubricant compositions.Selectively, the amount of this metal passivator can be less than 1.0, is less than 0.7 or be less than 0.5wt%, based on the gross weight of this lubricant compositions.

In use, this rust-preventive agent and/or friction change agent can be dissimilar.The example that rust-preventive agent and/or friction change agent suitable comprises organic acid, their ester, metal-salt, such as alkyl-and alkenyl succinic acid and they and alcohol, the partial ester of glycol or hydroxycarboxylic acid, the inclined acid amides of alkyl-and alkenyl succinic acid, 4-nonylphenoxyacetic acid, alkoxyl group-and alkoxyethoxy carboxylic acid such as dodecyl fluoroacetic acid, dodecyl oxygen (oxyethyl group) acetic acid, and N-oleoylsarcosine, sorbitan monooleates, lead naphthenate, alkenyl succinic anhydride is dodecenyl succinic anhydride such as, 2-carboxymethyl-1-dodecyl-3-methylglycerin(e) and combination thereof.Other example comprises heterogeneous ring compound such as: the tetrahydroglyoxaline of replacement is with oxazoline, with 2-heptadecene base-1-(2-hydroxyethyl) tetrahydroglyoxaline, P contained compound is such as: the amine salt of phosphoric acid partial ester or phosphonic acids partial ester, molybdate compound, such as molybdenum dithiocarbamate and other sulfur-bearings and phosphorus derivant, sulfocompound, such as: dinonyl naphthalene sulfonate barium, calcium mahogany sulfonate, the aliphatic carboxylic acid that alkyl sulfide replaces, the ester of aliphatics 2-sulfonate carboxylic acid and salt thereof, glycerol derivative, such as: XU 61518.10, 1-(alkyl phenoxy)-3-(2-hydroxyethyl) glycerine, 1-(alkyl phenoxy)-3-(2, 3-dihydroxypropyl) glycerine and 2-carboxyalkyl-1, 3-dialkyl glycerol and combination thereof.

In use, this rust-preventive agent and/or friction change agent can use with different amounts.It can be 0.01-0.1,0.05-0.01 or 0.07-0.1wt% that this rust-preventive agent and/or friction change the amount of agent in lubricant compositions, based on this lubricant compositions gross weight.Selectively, this rust-preventive agent and/or friction change the amount of agent can be less than 1, is less than 0.7 or be less than 0.5wt%, based on this lubricant compositions gross weight.

In use, this viscosity index improver can be dissimilar.The example that viscosity index improver is suitable comprises polyacrylic ester, polymethacrylate, vinyl pyrrolidone/alkylmethacrylate polymer, Polyvinylpyrolidone (PVP), polybutene, olefin copolymer, phenylethylene ethylene/propenoic acid ester copolymer and polyethers and combination thereof.

In use, this viscosity index improver can use with different amounts.The amount of this viscosity index improver in this lubricant compositions can be 0.01-20,1-15 or 1-10wt%, based on this lubricant compositions gross weight.Selectively, the amount of this viscosity index improver can be less than 10, is less than 8 or be less than 5wt%, based on this lubricant compositions gross weight.

In use, this pour point depressant can be dissimilar.The example that pour point depressant is suitable comprises polymethacrylate and alkylating naphthalene derivatives, and combination.

In use, this pour point depressant can use with different amounts.The amount of this pour point depressant in this lubricant compositions can be 0.01-0.1,0.05-0.01 or 0.07-0.1wt%, each based on this lubricant compositions gross weight.Selectively, the amount of this pour point depressant can be less than 1.0, is less than 0.7 or be less than 0.5wt%, based on this lubricant compositions gross weight.

In use, this sanitising agent can be dissimilar.The example that sanitising agent is suitable comprises high-alkali or neutral metal sulfonate (ester), phenates (ester) and salicylate (ester) and combination thereof.

In use, this sanitising agent can use with different amounts.The amount of this sanitising agent in this lubricant compositions can be 0.01-5,0.1-4,0.5-3 or 1-3wt%, based on this lubricant compositions gross weight.Selectively, the amount of this sanitising agent can be less than 5, is less than 4, is less than 3, is less than 2 or be less than 1wt%, based on this lubricant compositions gross weight.

In different embodiments, this lubricant compositions is substantially free of water, and such as this lubricant compositions comprises and is less than 5, is less than 4, is less than 3, is less than 2, is less than 1, is less than 0.5 or be less than the water of 0.1wt%, based on this lubricant compositions gross weight.Selectively, this lubricant compositions can be completely not moisture.

There is provided for comprising those with the preferred lubricant compositions used according to the present invention, it have passed the compatibility test of CEC L-39-T96 sealing member.CEC L-39-T96 tests to comprise and the test sample book of fluoropolymer is remained in the lubricant compositions of 150 DEG C.Then shift out seal sample, and dry, evaluate the performance of seal sample, and be not contained in the sealing member sample heated in this lubricant compositions and compare.Evaluate the per-cent of these performance variation, quantize the consistency of fluoropolymer seal part and lubricant compositions.Compared with not having the lubricant compositions of boroxin compound, boroxin compound is mixed in lubricant compositions the tendency reducing this lubricant compositions degraded sealing member.

By/be not included in fresh oil by standard and soak after 7 days, when there is no preconditioning, the maximum velocity of variation of some characteristic.The maximum velocity of variation of each characteristic depends on elastomeric type used, the type of engine used, and whether uses after-treatment device.

Characteristic measured before and after soaking comprises hardness DIDC (point); Tensile strength (%); Elongation at break (%); Volume change (%).For heavy duty diesel engine, pass through/do not provided in table 1 below by standard:

Table 1: for the fluoropolymer seal part consistency of CEC L-39-T96

In these tests, if it is-1% to+5% that the test sample book exposed to the open air shows changes in hardness; Tensile strength (compared with the sample do not tested) is-50% to+10%; Elongation at break change (compared with the sample do not tested) is-60% to+10%; Be-1% to+5% with volume change (compared with the sample do not tested), then conventional lubricant compositions is by test.

When this lubricant compositions be test according to the CEC L-39-T96 for heavy duty diesel engine time, changes in hardness can be-1 to 5% ,-0.5 to 5% ,-0.1 to 5%, 0.5 to 5%, or 1 to 5%; The change of tensile strength can be-50 to 10% ,-45 to 10% ,-40 to 10%, or-35 to 10%; The change of elongation at break can be-60 to 10% ,-55 to 10% ,-50 to 10%, or-45 to 10%; Can be-1 to 5% ,-0.75 to 5% ,-0.5 to 5% ,-0.1 to 5% with the change of volume change, or 0 to 5%.

When this boroxin composition is used in described lubricant compositions, the lubricant compositions formed has certain fluoropolymer consistency, to make when testing according to the CEC L-39-T96 for heavy duty diesel engine, the fluoropolymer seal part immersed in described lubricant compositions shows and is less than 10, be less than 15, be less than 20, be less than 25, be less than 30, be less than 35, be less than 40, be less than 45, be less than 50, be less than 55 or be less than 60% tensile strength change.Similarly, when this boroxin compound is used in described lubricant compositions, the lubricant compositions formed has certain fluoropolymer consistency, to make when testing according to the CEC L-39-T96 for heavy duty diesel engine, fluoropolymer shows and is less than 20, be less than 25, be less than 30, be less than 35, be less than 40, be less than 45, be less than 50, be less than 55 or be less than 60% tensile strength elongation at break change.

Some above-claimed cpds can interact with this lubricant compositions, with the component of the lubricant compositions being in final form is different from initially add or those components of combining.Some products formed thus, comprise by lubricant compositions of the present invention being used for its intended applications and the product that formed, are to be not easy to describe or not describable.But, all such change, reaction product, and by lubricant compositions of the present invention being used for its intended applications and the product formed, clearly it is expected to, and being included in this thus.The embodiment that the present invention is different comprises one or more change, reaction product, and the product using this lubricant compositions to be formed, as mentioned above.

Provide the method that system is lubricated.The method comprises and this system being contacted with above-mentioned lubricant compositions.This system may further include oil engine.Selectively, this system may further include any oil engine or the application that make lubricant compositions.This system comprises at least one fluoropolymer seal part.

This fluoropolymer seal part can comprise fluoroelastomer.This fluoroelastomer can be classified and ISO 1629 title FKM under such as ASTM D1418.This fluoroelastomer can comprise the multipolymer of R 1216 (HFP) and vinylidene (VDF of VF2), the terpolymer of tetrafluoroethylene (TFE), vinylidene and R 1216, perfluoro methyl vinyl ether (PMVE), the multipolymer of the multipolymer of TFE and propylene and TFE, PMVE and ethene.Fluorine content changes, based on the gross weight of this fluoropolymer seal part such as 66 to 70wt%.FKM is the viton of the polymethylene type on polymer chain with substituting group fluorine and perfluoroalkyl or perfluoro alkoxy.

In addition, the method forming this lubricant compositions is provided.The method comprises base oil and boroxin compound, and optionally amine compound merges.This boroxin compound can be mixed in base oil by any convenient manner.Therefore, this boroxin compound by it being disperseed with the concentration level expected or being dissolved in base oil, and directly can add in base oil.Selectively, this base oil can under agitation directly add in boroxin compound, until provide the boroxin compound being in and expecting concentration level.Such mixing can be carried out in envrionment temperature or lower temperature, such as 30,25,20,15,10 or 5 DEG C.

Embodiment

Do not limit, in the following embodiments, illustrative lubricant composition is by each component being mixed, until realize evenly preparing.Prepared the lubricating oil composition prepared completely, it contains dispersion agent, sanitising agent, amine antioxidant, phenolic antioxidant, defoamer, base oil, antiwear additive, pour point depressant and viscosity-modifying agent.This lubricant compositions (it is representational commercially available crankcase lubricant) is referred to as " with reference to lubricant ", and as baseline, for the effect of more different components for sealing member consistency.

This reference lubricant is merged from multiple different boron-containing compound and multiple different nitrogenous compound, confirms boron-containing compound and the nitrogenous compound effect for sealing member consistency.Practical embodiments #1, #2, #3 and #4 are each comprises one of actual rings boroxane compound and one of actual amine compound.Comparative example #1-5 does not comprise any actual rings boroxane compound.Comparative example #6-8 does not comprise any actual amine compound.Comparative example #9-#12 does not comprise actual amine compound or actual rings boroxane compound.

Joining with reference to the boron-containing compound in lubricant in practical embodiments #1 and #2 is trimethoxy boroxin.Adding with reference to the boron-containing compound in lubricant in practical embodiments #3 is triethoxy boroxin.Adding with reference to the boron-containing compound in lubricant in practical embodiments #4 is three n-butoxy boroxins.

As mentioned above, comparative example #1-5 does not comprise actual rings boroxane compound.Instead, the composition of both comparative example #1 and comparative example #2 is not containing any boron-containing compound.Comparative example #1 comprises actual amine compound, and comparative example #2 does not comprise actual amine compound.Joining with reference to the boron-containing compound in lubricant in comparative example #3 is three-(2-ethylhexyl) boroxins.Joining with reference to the boron-containing compound in lubricant in comparative example #4 is tri butyl boron acid esters.Joining with reference to the boron-containing compound in lubricant in comparative example #5 is triisopropyl boric acid ester.

Comparative example #6-9 comprises actual rings boroxane compound, but does not comprise actual amine compound.Joining with reference to the boroxin compound in lubricant in comparative example #6 and 7 is trimethoxy boroxin.Joining with reference to the boroxin compound in lubricant in comparative example #8 is triethoxy boroxin.Joining with reference to the boroxin compound in lubricant in comparative example #9 is three n-butoxy boroxins.

Comparative example #10-12 does not comprise actual rings boroxane compound or actual amine compound.Boron-containing compound in comparative example #10 is three-(2-ethylhexyl) boroxins.Boron-containing compound in comparative example #11 is tri butyl boron acid esters.Boron-containing compound in comparative example #12 is triisopropyl boric acid ester.

The amine compound be included in practical embodiments #1-4 and comparative example #1 and 3-5 is (2,2,6,6-tetramethyl--4-piperidyl) dodecylate.

Be presented in following table 2,3 and 4 for the reference lubricant of each practical embodiments and comparative example and any other component amount separately:

The formula of table 2: practical embodiments #1-#4

The formula of table 3: comparative example #1-5 (C1-C5)

	C1	C2	C3	C4	C5
						With reference to lubricant (g)	80	80	80	80	80
Other base oil (g)	18.5	20	18	18	18
						Boron-containing compound (g)	0	0	0.5	0.5	0.5
Actual amine compound (g)	1.5	0	1.5	1.5	1.5
						Gross weight (g)	100	100	100	100	100

The formula of table 4: comparative example #6-11 (C6-C12)

	C6	C7	C8	C9	C10	C11	C12
								With reference to lubricant (g)	80	80	80	80	80	80	80
Other base oil (g)	19.5	18	19.5	19.5	19.5	19.5	19.5
								Boron-containing compound (g)	0.5	2	0.5	0.5	0.5	0.5	0.5
Actual amine compound (g)	0	0	0	0	0	0	0
								Gross weight (g)	100	100	100	100	100	100	100

The sealing member consistency of practical embodiments and comparative example uses the compatibility test of industrial standards CECL-39-T96 sealing member to evaluate.This CEC-L-39-T96 sealing member compatibility test is carried out as follows: sealing member or packing ring are placed in lubricant compositions, and this lubricant compositions and the sealing member be included in wherein are heated to high temperature, and keeps this high temperature for some time.Then removing and the dry seal, and evaluate the mechanical property of the seal, compare with the sealing member sample do not heated in this lubricant compositions.Analyze the change per-cent of these performances, evaluate the consistency of sealing member and lubricant compositions.Each formula is tested twice (run #1 and run #2) at identical conditions.The result of seal compatibility test is presented in following table 5-10.

Table 5: sealing member compatibility test result (running 1)-practical embodiments #1-#4

Table 6: sealing member compatibility test result (running 2)-practical embodiments #1-#4

Table 7: sealing member compatibility test result (running 1)-comparative example #1-#6 (C1-C6)

	C1	C2	C3	C4	C5	C6
							Volume change (%)	0.3	0.2	0.8	0.4	0.7	0.5
Point hardness DIDC	7	5	7	6	8	2
							Tensile strength (%)	-44	-32	-47	-39	-44	-29
Elongation at break (%)	-69	-40	-72	-64	-66	-38

Table 8: sealing member compatibility test result (running 2)-comparative example #1-#6 (C1-C6)

	C1	C2	C3	C4	C5	C6
							Volume change (%)	0.4	0.2	0.8	0.6	0.7	0.4
Point hardness DIDC	8	4	8	6	7	2
							Tensile strength (%)	-49	-31	-44	-41	-42	-23
Elongation at break (%)	-71	-40	-68	-61	-67	-34

Table 9: sealing member compatibility test result (running 1)-comparative example #7-#12 (C7-C12)

	C7	C8	C9	C10	C11	C12
							Volume change (%)	0.7	0.3	0.2	0.5	0.4	0.6
Point hardness DIDC	1	1	2	3	4	4
							Tensile strength (%)	5	-26	-21	-29	-31	-29
Elongation at break (%)	-25	-40	-40	-43	-42	-49

Table 10: sealing member compatibility test result (running 2)-comparative example #7-#12 (C7-C12)

	C7	C8	C9	C10	C11	C12
							Volume change (%)	0.7	0.6	0.4	0.6	0.3	0.5
Point hardness DIDC	1	2	2	4	4	3
							Tensile strength (%)	0	-23	-25	-27	-28	-26
Elongation at break (%)	-20	-33	-42	-45	-43	-51

Comparative example #1 is the explanation of amine compound for the effect of the sealing member consistency of lubricant compositions.If compare tensile strength and the elongation at break of comparative example #1 and comparative example #2, the present inventor finds that adding actual amine compound creates disadvantageous effect to reference in lubricant to the sealing member consistency with reference to lubricant.Practical embodiments #1, #2, #3 and #4 are each comprises the actual amine compound identical with comparative example #1, together with the one of actual rings boroxane compound.From the result shown in table 4-7, in both tensile strength and elongation at break, the sealing member consistency of practical embodiments #1-4 is obviously improved compared to the sealing member consistency of comparative example #1.

Table 5-8 have also demonstrated in tensile strength and elongation at break, and compared with the sealing member consistency of comparative example #3-5, the sealing member consistency of practical embodiments #1 and 2 is improved.The tensile strength of practical embodiments #1 is-39 and-32%;-2 and-5% with the tensile strength of practical embodiments #2; And comparative example #3, the tensile strength of 4 and 5 is-47 and-44% respectively;-39 and-41; With-44 and-42%.Similarly, the elongation at break of practical embodiments #1 is-54 and-51%; The elongation at break of practical embodiments #2 is 8 and-5%; And comparative example #3, the elongation at break of 4 and 5 is-72 and-68% respectively;-64 and-61%; With-66% and-67%.This test shows the lubricant compositions of practical embodiments #1 and 2 and sealing member has larger consistency in tensile strength and elongation at break.This compares and provides evidence, namely, compared with comprising the lubricant compositions of other boron-containing compounds (those boron-containing compounds that such as comparative example #3-5 is used), trimethoxy boroxin and the combination of actual amine compound in lubricant compositions create the sealing member consistency obviously improved.

Finally, comparative example #2 and comparative example #6-12 relatively confirm that lubricant compositions (it comprises boron-containing compound, but does not comprise actual amine compound) does not have adversely to affect in a substantial way the sealing member consistency of this lubricant compositions.Therefore, present inventor has recognized that the combination of actual amine compound and actual rings boroxane compound has synergistic effect for sealing member consistency when being present in reference lubricant surprisingly.

Be to be understood that additional claim is not limited to the expression described in detailed description and concrete compound, composition or method, it can change between specific embodiment, and this fall in the scope of additional claim.About rely herein describe different embodiments specific features or in any Ma Kushi group, be to be understood that different, concrete and/or beat all result can available from each composition of respective Ma Kushi group, and it is independent of other Ma Kushi compositions whole.Separately and/or each composition of dependence Ma Kushi group of combination, and the abundant support for the specific embodiments within the scope of accessory claim can be provided.

It is to be further understood that any scope and the subrange of description different embodiments of the present invention of relying fall in additional right with whole independently, and be to be understood that and describe and contemplate four corner, comprise integer wherein and/or fractional value, even if such value is not clearly write out at this.Those skilled in the art will readily recognize that cited scope and subrange are enough to describe to carry out with the embodiment making the present invention different, and such scope and subrange can further describe into relevant half, 1/3rd, 1/4th, five/first-class.As just an example, scope " 0.1-0.9 " can further describe as 1/3rd below, namely, 0.1-0.3, middle 1/3rd, that is, 0.4-0.6, above 1/3rd, that is, 0.7-0.9, what they were single and whole is in the scope of additional claim, and can rely on separately and/or all, and the abundant support for the specific embodiments within the scope of accessory claim is provided.

In addition, about definition or the language of extent of amendment, such as " at least ", " being greater than ", " being less than ", " being not more than " etc., be to be understood that such language includes subrange and/or the upper limit or lower limit.As another example, scope " at least 10 " comprises subrange at least 10-35 in essence, and subrange is 10-25 at least, subrange 25-35 etc., can rely on separately and/or all with each subrange, and the abundant support for the specific embodiments within the scope of accessory claim is provided.Finally, the individual digit in disclosed scope can be relied on, and the abundant support for the specific embodiments within the scope of accessory claim is provided.Such as scope " 1-9 " comprises different individual integer such as 3, and comprises the single number (or mark) such as 4.1 of radix point, and it can rely on, and provides the abundant support for the specific embodiments within the scope of accessory claim.

The present invention is illustratively described, and be to be understood that term object used be in describe and in nonrestrictive linguistic property.According to above-mentioned instruction, many changes of the present invention and change are possible, and the present invention can according to putting into practice of clearly not describing.

The theme of whole combinations of independent sum dependent claims, single and multiple both dependent claims, clearly it is expected at this.Example includes but not limited to below:

Claim 3 can quote any one of claim 1-2;

Claim 4 can quote any one of claim 1-3;

Claim 5 can quote any one of claim 1-4;

Claim 7 can quote any one of claim 1-6;

Claim 8 can quote any one of claim 1-7;

Claim 9 can quote any one of claim 1-8;

Claim 10 can quote any one of claim 1-9;

Claim 11 can quote any one of claim 1-10; With

Claim 12 can quote any one of claim 1-11.

Claims

1. lubricant compositions, it comprises:

Base oil;

There is the boroxin compound of general formula (I):

Wherein each R ¹the alkyl with 1-7 carbon atom independently; With

Amine compound, it, when testing according to ASTM D4739, has the total basicnumber of at least 80mg KOH/g.

2. the lubricant compositions of claim 1, wherein each R ¹the alkyl with 1-5 carbon atom independently.

3. the lubricant compositions of claim 1, wherein each R ¹it is methyl.

4. the lubricant compositions of claim 1, wherein said boroxin compound is involved with the amount of 0.1-5wt%, based on the gross weight of described lubricant compositions.

5. the lubricant compositions of claim 1, wherein said amine compound is involved with the amount of 0.1-20wt%, based on the gross weight of described lubricant compositions.

6. the lubricant compositions of aforementioned any one claim, wherein said amine compound comprises at least one piperidine ring and at least one ester group.

7. the lubricant compositions of claim 1, wherein said amine compound is made up of hydrogen, carbon, nitrogen and oxygen substantially, or wherein said amine compound is made up of hydrogen, carbon and nitrogen substantially.

8. the lubricant compositions of claim 1, wherein said lubricant compositions is phosphoric acid amine salt not.

9. the lubricant compositions of claim 1, before any reaction wherein in described lubricant compositions, based on the gross weight of the described boroxin compound for the formation of described lubricant compositions, at least the described boroxin compound of 50wt% remains unreacted in described lubricant compositions.

10. the lubricant compositions of claim 1, wherein said lubricant compositions has fluoropolymer consistency, to make the fluoropolymer seal part immersed in described lubricant compositions, when testing according to CEC L-39-T96, show the elongation at break change being less than 60%; Or wherein said lubricant compositions has fluoropolymer consistency, show the tensile strength change being less than 45% when testing according to CEC L-39-T96 to make the fluoropolymer seal part immersed in described lubricant compositions.

The lubricant compositions of 11. claims 1, it comprises dispersion agent further.

The lubricant compositions of 12. claims 1, it comprises dialkyl dithiophosphate further.

13. lubricant compositions, it comprises:

Base oil;

The boroxin compound of general formula (I):

Wherein each R ¹the alkyl with 1-7 carbon atom independently; With

Be selected from amine compound below:

A) there is the stereo hindered amine compound of general formula (VI) or (VII):

Wherein each R ⁵hydrogen atom or the alkyl with 1-17 carbon atom independently, and wherein R ⁵at least two represented groups are alkyl;

Wherein each R ⁶hydrogen atom or the alkyl with 1-17 carbon atom independently;

Wherein each R ⁷hydrogen atom or the alkyl with 1-17 carbon atom independently, and wherein R ⁷at least two represented groups are alkyl;

Wherein each R ⁸hydrogen atom or the alkyl with 1-17 carbon atom independently, and

Wherein R ⁵, R ⁶, R ⁷and R ⁸represented described alkyl is each is alcohol radical, alkyl, amide group, ether or ester group independently; With

B) amine compound that monomer is acyclic, its weight-average molecular weight is less than 500 and is made up of covalent linkage;

C) monomeric circular amine compound, its weight-average molecular weight is less than 500 and comprises the nitrogen-atoms being not more than 2; With

D) its combination.

The lubricant compositions of 14. claims 13, wherein said amine compound is the stereo hindered amine compound with general formula (VIII):

Wherein each R ⁵and R ⁶as mentioned above, wherein at least three R ⁵alkyl independently.

15. for the additive-package of lubricant compositions, and described additive-package comprises:

There is the boroxin compound of general formula (I):

Wherein each R ¹the alkyl with 1-7 carbon atom independently; With