RU2015102717A - METHOD FOR CARBON-ACID REFORMING OF HYDROCARBONS AT HIGH PRESSURE IN THE PRESENCE OF CONTAINING IRIDIUM - Google Patents

METHOD FOR CARBON-ACID REFORMING OF HYDROCARBONS AT HIGH PRESSURE IN THE PRESENCE OF CONTAINING IRIDIUM Download PDF

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RU2015102717A
RU2015102717A RU2015102717A RU2015102717A RU2015102717A RU 2015102717 A RU2015102717 A RU 2015102717A RU 2015102717 A RU2015102717 A RU 2015102717A RU 2015102717 A RU2015102717 A RU 2015102717A RU 2015102717 A RU2015102717 A RU 2015102717A
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zirconia
group
elements
proportion
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Андриан МИЛАНОВ
Эккехард Шваб
Штефан ШУНК
Гуидо ВАССЕРШАФФ
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Басф Се
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Abstract

1. Катализатор углекислотного риформинга углеводородов, активная масса которого включает содержащий иридий активный компонент и содержащий диоксид циркония материал подложки, причем:a) содержание иридия в пересчете на содержание активной массы составляет от 0,01 до 10 мас.%, предпочтительно от 0,05 до 5 мас.%, более предпочтительно от 0,1 до 1 мас.%, иb) преимущественная часть диоксида циркония в содержащем диоксид циркония материале подложки обладает кубической и/или тетрагональной структурой, причем доля кубической и/или тетрагональной фазы составляет >50 мас.%, предпочтительно >70 мас.%, в особенности предпочтительно >90 мас.%2. Катализатор по п. 1, отличающийся тем, что содержащая диоксид циркония подложка включает дополнительные ингредиенты, причем доля тетрагонального и/или кубического диоксида циркония в пересчете на общую массу подложки составляет >80 мас.%, предпочтительно >90 мас.%, более предпочтительно >95 мас.%.3. Катализатор по п. 1 или 2, отличающийся тем, что содержащая диоксид циркония активная масса обладает удельной поверхностью >5 м/г, предпочтительно >10 м/г, более предпочтительно >20 м/г, еще более предпочтительно >50 м/г, особенно предпочтительно >80 м/г.4. Катализатор по п. 1 или 2, отличающийся тем, что активная масса легирована одним или несколькими элементами, выбранными из группы, включающей редкоземельные элементы (скандий, иттрий, лантан, церий, празеодим, неодим, самарий, европий, гадолиний, тербий, диспрозий, гольмий, эрбий, тулий, иттербий, лютеций), элементы группы IIa (магний, кальций, стронций, барий), элементы группы IVb (титан, гафний), элементы группы Vb (ванадий, ниобий, тантал) и кремний, причем доля легирующих элементов в пересчете на количество активной массы составляет от 0,01 до 80 мас.%,1. The catalyst for carbon dioxide reforming of hydrocarbons, the active mass of which includes an iridium-containing active component and a zirconia-containing substrate material, wherein: a) the iridium content, calculated on the active mass content, is from 0.01 to 10 wt.%, Preferably from 0.05 up to 5 wt.%, more preferably from 0.1 to 1 wt.%, and b) the predominant part of zirconia in the zirconia-containing substrate material has a cubic and / or tetragonal structure, and the proportion of cubic and / or tetragonal phase co ulation> 50 wt.%, preferably> 70 wt.%, particularly preferably> 90 wt.% 2. The catalyst according to claim 1, characterized in that the zirconia-containing substrate contains additional ingredients, wherein the proportion of tetragonal and / or cubic zirconia, based on the total weight of the substrate, is> 80 wt.%, Preferably> 90 wt.%, More preferably> 95 wt.%. 3. The catalyst according to claim 1 or 2, characterized in that the zirconia-containing active mass has a specific surface area> 5 m / g, preferably> 10 m / g, more preferably> 20 m / g, even more preferably> 50 m / g, particularly preferably> 80 m / g. 4. The catalyst according to claim 1 or 2, characterized in that the active mass is doped with one or more elements selected from the group consisting of rare earth elements (scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium), elements of group IIa (magnesium, calcium, strontium, barium), elements of group IVb (titanium, hafnium), elements of group Vb (vanadium, niobium, tantalum) and silicon, with the proportion of alloying elements in terms of the amount of active mass is from 0.01 to 80 wt.%,

Claims (14)

1. Катализатор углекислотного риформинга углеводородов, активная масса которого включает содержащий иридий активный компонент и содержащий диоксид циркония материал подложки, причем:1. A catalyst for carbon dioxide reforming of hydrocarbons, the active mass of which includes an iridium-containing active component and a zirconia-containing substrate material, wherein: a) содержание иридия в пересчете на содержание активной массы составляет от 0,01 до 10 мас.%, предпочтительно от 0,05 до 5 мас.%, более предпочтительно от 0,1 до 1 мас.%, иa) the content of iridium in terms of the content of the active mass is from 0.01 to 10 wt.%, preferably from 0.05 to 5 wt.%, more preferably from 0.1 to 1 wt.%, and b) преимущественная часть диоксида циркония в содержащем диоксид циркония материале подложки обладает кубической и/или тетрагональной структурой, причем доля кубической и/или тетрагональной фазы составляет >50 мас.%, предпочтительно >70 мас.%, в особенности предпочтительно >90 мас.%b) the predominant portion of zirconia in the zirconia-containing substrate material has a cubic and / or tetragonal structure, wherein the proportion of cubic and / or tetragonal phase is> 50 wt.%, preferably> 70 wt.%, particularly preferably> 90 wt.% 2. Катализатор по п. 1, отличающийся тем, что содержащая диоксид циркония подложка включает дополнительные ингредиенты, причем доля тетрагонального и/или кубического диоксида циркония в пересчете на общую массу подложки составляет >80 мас.%, предпочтительно >90 мас.%, более предпочтительно >95 мас.%.2. The catalyst according to claim 1, characterized in that the zirconia-containing substrate contains additional ingredients, the proportion of tetragonal and / or cubic zirconia in terms of the total weight of the substrate is> 80 wt.%, Preferably> 90 wt.%, More preferably> 95 wt.%. 3. Катализатор по п. 1 или 2, отличающийся тем, что содержащая диоксид циркония активная масса обладает удельной поверхностью >5 м2/г, предпочтительно >10 м2/г, более предпочтительно >20 м2/г, еще более предпочтительно >50 м2/г, особенно предпочтительно >80 м2/г.3. The catalyst according to claim 1 or 2, characterized in that the active mass containing zirconia has a specific surface area> 5 m 2 / g, preferably> 10 m 2 / g, more preferably> 20 m 2 / g, even more preferably> 50 m 2 / g, particularly preferably> 80 m 2 / g. 4. Катализатор по п. 1 или 2, отличающийся тем, что активная масса легирована одним или несколькими элементами, выбранными из группы, включающей редкоземельные элементы (скандий, иттрий, лантан, церий, празеодим, неодим, самарий, европий, гадолиний, тербий, диспрозий, гольмий, эрбий, тулий, иттербий, лютеций), элементы группы IIa (магний, кальций, стронций, барий), элементы группы IVb (титан, гафний), элементы группы Vb (ванадий, ниобий, тантал) и кремний, причем доля легирующих элементов в пересчете на количество активной массы составляет от 0,01 до 80 мас.%, предпочтительно от 0,1 до 50 мас.%, особенно предпочтительно от 1,0 до 30 мас.%.4. The catalyst according to claim 1 or 2, characterized in that the active mass is doped with one or more elements selected from the group consisting of rare earth elements (scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium), elements of group IIa (magnesium, calcium, strontium, barium), elements of group IVb (titanium, hafnium), elements of group Vb (vanadium, niobium, tantalum) and silicon, and the proportion alloying elements in terms of the amount of active mass is from 0.01 to 80 wt.%, preferably from 0.1 to 50 wt.%, particularly preferably from 1.0 to 30 wt.%. 5. Катализатор по п. 1 или 2, отличающийся тем, что активная масса легирована одним или несколькими элементами, выбранными из группы, включающей редкоземельные элементы (скандий, иттрий, лантан, церий, празеодим, неодим, самарий, европий, гадолиний, тербий, диспрозий, гольмий, эрбий, тулий, иттербий, лютеций), причем доля легирующих элементов в пересчете на количество активной массы составляет от 0,01 до 80 мас.%, предпочтительно от 0,1 до 50 мас.%, особенно предпочтительно от 1,0 до 30 мас.%.5. The catalyst according to claim 1 or 2, characterized in that the active mass is doped with one or more elements selected from the group consisting of rare earth elements (scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium), and the proportion of alloying elements in terms of the amount of active mass is from 0.01 to 80 wt.%, preferably from 0.1 to 50 wt.%, particularly preferably from 1, 0 to 30 wt.%. 6. Катализатор по п. 1 или 2, отличающийся тем, что материал подложки содержит иттрий в качестве легирующего элемента или лантан и/или церий в качестве легирующих элементов.6. The catalyst according to claim 1 or 2, characterized in that the substrate material contains yttrium as an alloying element or lanthanum and / or cerium as alloying elements. 7. Катализатор по п. 1 или 2, отличающийся тем, что в активной массе присутствует по меньшей мере один содержащий благородный металл промотор, выбранный из группы, включающей платину, родий, палладий, рутений и золото, доля которого составляет от 0,01 до 5 мас.%, более предпочтительно от 0,1 до 3 мас.%.7. The catalyst according to claim 1 or 2, characterized in that the active mass contains at least one noble metal containing promoter selected from the group comprising platinum, rhodium, palladium, ruthenium and gold, the proportion of which is from 0.01 to 5 wt.%, More preferably from 0.1 to 3 wt.%. 8. Катализатор по п. 1 или 2, отличающийся тем, что в активной массе присутствует по меньшей мере один содержащий неблагородный металл промотор, выбранный из группы, включающей никель, кобальт, железо, марганец, молибден и вольфрам, доля которого составляет от 0,1 до 50 мас.%, более предпочтительно от 0,5 до 30 мас.%, еще более предпочтительно от 1 до 20 мас.%.8. The catalyst according to claim 1 or 2, characterized in that at least one promoter containing a base metal is selected from the group comprising nickel, cobalt, iron, manganese, molybdenum and tungsten, the proportion of which is from 0, 1 to 50 wt.%, More preferably from 0.5 to 30 wt.%, Even more preferably from 1 to 20 wt.%. 9. Катализатор по п. 1 или 2, отличающийся тем, что активная масса содержит по меньшей мере катионы других металлов, предпочтительно выбранные из группы, включающей магний, кальций, стронций, галлий, бериллий, хром и марганец, более предпочтительно из группы, включающей кальций и/или магний.9. The catalyst according to claim 1 or 2, characterized in that the active mass contains at least cations of other metals, preferably selected from the group consisting of magnesium, calcium, strontium, gallium, beryllium, chromium and manganese, more preferably from the group including calcium and / or magnesium. 10. Способ углекислотного риформинга углеводородов, предпочтительно метана, для получения синтез-газа посредством контактирования подлежащего риформингу газа с катализатором, отличающийся тем, что:10. A method of carbon dioxide reforming of hydrocarbons, preferably methane, to produce synthesis gas by contacting the gas to be reformed with a catalyst, characterized in that: (i) в качестве катализатора используют катализатор по одному из п.п. 1-9,(i) the catalyst used is the catalyst according to one of claims 1-9, (ii) совокупное содержание углеводородов, предпочтительно метана, и диоксида углерода в подлежащем риформингу газе составляет более 80 об.%, предпочтительно более 85 об.%, особо предпочтительно более 90 об.%,(ii) the combined content of hydrocarbons, preferably methane, and carbon dioxide in the gas to be reformed is more than 80 vol.%, preferably more than 85 vol.%, particularly preferably more than 90 vol.%, (iii) при контактировании с катализатором давление подлежащего риформингу газа составляет от 5 до 500 бар, предпочтительно от 10 до 250 бар, более предпочтительно от 20 до 100 бар, а температура подлежащего риформингу газа при контактировании с катализатором находится в диапазоне от 600 до 1200°C, предпочтительно от 850 до 1100°C, особенно предпочтительно от 850 до 950°C,(iii) when in contact with the catalyst, the pressure of the gas to be reformed is from 5 to 500 bar, preferably from 10 to 250 bar, more preferably from 20 to 100 bar, and the temperature of the gas to be reformed when contacted with the catalyst is in the range from 600 to 1200 ° C, preferably from 850 to 1100 ° C, particularly preferably from 850 to 950 ° C, (iv) объемная скорость подачи газа в данном способе составляет от 500 до 100000 ч-1, предпочтительно от 500 до 50000 ч-1, и(iv) the volumetric gas flow rate in this method is from 500 to 100,000 h -1 , preferably from 500 to 50,000 h -1 , and (v) отношение водорода к монооксиду углерода в получаемом синтез-газе составляет от 0,5 до 1,4, особенно предпочтительно от 0,6 до 1,2.(v) the ratio of hydrogen to carbon monoxide in the resulting synthesis gas is from 0.5 to 1.4, particularly preferably from 0.6 to 1.2. 11. Способ по п. 10, отличающийся тем, что активная масса с содержащим иридий диоксидом циркония по п. 1 включает по меньшей мере один элемент из группы редкоземельных элементов, предпочтительно редкоземельный элемент выбран из группы, включающей церий и/или лантан, более предпочтительно содержит стабилизирующий элемент иттрий.11. The method according to p. 10, characterized in that the active mass containing iridium zirconia according to p. 1 includes at least one element from the group of rare earth elements, preferably the rare earth element is selected from the group comprising cerium and / or lanthanum, more preferably contains a stabilizing element of yttrium. 12. Способ по п. 10 или 11, отличающийся тем, что подлежащий риформингу газ содержит незначительные количества H2O, причем отношение доли водяного пара и углерода в подлежащем риформингу газе составляет менее 0,2, более предпочтительно менее 0,1, еще более предпочтительно 0,05.12. The method according to p. 10 or 11, characterized in that the gas to be reformed contains minor amounts of H 2 O, and the ratio of the proportion of water vapor and carbon in the gas to be reformed is less than 0.2, more preferably less than 0.1, even more preferably 0.05. 13. Способ по п. 10 или 11, отличающийся тем, что содержащая иридий активная масса снабжена промоторами.13. The method according to p. 10 or 11, characterized in that the iridium-containing active mass is provided with promoters. 14. Способ по п. 10 или 11, отличающийся тем, что подлежащий риформингу газ не содержит H2O. 14. The method according to p. 10 or 11, characterized in that the gas to be reformed does not contain H 2 O.
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Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20170354962A1 (en) * 2014-12-01 2017-12-14 Sabic Global Technologies B.V. Synthesis of trimetallic nanoparticles by homogeneous deposition precipitation, and application of the supported catalyst for carbon dioxide reforming of methane
JP6212065B2 (en) * 2015-03-02 2017-10-11 株式会社ノリタケカンパニーリミテド Ceria zirconia composite oxide particles and production method thereof
CN107405602B (en) * 2015-03-05 2020-08-21 国际壳牌研究有限公司 Methane oxidation catalyst, method of making and method of using the same
CN110325275B (en) 2016-08-05 2022-08-09 韩国科学技术院 Dry reforming catalyst using metal oxide support and method for preparing syngas by using the same
EP3507009B1 (en) 2016-08-31 2021-09-22 Shell Internationale Research Maatschappij B.V. Process to prepare a methane oxidation catalyst
SG11201901348XA (en) 2016-08-31 2019-03-28 Shell Int Research Methane oxidation catalyst, process to prepare the same and method of using the same
CN108940381A (en) * 2017-05-27 2018-12-07 中国石油化工股份有限公司 A kind of tetragonal phase zirconium oxide carrier, the catalyst containing the carrier and its application in the reaction of methane dry reforming
CN109718799A (en) * 2017-10-31 2019-05-07 中国石油化工股份有限公司 The method of loaded catalyst and its preparation method and application and methane dry reforming preparing synthetic gas
GB2568564B (en) 2018-07-17 2020-01-01 Omnagen Ltd Carbon dioxide conversion using combined fuel cell and electrolysis cell
RU2719176C1 (en) * 2019-09-13 2020-04-17 федеральное государственное автономное образовательное учреждение высшего образования "Российский государственный университет нефти и газа (национальный исследовательский университет) имени И.М. Губкина" Synthetic gas production method
CN114713223A (en) * 2021-01-04 2022-07-08 中国科学院大连化学物理研究所 Method for preparing tetragonal-phase zirconia in one step, copper-based supported catalyst and application thereof
WO2024003354A1 (en) 2022-07-01 2024-01-04 Basf Se Cobalt-based catalyst for the conversion of hydrocarbons to synthesis gas
WO2024003347A1 (en) 2022-07-01 2024-01-04 Basf Se Cobalt- and strontium-based catalyst for the conversion of hydrocarbons to synthesis gas

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5753143A (en) 1996-03-25 1998-05-19 Northwestern University Process for the CO2 reforming of methane in the presence of rhodium zeolites
AU740872B2 (en) 1998-06-09 2001-11-15 Idemitsu Kosan Co. Ltd Catalyst and process for reforming hydrocarbon
AU746783B2 (en) * 1998-06-30 2002-05-02 Shell Internationale Research Maatschappij B.V. Catalytic partial oxidation with two catalytically-active metals
AU2002211004A1 (en) 2000-11-08 2002-05-21 Idemitsu Kosan Co. Ltd. Catalyst for hydrocarbon reforming and method of reforming hydrocarbon with the same
ATE549082T1 (en) * 2001-03-29 2012-03-15 Idemitsu Kosan Co METHOD FOR REFORMING A HYDROCARBON
FR2864528B1 (en) 2003-12-31 2006-12-15 Total France PROCESS FOR TREATING METHANE / CARBON DIOXIDE MIXTURES
US7309480B2 (en) 2004-04-16 2007-12-18 H2Gen Innovations, Inc. Catalyst for hydrogen generation through steam reforming of hydrocarbons
GB0510514D0 (en) * 2005-05-24 2005-06-29 Johnson Matthey Plc Steam reforming
WO2008135581A1 (en) * 2007-05-08 2008-11-13 Basf Se Iridium catalysts for converting hydrocarbons in the presence of water vapour and especially for the steam dealkylation of alkyl-substituted aromatic hydrocarbons
CN101289166B (en) * 2008-06-13 2011-09-14 清华大学 Process and device for preparing H2 and CO by co-transformation of CH4 and CO2

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