RU2015100467A - The method of producing fullerene oximes: 1- [hydroxy] -9- [1'-hydroxyimino-2'-oxo-2'-alkyl-ethyl] -1,9-dihydro [C60-Ih] bis-adducts [5,6 ] fullerenes - Google Patents

The method of producing fullerene oximes: 1- [hydroxy] -9- [1'-hydroxyimino-2'-oxo-2'-alkyl-ethyl] -1,9-dihydro [C60-Ih] bis-adducts [5,6 ] fullerenes Download PDF

Info

Publication number
RU2015100467A
RU2015100467A RU2015100467A RU2015100467A RU2015100467A RU 2015100467 A RU2015100467 A RU 2015100467A RU 2015100467 A RU2015100467 A RU 2015100467A RU 2015100467 A RU2015100467 A RU 2015100467A RU 2015100467 A RU2015100467 A RU 2015100467A
Authority
RU
Russia
Prior art keywords
hydroxyimino
fullerenes
dihydro
oxo
hydroxy
Prior art date
Application number
RU2015100467A
Other languages
Russian (ru)
Other versions
RU2605453C2 (en
Inventor
Рамиль Гарифович Булгаков
Земфира Сабитовна Кинзябаева
Original Assignee
Федеральное Государственное Бюджетное Учреждение Науки Институт Нефтехимии И Катализа Ран
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Федеральное Государственное Бюджетное Учреждение Науки Институт Нефтехимии И Катализа Ран filed Critical Федеральное Государственное Бюджетное Учреждение Науки Институт Нефтехимии И Катализа Ран
Priority to RU2015100467/04A priority Critical patent/RU2605453C2/en
Publication of RU2015100467A publication Critical patent/RU2015100467A/en
Application granted granted Critical
Publication of RU2605453C2 publication Critical patent/RU2605453C2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/32—Oximes
    • C07C251/34—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
    • C07C251/42—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with the carbon atom of at least one of the oxyimino groups bound to a carbon atom of a ring other than a six-membered aromatic ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Способ получения бис-аддуктов 1-[гидроксо]-9-[1′-гидроксимино-2′-оксо-2′-алкил-этил]-1,9-дигидро-[С-I][5,6]фуллеренов общей формулы (1)характеризующийся тем, что фуллерен Свзаимодействует с кетонами ((Ме)СО, или (Me)(Ph)CO, или (Et)(Me)CO, или (i-Pr)(Me)CO) в присутствии нитрита натрия и соляной кислоты, взятыми в мольном соотношении 0,01:(0,01-100):(0,01-25):(0,01-50) в среде CClв качестве растворителя при ~20°C в течение 30 мин.The method of producing bis adducts of 1- [hydroxy] -9- [1′-hydroxyimino-2′-oxo-2′-alkyl-ethyl] -1,9-dihydro [CI] [5,6] fullerenes total formula (1) characterized in that fullerene interacts with ketones ((Me) CO, or (Me) (Ph) CO, or (Et) (Me) CO, or (i-Pr) (Me) CO) in the presence of nitrite sodium and hydrochloric acid, taken in a molar ratio of 0.01: (0.01-100) :( 0.01-25) :( 0.01-50) in CCl medium as a solvent at ~ 20 ° C for 30 min .

Claims (1)

Способ получения бис-аддуктов 1-[гидроксо]-9-[1′-гидроксимино-2′-оксо-2′-алкил-этил]-1,9-дигидро-[С60-Ih][5,6]фуллеренов общей формулы (1)
Figure 00000001
The method of producing bis adducts of 1- [hydroxy] -9- [1′-hydroxyimino-2′-oxo-2′-alkyl-ethyl] -1,9-dihydro [C 60 -I h ] [5,6] fullerenes of the general formula (1)
Figure 00000001
 характеризующийся тем, что фуллерен С60 взаимодействует с кетонами ((Ме)2СО, или (Me)(Ph)CO, или (Et)(Me)CO, или (i-Pr)(Me)CO) в присутствии нитрита натрия и соляной кислоты, взятыми в мольном соотношении 0,01:(0,01-100):(0,01-25):(0,01-50) в среде CCl4 в качестве растворителя при ~20°C в течение 30 мин. characterized in that C 60 fullerene interacts with ((Me) 2 CO, or (Me) (Ph) CO, or (Et) (Me) CO, or (i-Pr) (Me) CO) ketones in the presence of sodium nitrite and hydrochloric acid, taken in a molar ratio of 0.01: (0.01-100) :( 0.01-25) :( 0.01-50) in CCl 4 medium as a solvent at ~ 20 ° C for 30 min
RU2015100467/04A 2015-01-12 2015-01-12 METHOD OF PRODUCING FULLERENE OXIMES: BIS-ADDUCTS OF 1-[HYDROXO]-9-[1'-HYDROXYIMINO-2'-OXO-2'-ALKYL-ETHYL]-1,9-DIHYDRO-[C60-Ih][5,6]FULLERENES RU2605453C2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2015100467/04A RU2605453C2 (en) 2015-01-12 2015-01-12 METHOD OF PRODUCING FULLERENE OXIMES: BIS-ADDUCTS OF 1-[HYDROXO]-9-[1'-HYDROXYIMINO-2'-OXO-2'-ALKYL-ETHYL]-1,9-DIHYDRO-[C60-Ih][5,6]FULLERENES

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2015100467/04A RU2605453C2 (en) 2015-01-12 2015-01-12 METHOD OF PRODUCING FULLERENE OXIMES: BIS-ADDUCTS OF 1-[HYDROXO]-9-[1'-HYDROXYIMINO-2'-OXO-2'-ALKYL-ETHYL]-1,9-DIHYDRO-[C60-Ih][5,6]FULLERENES

Publications (2)

Publication Number Publication Date
RU2015100467A true RU2015100467A (en) 2016-07-27
RU2605453C2 RU2605453C2 (en) 2016-12-20

Family

ID=56556809

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2015100467/04A RU2605453C2 (en) 2015-01-12 2015-01-12 METHOD OF PRODUCING FULLERENE OXIMES: BIS-ADDUCTS OF 1-[HYDROXO]-9-[1'-HYDROXYIMINO-2'-OXO-2'-ALKYL-ETHYL]-1,9-DIHYDRO-[C60-Ih][5,6]FULLERENES

Country Status (1)

Country Link
RU (1) RU2605453C2 (en)

Also Published As

Publication number Publication date
RU2605453C2 (en) 2016-12-20

Similar Documents

Publication Publication Date Title
CY1119585T1 (en) Tetrahydropyrrolothiazine compounds
CY1117846T1 (en) 1- (3,3-Dimethylbutyl) -3- (2-fluoro-4-methyl-5- (7-methyl-2- (methylamino) pyridine- [2,3-d] pyrimidin-6-yl) FINISH URINE AS RAF MOUNTAIN POPULATION IN CANCER AGAINST CANCER
BR112012025185A2 (en) artifact reduction in the iterative inversion method of geophysical data
AR077833A1 (en) A METHOD FOR THE PRODUCTION OF A STABLE OXIDIZING BIOCIDE
EA201591349A1 (en) METHOD OF OBTAINING VORTIOXETIN
EA032933B1 (en) Process for manufacturing pyrimidine sulfamide derivatives
MY185367A (en) Improved process for the preparation of osimertinib (azd9291) or a salt thereof, and ?azd9291 aniline? or a salt thereof
ECSP13012652A (en) TRAINING GUIDE FOR ENTRY IN A WELL SUSPENSION BAR
RU2015100467A (en) The method of producing fullerene oximes: 1- [hydroxy] -9- [1'-hydroxyimino-2'-oxo-2'-alkyl-ethyl] -1,9-dihydro [C60-Ih] bis-adducts [5,6 ] fullerenes
MX2017013304A (en) Antiviral and antibacteria agents based on quaternary ammonium compound complexed with boric acid and its derivatives.
RU2007112594A (en) HYALURONIC ACID DERIVATIVES WITH REDUCED BIODEGRADABILITY
UA118008C2 (en) METHOD OF SYNTHESIS (2E) -3- (3,4-DIMETOXIFYNEL) PROP-2-ENNITRIL AND APPLICATION IN SYNTHESIS OF IVABRADINE AND ITS ADDITIVE PHARMACYTESE PHARMACEUTICAL SALTS
RU2010119316A (en) POLY - N, N- DIALYLAMINETHANIC ACID
SI2803659T1 (en) Method for synthesising 3,4-dimethoxybicyclo(4.2.0)octa-1,3,5-triene-7-carbonitrile and use for synthesising ivabradine and the added salts thereof with a pharmaceutically acceptable acid
RU2011101003A (en) METHOD FOR PRODUCING 1-HYDROXYADAMANTAN-4-OH
RU2011111804A (en) METHOD FOR PRODUCING N-ALKYL-3-METHYL-4-NITROZOANILINES
EA201400171A1 (en) METHOD OF ENZYMATIVE SYNTHESIS OF (7S) -3,4-DIMETOXYBICYCLO [4.2.0] OCTA-1,3,5-TRIEN-7-CARBONIC ACID AND APPLICATION IN THE SYNTHESIS OF IVABRADIN AND ITS SALTS
RU2013152020A (en) METHOD FOR PRODUCING (1,5,3-DITIAZEPAN-3-IL) -ALKANDIOLS
RU2014150141A (en) METHOD FOR PRODUCING AZIRIDINO [2 ', 3': 1.9] FULLERENES [60] CONTAINING FRAME AND POLYCYCLIC SUBSTITUTES
EA201400269A1 (en) METHOD OF SYNTHESIS OF 7,8-DIMETOXY -1,3-DIHYDRO-2H-3-BENZAZEPIN-2-SHE COMPOUNDS AND IVABRADIN
FR3022568B1 (en) METHOD FOR BUILDING A BUILDING, PARTICULARLY FOR USE IN A DOUBLE HULL HOUSING, HOUSING OBTAINED
UA111156C2 (en) METHOD OF SYNTHESIS OF IVABRADINE AND ITS ADDITIVE SALTS WITH PHARMACEUTICALLY ACCEPTABLE ACID
RU2008148425A (en) 4-IMINOMETHYL-3- (7-ACETOXYCHROMON-3-IL) BENZOIC ACID WITH ANTIBACTERIAL ACTIVITY
Sahoo et al. Correction to “Coupled 3D Time-Dependent Wave-Packet Approach in Hyperspherical Coordinates: Application to the Adiabatic Singlet-State (11A′) D++ H2 Reaction”
RU2014150139A (en) METHOD FOR PRODUCING N-ALKYLAZIRIDINO [2 ', 3': 1.9] FULLERENES [60]

Legal Events

Date Code Title Description
MM4A The patent is invalid due to non-payment of fees

Effective date: 20170113