RU2012129995A - BINTERNESS MICROEMULSION WASHING COMPOSITION - Google Patents

BINTERNESS MICROEMULSION WASHING COMPOSITION Download PDF

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Publication number
RU2012129995A
RU2012129995A RU2012129995/04A RU2012129995A RU2012129995A RU 2012129995 A RU2012129995 A RU 2012129995A RU 2012129995/04 A RU2012129995/04 A RU 2012129995/04A RU 2012129995 A RU2012129995 A RU 2012129995A RU 2012129995 A RU2012129995 A RU 2012129995A
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RU
Russia
Prior art keywords
composition according
oil
composition
fatty
mpa
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RU2012129995/04A
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Russian (ru)
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RU2542993C2 (en
Inventor
Арун Кумар Нагараян
Дилип Кумар Роут
Ритеш Кумар Синха
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Юнилевер Н.В.
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Priority claimed from EP10152245A external-priority patent/EP2361963A1/en
Application filed by Юнилевер Н.В. filed Critical Юнилевер Н.В.
Publication of RU2012129995A publication Critical patent/RU2012129995A/en
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Publication of RU2542993C2 publication Critical patent/RU2542993C2/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0017—Multi-phase liquid compositions
    • C11D17/0021—Aqueous microemulsions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/2037—Terpenes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C11D3/2062—Terpene
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)

Abstract

1. Композиция бинепрерывной моющей микроэмульсии, содержащая:a) 40-90 масс.% поверхностно-активной системы, содержащей:i) 10-50 масс.% поверхностно-активной системы из линейного или разветвленного жирного спирта, имеющего 5-8 атомов углерода, или продукта конденсации линейного или разветвленного жирного спирта, имеющего 5-8 атомов углерода и содержащего не более 5 алкиленоксидных групп, и их смесей; иii) дополнительное поверхностно-активное вещество; иb) 5-30 масс.% водного раствора, содержащего:i)воду; иii) электролит, помимо поверхностно-активной системы (а),характеризующегося тем, что водный раствор имеет ионную силу 0,1-4 моль/л; иc) 5-30 масс.% масла или растворителя, характеризующегося наличиемi) показателя растворимости Хансена между 14 и 20 (МПа); иii) величины растворимости твердого трилауринового жирового материала в масле, превышающей 3 масс.%;и, кроме того, характеризующаяся тем, что вязкость данной композиции составляет менее 1000 МПа·с (25°С и 20 с).2. Композиция по п.1, в которой алкиленоксид является оксидом этилена.3. Композиция по п.1, в которой показатель растворимости Хансена составляет между 16 и 18 МПа.4. Композиция по одному из п.п.1-3, в которой масло выбрано из эфирных масел, масел на основе жирных кислот, моно- ди- и триглицеридов, полиэфирных производных сахаров и полиэфиров сахарозы, а также терпенов и их смесей.5. Композиция по одному из п.п.1-3, в которой растворитель выбран из алкильных эфиров жирных кислот и/или спиртов жирного ряда, предпочтительно получаемых из возобновляемых источников, таких как пальма, кокосовый орех, соя, с распределением длин цепи жирной кислоты от С7 до С22 и распределением длин цепи алкила сложноэфирной1. The composition of a bi-continuous washing microemulsion containing: a) 40-90 wt.% A surface-active system containing: i) 10-50 wt.% A surface-active system of a linear or branched fatty alcohol having 5-8 carbon atoms, or a condensation product of a linear or branched fatty alcohol having 5-8 carbon atoms and containing no more than 5 alkylene oxide groups, and mixtures thereof; and ii) an additional surfactant; and b) 5-30 wt.% an aqueous solution containing: i) water; and ii) an electrolyte, in addition to the surface-active system (a), characterized in that the aqueous solution has an ionic strength of 0.1-4 mol / l; and c) 5-30% by weight of an oil or solvent characterized by i) a Hansen solubility index between 14 and 20 (MPa); and ii) the solubility of the solid trilaurin fatty material in oil exceeding 3 wt.%; and, in addition, characterized in that the viscosity of this composition is less than 1000 MPa · s (25 ° C and 20 s) .2. The composition of claim 1, wherein the alkylene oxide is ethylene oxide. The composition according to claim 1, in which the Hansen solubility index is between 16 and 18 MPa. The composition according to one of claims 1 to 3, in which the oil is selected from essential oils, oils based on fatty acids, mono- and triglycerides, polyester derivatives of sugars and sucrose polyesters, as well as terpenes and mixtures thereof. 5. The composition according to one of claims 1 to 3, in which the solvent is selected from fatty acid alkyl esters and / or fatty alcohols, preferably obtained from renewable sources, such as palm, coconut, soy, with a distribution of chain lengths of fatty acids from C7 to C22 and alkyl ester chain length distribution

Claims (12)

1. Композиция бинепрерывной моющей микроэмульсии, содержащая:1. The composition of a bi-continuous washing microemulsion containing: a) 40-90 масс.% поверхностно-активной системы, содержащей:a) 40-90 wt.% surface-active system containing: i) 10-50 масс.% поверхностно-активной системы из линейного или разветвленного жирного спирта, имеющего 5-8 атомов углерода, или продукта конденсации линейного или разветвленного жирного спирта, имеющего 5-8 атомов углерода и содержащего не более 5 алкиленоксидных групп, и их смесей; иi) 10-50 wt.% a surface-active system of a linear or branched fatty alcohol having 5-8 carbon atoms, or a condensation product of a linear or branched fatty alcohol having 5-8 carbon atoms and containing no more than 5 alkylene oxide groups, and mixtures thereof; and ii) дополнительное поверхностно-активное вещество; иii) an additional surfactant; and b) 5-30 масс.% водного раствора, содержащего:b) 5-30 wt.% an aqueous solution containing: i)воду; иi) water; and ii) электролит, помимо поверхностно-активной системы (а),ii) an electrolyte, in addition to the surface active system (a), характеризующегося тем, что водный раствор имеет ионную силу 0,1-4 моль/л; иcharacterized in that the aqueous solution has an ionic strength of 0.1-4 mol / l; and c) 5-30 масс.% масла или растворителя, характеризующегося наличиемc) 5-30 wt.% oil or solvent, characterized by the presence of i) показателя растворимости Хансена между 14 и 20 (МПа)0,5; иi) Hansen solubility index between 14 and 20 (MPa) 0.5 ; and ii) величины растворимости твердого трилауринового жирового материала в масле, превышающей 3 масс.%;ii) the solubility of solid trilaurin fatty material in oil in excess of 3 wt.%; и, кроме того, характеризующаяся тем, что вязкость данной композиции составляет менее 1000 МПа·с (25°С и 20 с-1).and, in addition, characterized in that the viscosity of this composition is less than 1000 MPa · s (25 ° C and 20 s -1 ). 2. Композиция по п.1, в которой алкиленоксид является оксидом этилена.2. The composition according to claim 1, in which the alkylene oxide is ethylene oxide. 3. Композиция по п.1, в которой показатель растворимости Хансена составляет между 16 и 18 МПа0,5.3. The composition according to claim 1, in which the Hansen solubility index is between 16 and 18 MPa 0.5 . 4. Композиция по одному из п.п.1-3, в которой масло выбрано из эфирных масел, масел на основе жирных кислот, моно- ди- и триглицеридов, полиэфирных производных сахаров и полиэфиров сахарозы, а также терпенов и их смесей.4. The composition according to one of claims 1 to 3, in which the oil is selected from essential oils, oils based on fatty acids, mono- and triglycerides, polyester derivatives of sugars and sucrose polyesters, as well as terpenes and mixtures thereof. 5. Композиция по одному из п.п.1-3, в которой растворитель выбран из алкильных эфиров жирных кислот и/или спиртов жирного ряда, предпочтительно получаемых из возобновляемых источников, таких как пальма, кокосовый орех, соя, с распределением длин цепи жирной кислоты от С7 до С22 и распределением длин цепи алкила сложноэфирной группы 1-22, а также их смесей.5. The composition according to one of claims 1 to 3, in which the solvent is selected from fatty acid alkyl esters and / or fatty alcohols, preferably obtained from renewable sources, such as palm, coconut, soy, with a fatty chain length distribution acids from C7 to C22 and the distribution of chain lengths of the alkyl ester group 1-22, as well as mixtures thereof. 6. Композиция по п.1, в которой показатель рН композиции находится между 5 и 9.6. The composition according to claim 1, in which the pH of the composition is between 5 and 9. 7. Композиция по п.1, дополнительно содержащая противомоскитный компонент.7. The composition according to claim 1, additionally containing a mosquito component. 8. Композиция по п.7, в которой противомоскитный компонент выбран из масла лимонной вербены, цитронеллового масла и масла лимонного сорго, а также их смесей.8. The composition according to claim 7, in which the mosquito component is selected from lemon verbena oil, citronella oil and lemon sorghum oil, as well as mixtures thereof. 9. Композиция по п.1, дополнительно содержащая ароматизирующее вещество.9. The composition according to claim 1, additionally containing a flavoring substance. 10. Разбрызгиватель, содержащий композицию по одному из п.п.1-9.10. A sprinkler containing the composition according to one of claims 1 to 9. 11. Устройство для предварительного выведения пятен, выбираемое из ручки для удаления пятен, шарикового пятновыводителя, ручки со щеткой, содержащих композицию по одному из п.п.1-9.11. A device for preliminary removal of stains, selected from a pen for removing stains, ball stain remover, pens with a brush containing the composition according to one of claims 1 to 9. 12. Способ приготовления микроэмульсии по одному из п.п.1-9, содержащий следующую последовательность этапов:12. A method of preparing a microemulsion according to one of claims 1 to 9, comprising the following sequence of steps: a) добавление поверхностно-активной системы к маслу/растворителю,a) adding a surfactant system to the oil / solvent, b) смешивание их друг с другом с помощью верхнеприводной мешалки,b) mixing them together using an overhead mixer, c) необязательное добавление гидрофобных ингредиентов,c) optionally adding hydrophobic ingredients, d) добавление водной фазы, содержащей электролиты. d) adding an aqueous phase containing electrolytes.
RU2012129995/04A 2009-12-16 2010-12-08 Bicontinuous microemulsion detergent composition RU2542993C2 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
IN2899MU2009 2009-12-16
IN2899/MUM/2009 2009-12-16
EP10152245A EP2361963A1 (en) 2010-02-01 2010-02-01 Bi-continuous micro-emulsion detergent composition
EP10152245.6 2010-02-01
PCT/EP2010/069121 WO2011073062A1 (en) 2009-12-16 2010-12-08 Bi-continuous micro-emulsion detergent composition

Publications (2)

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RU2012129995A true RU2012129995A (en) 2014-01-27
RU2542993C2 RU2542993C2 (en) 2015-02-27

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EP (1) EP2513277B1 (en)
CN (1) CN102753668B (en)
AR (1) AR079468A1 (en)
BR (1) BR112012014673A2 (en)
CL (1) CL2012001576A1 (en)
ES (1) ES2551384T3 (en)
MX (1) MX337579B (en)
RU (1) RU2542993C2 (en)
WO (1) WO2011073062A1 (en)
ZA (1) ZA201204426B (en)

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WO2016202572A1 (en) 2015-06-19 2016-12-22 Unilever N.V. Laundry pretreatment composition
DE102016204268A1 (en) 2016-03-15 2017-09-21 Henkel Ag & Co. Kgaa detergent composition
DE102016204390A1 (en) 2016-03-16 2017-09-21 Henkel Ag & Co. Kgaa Method for cleaning laundry in a washing machine and a washing machine
JP7114879B2 (en) * 2016-12-15 2022-08-09 株式会社リコー Cleaning liquid, storage container, inkjet printing method, inkjet printing apparatus, and set of ink and cleaning liquid
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EP3572491A1 (en) 2018-05-24 2019-11-27 The Procter & Gamble Company Spray container comprising a detergent composition
EP3572493A1 (en) 2018-05-24 2019-11-27 The Procter & Gamble Company Spray container comprising a detergent composition
EP3572490A1 (en) 2018-05-24 2019-11-27 The Procter & Gamble Company Spray container comprising a detergent composition
EP3572489A1 (en) 2018-05-24 2019-11-27 The Procter & Gamble Company Spray container comprising a detergent composition

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CL2012001576A1 (en) 2013-01-25
EP2513277A1 (en) 2012-10-24
WO2011073062A1 (en) 2011-06-23
RU2542993C2 (en) 2015-02-27
CN102753668A (en) 2012-10-24
EP2513277B1 (en) 2015-07-29
ZA201204426B (en) 2013-08-28
MX337579B (en) 2016-03-10
CN102753668B (en) 2014-05-14
BR112012014673A2 (en) 2017-12-12
MX2012007057A (en) 2012-08-23
ES2551384T3 (en) 2015-11-18
AR079468A1 (en) 2012-01-25

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