RU2011117521A - JOINT TREATMENT OF DIESEL FUEL AND VEGETABLE OIL FOR PRODUCING A HYBRID DIESEL BIOFUEL WITH A LOW TURBIDITY TEMPERATURE - Google Patents

JOINT TREATMENT OF DIESEL FUEL AND VEGETABLE OIL FOR PRODUCING A HYBRID DIESEL BIOFUEL WITH A LOW TURBIDITY TEMPERATURE Download PDF

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RU2011117521A
RU2011117521A RU2011117521/04A RU2011117521A RU2011117521A RU 2011117521 A RU2011117521 A RU 2011117521A RU 2011117521/04 A RU2011117521/04 A RU 2011117521/04A RU 2011117521 A RU2011117521 A RU 2011117521A RU 2011117521 A RU2011117521 A RU 2011117521A
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mixture
hydrotreating
diesel fuel
catalyst
vegetable oil
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RU2011117521/04A
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RU2487923C2 (en
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Стефен Джозеф МИЛЛЕР (US)
Стефен Джозеф МИЛЛЕР
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ШЕВРОН Ю. Эс. Эй. ИНК. (US)
ШЕВРОН Ю. Эс. Эй. ИНК.
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
    • C10G3/46—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof in combination with chromium, molybdenum, tungsten metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/62—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C10L1/08—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for compression ignition
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1055—Diesel having a boiling range of about 230 - 330 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/304—Pour point, cloud point, cold flow properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Abstract

1. Способ, включающий стадии, в которых: ! а) объединяют растительное масло с дизелем с образованием первой смеси, в которой растительное масло составляет не более 10 вес.% указанной первой смеси; ! b) проводят гидроочистку первой смеси с образованием второй смеси, в которой триглицеридные компоненты первой смеси подвергаются дезоксигенированию, и в которой по меньшей мере 95 ат.% серы, присутствующей в первой смеси, преобразуются в H2S во второй смеси; ! с) проводят изомеризацию второй смеси в присутствии катализатора изомеризации с образованием третьей смеси, включающей гибридное дизельное топливо, имеющее температуру помутнения, которая является более низкой, чем температура помутнения второй смеси, причем H2S во второй смеси не удаляли перед изомеризацией; и ! d) выделяют гибридное дизельное топливо из третьей смеси с образованием гибридного дизельного топливного продукта. ! 2. Способ по п.1, в котором первая смесь имеет содержание азота более 50 ppm. ! 3. Способ по п.1, в котором первая смесь имеет содержание азота вплоть до около 500 ppm. ! 4. Способ по п.1, в котором катализатор изомеризации включает Pt на SM-7 в качестве носителя. ! 5. Способ по п.1, в котором катализатор изомеризации включает Pt на SAPO-11 в качестве носителя. ! 6. Способ по п.1, в котором растительное масло включает одно или более масел биологического происхождения, выбранных из группы, состоящей из канола, сои, рапса, пальмы, арахиса, ятрофы, солидола, водорослей и их комбинаций. ! 7. Способ по п.1, в котором стадия гидроочистки включает катализатор гидроочистки, включающий компонент катализатора гидроочистки из активного металла или металлического сплава, выбранный из � 1. A method comprising stages in which:! a) combine the vegetable oil with diesel to form a first mixture, in which the vegetable oil is not more than 10 wt.% of the specified first mixture; ! b) hydrotreating the first mixture to form a second mixture in which the triglyceride components of the first mixture are deoxygenated and in which at least 95 at.% of the sulfur present in the first mixture is converted to H2S in the second mixture; ! c) isomerizing the second mixture in the presence of an isomerization catalyst to form a third mixture comprising hybrid diesel fuel having a cloud point that is lower than the cloud point of the second mixture, the H2S in the second mixture not being removed prior to isomerization; and! d) separating the hybrid diesel fuel from the third mixture to form a hybrid diesel fuel product. ! 2. The method of claim 1, wherein the first mixture has a nitrogen content of more than 50 ppm. ! 3. The method of claim 1, wherein the first mixture has a nitrogen content of up to about 500 ppm. ! 4. The method of claim 1, wherein the isomerization catalyst comprises Pt on SM-7 as a support. ! 5. The method of claim 1, wherein the isomerization catalyst comprises Pt on SAPO-11 as a support. ! 6. The method of claim 1, wherein the vegetable oil comprises one or more oils of biological origin selected from the group consisting of canola, soy, rapeseed, palm, peanut, jatropha, solid oil, algae, and combinations thereof. ! 7. The method of claim 1, wherein the hydrotreating step comprises a hydrotreating catalyst comprising an active metal or metal alloy hydrotreating catalyst component selected from

Claims (22)

1. Способ, включающий стадии, в которых:1. The method comprising the steps in which: а) объединяют растительное масло с дизелем с образованием первой смеси, в которой растительное масло составляет не более 10 вес.% указанной первой смеси;a) combine vegetable oil with diesel to form the first mixture, in which the vegetable oil is not more than 10 wt.% the specified first mixture; b) проводят гидроочистку первой смеси с образованием второй смеси, в которой триглицеридные компоненты первой смеси подвергаются дезоксигенированию, и в которой по меньшей мере 95 ат.% серы, присутствующей в первой смеси, преобразуются в H2S во второй смеси;b) hydrotreating the first mixture to form a second mixture in which the triglyceride components of the first mixture are deoxygenated and in which at least 95 atomic percent sulfur present in the first mixture is converted to H 2 S in the second mixture; с) проводят изомеризацию второй смеси в присутствии катализатора изомеризации с образованием третьей смеси, включающей гибридное дизельное топливо, имеющее температуру помутнения, которая является более низкой, чем температура помутнения второй смеси, причем H2S во второй смеси не удаляли перед изомеризацией; иc) isomerizing the second mixture in the presence of an isomerization catalyst to form a third mixture comprising a hybrid diesel fuel having a cloud point that is lower than the cloud point of the second mixture, wherein the H 2 S in the second mixture is not removed before isomerization; and d) выделяют гибридное дизельное топливо из третьей смеси с образованием гибридного дизельного топливного продукта.d) isolating hybrid diesel fuel from the third mixture to form a hybrid diesel fuel product. 2. Способ по п.1, в котором первая смесь имеет содержание азота более 50 ppm.2. The method according to claim 1, in which the first mixture has a nitrogen content of more than 50 ppm. 3. Способ по п.1, в котором первая смесь имеет содержание азота вплоть до около 500 ppm.3. The method according to claim 1, in which the first mixture has a nitrogen content up to about 500 ppm. 4. Способ по п.1, в котором катализатор изомеризации включает Pt на SM-7 в качестве носителя.4. The method of claim 1, wherein the isomerization catalyst comprises Pt on SM-7 as a carrier. 5. Способ по п.1, в котором катализатор изомеризации включает Pt на SAPO-11 в качестве носителя.5. The method according to claim 1, wherein the isomerization catalyst comprises Pt on SAPO-11 as a carrier. 6. Способ по п.1, в котором растительное масло включает одно или более масел биологического происхождения, выбранных из группы, состоящей из канола, сои, рапса, пальмы, арахиса, ятрофы, солидола, водорослей и их комбинаций.6. The method according to claim 1, in which the vegetable oil includes one or more oils of biological origin selected from the group consisting of canola, soy, rape, palm, peanuts, jatropha, solidol, algae, and combinations thereof. 7. Способ по п.1, в котором стадия гидроочистки включает катализатор гидроочистки, включающий компонент катализатора гидроочистки из активного металла или металлического сплава, выбранный из группы, состоящей из кобальт-молибденового (Co-Mo) катализатора, никель-молибденового (Ni-Mo) катализатора, катализатора на основе благородных металлов и их комбинаций.7. The method according to claim 1, wherein the hydrotreating step comprises a hydrotreating catalyst comprising a component of a hydrotreating catalyst of an active metal or metal alloy selected from the group consisting of a cobalt-molybdenum (Co-Mo) catalyst, nickel-molybdenum (Ni-Mo ) a catalyst, a catalyst based on noble metals and their combinations. 8. Способ по п.7, в котором катализатор гидроочистки включает огнеупорный оксидный носитель.8. The method according to claim 7, in which the hydrotreating catalyst comprises a refractory oxide carrier. 9. Способ по п.7, в котором катализатор гидроочистки включает компонент носителя, выбранный из группы, состоящей из Al2O3 и SiO2-Al2O3.9. The method according to claim 7, in which the hydrotreating catalyst comprises a carrier component selected from the group consisting of Al 2 O 3 and SiO 2 -Al 2 O 3 . 10. Способ по п.1, в котором в гидроочистке используют никель-молибденовый катализатор на носителе из оксида алюминия.10. The method according to claim 1, wherein the hydrotreatment uses a nickel-molybdenum catalyst supported on an alumina carrier. 11. Способ по п.1, в котором гидроочистку проводят при температуре от 550°F и до 800°F (287,8-426,7°С).11. The method according to claim 1, in which the hydrotreating is carried out at a temperature of from 550 ° F to 800 ° F (287.8-426.7 ° C). 12. Способ по п.1, в котором гидроочистку проводят при парциальном давлении Н2 от 400 psig и до 2000 psig (2,76-13,79 МПа, избыточных).12. The method according to claim 1, in which the hydrotreating is carried out at a partial pressure of H 2 from 400 psig and up to 2000 psig (2.76-13.79 MPa, excess). 13. Способ по п.1, в котором гидроочистку проводят при парциальном давлении Н2 от 500 psig и до 1500 psig (3,45-10,34 МПа, избыточных).13. The method according to claim 1, in which the hydrotreating is carried out at a partial pressure of H 2 from 500 psig and up to 1500 psig (3.45-10.34 MPa, excess). 14. Способ по п.1, в котором вторая смесь имеет, за исключением H2S, содержание серы не более 20 ppm.14. The method according to claim 1, in which the second mixture has, with the exception of H 2 S, a sulfur content of not more than 20 ppm. 15. Способ по п.1, в котором вторая смесь имеет температуру помутнения -8°С или менее.15. The method according to claim 1, in which the second mixture has a cloud point of -8 ° C or less. 16. Способ по п.1, в котором гибридное дизельное топливо имеет, за исключением H2S, содержание серы не более 10 ppm.16. The method according to claim 1, in which the hybrid diesel fuel has, with the exception of H 2 S, a sulfur content of not more than 10 ppm. 17. Способ по п.1, в котором гибридное дизельное топливо имеет температуру помутнения -10°С или менее.17. The method according to claim 1, in which the hybrid diesel fuel has a cloud point of -10 ° C or less. 18. Способ по п.1, в котором выделение гибридного дизельного топлива, по меньшей мере частично, достигают отпариванием H2S от третьей смеси.18. The method according to claim 1, in which the selection of hybrid diesel fuel, at least in part, is achieved by steaming H 2 S from the third mixture. 19. Система для получения гибридного дизельного топливного продукта, причем указанная система включает:19. A system for producing a hybrid diesel fuel product, wherein said system includes: а) смесительное устройство для объединения растительного масла с дизелем для образования первой смеси, в которой растительное масло составляет не более 10% вес. от указанной первой смеси;a) a mixing device for combining vegetable oil with diesel to form the first mixture, in which vegetable oil is not more than 10% by weight. from said first mixture; (b) гидроочистительную установку для гидроочистки первой смеси с образованием второй смеси, причем указанная установка действует для дезоксигенирования триглицеридных компонентов первой смеси, и в которой по меньшей мере 95 атомных процентов серы, присутствующей в первой смеси, преобразуются в H2S во второй смеси; и(b) a hydrotreating unit for hydrotreating the first mixture to form a second mixture, said unit operating to deoxygenate the triglyceride components of the first mixture, and in which at least 95 atomic percent of the sulfur present in the first mixture is converted to H 2 S in the second mixture; and (с) изомеризационную установку для изомеризации второй смеси в присутствии катализатора изомеризации с образованием третьей смеси, включающей гибридное дизельное топливо, имеющее температуру помутнения, которая является более низкой, чем температура помутнения второй смеси, в которой H2S во второй смеси не был удален перед изомеризацией.(c) an isomerization unit for isomerizing the second mixture in the presence of an isomerization catalyst to form a third mixture comprising hybrid diesel fuel having a cloud point that is lower than the cloud point of the second mixture in which H 2 S in the second mixture has not been removed before isomerization. 20. Система по п.19, дополнительно включающая разделительную установку для выделения гибридного дизельного топлива в третьей смеси для получения гибридного дизельного топливного продукта.20. The system according to claim 19, further comprising a separation unit for separating hybrid diesel fuel in a third mixture to produce a hybrid diesel fuel product. 21. Система по п.20, в которой катализатор изомеризации включает Pt на SM-7 в качестве носителя.21. The system of claim 20, wherein the isomerization catalyst comprises Pt on SM-7 as a carrier. 22. Система по п.20, в которой разделительная установка включает устройство для отпаривания H2S. 22. The system according to claim 20, in which the separation unit includes a device for steaming H 2 S.
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