RU2007132158A - SURFACE MODIFICATION BY POLYEDRAL OLIGOMERIC SILESESQUIOXANSILANOLES - Google Patents

SURFACE MODIFICATION BY POLYEDRAL OLIGOMERIC SILESESQUIOXANSILANOLES Download PDF

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Publication number
RU2007132158A
RU2007132158A RU2007132158/04A RU2007132158A RU2007132158A RU 2007132158 A RU2007132158 A RU 2007132158A RU 2007132158/04 A RU2007132158/04 A RU 2007132158/04A RU 2007132158 A RU2007132158 A RU 2007132158A RU 2007132158 A RU2007132158 A RU 2007132158A
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Russia
Prior art keywords
base
rsio
nanostructured chemical
group
nanostructured
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RU2007132158/04A
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Russian (ru)
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RU2425082C2 (en
Inventor
Джозеф Д. ЛИХТЕНАН (US)
Джозеф Д. ЛИХТЕНАН
Джозеф Дж. ШВАБ (US)
Джозеф Дж. ШВАБ
И-Чжун АНЬ (US)
И-Чжун АНЬ
Уилль м РЕЙНЕРТ (US)
Уилльям РЕЙНЕРТ
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Хайбрид Плэстикс, Инк. (Us)
Хайбрид Плэстикс, Инк.
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Publication of RU2007132158A publication Critical patent/RU2007132158A/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/21—Cyclic compounds having at least one ring containing silicon, but no carbon in the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/11—Compounds covalently bound to a solid support

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Ceramic Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Silicon Polymers (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Claims (19)

1. Способ введения свойств наноскопических поверхностей в основу, выбранную из группы, состоящей из цеолитов, синтетических и натуральных силикатов, оксидов кремния, оксидов алюминия, минералов, натуральных и искусственных волокон, стекла и металлических волокон, включающий покрытие основы наноструктурированным химикатом.1. The method of introducing the properties of nanoscopic surfaces into a base selected from the group consisting of zeolites, synthetic and natural silicates, silicon oxides, aluminum oxides, minerals, natural and artificial fibers, glass and metal fibers, including coating the base with a nanostructured chemical. 2. Способ по п.1, в котором основу покрывают смесью наноструктурированных химикатов.2. The method according to claim 1, in which the base is coated with a mixture of nanostructured chemicals. 3. Способ по п.1, в котором наноструктурированный химикат выбран из группы, состоящей из полиэдральных олигомерных силсесквиоксанов, полиэдральных олигомерных силикатов и их полимеров.3. The method according to claim 1, in which the nanostructured chemical is selected from the group consisting of polyhedral oligomeric silsesquioxanes, polyhedral oligomeric silicates and their polymers. 4. Способ по п.1, в котором наноструктурный химикат внедрен в основу.4. The method according to claim 1, in which the nanostructured chemical is incorporated into the base. 5. Способ по п.1, в котором наноструктурный химикат расслаивает основу.5. The method according to claim 1, in which the nanostructured chemical exfoliates the base. 6. Способ по п.1, в котором основа покрыта с использованием метода без применения растворителя.6. The method according to claim 1, wherein the base is coated using a solvent-free method. 7. Способ по п.6, в котором метод без применения растворителя представляет собой обработку в расплавленном состоянии.7. The method according to claim 6, in which the method without the use of a solvent is a treatment in a molten state. 8. Способ по п.1, в котором основу покрывают с использованием метода, в котором участвует растворитель.8. The method according to claim 1, in which the base is coated using a method in which a solvent is involved. 9. Способ по п.8, в котором метод с участием растворителя выбран из группы, состоящей из методов обработки напылением, в потоке и смешением.9. The method according to claim 8, in which the solvent method is selected from the group consisting of spraying, flow, and mixing methods. 10. Способ по п.1, в котором основу покрывают с применением метода с использованием сверхкритической жидкости.10. The method according to claim 1, in which the base is coated using the method using supercritical fluid. 11. Способ по п.10, в котором метод с использованием сверхкритической жидкости включает методы обработки напылением, в потоке и смешением.11. The method according to claim 10, in which the method using supercritical fluid includes methods of processing by spraying, in the stream and mixing. 12. Композиция, содержащая частицы основы, выбранной из группы, состоящей из цеолитов, синтетических и натуральных силикатов, оксидов кремния, оксидов алюминия, минералов, натуральных и искусственных волокон, стекла и металлических волокон, и покрытие указанных частиц наноструктурированным химикатом.12. A composition comprising particles of a base selected from the group consisting of zeolites, synthetic and natural silicates, silicon oxides, aluminum oxides, minerals, natural and artificial fibers, glass and metal fibers, and coating said particles with a nanostructured chemical. 13. Композиция по п.12, в которой наноструктурированный химикат получен из членов группы, состоящей из POSS-силанолов, силоксидов формулы [(RSiO1,5)4(RXSiO1,0)3]∑7, полисилсесквиоксанов [(RSiO1,5)n]∑# и фрагментов POSS [(RSiO1,5)m(RXSiO1,0)n]∑#.13. The composition according to item 12, in which the nanostructured chemical is obtained from members of the group consisting of POSS-silanols, siloxides of the formula [(RSiO 1,5 ) 4 (RXSiO 1,0 ) 3 ] ∑ 7 , polysilsesquioxanes [(RSiO 1, 5 ) n ] ∑ # and POSS fragments [(RSiO 1.5 ) m (RXSiO1.0) n ] ∑ # . 14. Композиция по п.13, в которой наноструктурированный химикат является силоксидом формулы [(RSiO1,5)4(RXSiO1,0)3]∑7, где X означает OH или OR.14. The composition according to item 13, in which the nanostructured chemical is a siloxide of the formula [(RSiO 1,5 ) 4 (RXSiO 1,0 ) 3 ] ∑ 7 , where X is OH or OR. 15. Композиция по п.12, в которой группа состоит из синтетических и натуральных силикатов и оксидов кремния, причем в частицы основы внедрен наноструктурированный химикат или частицы основы расслоены им.15. The composition according to item 12, in which the group consists of synthetic and natural silicates and silicon oxides, wherein a nanostructured chemical is embedded in the base particles, or the base particles are stratified by it. 16. Композиция по п.15, в которой наноструктурированный химикат получают из членов группы, состоящей из POSS-силанолов, силоксидов формулы [(RSiO1,5)4(RXSiO1,0)3]∑7, полисилсесквиоксанов [(RSiO1,5)n]∑#, фрагментов POSS [(RSiO1,5)m(RXSiO1,0)n]∑# и нефункционализованных молекулярных POSS-оксидов кремния [(RSiO1,5)m(RSiO1,5)n]∑#.16. The composition according to clause 15, in which the nanostructured chemical is obtained from members of the group consisting of POSS-silanols, siloxides of the formula [(RSiO 1,5 ) 4 (RXSiO 1,0 ) 3 ] ∑ 7 , polysilsesquioxanes [(RSiO 1, 5 ) n ] ∑ # , POSS fragments [(RSiO 1.5 ) m (RXSiO 1.0 ) n ] ∑ # and non-functional molecular POSS silicon oxides [(RSiO 1.5 ) m (RSiO 1.5 ) n ] ∑ # . 17. Композиция по п.16, в которой наноструктурированный химикат является силоксидами формулы [(RSiO1,5)4(RXSiO1,0)3]∑7, где X означает OH или OR.17. The composition according to clause 16, in which the nanostructured chemical is a siloxide of the formula [(RSiO 1,5 ) 4 (RXSiO 1,0 ) 3 ] ∑ 7 , where X is OH or OR. 18. Способ по п.1, в котором наноструктурированный химикат связывается с основой в результате реакции.18. The method according to claim 1, in which the nanostructured chemical binds to the base as a result of the reaction. 19. Способ по п.1, в котором наноструктурированный химикат связывается с основой без протекания реакции. 19. The method according to claim 1, in which the nanostructured chemical binds to the base without a reaction.
RU2007132158/04A 2005-01-27 2006-01-27 Surface modification with polyhedral oligomeric silsesquioxane silanols RU2425082C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US64832705P 2005-01-27 2005-01-27
US60/648,327 2005-01-27

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RU2425082C2 RU2425082C2 (en) 2011-07-27

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EP (1) EP1841592A4 (en)
JP (1) JP5086100B2 (en)
KR (1) KR101288000B1 (en)
CN (1) CN101203378B (en)
RU (1) RU2425082C2 (en)
TW (1) TWI399297B (en)
WO (1) WO2006081512A2 (en)

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CN109180943A (en) * 2018-07-26 2019-01-11 东华大学 A kind of preparation method of polyhydroxy function POSS hybrid material
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EP1841592A4 (en) 2011-04-20
JP5086100B2 (en) 2012-11-28
CN101203378B (en) 2013-03-27
RU2425082C2 (en) 2011-07-27
EP1841592A2 (en) 2007-10-10
CN101203378A (en) 2008-06-18
KR20070121648A (en) 2007-12-27
WO2006081512A2 (en) 2006-08-03
JP2008530257A (en) 2008-08-07
WO2006081512A3 (en) 2007-11-01
KR101288000B1 (en) 2013-07-19
TWI399297B (en) 2013-06-21
TW200639058A (en) 2006-11-16

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