RU2007132080A - DEVICE FOR HYDRAULIC AND / OR HEAT EXCHANGE, FOR example, LAMINATED HEAT EXCHANGER, SORPTION ROTOR, ADSORPTION WATER-ABSORBING ROTOR OR SIMILAR TO THIS - Google Patents

DEVICE FOR HYDRAULIC AND / OR HEAT EXCHANGE, FOR example, LAMINATED HEAT EXCHANGER, SORPTION ROTOR, ADSORPTION WATER-ABSORBING ROTOR OR SIMILAR TO THIS Download PDF

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Publication number
RU2007132080A
RU2007132080A RU2007132080/06A RU2007132080A RU2007132080A RU 2007132080 A RU2007132080 A RU 2007132080A RU 2007132080/06 A RU2007132080/06 A RU 2007132080/06A RU 2007132080 A RU2007132080 A RU 2007132080A RU 2007132080 A RU2007132080 A RU 2007132080A
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RU
Russia
Prior art keywords
moisture
rotor
heat transfer
zeolite
nanozeolite
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Application number
RU2007132080/06A
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Russian (ru)
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RU2392556C2 (en
Inventor
Юрген ЗАУЕР (DE)
Юрген Зауер
Томас ВЕСТЕРДОРФ (DE)
Томас Вестердорф
Ханс КЛИНГЕНБУРГ (DE)
Ханс Клингенбург
Original Assignee
Клингенбург Гмбх (De)
Клингенбург Гмбх
Наноскейп Аг (De)
Наноскейп Аг
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Publication of RU2007132080A publication Critical patent/RU2007132080A/en
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Publication of RU2392556C2 publication Critical patent/RU2392556C2/en

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F17/00—Removing ice or water from heat-exchange apparatus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/183—Physical conditioning without chemical treatment, e.g. drying, granulating, coating, irradiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0407—Constructional details of adsorbing systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/26—Drying gases or vapours
    • B01D53/261—Drying gases or vapours by adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/26—Drying gases or vapours
    • B01D53/28—Selection of materials for use as drying agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B01J20/28007—Sorbent size or size distribution, e.g. particle size with size in the range 1-100 nanometers, e.g. nanosized particles, nanofibers, nanotubes, nanowires or the like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28016—Particle form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28033—Membrane, sheet, cloth, pad, lamellar or mat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/2808—Pore diameter being less than 2 nm, i.e. micropores or nanopores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28088—Pore-size distribution
    • B01J20/2809—Monomodal or narrow distribution, uniform pores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F3/00—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems
    • F24F3/12—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling
    • F24F3/14—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by humidification; by dehumidification
    • F24F3/1411—Air-conditioning systems in which conditioned primary air is supplied from one or more central stations to distributing units in the rooms or spaces where it may receive secondary treatment; Apparatus specially designed for such systems characterised by the treatment of the air otherwise than by heating and cooling by humidification; by dehumidification by absorbing or adsorbing water, e.g. using an hygroscopic desiccant
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F13/00—Arrangements for modifying heat-transfer, e.g. increasing, decreasing
    • F28F13/18—Arrangements for modifying heat-transfer, e.g. increasing, decreasing by applying coatings, e.g. radiation-absorbing, radiation-reflecting; by surface treatment, e.g. polishing
    • F28F13/185—Heat-exchange surfaces provided with microstructures or with porous coatings
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
    • F28F21/04—Constructions of heat-exchange apparatus characterised by the selection of particular materials of ceramic; of concrete; of natural stone
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/304—Linear dimensions, e.g. particle shape, diameter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/308—Pore size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/31—Pore size distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/80—Water
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F2203/00—Devices or apparatus used for air treatment
    • F24F2203/10—Rotary wheel
    • F24F2203/1032—Desiccant wheel
    • F24F2203/1036—Details

Claims (13)

1. Устройство для влаго- и/или теплообмена, например пластинчатый теплообменник, сорбционный ротор, адсорбционный влагопоглощающий ротор или т.п., с поверхностями для влаго- или теплообмена, с помощью которых влага и/или тепло могут передаваться потоку текучей среды, и/или забираться потоком текучей среды, и/или обмениваться между потоками текучей среды, и покрытием, которым покрыты поверхности для влаго- или теплообмена, и которое образовано из пеолитового материала и вяжущего средства, отличающееся тем, что цеолитовый материал представляет собой синтетический наноцеолит с размером частиц <1000 нм.1. A device for moisture and / or heat transfer, for example a plate heat exchanger, a sorption rotor, an adsorption moisture-absorbing rotor or the like, with surfaces for moisture or heat transfer, by which moisture and / or heat can be transferred to a fluid stream, and / or taken up by the fluid stream, and / or exchanged between the fluid flows, and the coating that covers the surfaces for moisture or heat transfer, and which is formed from a peolitic material and a binder, characterized in that the zeolite material is It is a synthetic nanozeolite with a particle size <1000 nm. 2. Устройство по п.1, отличающееся тем, что наноцеолит выбран таким образом, что он обладает однородным распределением пор с диаметром пор <1,5 нм, преимущественно 0,4 нм.2. The device according to claim 1, characterized in that the nanozeolite is selected in such a way that it has a uniform pore distribution with a pore diameter <1.5 nm, preferably 0.4 nm. 3. Устройство по п.1 или 2, отличающееся тем, что частицы цеолитового материала имеют нанокристаллическую форму.3. The device according to claim 1 or 2, characterized in that the particles of zeolite material have a nanocrystalline shape. 4. Устройство по п.1 или 2, отличающееся тем, что толщина покрытия составляет от 0,2 до 100 мкм, преимущественно от 1 до 2 мкм (10-6 м).4. The device according to claim 1 or 2, characterized in that the coating thickness is from 0.2 to 100 microns, mainly from 1 to 2 microns (10 -6 m). 5. Устройство по п.3, отличающееся тем, что толщина покрытия составляет от 0,2 до 100 мкм, преимущественно от 1 до 2 мкм (10-6 м).5. The device according to claim 3, characterized in that the coating thickness is from 0.2 to 100 microns, mainly from 1 to 2 microns (10 -6 m). 6. Устройство по п.1 или 2, отличающееся тем, что поверхности для влаго- или теплообмена изготовлены из бумажного материала и пропитаны суспензией, содержащей синтетический наноцеолит.6. The device according to claim 1 or 2, characterized in that the surface for moisture or heat transfer are made of paper material and impregnated with a suspension containing synthetic nanozeolite. 7. Устройство по п.3, отличающееся тем, что поверхности для влаго- или теплообмена изготовлены из бумажного материала и пропитаны суспензией, содержащей синтетический наноцеолит.7. The device according to claim 3, characterized in that the surfaces for moisture or heat transfer are made of paper material and impregnated with a suspension containing synthetic nanozeolite. 8. Устройство по п.6, отличающееся тем, что после его пропитки суспензией, содержащей синтетический наноцеолит, состоит, по меньшей мере, на 30, преимущественно от 40 до 80 мас.% из наноцеолитового материала.8. The device according to claim 6, characterized in that after its impregnation with a suspension containing synthetic nano-zeolite, consists of at least 30, mainly from 40 to 80 wt.% Of the nano-zeolite material. 9. Устройство по п.7, отличающееся тем, что после его пропитки суспензией, содержащей синтетический наноцеолит, состоит, по меньшей мере, на 30, преимущественно от 40 до 80 мас.% из наноцеолитового материала.9. The device according to claim 7, characterized in that after impregnation with a suspension containing synthetic nano-zeolite, it consists of at least 30, preferably from 40 to 80 wt.%, Of the nano-zeolite material. 10. Устройство по любому из пп.1, 2, 5, 7-9, отличающееся тем, что вяжущее средство содержит дисперсионный клей, например рассол акрилата, к которому может добавляться дополнительно коллоидный SiO2.10. The device according to any one of claims 1, 2, 5, 7-9, characterized in that the astringent contains dispersion adhesive, for example, acrylate brine, to which colloidal SiO 2 can be added. 11. Устройство по п.3, отличающееся тем, что вяжущее средство содержит дисперсионный клей, например рассол акрилата, к которому может добавляться дополнительно коллоидный SiO2.11. The device according to claim 3, characterized in that the astringent contains dispersion adhesive, for example, acrylate brine, to which colloidal SiO 2 can be added. 12. Устройство по п.4, отличающееся тем, что вяжущее средство содержит дисперсионный клей, например рассол акрилата, к которому может добавляться дополнительно коллоидный SiO2.12. The device according to claim 4, characterized in that the astringent comprises dispersion adhesive, for example, acrylate brine, to which colloidal SiO 2 can be added. 13. Устройство по п.6, отличающееся тем, что вяжущее средство содержит дисперсионный клей, например рассол акрилата, к которому может добавляться дополнительно коллоидный SiO2. 13. The device according to claim 6, characterized in that the astringent comprises dispersion adhesive, for example, acrylate brine, to which colloidal SiO 2 can be added.
RU2007132080/06A 2005-01-26 2006-01-11 Device for fluid- and/or heat exchange, for example sorption rotor, adsorption fluid absorbing rotor and similar hardware RU2392556C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005003543A DE102005003543A1 (en) 2005-01-26 2005-01-26 Humidity/heat-exchange device e.g. plate heat exchanger, useful for keeping the area at moderate temperature and for air-conditioning the area, comprises humidity/heat exchange surface
DE102005003543.4 2005-01-26

Publications (2)

Publication Number Publication Date
RU2007132080A true RU2007132080A (en) 2009-03-10
RU2392556C2 RU2392556C2 (en) 2010-06-20

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US (1) US20080308262A1 (en)
EP (1) EP1842024A1 (en)
JP (1) JP2008528263A (en)
KR (1) KR20070104439A (en)
CN (1) CN100565081C (en)
CA (1) CA2595318C (en)
DE (1) DE102005003543A1 (en)
NO (1) NO20074321L (en)
RU (1) RU2392556C2 (en)
UA (1) UA93497C2 (en)
WO (1) WO2006079448A1 (en)

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UA93497C2 (en) 2011-02-25
CA2595318A1 (en) 2006-08-03

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