RU2006120720A - METHOD FOR REDUCING THE CONTENT OF SULFUR AND / OR NITROGEN IN DISTILLED RAW MATERIALS - Google Patents

METHOD FOR REDUCING THE CONTENT OF SULFUR AND / OR NITROGEN IN DISTILLED RAW MATERIALS Download PDF

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Publication number
RU2006120720A
RU2006120720A RU2006120720/04A RU2006120720A RU2006120720A RU 2006120720 A RU2006120720 A RU 2006120720A RU 2006120720/04 A RU2006120720/04 A RU 2006120720/04A RU 2006120720 A RU2006120720 A RU 2006120720A RU 2006120720 A RU2006120720 A RU 2006120720A
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RU
Russia
Prior art keywords
nitrogen
sulfur
metal
group viii
amount
Prior art date
Application number
RU2006120720/04A
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Russian (ru)
Other versions
RU2341549C2 (en
Inventor
Грэхем У. КЕТЛИ (US)
Грэхем У. КЕТЛИ
Дженет Л. ЕДИНАК (US)
Дженет Л. ЕДИНАК
Майкл ХОДЖЕС (US)
Майкл Ходжес
Джордж А. ХАФФ (US)
Джордж А. ХАФФ
Original Assignee
Бп Корпорейшн Норт Америка Инк. (Us)
Бп Корпорейшн Норт Америка Инк.
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Publication of RU2006120720A publication Critical patent/RU2006120720A/en
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Publication of RU2341549C2 publication Critical patent/RU2341549C2/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
    • C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
    • C10G53/14—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one oxidation step
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/10—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of metal-containing organic complexes, e.g. chelates, or cationic ion-exchange resins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/10—Magnesium; Oxides or hydroxides thereof

Claims (12)

1. Способ уменьшения содержания серы и/или азота в дистиллятном сырье для получения транспортного топлива на нефтеперерабатывающем заводе или смешения компонентов транспортного топлива нефтеперерабатывающего завода, в котором сырье содержит серосодержащие и/или азотосодержащие органические примеси, включающий:1. A method of reducing the content of sulfur and / or nitrogen in a distillate feedstock to produce transport fuel in an oil refinery or to mix components of a transport fuel of an oil refinery in which the feed contains sulfur-containing and / or nitrogen-containing organic impurities, including: (a) контактирование сырья с кислородсодержащим газом в зоне окисления в присутствии катализатора окисления, представляющего собой металл VIII группы и основной носитель, для превращения серо- и/или азотсодержащих примесей в окисленные серо- и/или азотсодержащие соединения; и(a) contacting the feed with an oxygen-containing gas in the oxidation zone in the presence of an oxidation catalyst, which is a Group VIII metal and a main support, to convert sulfur and / or nitrogen-containing impurities into oxidized sulfur and / or nitrogen-containing compounds; and (b) выделение части окисленных серо- и/или азотсодержащих соединений из выходящего потока зоны окисления с образованием на выходе потока дистиллята с пониженным количеством окисленных серо- и/или азотсодержащих соединений.(b) separating part of the oxidized sulfur and / or nitrogen-containing compounds from the outlet stream of the oxidation zone with the formation of a distillate with a reduced amount of oxidized sulfur and / or nitrogen-containing compounds at the outlet of the stream. 2. Способ по п.1, в котором металлом VIII группы является кобальт.2. The method according to claim 1, in which the metal of group VIII is cobalt. 3. Способ по п.1, в котором основным носителем является оксид магния.3. The method according to claim 1, in which the main carrier is magnesium oxide. 4. Способ по п.1, в котором основным носителем является оксид кальция.4. The method according to claim 1, in which the main carrier is calcium oxide. 5. Способ по п.1, в котором металл VIII группы присутствует в катализаторе окисления в количестве от примерно 0,1 мас.% до примерно 50 мас.% в расчете на общую массу катализатора.5. The method according to claim 1, in which the metal of group VIII is present in the oxidation catalyst in an amount of from about 0.1 wt.% To about 50 wt.% Based on the total weight of the catalyst. 6. Способ по п.1, в котором дистиллятный отходящий поток имеет общее кислотное число TAN меньше примерно 2,0 мг КОН/г.6. The method according to claim 1, in which the distillate effluent stream has a total acid number TAN less than about 2.0 mg KOH / g 7. Способ по п.1, в котором металл VIII группы присутствует в катализаторе окисления в количестве от примерно 2 мас.% до примерно 20 мас.% в расчете на общую массу катализатора.7. The method according to claim 1, in which the metal of group VIII is present in the oxidation catalyst in an amount of from about 2 wt.% To about 20 wt.% Based on the total weight of the catalyst. 8. Способ по п.1, в котором металл VIII группы присутствует в катализаторе окисления в количестве от примерно 4 мас.% до примерно 12 мас.% в расчете на общую массу катализатора.8. The method according to claim 1, in which the metal of group VIII is present in the oxidation catalyst in an amount of from about 4 wt.% To about 12 wt.% Based on the total weight of the catalyst. 9. Способ по п.1, в котором металл VIII группы является кобальтом, а основный носитель является оксидом магния.9. The method according to claim 1, in which the metal of group VIII is cobalt, and the main carrier is magnesium oxide. 10. Способ по п.9, в котором металл VIII группы присутствует в количестве от примерно 4 мас.% до примерно 12 мас.%.10. The method according to claim 9, in which the metal of group VIII is present in an amount of from about 4 wt.% To about 12 wt.%. 11. Способ по п.1, в котором отходящий дистиллятный поток содержит серу в количестве менее 5 м.д. по массе.11. The method according to claim 1, in which the exhaust distillate stream contains sulfur in an amount of less than 5 ppm. by weight. 12. Способ по п.1, в котором отходящий дистиллятный поток содержит азот в количестве менее 10 м.д. по массе.12. The method according to claim 1, in which the exhaust distillate stream contains nitrogen in an amount of less than 10 ppm. by weight.
RU2006120720/04A 2003-11-21 2004-11-16 Method of reducing content of sulfur and/or nitrogen in distillate raw material RU2341549C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/718,912 2003-11-21
US10/718,912 US20050109678A1 (en) 2003-11-21 2003-11-21 Preparation of components for refinery blending of transportation fuels

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RU2006120720A true RU2006120720A (en) 2008-01-10
RU2341549C2 RU2341549C2 (en) 2008-12-20

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US (2) US20050109678A1 (en)
EP (1) EP1682635A1 (en)
AU (1) AU2004293779B2 (en)
RU (1) RU2341549C2 (en)
WO (1) WO2005052092A1 (en)

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US20100282567A1 (en) * 2009-05-08 2010-11-11 Krishnan Sankaranarayanan On-board desulfurization system
US9296960B2 (en) * 2010-03-15 2016-03-29 Saudi Arabian Oil Company Targeted desulfurization process and apparatus integrating oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
US20110220550A1 (en) * 2010-03-15 2011-09-15 Abdennour Bourane Mild hydrodesulfurization integrating targeted oxidative desulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
US8658027B2 (en) 2010-03-29 2014-02-25 Saudi Arabian Oil Company Integrated hydrotreating and oxidative desulfurization process
JP5986203B2 (en) 2011-07-29 2016-09-06 サウジ アラビアン オイル カンパニー Oxidative desulfurization in fluid catalytic cracking process.
US8906227B2 (en) 2012-02-02 2014-12-09 Suadi Arabian Oil Company Mild hydrodesulfurization integrating gas phase catalytic oxidation to produce fuels having an ultra-low level of organosulfur compounds
RU2510640C1 (en) * 2013-01-10 2014-04-10 Андрей Владиславович Курочкин Method for treatment of oil containing hydrogen sulfide and mercaptan
US8920635B2 (en) 2013-01-14 2014-12-30 Saudi Arabian Oil Company Targeted desulfurization process and apparatus integrating gas phase oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
RU2630214C1 (en) * 2016-12-09 2017-09-06 Андрей Владиславович Курочкин Plant for sulfur purification of associated oil gas
RU2740131C2 (en) * 2016-12-20 2021-01-11 Общество с ограниченной ответственностью научно-исследовательский и проектный институт "ПЕГАЗ" Desulphurisation unit for associated petroleum gas

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Also Published As

Publication number Publication date
WO2005052092A1 (en) 2005-06-09
AU2004293779B2 (en) 2009-10-29
AU2004293779A1 (en) 2005-06-09
US20080172929A1 (en) 2008-07-24
US20050109678A1 (en) 2005-05-26
EP1682635A1 (en) 2006-07-26
RU2341549C2 (en) 2008-12-20

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Effective date: 20111117