RU2000104001A - COSMETIC USE OF DERIVATIVE BIS (RESORTSINIL) TRIAZINE - Google Patents

COSMETIC USE OF DERIVATIVE BIS (RESORTSINIL) TRIAZINE

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Publication number
RU2000104001A
RU2000104001A RU2000104001/14A RU2000104001A RU2000104001A RU 2000104001 A RU2000104001 A RU 2000104001A RU 2000104001/14 A RU2000104001/14 A RU 2000104001/14A RU 2000104001 A RU2000104001 A RU 2000104001A RU 2000104001 A RU2000104001 A RU 2000104001A
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RU
Russia
Prior art keywords
formula
alkyl
derivatives
hydrogen
radical
Prior art date
Application number
RU2000104001/14A
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Russian (ru)
Other versions
RU2223089C2 (en
Inventor
Дитмар ХЮГЛИН
Гельмут ЛЮТНЕР
Дитер РЕЙНЕР
Original Assignee
Циба Спешиалти Кемикалз Холдинг Инк.
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Application filed by Циба Спешиалти Кемикалз Холдинг Инк. filed Critical Циба Спешиалти Кемикалз Холдинг Инк.
Publication of RU2000104001A publication Critical patent/RU2000104001A/en
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Publication of RU2223089C2 publication Critical patent/RU2223089C2/en

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Claims (9)

1. Использование абсорбера ультрафиолетового излучения формулы
Figure 00000001

где R1 и R2 каждый самостоятельно обозначает водород; разветвленный С5-С18-алкил; С2-С18-алкенил; радикал формулы -СН2-СН(-ОН)-СН2-O-T1; радикал формулы
Figure 00000002

или радикал формулы
Figure 00000003

R3 и R4 каждый самостоятельно обозначает водород или С1-С5-алкил;
R5 обозначает гидрокси; С1-С5-алкокси, который не замещен или замещен одной или несколькими группами ОН; амино; моно- или ди-С1-С5-алкиламино; М; радикал формулы
Figure 00000004

Figure 00000005

Figure 00000006

Figure 00000007

R6 обозначает прямую связь; прямоцепочечный или разветвленный С1-С4-алкилен или радикал формулы
Figure 00000008
или
Figure 00000009

R7, R8 и R9 каждый самостоятельно обозначает C1-C18-алкил; C1-C18-алкокси или радикал формулы (1i)
Figure 00000010

R10, R11 и R12 каждый самостоятельно обозначает С1-С14-алкил, который не замещен или замещен одной или несколькими группами ОН;
R13 обозначает водород; М; С1-С5-алкил или радикал формулы
Figure 00000011

R14 обозначает С1-С5-алкил;
М обозначает катион металла;
T1 обозначает водород или C1-C8-алкил;
m1 равняется 1-3;
m2 равняется 2-14 и
p1 равняется 0 или обозначает число от 1 до 5,
для защиты кожи и волос людей и животных от пагубного воздействия ультрафиолетового излучения.1. Using ultraviolet absorber formula
Figure 00000001

where R 1 and R 2 each independently represents hydrogen; branched C 5 -C 18 alkyl; C 2 -C 18 alkenyl; a radical of the formula —CH 2 —CH (—OH) —CH 2 —OT 1 ; radical of the formula
Figure 00000002

or radical of the formula
Figure 00000003

R 3 and R 4 each independently represents hydrogen or C 1 -C 5 -alkyl;
R 5 is hydroxy; C 1 -C 5 -alkoxy, which is unsubstituted or substituted by one or more OH groups; amino; mono- or di-C 1 -C 5 -alkylamino; M; radical of the formula
Figure 00000004

Figure 00000005

Figure 00000006

Figure 00000007

R 6 is a direct bond; straight-chained or branched C 1 -C 4 alkylene or a radical of the formula
Figure 00000008
or
Figure 00000009

R 7 , R 8 and R 9 each independently denotes C 1 -C 18 -alkyl; C 1 -C 18 -alkoxy or a radical of formula (1i)
Figure 00000010

R 10 , R 11 and R 12 each independently represents a C 1 -C 14 -alkyl, which is unsubstituted or substituted by one or more OH groups;
R 13 is hydrogen; M; C 1 -C 5 -alkyl or a radical of formula
Figure 00000011

R 14 is C 1 -C 5 alkyl;
M denotes a metal cation;
T 1 is hydrogen or C 1 -C 8 alkyl;
m 1 is 1-3;
m 2 is 2-14 and
p 1 is 0 or denotes a number from 1 to 5,
to protect the skin and hair of people and animals from the harmful effects of ultraviolet radiation. 2. Использование по п.1, отличающееся тем, что используемый бис(резорцинил)триазин представляет собой соединение формулы
Figure 00000012

где R15 и R16 каждый самостоятельно обозначает разветвленный C5-C18-алкил или группу формулы -CH2-CH(-OH)-CH2-O-T1;
R17 и R18 каждый самостоятельно обозначает водород и T1 обозначает водород или С1-С5-алкил.2. The use according to claim 1, characterized in that the bis (resorcinyl) triazine used is a compound of the formula
Figure 00000012

where R 15 and R 16 each independently denotes a branched C 5 -C 18 -alkyl or a group of the formula -CH 2 -CH (-OH) -CH 2 -OT 1 ;
R 17 and R 18 each independently is hydrogen and T 1 is hydrogen or C 1 -C 5 -alkyl. 3. Использование по п.2, отличающееся тем, что в формуле (2) R15 и R16 каждый самостоятельно обозначает C1-C18-алкил или группу формулы -CH2-CH(-OH)-CH2-O-T1; R17 и R18 обозначают водород и T1 обозначает водород или С1-С5-алкил.3. Use according to claim 2, characterized in that in formula (2), R 15 and R 16 each independently denotes a C 1 -C 18 alkyl or a group of the formula —CH 2 —CH (—OH) —CH 2 -OT 1 ; R 17 and R 18 are hydrogen and T 1 is hydrogen or C 1 -C 5 -alkyl. 4. Использование по п.3, отличающееся тем, что в формуле (2) R15 и R16 каждый самостоятельно обозначает разветвленный C5-C18-алкил и R17 и R18 обозначают водород.4. Use according to claim 3, characterized in that in formula (2), R 15 and R 16 each independently designates a branched C 5 -C 18 alkyl and R 17 and R 18 denote hydrogen. 5. Использование по пп.2-4, отличающееся тем, что в формуле (2) R15 и R16 имеют одинаковые значения.5. Use according to claims 2-4, characterized in that in formula (2) R 15 and R 16 have the same values. 6. Использование по п.1, которое включает использование бис(резорцинил)триазина формулы
Figure 00000013

где R19 и R20 каждый самостоятельно обозначает радикал формулы
Figure 00000014

и R21, R22 и R23 каждый самостоятельно обозначает водород или C1-С10-алкил.6. The use according to claim 1, which includes the use of bis (resorcinyl) triazine of the formula
Figure 00000013

where R 19 and R 20 each independently denotes a radical of the formula
Figure 00000014

and R 21 , R 22 and R 23 each independently represents hydrogen or C 1 -C 10 -alkyl. 7. Косметический состав, который содержит абсорбер ультрафиолетового излучения формулы (I) по п.1 вместе с косметически совместимыми носителями или вспомогательными веществами. 7. A cosmetic composition that contains an ultraviolet absorber of formula (I) according to claim 1, together with cosmetically compatible carriers or excipients. 8. Состав по п.7, который содержит дополнительные вещества, защищающие от ультрафиолетового излучения. 8. The composition according to claim 7, which contains additional substances that protect against ultraviolet radiation. 9. Состав по п.7 или 8, отличающийся тем, что дополнительные вещества, защищающие от ультрафиолетового излучения, представляют собой органический абсорбер ультрафиолетового излучения из классов производных пара-аминобензойной кислоты, производных салициловой кислоты, производных бензофенона, производных дибензоилметана, производных дифенилакрилата, производных бензофурана, полимерных УФ-абсорберов, содержащих один или более кремнийорганических радикалов, производных коричной кислоты, производных камфоры, производных трианилино-втор-триазина, фенилбензимидазолсульфокислоты и ее солей, ментилантранилатов, производных бензотриазола и/или неорганического микропигмента, выбранного из группы, состоящей из ТiO2, оксида цинка или слюды, инкапсулированных оксидом алюминия или диоксидом кремния.9. The composition according to claim 7 or 8, characterized in that the additional substances that protect against ultraviolet radiation are an organic absorber of ultraviolet radiation from the classes of para-aminobenzoic acid derivatives, salicylic acid derivatives, benzophenone derivatives, dibenzoylmethane derivatives, diphenyl acrylate derivatives, derivatives benzofuran, polymer UV absorbers containing one or more organosilicon radicals, derivatives of cinnamic acid, derivatives of camphor, derivatives of trianilino-second triazine, fenilbenzimidazolsulfokisloty and its salts mentilantranilatov, benzotriazole derivatives, and / or inorganic micropigments selected from the group consisting of TiO 2, zinc oxide or mica, encapsulated alumina or silica.
RU2000104001/15A 1997-08-20 1998-08-08 Agent for protection of human and animal skin and hair against harmful effect of ultraviolet radiation and cosmetic composition RU2223089C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP97810585.6 1997-08-20
EP97810585 1997-08-20

Publications (2)

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RU2000104001A true RU2000104001A (en) 2001-12-27
RU2223089C2 RU2223089C2 (en) 2004-02-10

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US (1) US6221342B1 (en)
EP (1) EP1005325B1 (en)
JP (1) JP3964133B2 (en)
KR (1) KR100548980B1 (en)
CN (1) CN1170522C (en)
AU (1) AU747205B2 (en)
BR (1) BR9811958B1 (en)
DE (1) DE69827393T2 (en)
ES (1) ES2232009T3 (en)
IL (1) IL134244A0 (en)
MX (1) MX224819B (en)
NZ (1) NZ502708A (en)
PL (1) PL338738A1 (en)
RU (1) RU2223089C2 (en)
WO (1) WO1999008653A1 (en)

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KR100494448B1 (en) * 1996-06-04 2005-12-02 화브리까 에스파놀라 데 프로둑또스 뀌미꼬스 이 화르마세우띠꼬스 쏘시에떼 아노님 Novel benzoimidazole derivatives with antihistamine activity
DE19817292A1 (en) * 1998-04-18 1999-10-21 Beiersdorf Ag Stable cosmetic or dermatological preparations in the form of W / O emulsions containing unsymmetrically substituted triazine derivatives
FR2789580A1 (en) * 1999-02-12 2000-08-18 Oreal Cosmetic composition useful for photoprotection of the skin or hair comprises a synergistic combination of two ultraviolet filters
FR2789579B1 (en) * 1999-02-12 2002-02-01 Oreal COSMETIC COMPOSITIONS FOR PHOTOPROTECTION OF THE SKIN AND / OR HAIR CONTAINING A BENZOTRIAZOLE DERIVATIVE AND A BIS-RESORCINYL TRIAZINE
FR2789583B1 (en) 1999-02-12 2002-02-01 Oreal ANTISOLAR COSMETIC COMPOSITIONS BASED ON A SYNERGISTIC MIXTURE OF FILTERS AND USES
DE19910477A1 (en) 1999-03-10 2000-09-14 Beiersdorf Ag Use of octocrylene to solubilize 2,4-bis - {[4- (2-ethyl-hexyloxy-2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1,3,5-triazine in cosmetic or dermatological light stabilizers
EP1068866A3 (en) 1999-07-12 2004-03-17 Ciba SC Holding AG Use of mixtures of micropigments for prevening tannig and to induce skin and hair lightening
ES2258035T3 (en) * 1999-12-23 2006-08-16 Ciba Specialty Chemicals Holding Inc. STABILIZING MIX
CA2423262A1 (en) * 2000-09-21 2002-03-28 Pfizer Products Inc. Resorcinol derivatives
DE10130963A1 (en) * 2001-06-27 2003-01-16 Beiersdorf Ag Use of bis-resorcinyltriazine derivatives to improve the effectiveness of lipophilic active ingredients in cosmetic or dermatological preparations
US7534421B2 (en) 2003-03-03 2009-05-19 L'oreal s-Triazine compounds bearing at least one para-aminobenzalmalonic salt substituent and photoprotective cosmetic compositions comprised thereof
US20050012594A1 (en) * 2003-07-17 2005-01-20 Youngtack Shim Key assemblies and methods
CN102292397B (en) 2009-01-19 2014-12-10 巴斯夫欧洲公司 Organic black pigments and their preparation
CN102010520A (en) * 2010-11-10 2011-04-13 大连化工研究设计院 Triazine light stabilizer containing hindered amine groups
CN118084811A (en) * 2024-04-23 2024-05-28 安庆科思化学有限公司 Environment-friendly preparation method of sun-screening agent intermediate RET

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CH480090A (en) 1962-10-30 1969-10-31 Ciba Geigy Use of new hydroxyphenyl-1,3,5-triazines as ultraviolet protection agents outside the textile industry
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CH469053A (en) 1963-07-26 1969-02-28 Ciba Geigy Use of new hydroxyphenyl-1,3,5-triazines as protective agents against ultraviolet radiation for non-textile organic materials
GB9403451D0 (en) 1994-02-23 1994-04-13 Ciba Geigy Ag Sunscreen compositions
DE19543730A1 (en) 1995-11-23 1997-05-28 Ciba Geigy Ag Until resorcinyl-triazines
EP0878469B1 (en) 1997-05-16 2004-10-27 Ciba SC Holding AG Resorcinyl-triazines

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