RU1838396C - Toilet soap - Google Patents

Abstract

. The invention relates to the soap industry. SUBSTANCE: toilet soap, consisting of sodium soaps of animal and vegetable fats, as well as improving additives and aimed at obtaining high physicochemical parameters and good consumer properties, contains 20-60% of the mass fraction of sodium soaps of fat and / or 22-30 % of the mass fraction of sodium soaps of crude lard, and / or 5-18% of the mass fraction of sodium soaps of hydrogenated fat, best hydrogenated lard, -15-30% of the mass fraction of sodium soaps of vegetable oil, especially coconut oil or palm kernel oil, in up to 2% of the mass fraction of rosin is possible, the total amount of crude fat being at least 84%, 0.2-0.8% of the mass fraction of an emulsifier selected from the group: ethoxylated fat of fur animals and / or ethoxylated saturated alcohols, 0 , 3-1.7% of the mass fraction of special additives selected by their group: collagen or collagen with elastin, and / or liquid lanolin, and / or triglycerides of fatty acids C8-C16, eventually 0.2-0.7% mass the proportion of improving additives selected from the group: methyl silicone oil or oxyethylated nonylphenol sulfosuccinate, 0.2- 1.2% of the mass fraction of protective agents selected from the group: propylene glycol and / or polyoxyethylene stearate 1.4 sorbitol and / or hexahydroxyl alcohol and / or diethanolamide of acids of coarse low-erucic oil, 0.05-0.25% of the mass fraction of dye including 0.1-0.2% of titanium white, 0.9-1.6% of the mass fraction of the fragrant composition, possibly a preservative, as well as water up to 100% of the mass, all additives except titanium white are liquid mi, and their total amount is 1.6-3.2% of the mass fraction. ate with soo soo soo about soo

Description

A subject of the invention is a bar soap. Toilet soaps, depending on their physicochemical characteristics, are divided into two varieties: luxury and popular. Depending on grade

soap must meet different requirements.

In order to obtain good physicochemical parameters, as well as very good consumer properties, a

the composition of wood soap, as well as specially selected compositions in improving additives.

The soap according to the invention consists of 20-60% of the mass fraction of sodium soap of lard or 22-30% of the mass fraction of sodium soap of crude lard and / or 5-18% of the mass fraction of sodium soap of hydrogenated fat, useful hydrogenated lard , 15-30% of the mass fraction of sodium soaps of vegetable oil, especially coke oil or palm oil, eventually up to 2% of the mass fraction of rosin, with the total amount of fatty raw materials being at least 84%, 0.2-0.8% mass fraction of emulsifier selected from the group: ethoxylated fat of fur animals th and / or ethoxylated saturated alcohols, 0.3-1.7% of the mass fraction of special additives selected from the groups: collagen or collagen with elastin and / or liquid lanolin and / or triglycerides of fatty acids Ce-Syu, or 0.2- 0.7% of the mass fraction of improving additives selected from the group: methyl silicone oil or sulfosuccinate rksietilirovanno nonylphenol, 0.2-1.2% of the mass fraction of protecting agents selected from the group: propylene glycol and / or polyoxyethylene 1,4-sorbitan stearate and / or hexahydroxyl alcohol and / or di-ethanolamide of acid of sera low eruco- oil, 0.05-0.15% of the mass fraction of the dye, including 0.1-012% of the mass fraction of titanium dioxide, 0.9-1.6% of the mass fraction of the fragrant composition, eventually preserving substance, as well as water up to 100% mass fraction, with all additives except titanium dioxide being liquids, and their total amount is 1.6-3.2% mass fraction.

Soap with a so selected qualitative and quantitative composition fulfills all the requirements set for soaps such as luxury :. This applies to both physicochemical parameters and high consumer qualities. This soap is smooth, uniform throughout the mass, has a slippery surface, does not dry out human skin, foam well and gives a soft foam. In addition, due to the very low content of synthetic substances, it does not irritate the skin.

Example 1. In a digester, 3750 kg of coconut oil and 4275 kg of beef fat were washed with a first solution of sodium hydroxide solution. In a second digester, 2250 kg of hydrogenated lard and 4500 kg of raw pork lard were washed with sodium hydroxide solution. After the operation of grinding, grinding and sanding soap liquors, the contents of the second boiler were pumped to the first

boiler. The soap was set aside in the boiler for 50 hours to settle. The soap was then pumped to a vacuum tower to dry to about 80% fatty acids.

Dried chips, i.e. wood soap was stored in silos. An emulsion was prepared in the homogenizer with the composition: 5 kg of soap, 3 kg of ethoxylated saturated alcohols / Rokanol L4 /, 5 kg of methyl silicone oil / Pollsil OM 300 /, 6 kg of hexahydroxyl alcohol / Sorbitol /, 5 kg of collagen, 0.2 kg 2- bromine-2-nitor-propane-1,3-diol / Groprof / in the form of a 2% aqueous solution, 1 kg of titanium dioxide and 11 kg of Luxy fragrance

1000 kg of dried soap shavings were mixed in a pelotosis with a prepared emulsion. After passing through the pelotez system, the soap was molded into bars and stamped.

Thus obtained luxury toilet soap was characterized by the following parameters:

fatty acid content,%

mass fraction 81

titer of oily

acids / ° C / 39

neutralization number allocated

fatty acids along with

gum / mg KOH / g / 216

foaming ability / ml / 320

PRI me R 2. The kernel soap was obtained by the method presented in example 1.

An emulsion was prepared in the homogenizer consisting of 5 kg of soap soap, 5 kg of fat from mink ethoxylated with 12 moles of ethylene oxide / emulsifier TN 12 /, 6 kg of trigly. C & -Cio fatty acid cerides / Migliol 812 /. 5 kg polyoxyethylene stearate 1,4-sorbitol / Rokvinol 60 /, 4 kg methyl silicone oil / Polsil OM 300 /, 0.2 kg gropol in the form of an aqueous solution, 1 kg titanium dioxide, 0.4 kg lithium red RCJ 15630, 11 kg of fragrant composition Kamea.

Configuring and finishing the soap was carried out by the method presented in example 1.

The resulting luxury toilet soap was characterized by the following parameters:

fatty acid content%

mass fraction 80.9

titer of oily

acids / ° C / 40

neutralization number allocated

fatty acids along with

gum / mg KOH / g / 216.9

ability to retire education / ml / 315.

Example 3. Soap was prepared by the method described in Example 1. An emulsion was prepared using 5 kg of soap dust, 3 kg of Rokanol L4.3 kg of sulfosuccinate hydroxyethylated nonylphenol, 2 kg of liquid lanolin, 1 kg of propylene glycol, 2 kg of titanium white. After mass homogenization, 15 kg of fragrant composition Bouquet Fresh was added. The soap was subjected to the decoration presented in example 1. The resulting luxury soap was characterized by the following parameters:

fatty acid content,%

mass fraction81.5

titer of oily

acids / ° C / 39.1

neutralization number allocated

fatty acids along with

gum / mg KOH / g / 215

foaming ability / ml / 300.

PRI me R 4. The kernel soap was prepared by the method described in example 1. Additives were prepared in the form of an emulsion: 2 kg of soap dust was mixed with 4 kg of palm oil, 2 kg of Rokanol L4.1 kg of sorbitol and then 2 kg of titanium dioxide was added . After homogenization, 1.5 kg of the fragrance composition Yuxori was added.

The soap was subjected to the decoration described in example 1. Received a luxury toilet soap, characterized by the following parameters:

fatty acid content

mass fraction81.0

titer of oily

acids / ° C / 39

neutralization number allocated

fatty acids along with

gum / mg KOH / g / 216

foaming ability / ml / 320.

PRI me R 5. The kernel soap was obtained by the method presented in example 1.

An emulsion was prepared in the homogenizer with the composition: 3 kg of soap dust 8 kg of fat from oxyethylated mink 6 moles of ethylene oxide / emulsifier TN 6 /, 3 kg of collagen, 2 kg Polsil OM-100, 3 kg propylene glycol, 0.2 kg Gropol in the form 2% aqueous solution, 1 kg of titanium dioxide, as well as 11 kg of fragrance Luxofresh ..

Configuring and finishing the soap was carried out by the method presented in example 1.

Thus obtained luxury toilet soap was characterized by the following parameters:

fatty acid content%

mass fraction80

titer of oily

acids / ° C / .39

neutralization number allocated

fatty acids along with

gum / mg KOH / g / 215

Foam ability

education / ml / 325.

Example The soap was obtained by the method presented in example 1.

An emulsion was prepared in the homogenizer with the following composition: 3 kg of soapy kg of oxyethylated fat 12 moles of ethylene oxide / emulsifier TL 12 /, 3 kg of liquid lanolin, 12 kg of roquinol W, 2 kg of diethanolamide of acid of low-erucic oil / Stremid DO /, 0.2 kg gropol in the form of 2%. aqueous solution, 2 kg of titanium dioxide, 0.2 kg of pigmented green GG, 9 kg of a fragrant substance. Fresh bouquet ..

Configuring and. Soap finishing was carried out by the method presented in example 1 ..

Thus obtained luxury toilet soap was characterized by the following parameters:

fatty acid content%

mass fraction79

titer of oily

acids / ° C / 39

neutralization number allocated

fatty acids along with

gum / mg KOH / g / 215

foaming ability / ml / 330.

Example. The soap was obtained by the method presented in example 1.

An emulsion was prepared in the homogenizer with the following composition: 5 kg of soap dust, 4 kg of Rokanol L4, 3 kg of collagen with elastin, 2 kg of Sorbite, 1 kg of titanium dioxide, 0.3 kg of pigmented green GG, 16 kg of fragrant composition Florelle Green. Configuring and finishing the soap was carried out by the method described in example 1. Thus obtained luxury toilet soap was characterized by the following parameters:

fatty acid content%

mass fraction78

titer of oily

acids / ° C / 40

neutralization number allocated

fatty acids along with

gum / mg KOH / g / 216

foaming ability / ml / 330.

Example The core soap was obtained by the method presented in example 1.

An emulsion was prepared in the homogenizer with the following composition: 2 kg of soap dust, 2 kg of emulsifier TL 6, 3 kg Migliol 812.2 kg Rokvinol 60.0.2 kg Gropol in the form of a 2% aqueous solution, 1 kg of titanium dioxide, 0, 3 kg of pigmented green GG, 0.16 kg of pigmented yellow GG, 9 kg of fragrant composition Florelle Green.

Configuring and finishing the soap was carried out by the method presented in example 1. Obtained in this way, toilet soap type luxury was characterized by the following parameters:

fatty acid content of mass fraction79 titer of selected fatty acids / ° C / 39 number of neutralization of selected fatty acids together with tar / mg KOH / g / 215 foaming capacity / ml / 330. EXAMPLE 9. In a digester the first was washed with a solution of sodium hydroxide 3750 kg of coconut oil and 9525 kg of beef tallow. In a second digester, 1,500 kg of hydrogenated sera low erucic oil and 225 kg of rosin were washed with a solution of sodium hydroxide solution. After the operation of grinding, grinding and drawing off the soap liquor, the contents of the second boiler were pumped to the first boiler. The soap in the boiler was left to stand for 60 hours. The soap was then pumped into a vacuum tower to dry to. content of about 80% fatty acids. The dried wood chips, which were wood soap, were stored in silos.

An emulsion was prepared in the homogenizer with the following composition: 3 kg of soap dust, 7 kg of emulsifier TL 12, 6 kg Migliol 818, 4 kg Rokvinol 60, 2 kg Stremida DO, 1 kg of titanium dioxide, 0.4 kg of lithium red R and 11 kg of fragrant Camon’s compositions,

Configuring and finishing the soap was carried out by the method described in example 1. Obtained in this way toilet soap type lux was characterized by the following parameters:

fatty acid content%

mass fraction80

titer of oily

acids / ° C / 40

neutralization number allocated

fatty acids along with

gum / mg KOH / g / 216

foaming ability / ml / 340.

PRI me R 10. The kernel soap was obtained by the method presented in example 9.

An emulsion was prepared in the homogenizer with the following composition: 6 kg Rokanol L 4, 3 kg Migliol 818, 2 kg Pollsil OM-200, 2 kg Stremida DO, 0.2 kg Gropol in the form of an aqueous solution, 2 kg of titanium dioxide, 0.08 kg Rhodamine B, 12 kg of Isali fragrance composition, Configuring and finishing the soap was carried out by the method described in example 1. The resulting luxury toilet soap was characterized by the following parameters:

fatty acid content%

mass fraction} 80 5 titer of selected fatty

acids / ° C / 39

neutralization number allocated

fatty acids along with

resinous / mg KOH / g / 216 0 foaming ability / ml / 335.

PRI me R 11. The kernel soap was prepared by the method described in example 9.

An emulsion was prepared in the homogenizer with the following composition: 3 kg of soap dust, 5 kg of TL 12 emulsifier, 5 kg of palm oil, 3 kg of Rokvinol 60, 2 kg Stremida DO, 0.2 kg Gropol in the form of an aqueous solution, 1 kg of dioxide titanium, 12 kg of fragrant composition Kopriy. Configuring and finishing the soap was carried out by the method described in example 1. The resulting luxury toilet soap was characterized by the following parameters: 5 fatty acid content%

mass fraction79

titer of oily

acids / ° C / 39

the number of neutralization of the isolated 0 fatty acids together with

gum / mg KOH / g / 217

ability to retire education / ml / 350.

PRI me R 12. The kernel soap was obtained by the 5 method shown in example 9. In the homogenizer prepared an emulsion with the following composition: 10 kg of Rokanol L 3, 5 kg of collagen with elastin, 2 kg Pollsil OM-100, 3 kg Sorbite, 1 kg of titanium dioxide, 0.3 kg of pigment green GG, 0.16 kg of pigment yellow G, 9 kg of fragrant Camon composition. Configuring and finishing the soap was carried out by the method described in example 1. Received the same number of soap suites 5 was characterized by the following parameters:

fatty acid content%

mass fraction 80

titer of oily

acids / ° C / 40

neutralization number allocated

fatty acids along with

gum / mg KOH / g / 215

foaming ability / ml / 350.

Example 13. A soap was obtained by the method described in Example 9. An emulsion was prepared in the homogenizer with the following composition: 2 kg of soap dust, 4 kg of emulsifier TN 12, 4 kg of Migliol 812, 2 kg of propylene glycol, 2 kg Stremida DO, 2 kg of titanium dioxide, 0.2 kg of gropol in the form of an aqueous solution, 0.15 kg of pigmented carmine B, 15 kg of the fragrant Kamea composition. Configuring and finishing the soap was carried out by the method presented in example 1. Obtained in this way toilet soap type lux was characterized by the following parameters:

fatty acid content%

mass fraction 79

titer of oily

acids / ° C / 40

neutralization number allocated

fatty acids along with

gum / mg KOH / g / 216

foaming ability / ml / 340.

Example 14. The core soap was obtained by the method described in Example 9. An emulsion was prepared in the homogenizer with the following composition: 2 kg of soap dust, 5 kg of Rokanol L 3, 5 kg of palm oil, 2 kg of Pollsil OM-150, 5 kg of Stremida DO., 1 kg of dioxide titanium, 0.2 kg gropol in the form of an aqueous solution, 0.4 kg of lithol red R, 12 kg of fragrant Luxoni composition. Configuring and finishing the soap was carried out by the method described in example 1. The resulting luxury toilet soap was characterized by the following parameters:

fatty acid content. %

mass fraction80

titer of oily

acids / ° C /. 41

neutralization number allocated

fatty acids along with

gum / mg KOH / g / 216

foaming ability / ml / 350.

Example 15. In a digester, 4500 kg of palm oil, 10200 kg of beef tallow and 300 kg of rosin were washed with the first solution of sodium hydroxide. After the shredding process. After grinding and polishing the soap liquors, the contents of the boiler were left to stand for 60 hours. Next, the soap was pumped into a vacuum tower to dry to about

80% fatty acids. Dried wood shavings, which are wood soap, were stored in bins.

An emulsion was prepared in the homogenizer with the following composition: 8 kg of TN 6 emulsifier. 4 kg of liquid lanolin, 3 kg of propylene glycol, 2 kg of Stremida DO, 0.2 kg of gropol in the form of an aqueous solution, 1 kg of titanium dioxide, 0.3 kg of pigmented green GG, 0 12 kg of fragrant composition Bouquet Fresh. Confection and finishing was carried out by the method presented in example 1. Received luxury toilet soap, characterized by the following parameters: 5 content of fatty acids%

mass fraction80

titer of oily

acids / ° C / 40

the number of neutralization of the selected 0 fatty acids together with

gum / mg KOH / g / 217

foam ability.

education / ml / 355.

Example 16. The soap was prepared by the method described in Example 15. An emulsion was prepared in the homogenizer with the following composition: 5 kg of soap dust, 6 kg of Rokanol L 3, 4 kg of liquid lanolin, 2 kg of Polls OM- 100, 3 kg Sorbite, 0 0.2 kg Gropol, 1 kg of titanium dioxide, 0.0105 kg of Rhodamine B, 15 kg of the fragrant composition of Isali. Configuring and finishing the soap was carried out by the method described in example 1. The characteristic of the soap was 5 as follows:;

fatty acid content%

mass fraction 80

titer of oily

acids / ° C / 39 0 the number of neutralization allocated

fatty acids along with.

with molar / mg KOH / g / 215

foaming ability / ml / .320. 5 PRI me R 17. The core soap was prepared by the method described in example 15. An emulsion was prepared in the homogenizer with the following composition: 6 kg of emulsifier TL 6, 4 kg of collagen with elastin, 2 kg 0 Migliol 812, 2 kg Gamal NF 06 , 1 kg Sorbite, 0.2 kg Gropol, 1 kg of titanium dioxide, 0.18 kg of pigmented yellow G, 12 kg of fragrant composition Luxofresh. Configuring and finishing the soap was carried out in 5 ways, presented in example 1. The resulting luxury toilet soap was characterized by the following physicochemical parameters:

fatty acid content%

mass fraction80

titer of oily

acids / ° C / 39

neutralization number allocated

fatty acids along with

gum / mg KOH / g / 216

foaming ability / ml / 340.

PRI me R 18. The kernel soap was prepared by the method described in example 1. The emulsion was prepared using the following components: 3 kg of soap dust / 8 kg of emulsifier TN 12, 2 kg of palm oil, 2 kg of Rokvinol 60, 2 kg Stremida DO, 2 kg of titanium dioxide. About kg litol red R, 14 kg of fragrant composition Kame. Confection and finishing of the soap was carried out by the method described in example 1. The resulting luxury toilet soap was characterized by the following physicochemical parameters:

fatty acid content%

mass fraction79

titer of oily

 acids / ° C / 39

neutralization number allocated

fatty acids along with

gum / mg KOH / g / 215

foaming ability / ml / 330.

PRI me R 19. The core soap was prepared by the method described in example 15. The emulsion was prepared in a homogenizer of the following components: 8 kg of emulsifier TL 12, 3 kg of liquid lanolin, 1 kg of sorbite, 3 kg Stremida DO, 0.2 kg Gropol, 1 kg of titanium dioxide, 0.15 kg of pigmented carmine, 12 kg of Kopri fragrant composition. Configuring and finishing the soap was carried out by the method described in example 1. The resulting luxury toilet soap was characterized by the following physicochemical parameters:

fatty acid content

mass fraction79

titer of oily

acids / ° C / 40

neutralization number allocated

fatty acids along with

resin / kg KOH / g / 216

foaming ability / ml / 335.

PRI me R 20. The core soap was prepared by the method described in example 15. An emulsion was prepared in the homogenizer with the following composition: 3 kg of soap dust, 5 kg of Rokanol L 3, 2 kg of Migliol 818,

2 kg Paulsil OM-100, 2 kg popylene glycol,

3 kg Stremida DO, Q, 2 kg Gropol, 1 kg of titanium dioxide, 0.8 kg of lithol red R, 16 kg of the fragrant Kame composition. Configuring and finishing the soap was carried out by the method described in example 1. Received a luxury toilet soap with the following physicochemical parameters:

fatty acid content,% mass fraction80 titer of isolated fatty acids / ° C / 40 number of neutralization of the isolated fatty acids together with tar / mg KOH / g / 216 pensionability / ml / 345.

Claims (5)

1. Toilet soap containing sodium soaps of animal fats, sodium soaps of coke oil or palm kernel oil, an emulsifier, a dye containing a coloring substance in an aqueous solution, titanium white in an amount of 0.1-0.2 wt.%, perfume and water, characterized in that, in order to improve physicochemical parameters, sodium soaps of animal fat use sodium soaps of lard and / or crude lard, and / or hydrogenated fat with a total amount of fat of at least 84%, it is an emulsifier contains ethoxylated fat of fur animals and / or ethoxylated saturated alcohol, in addition it includes collagen or collagen with elastin and / or liquid lanolin and / or Ce-Cte fatty acid triglycerides, propylene glycol, and / or sorbitol polyoxy-1 tylenostearate, and / or hexahydroxyl alcohol and / or diethanolamide of acid of low-eruc oil, and soap contains all additives and coloring matter in the form of liquids and their total amount is 1.6-3.2 wt.%, the components are taken in the following ratio, wt.%: 0 5 sodium soaps sala-20-60 and / or crude sodium soaps lard - 22-30 and / or sodium soaps hydrogenated fat 5-18; coke sodium soaps palm oil or oil grains 15-30; the specified emulsifier is 0.2-0.8; collagen or collagen with elastin and / or liquid lanolin and / or triglycerides Ca-Cie fatty acids 0.3-1.7; propylene glycol, and / or . sorbitol polyoxyethylene stearate, and / or hexahydroxyl alcohol and / or diethanolamide acid of severe low erucic oil-0.2-1.2; dye.-0.05-0.25; perfume-0.9-1.6; water is the rest. 2. Soap according to claim 1, on the basis of its topics. that sodium soap packs additionally contain until May 2. % rosin. 0 3. Soap according to claim 1, with the exception of g; by that. that it additionally contains 0.2-0.7% methylsilicone oil or hydroxyethylated ionylphenol sulfsuccinate. 4. Mylopop. 1, characterized in that it contains hydrogenated lard soap as a hydrogenated fat soap. t 5. Soap according to claim 1, characterized in that it contains a preservative.