KR960002195B1 - Toilet soap composition - Google Patents

Abstract

The beauty soap composition is composed of 0.01˜5wt.pt of a green bean and/or its extract, 0.05˜2wt.pt. of a 2,4,4'-trichloro-2'-hydroxy diphenyl ether and/or a 3,4,4'-trichloro carbanilide, and 0.1˜5wt.pt. of a bamboo salt. In the example, the beauty soap is produced by mixing 96.3wt.pt beauty soap base, 0.5wt.pt green bean and/or its extract, 1.0wt.% bamboo salt, 0.1wt.pt triclosan, 0.1wt.pt. triclocarban, 0.2wt.pt. propylene glycol, 1.2wt.pt perfume, 0.1wt.pt. ethylene diamine tetraacetic acid and 0.5wt.pt. titanium dioxide. The beauty soap has a good beauty and deodorizing effect.

Description

Cosmetic soap composition

The present invention relates to a cosmetic soap composition that improves and enhances the deodorizing effect while having an excellent cosmetic effect on the skin. In detail, the present invention is a green water or skin extract excellent in the beauty of the effect and bactericidal 2,2 ', 4'-trichloro-2'-hydroxydiphenyl ether [2,4,4'-trichloro-2 '-hydroxy diphenylether; Trade names-triclosan] and 3,4,4'-trichloro carbanilide [3,4,4'-trichloro carbanilide; The present invention relates to a cosmetic soap composition having good workability without discoloration and cracking while having excellent skin beauty effect and improving or enhancing deodorant effect after being used alone or mixed with triclocarban.

Normally, the condition that the cosmetic soap should be equipped with is excellent in the degree and quantity of bubbles when using soap, smooth surface feel, no coating irritation before and after use, and it should not be cracked when dried. It should be easy to manufacture and have good stability over time.

In general, cosmetic soaps, except for synthetic surfactant soaps, which use surfactants as the main agent, are made by neutralizing weak acids, strong bases, caustic soda or caustic, and are alkaline in aqueous solution. It removes the ingredients and sebum in the sebaceous glands is broken down to the skin surface through the pores to suppress the evaporation of moisture of the skin and maintain elasticity.

However, due to abnormal keratinization of skin epithelial cells, pores are blocked, sebum is not discharged to the surface of the skin, and sebum becomes clumped in the pores, where invasion of anaerobic bacteria (Proipionbacterium Acne) causes inflammation and reddens the skin. And even if sebum is well discharged on the surface of the skin, microorganisms in the air multiply on the surface of the skin and dissipate sebum, which makes the odor of the skin worse. The effect was, but not complete.

In order to suppress the occurrence of the odor of the skin, U.S. Patent No. 4422111 attempts to remove the odor of the skin using bactericidal triclosan, and also in the Journal of the society of cosmetic chemists (84, 11). It is reported that it is effective in the sterilization test using triclocaban, but all of these raw materials are chemically manufactured raw materials, and the stability of light is poor, so the deodorizing effect of the skin is excellent. There was a limit.

Accordingly, the present inventors have diligently researched to solve the problems of the prior arts, and when mung bean powder and / or its extract are contained in a conventional makeup soap, the beauty of the skin is excellent and the effect is enhanced when mixed with bamboo salt. In addition, by mixing the bactericidal triclosan and / or triclocaban and then using bamboo salt to improve or deodorize the skin, it is possible to prepare a cosmetic soap having excellent stability by light and no cracking phenomenon. It has been found and completed the present invention.

0.01 to 5 parts by weight of mung beans and / or extracts, 2,4,4'-trigloro-2'-hydroxy diphenylether and / or 3,4,4'-trichloro carbanide 0.05 It relates to a cosmetic soap composition characterized in that it contains from 2 to 2 parts by weight and from 0.1 to 5 parts by weight of bamboo salt.

Mung bean used in the present invention is a herbaceous herb that grows straight about 30 to 50cm, grows many branches, and has light brown hairs on the whole. Rich in essential amino acids, unsaturated fats and carbohydrates.

In addition, bamboo salt used in the present invention was manufactured by using a bamboo and a salt method, which is repeated by several times of high temperature treatment in a furnace with bamboo which acts as a cell to generate new cells and a bacterium to prevent sterilization and rot. Elixir is known as a elixir that eliminates toxins and enhances its efficacy. Salt used in the manufacture of bamboo salt is usually used as a natural salt, in addition to edible salt, rock salt, reagent gold sodium chloride and potassium chloride, bamboo or cotton bamboo is used as bamboo, but there is no need to limit the type of bamboo.

Bamboo salt used in the present invention is a commercially available bamboo and ocher, and the bacterium to prevent the decay, decay of the cells to generate cells by repeated treatment at high temperatures (1,000 ℃) in the furnace to remove toxins and increase the efficacy of the drug as much as possible It is.

In the production method of bamboo salt used in the present invention, the following method is introduced to the old book. Cut the bamboo which grew with the sea breeze (three years old is suitable), and cut it one by one to block the other, then squeeze the sun-dried salt into the container and beat it with the greasy clay soil in the mountain nine times and dry it in the shade. Put red pine salt, reinforcement mugwort, and leaves about 1cm and seal it with the clay soil kneaded about 2cm at the end. Make several of these bamboos, put pines on a porcelain kiln made in ocher, sprinkle pine nuts, and turn on fire (in room temperature above 1,000 ℃) and take out after about 24 hours (at this time, absorb the gin of red, red pine, wormwood, and ocher). Only salt column remains) Repeatedly repeat the method of crushing the salt mass finely and adding salt to the new bamboo in the same way as the first time to make a fire and repeating it eight times, and in the ninth, it can make a high temperature (above 1,500 ℃). When using a special stainless steel, the fire is melted by only the paper and melted down, and it flows like the molten metal in the furnace. When the fire goes out, the liquid solidifies and turns into a stone. This mass is bamboo salt, and it is crushed properly.

More specifically, the cosmetic soap composition according to the present invention contains 0.01 to 5 parts by weight of mung beans and / or extract thereof having excellent skin beauty effect and 0.05 to 2 parts by weight of triclosan and / or triclocaban excellent in deodorizing effect of the skin. After the mixing, preferably 0.1 to 1 parts by weight, 0.1 to 5 parts by weight, preferably 0.3 to 3 parts by weight of bamboo salt which can enhance or improve the skin deodorant effect is preferably used. Doing.

In the cosmetic soap composition of the present invention, it is preferable to use mung bean or its extract within the range of 0.01 to 5 parts by weight, but when the amount thereof is small, the beauty effect of the skin is not sufficient, and when the amount thereof is used, the skin beauty effect is excellent. Lack of binding force, etc. of the soap is not easy to manufacture, the stability by light after manufacturing is poor, there is a cracking phenomenon after use or after water deposition, which is a factor deteriorating the quality as a cosmetic soap.

In addition, the cosmetic soap composition of the present invention is preferably used in the range of 0.05 to 2 parts by weight of triclosan and triclocaban alone or mixed, when the amount is small, the effect of removing the odor of the skin is not sufficient, the amount used In many cases, the odor removal effect of the skin is excellent, but stability over time deteriorates over time, resulting in undesirable soap soap properties.

In addition, in the cosmetic soap composition of the present invention, after mixing triclosan and / or triclocaban, it is preferable to use bamboo salt within the range of 0.1 to 5 parts by weight. If the amount of bamboo salt is not used, it is difficult to manufacture the soap due to lack of bonding strength and plasticity during soap production, and deteriorates the skin cosmetic effect by worsening the feeling of general makeup soap after manufacture. .

Therefore, according to the present invention, 0.01 to 5 parts by weight of mung beans and / or their extracts and 0.05 to 2 parts by weight of triclosan and / or triclocaban, preferably 0.1 to 1 parts by weight, and then 0.1 to 5 parts by weight of bamboo salt, preferably Preferably it is 0.3 to 3 parts by weight can be used to prepare a cosmetic soap composition that is excellent in the beauty effect of the skin and improve or enhance the deodorant effect.

In the present invention, cosmetic soap refers to a general fatty acid soap and a synthetic surfactant soap using an alkali salt of a conventional fatty acid as a base or a synthetic surfactant soap and an alkali salt soap and a surfactant of a fatty acid, or It refers to a complex soap used by mixing as an auxiliary base, fatty acid soap is a sodium or potassium salt having 8 to 20 carbon atoms, fatty acids are vegetable oils such as palm oil, palm oil, soybean oil, castor oil, olive oil, palm kernel oil and tallow It is used alone or in combination obtained from animal fats and oils such as lard, larch, sun and fish oil.

In the case of the synthetic surfactant soap, any surfactant commonly used in the synthetic surfactant soap may be used, such as sodium lauryl sulfonate, sodium salt of alkylbenzenesulfonate, sodium cocoyl acetinate, and alkali salt of acylglutamate. In the case of the complex soap, the raw materials used in the fatty acid soap and the synthetic surfactant soap are mixed and used as a periodic or auxiliary base. In addition, the cosmetic soap composition of the present invention, such as glycerin, propylene glycol, sorbitol, and other commonly known softeners to give skin moisturizing effect along with natural oils, wax fatty alcohols, hydrocarbons, natural plant extracts, etc. Moisturizers and flavorings, colorants, fungicides, anti-inflammatory agents, metal ion disintegrants, antioxidants and preservatives can be used.

Hereinafter, the cosmetic beauty composition and so-called effects of the cosmetic soap composition of the present invention and cracking and time-dependent stability test method will be described.

** Skin Beauty Effect Test

After 20 people completely removed the moisture of the skin and made the same as when using the general cosmetic soap, the cosmetic effect was evaluated for the skin as follows. The average value of 20 evaluation scores was obtained and the value is shown as the following example.

Score

5 points | pieces: The skin has a soft feeling after using than a general cosmetic soap.

4 points | pieces: There is a feeling that skin is soft after use rather than normal makeup soap.

3 points | pieces: It is the same as general toilet soap.

2 points | pieces: A skin becomes rough after use rather than a normal cosmetic soap.

1 point | piece: Skin becomes rougher after use than a normal cosmetic soap.

-The results of the above average values are shown as below, and the skin beauty effect in the present invention is determined to be effective when the average value of the user is 4.0 or more.

4.5-5.-: ◎ 4.0-4.45: ○

3.0-3.95: △ 3.0 or less: ×

** Crack Test Method

After 24 hours of manufacture, the pins were inserted so as to be centered at a point about 2 cm in the length direction of the soap, and then immersed in water in a constant temperature water bath at 25 ° C. for 4 hours vertically, and then taken out 21 to 21 After drying for 24 to 36 hours at 25 ℃, 60 to 65% absolute humidity to maintain the crack degree as shown in the numerical value was evaluated.

** How to measure microorganisms on skin

A nutrient plate medium with a diameter of 47 mm is placed on the inner side of the test subject, wait 30 minutes for the skin microorganisms to replicate, and then detached and incubated at 37 ° C. for 1 day to measure colony numbers. After 2 days, the upper and lower inner sides of the same test paper were washed with a cosmetic soap composition, and after 1 minute, measured in the same manner to obtain the number of microorganisms after washing.

Microbial removal rate is determined to be effective only 90% or more. Nutritional medium is used by dissolving 3 grams of gravy, 5 grams of peptone, and 15 grams of agar in 1 liter of sterile water.

** Stability Test

Time stability by light in the present invention was prepared by the cosmetic soap composition and irradiated with ultraviolet rays for 48 hours to determine the degree of discoloration with the naked eye.

Hereinafter, the present invention will be described in detail based on Examples and Comparative Examples.

Example 1

Cosmetic soap base 96.3 parts, mung bean and / or its extract 0.5 parts by weight, bamboo salt 1.0 parts by weight, trichloric acid 0.1 parts by weight, triclocaban 0.1 parts by weight, propylene glycol 0.2 parts by weight, fragrance 1.2 parts by weight, ethylene diamine tetraacetic acid 0.1 After mixing by weight and 0.5 parts by weight of titanium dioxide in a mixer, a cosmetic soap was prepared by cutting and mold- ing through a molding and extrusion process using a general fatty acid soap manufacturing apparatus.

[Examples 2 to 3 and Comparative Examples 1 to 7]

Examples 2 to 3 and Comparative Examples 1 to 7 are the same as in Example 1, except that the composition is composed of the composition shown in Table I below. The cosmetic soap compositions of Examples 1 to 3 and Comparative Examples 1 to 7 thus prepared were tested for skin beauty effect, discoloration degree, cracking degree and deodorizing effect by the test method, and workability was performed by molding and extrusion processes. Was generally evaluated by comparison with the preparation of the cosmetic soap.

TABLE 1

As a result of testing the cosmetic soap composition of the present invention as shown in Table 1, Comparative Example 1, which does not use mung bean and / or its extract and bamboo salt, triclosan and triclocaban, has similar skin cosmetic effects to general cosmetic soap. It can be seen that the deodorizing effect is small and Comparative Example 3 which does not use mung bean and / or its extract and Comparative Example 4 where the use amount of mung bean and / or its extract is small has little skin cosmetic effect.

In addition, Comparative Example 5, which has a large amount of mung bean or its extract, has excellent skin beauty effect, but does not have good workability, and it is not suitable as a cosmetic soap due to severe discoloration after manufacture and cracking after water deposition. Comparative Example 7, which has a large amount of bamboo salt, is not only difficult to work with, but also shows cracking after water deposition, and deteriorates the feeling of use of soap, thereby degrading skin beauty effect.

However, in the cosmetic soap composition of the present invention Examples 1 to 3 using the amount of each component mixed within an appropriate range not only can be seen that the workability is good and the skin cosmetic effect and deodorant effect is excellent as well as discoloration after manufacture It can be seen that it is not suitable as a cosmetic soap. In particular, it can be seen that the skin cosmetic effect of Example 1 and Example 2 using mung bean and / or its extract is superior to Comparative Example 3 and the comparative example 4 which do not use mung bean and / or its extract, and bamboo salt Example 3 using a mixture within an appropriate range can be seen that the deodorizing effect is improved compared to Comparative Example 2 and Comparative Example 6, which does not use bamboo salt, so that the cosmetic soap composition of the present invention is mung bean and / or its extract and When mixed with triclosan, triclocyanban or bamboo salt within an appropriate range, cosmetic soap composition which has excellent workability, enhances or improves skin beauty and deodorizing effect, does not discolor after manufacture, and does not crack after water deposition. It can be seen that can be prepared.

Example 4

73.7 parts by weight of cosmetic soap base, 13.5 parts by weight of sodium cocoyl isethionate, 5.8 parts by weight of stearic acid, 3.5 parts by weight of coconut oil fatty acid, 0.5 parts by weight of mung bean and / or its extract, 1.0 parts by weight of bamboo salt, 0.2 parts by weight of triclosan, 1.2 parts by weight of fragrance, 0.1 parts by weight of ethylene diamine tetraacetic acid, and 0.5 parts by weight of titanium dioxide were mixed in a mixer, and then cut and molded through a molding and extrusion process using a general fatty acid soap manufacturing apparatus to prepare a cosmetic soap.

[Examples 5 to 6 and Comparative Examples 8 to 14]

Examples 5 to 6 and Comparative Examples 8 to 14 are the same as in Example 4, except that the composition is composed of the composition shown in Table II below. The cosmetic soap compositions of Examples 4 to 6 and Comparative Examples 8 to 14 thus prepared were tested for skin deodorizing effect, discoloration degree, cracking degree and deodorizing effect by the above test method. Was evaluated by indirect comparison with the general cosmetic soap preparation.

TABLE 2

As a result of testing the cosmetic soap composition of the present invention as shown in Table 2, Comparative Example 8, which does not use triclosan and triclocaban, does not have sufficient skin deodorizing effect, and does not use mung bean or its extract and bamboo salt. Comparative Example 9 has a good skin deodorizing effect but insufficient skin cosmetic effect, Comparative Examples 10 to 12 with a large amount of triclosan and triclocaban used in the Comparative Example 12 is excellent as a skin soap deodorizing effect, but suitable as a cosmetic soap It can be seen that the comparative example 13 with less usage of each component has good workability and no cracking after water deposition, but the skin care effect and deodorizing effect are insufficient, and the comparative example 14 with high usage of each component It can be seen that it is a factor that lowers the overall makeup soap quality.

However, Examples 4 to 6, in which each component used in the cosmetic soap composition of the present invention is mixed within an appropriate range, have good workability and excellent skin beauty effect, and do not cause discoloration or cracking, and have a skin deodorizing effect. Improved or enhanced cosmetic soap compositions can be prepared.

In addition, as can be seen in the above embodiment, it can be seen that the skin soap deodorant effect is improved or promoted when the mixed soap composition of the present invention is mixed with trichloric acid and / or triclocaban and then mixed with bamboo salt, in particular triclosan and triclocaa. Compared to Comparative Example 9 using only half, it can be seen that Example 6, which uses bamboo salt and mung beans and / or extract thereof, has excellent skin beauty and deodorant effects, and thus, each component used in the cosmetic soap composition of the present invention is within an appropriate range. It can be seen that when used in a mixture, the workability is excellent, the skin beauty effect and deodorant effect is enhanced or improved, and there is no discoloration after manufacture, and a cosmetic soap composition without cracking after water deposition can be prepared.

Claims (3)

0.01 to 5 parts by weight of mung beans and / or its extract, 2 to 4 parts by weight of 2,4,4'-trichloro-2'-hydroxy diphenyl ether and / or 0.05 to 2 parts by weight of 3,4,4'-trichlorocarbinide And 0.1 to 5 parts by weight of bamboo salt. The method according to claim 1, characterized in that it contains 0.1 to 1 parts by weight of 2,4,4'-trichloro-2'-hydroxy diphenyl ether and / or 3,4,4'-trichlorocarbanilide. Cosmetic soap composition. The cosmetic soap composition according to claim 1, which contains 0.3 to 3 parts by weight of bamboo salt.