RS20220316A1 - Organosilica particles based on bridging polysixesquioxanes for blocking ultraviolet rays - Google Patents

Organosilica particles based on bridging polysixesquioxanes for blocking ultraviolet rays

Info

Publication number
RS20220316A1
RS20220316A1 RS20220316A RSP20220316A RS20220316A1 RS 20220316 A1 RS20220316 A1 RS 20220316A1 RS 20220316 A RS20220316 A RS 20220316A RS P20220316 A RSP20220316 A RS P20220316A RS 20220316 A1 RS20220316 A1 RS 20220316A1
Authority
RS
Serbia
Prior art keywords
component
organosilica particles
bridging
ultraviolet rays
particles
Prior art date
Application number
RS20220316A
Other languages
Serbian (sr)
Inventor
Nikola Knežević
Original Assignee
Inst Biosens Istrazivacko Razvojni Inst Za Informacione Tehnologije Biosistema
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inst Biosens Istrazivacko Razvojni Inst Za Informacione Tehnologije Biosistema filed Critical Inst Biosens Istrazivacko Razvojni Inst Za Informacione Tehnologije Biosistema
Priority to RS20220316A priority Critical patent/RS20220316A1/en
Priority to PCT/RS2023/000004 priority patent/WO2023191649A1/en
Publication of RS20220316A1 publication Critical patent/RS20220316A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/14Polysiloxanes containing silicon bound to oxygen-containing groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/22Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/26Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/80Siloxanes having aromatic substituents, e.g. phenyl side groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • C08L83/06Polysiloxanes containing silicon bound to oxygen-containing groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • C08L83/08Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen

Abstract

Organosilica particles based on bridging polysilsesquioxanes for blocking ultraviolet rays, which have novelty components C and D in different ratios, which are covalently crosslinked within organosilica particles, whereby particles of different structure (porous or non-porous) and morphology can be obtained (spheres, cylinders or bean-shape) for use in UV protection. The role of component C is to provide potent absorption of UV rays, while component D may have a partial UV-protective effect, but its primary role is constructive, i.e. allows the construction of a desired structure of organosilica particles. Component C is based on triazine, and the organosilica particles are synthesized by mixing components C and D in different ratios, in a solution of surfactant in a solvent mixture composed of water and ethanol, in the presence of ammonia as a catalyst. Component C is obtained by reacting components A and B, where component A is mixed with component B in a ratio of 1: 3, in acetonitrile as a solvent, in the presence of N,N'-Dicyclohexylcarbodiimide (DCC) as a catalyst.
RS20220316A 2022-03-28 2022-03-28 Organosilica particles based on bridging polysixesquioxanes for blocking ultraviolet rays RS20220316A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
RS20220316A RS20220316A1 (en) 2022-03-28 2022-03-28 Organosilica particles based on bridging polysixesquioxanes for blocking ultraviolet rays
PCT/RS2023/000004 WO2023191649A1 (en) 2022-03-28 2023-03-28 Organosilica particles based on bridging polysilsesquioxanes for blocking ultraviolet rays

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RS20220316A RS20220316A1 (en) 2022-03-28 2022-03-28 Organosilica particles based on bridging polysixesquioxanes for blocking ultraviolet rays

Publications (1)

Publication Number Publication Date
RS20220316A1 true RS20220316A1 (en) 2023-09-29

Family

ID=86378616

Family Applications (1)

Application Number Title Priority Date Filing Date
RS20220316A RS20220316A1 (en) 2022-03-28 2022-03-28 Organosilica particles based on bridging polysixesquioxanes for blocking ultraviolet rays

Country Status (2)

Country Link
RS (1) RS20220316A1 (en)
WO (1) WO2023191649A1 (en)

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU6269101A (en) 2000-06-05 2001-12-17 Showa Denko Kk Cosmetic preparation
GB2365769A (en) 2000-08-18 2002-02-27 Secr Defence Skin preparations containing silicon
JP4125201B2 (en) 2003-08-05 2008-07-30 ロレアル Cosmetic composition containing porous particles encapsulating an optically active substance
KR100596740B1 (en) * 2004-04-30 2006-07-12 주식회사 사임당화장품 Polysilsesquioxane spherical particle containing ultraviolet light-absorbing group and manufacturing method thereof
DE102006025057A1 (en) 2006-05-24 2007-11-29 Beiersdorf Ag Cosmetic sunscreen preparation with special texture
IL206909A0 (en) 2008-01-11 2010-12-30 Antaria Ltd Mesoporous zinc oxide powder and method for production thereof
KR101544890B1 (en) 2008-01-11 2015-08-17 안타리아 리미티드 Mesoporous zinc oxide powder and method for production thereof
US20100003204A1 (en) 2008-07-02 2010-01-07 Energy Materials Corporation Nanoparticle hybrid sunscreens
KR101206939B1 (en) * 2010-07-15 2012-11-30 김영백 UV-Absorbing Polyorganosilicon oxide Particles with Enhanced Stability against Ultra-Violet and Their Preparation Process
US9138395B2 (en) 2012-12-19 2015-09-22 L'oreal Sunscreen compositions having synergistic combination of UV filters
JP6573482B2 (en) 2015-05-28 2019-09-11 日本板硝子株式会社 Zinc oxide-containing composite particles, method for producing zinc oxide-containing composite particles, ultraviolet shielding composition, and cosmetics
US10682294B2 (en) 2015-09-03 2020-06-16 International Business Machines Corporation Controlling zinc oxide particle size for sunscreen applications
US11389386B2 (en) 2016-01-29 2022-07-19 Arizona Board Of Regents On Behalf Of The University Of Arizona Photochemically stable, non-leaching, bridged polysilsesquioxane based sunscreens
US20190183756A1 (en) 2016-08-04 2019-06-20 Nippon Sheet Glass Company, Limited Zinc oxide-containing composite particles, ultraviolet-shielding composition, and cosmetic

Also Published As

Publication number Publication date
WO2023191649A1 (en) 2023-10-05

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