RO87682B1 - Heteronuclear complex combinations in vanadium-copper system - Google Patents
Heteronuclear complex combinations in vanadium-copper systemInfo
- Publication number
- RO87682B1 RO87682B1 RO111818A RO11181883A RO87682B1 RO 87682 B1 RO87682 B1 RO 87682B1 RO 111818 A RO111818 A RO 111818A RO 11181883 A RO11181883 A RO 11181883A RO 87682 B1 RO87682 B1 RO 87682B1
- Authority
- RO
- Romania
- Prior art keywords
- combinations
- vanadium
- copper system
- complex combinations
- heteronuclear
- Prior art date
Links
- KPZUWETZTXCDED-UHFFFAOYSA-N [V].[Cu] Chemical compound [V].[Cu] KPZUWETZTXCDED-UHFFFAOYSA-N 0.000 title abstract 2
- ROFVEXUMMXZLPA-UHFFFAOYSA-N Bipyridyl Chemical group N1=CC=CC=C1C1=CC=CC=N1 ROFVEXUMMXZLPA-UHFFFAOYSA-N 0.000 abstract 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-L Oxalate Chemical compound [O-]C(=O)C([O-])=O MUBZPKHOEPUJKR-UHFFFAOYSA-L 0.000 abstract 1
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- -1 aliphatic aldehydes Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 150000002500 ions Chemical group 0.000 abstract 1
- 239000003446 ligand Chemical group 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
Landscapes
- Pyridine Compounds (AREA)
- Catalysts (AREA)
Abstract
Inventia se refera la combinatii complexe heteronucleare în sistemul vanadiu-cupru combinatii complexe care contin doua centre metalice ionul Cu (II) si oxovanadiu (IV) iar drept liganzi functioneaza ionul oxalat, 2,2'-bipiridil si 1,10 fenantrolina. Aceste combinatii au structura corespunzatoare formulei generale (I) (vezi form. în desc.) în care pentru L= CuC2O4, n=1 L=bpy, n=0. Combinatiile conform inventiei au activitate catalitica la oxidarea cu oxigen a aldehidelor alifatice inferioare la acizii respectivi.The invention relates to complex heteronuclear combinations in the vanadium-copper system complex combinations containing two metal centers Cu (II) and oxovadium (IV) ion and ligands function as oxalate ion, 2,2'-bipyridyl and 1,10 phenanthroline. These combinations have the structure corresponding to general formula (I) (see form in the descendant) wherein for L = CuC2O4, n = 1 L = bpy, n = 0. The combinations according to the invention have catalytic activity in the oxygen oxidation of lower aliphatic aldehydes to the respective acids.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RO83111818A RO87682A2 (en) | 1983-08-05 | 1983-08-05 | HETERONUCLEAR COMPLEX COMBINATIONS IN VANADIU-CUPRU SYSTEM |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RO83111818A RO87682A2 (en) | 1983-08-05 | 1983-08-05 | HETERONUCLEAR COMPLEX COMBINATIONS IN VANADIU-CUPRU SYSTEM |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RO87682B1 true RO87682B1 (en) | 1985-10-02 |
| RO87682A2 RO87682A2 (en) | 1985-10-31 |
Family
ID=20113505
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO83111818A RO87682A2 (en) | 1983-08-05 | 1983-08-05 | HETERONUCLEAR COMPLEX COMBINATIONS IN VANADIU-CUPRU SYSTEM |
Country Status (1)
| Country | Link |
|---|---|
| RO (1) | RO87682A2 (en) |
-
1983
- 1983-08-05 RO RO83111818A patent/RO87682A2/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RO87682A2 (en) | 1985-10-31 |
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