RO87682B1 - Heteronuclear complex combinations in vanadium-copper system - Google Patents

Heteronuclear complex combinations in vanadium-copper system

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Publication number
RO87682B1
RO87682B1 RO111818A RO11181883A RO87682B1 RO 87682 B1 RO87682 B1 RO 87682B1 RO 111818 A RO111818 A RO 111818A RO 11181883 A RO11181883 A RO 11181883A RO 87682 B1 RO87682 B1 RO 87682B1
Authority
RO
Romania
Prior art keywords
combinations
vanadium
copper system
complex combinations
heteronuclear
Prior art date
Application number
RO111818A
Other languages
Romanian (ro)
Other versions
RO87682A2 (en
Inventor
Maria Brezeanu
Otilia Costisor
Victor Eliu-Ceausescu
Traian Cadariu
Original Assignee
îNTREPRINDEREA "PLAFAR"
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by îNTREPRINDEREA "PLAFAR" filed Critical îNTREPRINDEREA "PLAFAR"
Priority to RO83111818A priority Critical patent/RO87682A2/en
Publication of RO87682B1 publication Critical patent/RO87682B1/en
Publication of RO87682A2 publication Critical patent/RO87682A2/en

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Abstract

Inventia se refera la combinatii complexe heteronucleare în sistemul vanadiu-cupru combinatii complexe care contin doua centre metalice ionul Cu (II) si oxovanadiu (IV) iar drept liganzi functioneaza ionul oxalat, 2,2'-bipiridil si 1,10 fenantrolina. Aceste combinatii au structura corespunzatoare formulei generale (I) (vezi form. în desc.) în care pentru L= CuC2O4, n=1 L=bpy, n=0. Combinatiile conform inventiei au activitate catalitica la oxidarea cu oxigen a aldehidelor alifatice inferioare la acizii respectivi.The invention relates to complex heteronuclear combinations in the vanadium-copper system complex combinations containing two metal centers Cu (II) and oxovadium (IV) ion and ligands function as oxalate ion, 2,2'-bipyridyl and 1,10 phenanthroline. These combinations have the structure corresponding to general formula (I) (see form in the descendant) wherein for L = CuC2O4, n = 1 L = bpy, n = 0. The combinations according to the invention have catalytic activity in the oxygen oxidation of lower aliphatic aldehydes to the respective acids.

RO83111818A 1983-08-05 1983-08-05 HETERONUCLEAR COMPLEX COMBINATIONS IN VANADIU-CUPRU SYSTEM RO87682A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RO83111818A RO87682A2 (en) 1983-08-05 1983-08-05 HETERONUCLEAR COMPLEX COMBINATIONS IN VANADIU-CUPRU SYSTEM

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RO83111818A RO87682A2 (en) 1983-08-05 1983-08-05 HETERONUCLEAR COMPLEX COMBINATIONS IN VANADIU-CUPRU SYSTEM

Publications (2)

Publication Number Publication Date
RO87682B1 true RO87682B1 (en) 1985-10-02
RO87682A2 RO87682A2 (en) 1985-10-31

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ID=20113505

Family Applications (1)

Application Number Title Priority Date Filing Date
RO83111818A RO87682A2 (en) 1983-08-05 1983-08-05 HETERONUCLEAR COMPLEX COMBINATIONS IN VANADIU-CUPRU SYSTEM

Country Status (1)

Country Link
RO (1) RO87682A2 (en)

Also Published As

Publication number Publication date
RO87682A2 (en) 1985-10-31

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