PT84707A - Process for the preparation of liquid and polymerizable compositions containing oligomeric allylcarbonate suitable for the production of organic glasses endowed with high abrasion strength - Google Patents
Process for the preparation of liquid and polymerizable compositions containing oligomeric allylcarbonate suitable for the production of organic glasses endowed with high abrasion strengthInfo
- Publication number
- PT84707A PT84707A PT84707A PT8470787A PT84707A PT 84707 A PT84707 A PT 84707A PT 84707 A PT84707 A PT 84707A PT 8470787 A PT8470787 A PT 8470787A PT 84707 A PT84707 A PT 84707A
- Authority
- PT
- Portugal
- Prior art keywords
- component
- gps
- allylcarbonate
- esp
- prod
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/24—Esters of carbonic or haloformic acids, e.g. allyl carbonate
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Dental Preparations (AREA)
- Polyesters Or Polycarbonates (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Liq. compsns. polymerisable to organic glasses with high abrasion strength contain (i) 20-80, esp. 35-70wt.% oligomeric prods. with 2 terminal allyl gps. (Component A) of formula (I) CH2=CHCH2OCOO(CH2CH2OCH2 CH2OCOO)nCH2CH=CH2 (I) where n = 2-5; (ii) 20-50, esp. 25-45,wt.% monomer prod. (Component B) of formula (II). R = Me, Et, -CH2-OCOOCH2CH=CH2; n = 0, 1; R1 = -CH2OCOOCH2CH=CH2; (iii) 0-35, esp. 0-25,wt.% of reactive diluent contg. allyl, vinyl or methacrylic gps. Pref. component A is the transesterification prod. of diallyl carbonate and diethylene glycol in a mutual molar ratio of about 2:1. Component B is the transalkylation prod. of diallyl carbonate (DAC) and an aliphatic polyol with at least 4 alcoholic OH gps. in a 4:1 molar ratio of DAC:OH gps. of the polyol. Component C may be diethylene glycol bis(allylcarbonate), vinyl acetate or methyl methacrylate. The compsn. may contain 1-6 pts. wt. of a free radical initiator per 100 pts. wt. of (A+B+C). Pref. the polyol is di-trimethylolpropane, pentaerythritol, di-pentaerythritol or tri-pentaerythritol.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT20124/86A IT1190320B (en) | 1986-04-17 | 1986-04-17 | Abrasion resistant lenses etc. |
Publications (2)
Publication Number | Publication Date |
---|---|
PT84707A true PT84707A (en) | 1987-05-01 |
PT84707B PT84707B (en) | 1989-11-30 |
Family
ID=11164002
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PT84707A PT84707B (en) | 1986-04-17 | 1987-04-16 | PROCESS FOR THE PREPARATION OF LIQUID AND POLYMERIZABLE COMPOSITIONS CONTAINING OLIGOMERIC ALILO CARBONATE SUITABLE FOR THE PRODUCTION OF ORGANIC GLASSES PROVIDED WITH HIGH ABRASION RESISTANCE |
Country Status (10)
Country | Link |
---|---|
KR (1) | KR900007767B1 (en) |
AT (1) | ATE62259T1 (en) |
BR (1) | BR8702192A (en) |
DE (1) | DE3768998D1 (en) |
ES (1) | ES2022872B3 (en) |
GR (1) | GR3001840T3 (en) |
IN (1) | IN169366B (en) |
IT (1) | IT1190320B (en) |
MX (1) | MX169473B (en) |
PT (1) | PT84707B (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111689859B (en) * | 2020-05-25 | 2023-01-24 | 江苏乾元新材料科技有限公司 | Low-shrinkage resin and preparation method and application thereof |
-
1986
- 1986-04-17 IT IT20124/86A patent/IT1190320B/en active
-
1987
- 1987-03-31 IN IN233/MAS/87A patent/IN169366B/en unknown
- 1987-04-07 AT AT87200662T patent/ATE62259T1/en not_active IP Right Cessation
- 1987-04-07 DE DE8787200662T patent/DE3768998D1/en not_active Expired - Fee Related
- 1987-04-07 ES ES87200662T patent/ES2022872B3/en not_active Expired - Lifetime
- 1987-04-14 KR KR1019870003557A patent/KR900007767B1/en not_active IP Right Cessation
- 1987-04-15 MX MX006076A patent/MX169473B/en unknown
- 1987-04-15 BR BR8702192A patent/BR8702192A/en not_active IP Right Cessation
- 1987-04-16 PT PT84707A patent/PT84707B/en not_active IP Right Cessation
-
1991
- 1991-04-24 GR GR91400531T patent/GR3001840T3/en unknown
Also Published As
Publication number | Publication date |
---|---|
IT1190320B (en) | 1988-02-16 |
KR870010121A (en) | 1987-11-30 |
IN169366B (en) | 1991-10-05 |
DE3768998D1 (en) | 1991-05-08 |
IT8620124A0 (en) | 1986-04-17 |
PT84707B (en) | 1989-11-30 |
MX169473B (en) | 1993-07-07 |
ES2022872B3 (en) | 1991-12-16 |
ATE62259T1 (en) | 1991-04-15 |
IT8620124A1 (en) | 1987-10-17 |
KR900007767B1 (en) | 1990-10-19 |
GR3001840T3 (en) | 1992-11-23 |
BR8702192A (en) | 1988-02-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM3A | Annulment or lapse |
Free format text: LAPSE DUE TO NON-PAYMENT OF FEES Effective date: 19951130 |