PL99304B1 - - Google Patents
Download PDFInfo
- Publication number
- PL99304B1 PL99304B1 PL1976193304A PL19330476A PL99304B1 PL 99304 B1 PL99304 B1 PL 99304B1 PL 1976193304 A PL1976193304 A PL 1976193304A PL 19330476 A PL19330476 A PL 19330476A PL 99304 B1 PL99304 B1 PL 99304B1
- Authority
- PL
- Poland
- Prior art keywords
- formula
- model
- c3h7s
- c3h7sx
- carbon atoms
- Prior art date
Links
- 150000003217 pyrazoles Chemical class 0.000 claims description 3
- 230000000895 acaricidal effect Effects 0.000 claims description 2
- 239000000642 acaricide Substances 0.000 claims description 2
- 239000004480 active ingredient Substances 0.000 claims description 2
- 239000002917 insecticide Substances 0.000 claims description 2
- 125000003545 alkoxy group Chemical group 0.000 claims 3
- 125000004414 alkyl thio group Chemical group 0.000 claims 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims 2
- QSLPNSWXUQHVLP-UHFFFAOYSA-N $l^{1}-sulfanylmethane Chemical compound [S]C QSLPNSWXUQHVLP-UHFFFAOYSA-N 0.000 claims 1
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims 1
- WDJHALXBUFZDSR-UHFFFAOYSA-M acetoacetate Chemical compound CC(=O)CC([O-])=O WDJHALXBUFZDSR-UHFFFAOYSA-M 0.000 claims 1
- 125000003282 alkyl amino group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 125000004430 oxygen atom Chemical group O* 0.000 claims 1
- 239000011780 sodium chloride Substances 0.000 claims 1
- 229910052717 sulfur Chemical group 0.000 claims 1
- 125000004434 sulfur atom Chemical group 0.000 claims 1
- 150000002148 esters Chemical class 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
- C07F9/6509—Six-membered rings
- C07F9/650905—Six-membered rings having the nitrogen atoms in the positions 1 and 2
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
Przedmiotem wynalazku jest srodek owadobój¬ czy i roztoczobójczy zawierajacy nowe dwufosfo- rylowane pirazole jako substancje czynna.Wiadomo, ze dwufosforylowane pirazole, takie jak ester 0,0-dwumetylo- wzglednie 0,0-dwuety- lo - 0^3-metylo-lHdwumetoksytiioniofosiforyilopiraizoli- lowy-5/ kwasu fosforo- wzglednie tionofosforowe- go, ester 0-etylo-0-/3-metylo-l-dwumetoksytionofo- sforylopirazolilowy-5/ kwasu etanotionofosfonowe- go lub esiter 0-etyio^-(3nmietyao-l-drwuet PL
Claims (1)
1. Zastrzezenie patentowe Srodek owadobójczy i roztoczobójczy, znamien¬ ny tym, ze jako substancje czynna zawiera nowe dwufosforylowane pirazole o wzorze 1, w którym Rj oznacza grupe alkoksylowa o 1—4 atomach wegla, R2 i R8 oznaczaja jednakowe lub rózne grupy alkoksylowe lub alkilotio o 1—6 atomach wegla w kazdej, R4 oznacza grupe alkoksylowa, alkilotio, alkiloaminowa lub alkilowa o 1—5 ato¬ mach wegla w kazdej, przy czym przynajmniej jeden z rodników Ra, R8 i/lub R4 oznacza gfupe alkilotio, a X oznacza atom tlenu lub siarki.99304 2 5 \p_pi + i i 5 * "P-CL ¦ ^ n-C3H?S/ H3C/X^x0Na N-N-P(0C2H5)2 NaCl 1/1 nr u * H3C^Vp<°C^ S SC3H7"n SCHEMAT 1 R1\" , Ri' S ;P-HaL + wodzian hydrazyny =* ' /P-NH-NhL V S S CH3. acetylooctan */ LA R^ 2 2 McO CH3 SCHEMAT 2WZtfR 1 R^ii R 1^R—N—IM MeO^ WZÓR 2 CK, R X 3\r R P-Hal 4 WZÓR3 s (CH30)2P-fl—N (CH30)2P-0 CH S WZÓR 4 (CH30)2P-N-N (C2H50)2f-V^ S WZÓR 5 CH. (CH3o)2P-ri—ri (C2H50)2P-0 CH. O WZtfRó99304 s (CH30)2P-N—N ^p-o C2H50^ CK WZÓR 7 (C„KO),P-N-N -2' '5 C2H50x P-0 CK WZÓR 8 n-C3H7SXp_0 '2' 'S* n-C3H7Sx C2H50^ WZÓR 9 S C2H50Xt N—N 2' '5^ \p_n s., CK C2H50 S WZÓR 10 n-C3H7Sx C2H5CK C2H5°\p-0 ^2n5 S P-N—N WZÓR 11 (C2H50)2P-M-^ C2H50x CH3S/ P-0 CK WZÓR 1299304 s (C2H50)2P~^~-N ^P-0 TK n-C3H7S/ II WZÓR 13 ¦ f (c2H5o)2P-r^—n ^. (n-C3H7S)2P-0 S WZÓR 14 CK (c2H5o)2p-r^—r^ n-C,KS 3 *7 \p_0 n-C3H70/| WZÓR 15 S (C2H50)2P-^-y n-C3H7S\p_o CKj-NH^ WZÓR 16 n-C3H7S4_M C2H50/ (C,K0)2F-0 ^ CK '2' '5 O WZÓR 17 n-C3H7Sx« , y C2H50/ C2H50xp_0 lzo-C3H7NH/^ WZÓR 18 CK99304 n-C3H7S C2H50/' P-N—N * PL PL
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19752548183 DE2548183A1 (de) | 1975-10-28 | 1975-10-28 | Diphosphorylierte pyrazole, verfahren zu ihrer herstellung sowie ihre verwendung als insektizide und akarizide |
Publications (1)
Publication Number | Publication Date |
---|---|
PL99304B1 true PL99304B1 (pl) | 1978-07-31 |
Family
ID=5960272
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PL1976193304A PL99304B1 (pl) | 1975-10-28 | 1976-10-27 |
Country Status (17)
Country | Link |
---|---|
US (1) | US4034085A (pl) |
JP (1) | JPS5253858A (pl) |
AT (1) | AT343684B (pl) |
BE (1) | BE847728A (pl) |
BR (1) | BR7607184A (pl) |
DD (1) | DD127884A5 (pl) |
DE (1) | DE2548183A1 (pl) |
DK (1) | DK139818C (pl) |
ES (1) | ES452780A1 (pl) |
FR (1) | FR2329675A1 (pl) |
GB (1) | GB1527174A (pl) |
IL (1) | IL50759A0 (pl) |
NL (1) | NL7611910A (pl) |
PL (1) | PL99304B1 (pl) |
PT (1) | PT65751B (pl) |
SE (1) | SE7611924L (pl) |
ZA (1) | ZA766453B (pl) |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3010969A (en) * | 1960-01-25 | 1961-11-28 | Dow Chemical Co | O-pyrazolyl o-lower alkyl phosphoramidates and phosphoramidothioates |
DE1912972A1 (de) * | 1969-03-14 | 1970-10-01 | Bayer Ag | Phosphor-,Phosphon- bzw. Thionophosphor-(phosphon)-saeureester und Verfahren zu ihrer Herstellung |
DE1917741B2 (de) * | 1969-04-05 | 1976-12-02 | Bayer Ag, 5090 Leverkusen | (thiono)phosphor(phosphon) -saeureester bzw. -esteramide, verfahren zu ihrer herstellung sowie ihre verwendung |
DE2049692A1 (de) * | 1970-10-09 | 1972-04-13 | Farbenfabriken Bayer Ag, 5090 Leverkusen | Pyrazolo-(thiono)-phosphor(phosphon)säureester, Verfahren zu ihrer Herstellung sowie ihre Verwendung als Insektizide und Akarizide |
-
1975
- 1975-10-28 DE DE19752548183 patent/DE2548183A1/de active Pending
-
1976
- 1976-10-21 US US05/734,480 patent/US4034085A/en not_active Expired - Lifetime
- 1976-10-22 PT PT65751A patent/PT65751B/pt unknown
- 1976-10-25 IL IL50759A patent/IL50759A0/xx unknown
- 1976-10-26 DD DD7600195459A patent/DD127884A5/xx unknown
- 1976-10-26 JP JP51127904A patent/JPS5253858A/ja active Pending
- 1976-10-26 GB GB44422/76A patent/GB1527174A/en not_active Expired
- 1976-10-26 BR BR7607184A patent/BR7607184A/pt unknown
- 1976-10-27 PL PL1976193304A patent/PL99304B1/pl unknown
- 1976-10-27 ZA ZA766453A patent/ZA766453B/xx unknown
- 1976-10-27 NL NL7611910A patent/NL7611910A/xx not_active Application Discontinuation
- 1976-10-27 ES ES452780A patent/ES452780A1/es not_active Expired
- 1976-10-27 SE SE7611924A patent/SE7611924L/xx unknown
- 1976-10-27 DK DK485876A patent/DK139818C/da active
- 1976-10-27 AT AT796376A patent/AT343684B/de active
- 1976-10-28 FR FR7632615A patent/FR2329675A1/fr active Granted
- 1976-10-28 BE BE171862A patent/BE847728A/xx unknown
Also Published As
Publication number | Publication date |
---|---|
AT343684B (de) | 1978-06-12 |
PT65751B (fr) | 1978-04-20 |
US4034085A (en) | 1977-07-05 |
ATA796376A (de) | 1977-10-15 |
BE847728A (fr) | 1977-04-28 |
FR2329675B1 (pl) | 1980-06-13 |
DK139818C (da) | 1979-10-29 |
BR7607184A (pt) | 1977-09-13 |
IL50759A0 (en) | 1976-12-31 |
ZA766453B (en) | 1977-10-26 |
SE7611924L (sv) | 1977-04-29 |
ES452780A1 (es) | 1977-10-01 |
PT65751A (fr) | 1976-11-01 |
DE2548183A1 (de) | 1977-05-05 |
NL7611910A (nl) | 1977-05-02 |
GB1527174A (en) | 1978-10-04 |
FR2329675A1 (fr) | 1977-05-27 |
JPS5253858A (en) | 1977-04-30 |
DK485876A (da) | 1977-04-29 |
DK139818B (da) | 1979-04-23 |
DD127884A5 (de) | 1977-10-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
HUT68668A (en) | Process for producing 3-aryl-pyron-derivatives, arthropodicidal, nematicidal and herbicidal compositions and method for using the compounds | |
DE69301205D1 (de) | Pyridin-Amide und ihre Salze, Verfahren zur ihrer Herstellung und pestizide Zusammensetzungen davon | |
DE1793838C2 (de) | 3-Isoxazolylthiono-phosphorsäure-(-phosphonsäure-Werivate und Verfahren zu ihrer Herstellung | |
PL99304B1 (pl) | ||
KR910009149A (ko) | 안정화된 농화학 조성물 | |
Desmarchelier et al. | Mass spectra of organophosphorus esters and their alteration products | |
KR910009150A (ko) | 안정화된 농약 조성물 | |
PL102267B1 (pl) | An insecticide and an acaricide | |
ES461995A1 (es) | Procedimiento para la obtencion de derivados ter-butilpira- zolilicos. | |
ES382819A1 (es) | Procedimiento para la obtencion de esteres de acidos tria- zolo-tiazol (tiono)-fosforicos-fosfonicos y fosfinicos. | |
SON et al. | Some considerations regarding the nomenclature of organic phosphorus compounds | |
KR830009128A (ko) | 옥심 포스페이트 화합물의 제조방법 | |
HUT45541A (en) | Plant protecting compositions containing ester of phosphoric acid as active component and process for producing the active component | |
IE41338B1 (en) | 0-triazolyl-(thiono)-phsphoric(phosphonic, phosphinic) acid esters and ester-amides, prcess for their preparation and their use as insecticides, acaricides or nematocides | |
ES444361A1 (es) | Procedimiento para preparar esteres de acidos pirimidinil (tiono)-(tiol)-fosforicos-(fosfonicos). | |
ES466356A1 (es) | Procedimiento para preparar esteres y amidas-esteres de aci-dos pirimidil(tio)-fosforicos (fosfonicos) sustituidos. | |
GB1449443A (en) | Fungicidal compositions containing disubstituted phosphonates | |
ES437694A1 (es) | Procedimiento para preparar esteres y amidas de esteres de acidos o-triazolil(tiono)-fosforicos (fosfonicos). | |
GB2088718B (en) | Pesticidal compositions | |
IL65059A (en) | Process for the preparation of phosphoric,phosphonic and phosphinic esters of cyanohydrin,pesticidal compositions containing certain of such phosphonic esters and certain new such phosphonic esters | |
Segall et al. | Organophosphoro (thioperoxoic) acids: direct observation and reactivity | |
IE36776B1 (en) | Pesticidal cyclic derivatives of phosphorus | |
ES430786A1 (es) | Procedimiento para la obtencion de esteres de acidos tria- zolotiazol-fosforicos, -tionodosfoticos, -fosfonicos y tio- nodosfonicos, de efecto insecticida y acaricida. | |
FR2362151A1 (fr) | Nouveaux esters de 2-tertiopentyrylvinyle d'acide (thiono) (thiol) phosphorique (phosphonique), leur procede de preparation et leur application comme insecticides, acaricides et nematicides | |
GB1249595A (en) | (thiono)phosphoric(phosphonic)-acid esters and ester amides |