PL99192B1 - THE METHOD OF THE TAPING OF COWHER SURFACE SKINS - Google Patents
THE METHOD OF THE TAPING OF COWHER SURFACE SKINS Download PDFInfo
- Publication number
- PL99192B1 PL99192B1 PL17060374A PL17060374A PL99192B1 PL 99192 B1 PL99192 B1 PL 99192B1 PL 17060374 A PL17060374 A PL 17060374A PL 17060374 A PL17060374 A PL 17060374A PL 99192 B1 PL99192 B1 PL 99192B1
- Authority
- PL
- Poland
- Prior art keywords
- skins
- bath
- filling
- neutralizing
- carried out
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000011347 resin Substances 0.000 claims description 7
- 229920005989 resin Polymers 0.000 claims description 7
- 235000019198 oils Nutrition 0.000 claims description 6
- 125000002091 cationic group Chemical group 0.000 claims description 5
- 239000003925 fat Substances 0.000 claims description 5
- 235000021323 fish oil Nutrition 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 230000003472 neutralizing effect Effects 0.000 claims description 4
- 239000001887 acacia decurrens willd. var. dealbata absolute Substances 0.000 claims description 3
- 238000003287 bathing Methods 0.000 claims description 3
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 claims description 3
- 235000013311 vegetables Nutrition 0.000 claims description 3
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- 239000004280 Sodium formate Substances 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 210000000003 hoof Anatomy 0.000 claims description 2
- 235000019254 sodium formate Nutrition 0.000 claims description 2
- 238000010792 warming Methods 0.000 claims description 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims 3
- 101100399480 Caenorhabditis elegans lmn-1 gene Proteins 0.000 claims 1
- 239000013040 bath agent Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims 1
- 235000006408 oxalic acid Nutrition 0.000 claims 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims 1
- 241000283690 Bos taurus Species 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 229920001864 tannin Polymers 0.000 description 3
- 239000001648 tannin Substances 0.000 description 3
- 235000018553 tannin Nutrition 0.000 description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 101100127656 Caenorhabditis elegans lam-2 gene Proteins 0.000 description 1
- 241000283707 Capra Species 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000003026 cod liver oil Substances 0.000 description 1
- 235000012716 cod liver oil Nutrition 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000009191 jumping Effects 0.000 description 1
- 239000002960 lipid emulsion Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000004148 unit process Methods 0.000 description 1
Landscapes
- Treatment And Processing Of Natural Fur Or Leather (AREA)
Description
Przedmiotem wynalazku jest sposób wykoncza¬ nia kapielowego skór bydlecych wierzchnich abu- wiowych, polegajacycii na równoczesnym prowa¬ dzeniu w kapieli kilku procesów chemicznych jed¬ nostkowych.The subject of the invention is an implementation method bathing wear of cattle leathers relying on simultaneous conduct in a bath of several chemical processes one unitary.
W znanych sposobach wykonczania kapielowego skór bydlecych wierzchnich wykonuje sie oddziel¬ nie kolejno po sobie jednostkowe " procesy. Skóry plucze sie kilkakrotnie w wodzie, po czym zobojet¬ nia, ponownie plucze, dogarbowuje garbnikami ros¬ linnymi, syntanowymi i zywicowymi, po raz trzeci plucze, wreszcie natluszcza najpierw tluszczami amonowymi, w koncu tluszczami kationowymi. Zna¬ ny jest tez inny sposób bardziej rozbudowany, a mianowicie: skóry w pierwszej fazie dogairbowuje sie garbnikami chromowy/mi, po czym wyklada na kozly, poddaje odlezeniu w ciagu nocy i dalsze pro¬ cesy prowadzi sie wedlug sposobu pierwszego.In the known bath design Outer cowhides are separated not successive individual "processes. Skins rinses several times in water, then neutralizes it tans, rinses again, tans with rosé tannins linne, syntan and resin, for the third time he rinses, finally greases with fat first ammonium, and finally cationic fats. He knew there is also another, more elaborate way, a namely: the skins in the first phase are conditioned get chrome tannins / mi, then lay on goats, surrendered overnight and further pleaded Assignments are carried out according to the first method.
Sposób wykonczenia skór bydlecych wierzchnich wedlug wynalazku prowadzi sie, laczac wszystkie procesy jednostkowe w dwa procesy. W pierwszej fazie wykonuje sie w jednej kapieli procesy zo- bojetniamia> dogairbowania syntanowego i roslinne¬ go oraz napelniania zywicami, w drugiej fazie skó¬ ry natluszcza sie mieszanka tluszczów aninowo-ka- tionowych.The way of finishing cowhides according to the invention, all are combined unit processes into two processes. In first phase, the processes are performed in one bath Bojetniamia> syntanic and vegetable treatment it and filling with resins, in the second phase of leather the rice is greased with a mixture of aninic-ca- thionic.
Sposób wedlug wynalazku polega na tym, ze pro¬ ces zobojetniania, doganbowania syntamowego i ros¬ linnego oraz napelniania zywicami prowadzi sie w jednej kapieli. Skóry o wartosci pH = 3>4—3,8 ociepla sie najpierw w 100—2|00% wody o takiej temperaturze, aby po ociepleniu skór temperatura kapieli^ i skór wynosila 38^4j2°C. Nastepnie do kapieli dodaje sie równoczelshie srodki zoboijetnla- jaoo-dogarbowujacoHnapelniajace, najkorzystniej 2—5% zywicy dwucyjanodwuamddowej, 2—5% ekstraktu mimozy, 1—2(°/o poiimetafosforanu, 1— 1,5% wodoroweglanu sodowego, 1—il^5°/o mrówczanu sodowego i 2—7,5°/o garbnika syntetycznego i pro- io wadzi proces, przy ciaglym obracaniu bejbna w cza¬ sie 30—90 minut. Z kolei skóry plucze sie w 200% wody o temperaturze 40°ib, korzystnie przy doda¬ niu 0,3—'0,5% kwasu szczatwiowego. Natluszczanie skór prowadzi sie w swiezej kapieli o temperatu- rze 50'—6iO°C przy uzyciu emulsji tluszczów ando- nowo-kationowych, korzystnie (zlozonej z 1—3°/o siarczanowanego tranu, 0,5—£% siarczanowanego oleju olibrotowego, 1—2% siarczanowanego oleju kopyltikowego, 0,5^1% tranu i 0,5—il% emulgatora kationowego. Eroces natluszczenia prowadzi sie w ciagu 30—60 minuft.The method according to the invention consists in the fact that the process of neutralization, syntam catching up and growth lining and resin filling are carried out in one bath. Hides with a pH value of 3> 4-3.8 is first warmed in 100-2.00% water of this kind temperature to the temperature after the skins are warmed in the bath and the skin was 38-42 ° C. Then to in the bath are added at the same time means of neutralizing jaoo-dogarbowujacoHnapelniajace, best 2-5% of the di-cyanediamdium resin, 2-5% mimosa extract, 1-2 (% of polymethaphosphate, 1— 1.5% sodium bicarbonate, 1-1.5% formate sodium and 2-7.5% of a synthetic tannin and and a tricky process, with the drum constantly turning Aug 30-90 minutes. In turn, the skin is roughened by 200% of water at a temperature of 40 ° b, preferably with added n from 0.3 to 0.5% of rathic acid. Greasing skins are carried out in a fresh bath with a temperature at 50'-6iO ° C with the use of ando newly cationic, preferably (consisting of 1-3% sulfated cod liver oil, 0.5- £% sulfated olibrotic oil, 1-2% sulfated oil copyltic acid, 0.5 µl% fish oil and 0.5 µl% emulsifier cationic. The erosion of greasing takes place in within 30-60 minutes.
/W sposobie wedlug wynalazku lacznie z zobo¬ jetnianiem maskujacym nastepuje osadzenie sie w przestrzeniach miedizyfibrylarnych zywicy dwucy- janodwuamidowej i jednoczesne wiazanie garbni¬ ków roslinnych i syntetycznych. Wszystkie te pro¬ cesy biegna obok siebie, a uzyte srodki chemiczne wspóldzialaja w uzyskaniu prawidlowego efektu zobojetniania, dogarbowania i napelniania. Zasto- sowanie do natluszczenia skór emulsji tluszczów 99 19299 192 aniono-kationowych, a wiec tluszczów o zmniej¬ szonej reaktywnosci i o duzej czasteczce ulatwia przenikanie substancji natluszczajacych w glab skóry, polepsza efekty natluszczania, nie powodu¬ jac nadmiernego rozluzniania jej struktury./ In the method according to the invention, including commitments by masking, it settles into the interfibrillary spaces of the two-cy- ianodiamide and simultaneous tanning vegetable and synthetic. All these pro the cesses run side by side, and the chemicals used they help to obtain the correct effect de-icing, retanning and filling. Used use for greasing the skin of fat emulsions 99 19 299 192 anionic and thus fat reduced high reactivity and a large particle makes it easier penetration of oily substances into the soil skin, improves the lubrication effect, not for the reason jac excessive loosening of its structure.
Sposób wykonczenia kapielowego skór bydlecych wierzchnich wedlug wynalzaiku ma w stosunku- do metody klasycznej wiele cech dodatnich, a miano¬ wicie — skraca czas wykonczenia skór bydlecych z 5—6 godzin do 2—3 godzin, zmniejsza ilosc scie¬ ków i stopien ich zanieczyszczenia!, zmniejsza zna¬ cznie zuzycie wody technologicznej i srodków ener- gettyczmych. przyklad. Skóry bydlece garbowania chro¬ mowego o wartosci pH = 3f>6, przeznaczanie ma bok¬ sy bydlece, w stanie mokrym po struganiu, w ilosci 500 kg zaladowuje sie do bebna, wlewa 1000 litrów wody o takiej temperaturze, aby po ociepleniu skór temperatura kapieli wynosila 40°C, po czym wprowadza sie do bebna nastepujace srodki, w sta¬ nie stalym: 2l0/o zywicy dwucyjanodwuamidowej 2°/o ekstraktu mimozy ia°/o polimeitiafoisifoiranu sodu i 11% wodotroweglanu sodu il°/o mrówczanu sodu Po uruchomieniu bebna wprowadza ,sie 3 nika syntetycznego. Proces prowadzi sie, przy ciag¬ lym obracaniu bebna, 45 minut. Po tym czasie skóry plucze sie w bebnie w 1(000 litrów wódy o temperaturze 40°C z dodatkiem 0,3% kwasu szcza¬ wiowego, w ciagu 15 minut. Kapiel zlewa sie i po¬ nownie skóry plucze w 1000 litrów wody o tem¬ peraturze 45°C w ciagu 16 miLnut, i drugi raz takze w .1000 litrów wody, ale o temperaturze 50°C w ciagu 15 minut. Wyplukane skóry natluszcza sie w bebnie przy uzyciu emulsji tluszczowej anio¬ nówo-kationowej.The way of finishing the bathing of cowhides according to the inventor it has in relation to The classical method has many positive features, and the titer dawn - shortens the finishing time of cattle hides reduces the amount of sewage from 5-6 hours to 2-3 hours and the degree of their contamination !, reduces the mark including consumption of process water and energy resources ghettos. example. Protect cattle hides with a pH value of 3f> 6, the allocation is aside cattle sis, wet after planing, in quantity 500 kg is loaded into the drum, 1000 liters are poured water at such a temperature that after warming the skin temperature of the bath was 40 ° C, then the following measures are introduced into the drum, permanently not permanent: 2l0 / o of a di-cyanediamide resin 2% of mimosa extract and a% of sodium polymethiaphyforate and 11% sodium bicarbonate 1% of sodium formate After starting the drum, it introduces on August 3 synthetic material. The process is carried out continuously lym rotating the drum, 45 minutes. After this time skin is rinsed in the drum in 1 (000 liters of Fr. temperature of 40 ° C with the addition of 0.3% pancreatic acid within 15 minutes. The bath blends and swells new leather rinses in 1000 liters of water at a temperature at 45 ° C for 16 milnuts, and the second time also in .1000 liters of water, but at a temperature of 50 ° C at within 15 minutes. Rinsed skins are greased in the drum using an angel fat emulsion new-cationic.
Do bebna wlewa sie 400 litrów wody o tempe¬ raturze 50°C, a nastepnie wprowadza emulsje tlu¬ szczowa o skladzie 2,8°/o siarczanowanego, tranu, 40 ¦ ' 4 1,3% siarczanowanego oleju oibrotowego, l,76/o siarczanowanego oleju kopytkowego, 1,0% tranu i 1,0% emulgatora kationowego. Skóry obraca sie w ciagu 45 minut, po czym wyladowuje i uklada na kozlach dio odlezenia w ciagu 1 dojby. Tak przy¬ gotowane skóry przerabia sie dalej wedlug tra¬ dycyjnej metody wskoczenia wlasoiiwego. « lam 2, wiersz 12. jest: wody o temperaturze 40°C, powinno byc: wody o temperaturze okolo 40°C, DN-3, z. 457/78 Cena 45 zl400 liters of water is poured into the drum 50.degree. C., and then introduces tluemulsions oxy with a composition of 2.8% sulphated fish oil, 40 ¦ '4 1.3% sulfated oibrotic oil, 1.76% sulphated hoof oil, 1.0% fish oil and 1.0% cationic emulsifier. The skin turns within 45 minutes, then land and stack on the trestles until the release time within 1 walk. Yes, for the boiled hides are processed further according to the trays traditional method of jumping in. « lam 2, verse 12. is: water at 40 ° C, it should be: water at a temperature of around 40 ° C, DN-3, issue 457/78 Price PLN 45
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL17060374A PL99192B1 (en) | 1974-04-22 | 1974-04-22 | THE METHOD OF THE TAPING OF COWHER SURFACE SKINS |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL17060374A PL99192B1 (en) | 1974-04-22 | 1974-04-22 | THE METHOD OF THE TAPING OF COWHER SURFACE SKINS |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL99192B1 true PL99192B1 (en) | 1978-06-30 |
Family
ID=19967048
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL17060374A PL99192B1 (en) | 1974-04-22 | 1974-04-22 | THE METHOD OF THE TAPING OF COWHER SURFACE SKINS |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL99192B1 (en) |
-
1974
- 1974-04-22 PL PL17060374A patent/PL99192B1/en unknown
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