PL93041B1 - - Google Patents
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- Publication number
- PL93041B1 PL93041B1 PL18202275A PL18202275A PL93041B1 PL 93041 B1 PL93041 B1 PL 93041B1 PL 18202275 A PL18202275 A PL 18202275A PL 18202275 A PL18202275 A PL 18202275A PL 93041 B1 PL93041 B1 PL 93041B1
- Authority
- PL
- Poland
- Prior art keywords
- weight
- parts
- amount
- varnish
- vinyl
- Prior art date
Links
- 239000002966 varnish Substances 0.000 claims description 17
- 239000008119 colloidal silica Substances 0.000 claims description 6
- 239000004744 fabric Substances 0.000 claims description 4
- 238000010422 painting Methods 0.000 claims description 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 4
- 239000004800 polyvinyl chloride Substances 0.000 claims description 4
- 229920002545 silicone oil Polymers 0.000 claims description 4
- 229920006217 cellulose acetate butyrate Polymers 0.000 claims description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 3
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 claims 1
- 239000000314 lubricant Substances 0.000 claims 1
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- VHKIFHQXFVBCPL-UHFFFAOYSA-N CC(OC=CC=C)=O.Cl Chemical compound CC(OC=CC=C)=O.Cl VHKIFHQXFVBCPL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Description
Przedmiotem wynalazku jest lakier do malowania tkanin powlekanych zmiekczonym polichlorkiem winylu.The subject of the invention is a varnish for painting fabrics coated with softened polyvinyl chloride.
Lakier ten znajdzie zastosowanie do pokrywania tworzyw skóropodobnych z warstwa kryjaca ze zmiekczonego polichlorku winylu, uzywanych jako material tapicerski w przemysle samochodowym, do wyrobu róznych przedmiotów w przemysle galanteryjnym, do malowania tapet itp.This varnish can be used to cover imitation leather with a softened top layer polyvinyl chloride, used as upholstery material in the automotive industry, for the manufacture of various items in the haberdashery industry, for painting wallpaper, etc.
Znane lakiery do pokrywania omawianych tworzyw sa oparte na bazie mieszaniny dwóch zywic: akrylowej, najczesciej estrze kwasu akrylowego lub metakrylowego oraz winylowej w postaci polichlorku winylu lub kopolimeru chlorku winylu — octanu winylu.Known varnishes for covering the discussed materials are based on a mixture of two resins: acrylic, most often acrylic or methacrylic acid ester and vinyl acid in the form of polyvinyl chloride or vinyl chloride copolymer - vinyl acetate.
Jako rozpuszczalniki sa stosowane metyloetyloketon i cykloheksanon.The solvents used are methyl ethyl ketone and cyclohexanone.
Dla uzyskania powloki matowej uzywa sie dodatku krzemionki koloidalnej.To obtain a matte coating, the addition of colloidal silica is used.
Lakiery te nie wykazuja jednak odpornosci na sklejanie sie wymalowanych powlok w podwyzszonej temperaturze oraz nie posiadaja odpowiedniej sliskosci.These varnishes, however, do not show any resistance to sticking of the painted coatings in increased temperature and do not have the proper slipperiness.
Celem wynalazku jest lakier nie wykazujacy tych wad, które rzutuja na jakosc wymalowania w warunkach eksploatacji lakierowanych tkanin skóropodobnych.The object of the invention is a varnish which does not exhibit those drawbacks which affect the quality of the painting under conditions exploitation of lacquered imitation leather fabrics.
Lakiery wedlug wynalazku o poprawionych wlasnosciach otrzymuje sie przez wprowadzenie do lakieru akrylowo-winylowego srodków pomocniczych w postaci octanomaslanu celulozy oraz oleju silikonowego w scisle dobranych stosunkach wagowych.The varnishes according to the invention with the improved properties are obtained by incorporation into the varnish acrylic-vinyl auxiliary agents in the form of cellulose acetate butyrate and silicone oil in strict selected weight ratios.
Lakier zawierajacy omawiane dodatki przewyzsza inne lakiery stosowane do tych celów pod wzgledem wysokiej odpornosci na sklejanie sie wymalowan w temperaturze 75°C przy obciazeniu ciezarkiem 2,5 kg w czasie 2 godzin, oraz wykazuje zadana sliskosc max. 25°, okreslana wspólczynnikiem tarcia.The varnish containing the additives in question outperforms other varnishes used for these purposes in terms of high resistance to sticking, painted at a temperature of 75 ° C with a load of 2.5 kg within 2 hours, and shows the desired slipperiness max. 25 °, determined by the coefficient of friction.
Lakier wedlug wynalazku jest oparty na zywicach: akrylowej oraz winylowej. W sklad substancji blonotwórczej lakieru wchodza: polimetakrylan metylu w ilosci 6-10 czesci wagowych oraz kopolimer chlorek winylu—octan winylu równiez w tych samych ilosciach. Substancja powodujaca matowosc wymalowania stanowi krzemionka koloidalna w ilosci 1,5—3,0 czesci wagowych.The varnish according to the invention is based on acrylic and vinyl resins. The composition of the substance film-forming varnish includes: polymethyl methacrylate in the amount of 6-10 parts by weight and copolymer chloride vinyl - vinyl acetate also in the same amounts. Substance that makes the paint look dull is colloidal silica in an amount of 1.5-3.0 parts by weight.
Srodek poprawiajacy odpornosc na sklejanie sie powlok stanowi octanomaslan celulozy w ilosci 0,2-2,0 czesci wagowych. Skladnikiem umozliwiajacym otrzymanie odpowiedniego poslizgu wymalowania jest olej2 93041 silikonowy w ilosci 0,05—0,5 czesci wagowych. Reszte w lakierze stanowia rozpuszczalniki w ilosci 68—90 czesci wagowych, stanowiace mieszanine zlozona z metyloetyloketonu w ilosci 55—65 czesci wagowych, octanu etyloglikolu w ilosci 5—10 czesci wagowych oraz ksylenu w ilosci 8—15 czesci wagowych.The agent improving the resistance to sticking of the coatings is cellulose acetate butate in the amount of 0.2-2.0 parts by weight. Oil2 93041 is the component that allows to obtain the appropriate paint slip silicone in an amount of 0.05-0.5 parts by weight. The rest in the varnish are solvents in the amount of 68-90 parts by weight, consisting of a mixture consisting of 55-65 parts by weight methyl ethyl ketone, acetate ethyl glycol in the amount of 5-10 parts by weight and xylene in the amount of 8-15 parts by weight.
Lakier polega na rozpuszczeniu zywic akrylowej i winylowej oraz octanomaslanu celulozy, zzeiowaniu krzemionki koloidalnej w mieszaninie rozpuszczalników zlozonej z metyloetyloketonu, octanu etyloglikolu i ksylenu, oraz rozpuszczeniu oleju silikonowego w metyloetyloketonie i nastepnie wymieszanie otrzymanych roztworów.The varnish is based on dissolving acrylic and vinyl resins and cellulose acetate butyrate, and making zigzagging colloidal silica in a mixture of solvents consisting of methyl ethyl ketone, ethyl glycol acetate and xylene, and dissolving the silicone oil in methyl ethyl ketone and then mixing the obtained solutions.
Przyklad I. 8g polimetakrylanu metylu, 8g kopolimeru chlorku winylu — octanu winylu i0,3g octanomaslanu celulozy rozpuszcza sie w 58 g metyloetyloketonu do uzyskania klarownego roztworu.Example I. 8 g of polymethyl methacrylate, 8 g of copolymer of vinyl chloride - vinyl acetate and 0.3 g Cellulose Acetobutyrate is dissolved in 58 g of methyl ethyl ketone until a clear solution is obtained.
Oddzielnie zeluje sie 2g krzemionki koloidalnej w mieszaninie rozpuszczalników, skladajacej sie z2g metyloetyloketonu, 4,5 g octanu etyloglikolu i 10 g ksylenu do uzyskania jednorodnego bezbarwnego zelu.Separately, 2 g of colloidal silica in a mixture of solvents, consisting of 2 g of methyl ethyl ketone, 4.5 g of ethylglycol acetate and 10 g of xylene until a homogeneous colorless gel is obtained.
Równiez oddzielnie rozpuszcza sie 0,1 g oleju silikonowego w 7 g metyloetyloketonu.Also, 0.1 g of silicone oil is dissolved separately in 7 g of methyl ethyl ketone.
Wszystkie roztwory otrzymuje sie przy zastosowaniu mieszadla szybkobieznego, w temperaturze pokojo¬ wej.All solutions are prepared using a high speed mixer at room temperature in.
Przyklad II. W warunkach opisanych w przykladzie I otrzymuje sie lakier matowy. Lakier z polysk¬ iem otrzymuje sie w identyczny sposób, z pominieciem roztworu zzelowanej krzemionki koloidalnej.Example II. Under the conditions described in example 1, a matt varnish is obtained. Gloss varnish E is obtained in the same way, omitting the gelled colloidal silica solution.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL18202275A PL93041B1 (en) | 1975-07-12 | 1975-07-12 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL18202275A PL93041B1 (en) | 1975-07-12 | 1975-07-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL93041B1 true PL93041B1 (en) | 1977-05-30 |
Family
ID=19972943
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL18202275A PL93041B1 (en) | 1975-07-12 | 1975-07-12 |
Country Status (1)
| Country | Link |
|---|---|
| PL (1) | PL93041B1 (en) |
-
1975
- 1975-07-12 PL PL18202275A patent/PL93041B1/pl unknown
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