PL8359B1 - Method of obtaining both iron phosphide and remelted cement at the same time. - Google Patents
Method of obtaining both iron phosphide and remelted cement at the same time. Download PDFInfo
- Publication number
- PL8359B1 PL8359B1 PL8359A PL835927A PL8359B1 PL 8359 B1 PL8359 B1 PL 8359B1 PL 8359 A PL8359 A PL 8359A PL 835927 A PL835927 A PL 835927A PL 8359 B1 PL8359 B1 PL 8359B1
- Authority
- PL
- Poland
- Prior art keywords
- iron
- cement
- remelted
- iron phosphide
- obtaining
- Prior art date
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- 239000004568 cement Substances 0.000 title claims description 5
- VAKIVKMUBMZANL-UHFFFAOYSA-N iron phosphide Chemical compound P.[Fe].[Fe].[Fe] VAKIVKMUBMZANL-UHFFFAOYSA-N 0.000 title claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 17
- 229910052742 iron Inorganic materials 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 230000004907 flux Effects 0.000 claims description 6
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 235000021317 phosphate Nutrition 0.000 claims description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical class O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims description 2
- 239000007858 starting material Substances 0.000 claims description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims 2
- 239000000292 calcium oxide Substances 0.000 claims 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
- 239000011574 phosphorus Substances 0.000 description 5
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- 235000013980 iron oxide Nutrition 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 235000014413 iron hydroxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910001392 phosphorus oxide Inorganic materials 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- VSAISIQCTGDGPU-UHFFFAOYSA-N tetraphosphorus hexaoxide Chemical compound O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 description 1
Description
Pierwszenstwo: 10 marca 1926 r, ("Niemcy).Przy przerabianiu fosforanów w piecach elektrycznych lub szybowych, jak wiadomo, odpowiednie ilosci fosforu wiaza sie z ze¬ lazem, tworzac fosforek zelaza. Znane sa Fee, P do Fe. P zawierajace praktycznie okolo 16 do 23n/0 P.Wiadomo ponadto, iz do stopu redukcyj¬ nego dodaje sie taka ilosc rudy zelaznej, aby cala ilosc fosforu zostala zwiazana, skoro wiec obecnie przekroczyc te ilosc top¬ nika, zawierajacego tlenek zelaza, i dodac, zaleznie od skladu stapianych fosforanów surowych, ponadto dalsze topniki w postaci glinu, tlenku wapniowego lub krzemowego lub wszystkie te topniki jednoczesnie, tak iz z jednej strony cala ilosc fosforu zosta¬ nie zwiazana z zelazem, tworzac fosforek, i skoro sklad zuzla odpowiada skladowi cennego cementu przetopionego, natenczas obok fosforku zelaza, zawierajacego z jed¬ nej strony kwas fosforowy, fosfor jak i po¬ dobne materjaly otrzymuje sie z drugiej strony ponownie tlenki zelaza lub wodoro¬ tlenki, poza tern jeszcze jako cenny produkt poboczny cement przetopiony.Sposób niniejszy, dzieki temu, ze zelazo wiaze cala ilosc fosforu, i wobec tego na zuzel nie moga oddzialywac ujemnie nawet slady tlenku fosforowego, daje ponadto te korzysc, iz do cementu mozna dodac bez zadnych trudnosci taka ilosc tlenku zelaza, jaka jest niezbedna do nadania mu dobrej jakosci.Skoro jako materjalu wyjsciowego, uzyc fosforanów glinowych, natenczas oprócztopnika zelazowego nalezy tylko dodac wapnia i kwasu krzemowego, PL PLFirst: March 10, 1926 ("Germany). When processing phosphates in electric or shaft furnaces, it is known that the appropriate amounts of phosphorus are bound with iron to form iron phosphide. There are known Fee, P to Fe. P containing practically approx. 16 to 23n / 0 P. It is also known that such an amount of iron ore is added to the reducing alloy to bind all the phosphorus, so now this amount of iron oxide-containing melt is exceeded and add, depending on the composition fused raw phosphates, moreover, further fluxes in the form of aluminum, calcium or silica oxide, or all of these fluxes simultaneously, also on the one hand all phosphorus will be bound to the iron, forming phosphide, and since the composition of the slag corresponds to that of the valuable melted cement in addition to iron phosphide, containing on the one hand phosphoric acid, phosphorus and similar materials, on the other hand, again iron oxides or hydroxides, apart from the present The present method, because iron binds all phosphorus, and therefore even traces of phosphorus oxide cannot have a negative effect on the gels, it also has the advantage that it can be added to the cement without any difficulties. iron oxide, which is necessary to give it good quality. Since aluminum phosphate should be used as a starting material, then in addition to iron flux, only calcium and silicic acid should be added, EN EN
Claims (2)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL8359B1 true PL8359B1 (en) | 1928-02-29 |
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