PL8060B1 - Method for preparing volatile zinc-containing dust for further processing. - Google Patents

Method for preparing volatile zinc-containing dust for further processing. Download PDF

Info

Publication number
PL8060B1
PL8060B1 PL8060A PL806026A PL8060B1 PL 8060 B1 PL8060 B1 PL 8060B1 PL 8060 A PL8060 A PL 8060A PL 806026 A PL806026 A PL 806026A PL 8060 B1 PL8060 B1 PL 8060B1
Authority
PL
Poland
Prior art keywords
zinc
further processing
furnace
containing dust
volatile
Prior art date
Application number
PL8060A
Other languages
Polish (pl)
Filing date
Publication date
Application filed filed Critical
Publication of PL8060B1 publication Critical patent/PL8060B1/en

Links

Description

Wynalazek dotyczy sposobu przygoto¬ wywania lotnego pylu, zawierajacego cynk do dalszej przeróbki na czysty cynk. Przy wielu procesach' hutniczych wytwarza sie lotny pyl, zawierajacy cynk, którego bez¬ posrednia przeróbka na cynk zapomoca procesu destylacyjnego malo sie oplaca z powodu nieznacznej gestosci pylu i duzej czesto zawartosci obcych domieszek, jak np, As, Sb, Sn, Pb, Cd, Cl, S lub tez S03 i t d.Sposób, bedacy przedmiotem wynalazku, zmierza do usuniecia zawartosci obcych do¬ mieszek a polega na tern, ze materjal do¬ prowadza sie w sposób ciagly do pieca plomiennego, np, do obrotowego pieca ruro¬ wego, i wystawia go wsród nieustannego ruchu na podeszwie tego pieca na dzialanie tak wysokiej temperatury, ze ze spiekaniem materjalu laczy sie oczyszczenie go od szkodliwych skladników w drodze ulotnie¬ nia tychze. Skutkiem tego otrzymuje isje spieczony i oczysiZjczony tlenek cynku, na¬ dajacy sie do dalszego przerobu na czysty cynk. Przy tern ulatnianiu sie obcych dlomie- 8zek mozna w razie potrzeby zblizac sie pra¬ wie do temperatury ulatniania sie cynku, W danym razie mozna, celem ulatwienia proce¬ su czyszczenia przez tworzenie lotnych po¬ staci domieszek dodawac do materjalu drobne ilosci materjalów dodatkowych, juz w procesie Pape'go (patent niemiecki Nr 214 912) znajdujemy pomysl spiekania ce¬ lem ulatwienia transportu, natomiast usu¬ wanie obcych domieszek w procesie tym nie bylo zamierzone ani tez osiagniete. Pyl, o- padajacy w czasie procesu ulatniania isie w urzadzeniach skraplajacych mozna diopro-wadzic, np. zapomoca urzadzen transpor¬ towych, do dalszego, mniejszego pieca, w którym odbywa sie jego dalszy przerób i oczyszczenie w bezposredniem nastepstwie po procesie otrzymywania pylu. Piec moz¬ na prowadzic w ten sposób, ze nawet bez dadajnia wegla redukujacego mozna w znacznym stopniu osiagnac usuniecie zanie¬ czyszczen a w szczególnosci S i Pb. Trze¬ ba, zatem tylko rozstrzygnac, czy juz w pyle znajduja sie lotne formy, wzglednie polaczenia obcych domieszek czy tez za¬ chodzi potrzeba stworzenia ich dopiero za¬ pomoca stosgwtoych doda;tków. Do tego ce¬ lu mozna uzyc w sposób znany (co do swej istoty) srodków redukujacych, chlorków i tym podobnych, o ile oczywiscie nie znaj¬ duja sie iome juz w samym materjale wyj¬ sciowym. W kazdym jednak wypadku na¬ lezy w ten sposób uregulowac ilosc dodat¬ ków i wysokosc temperatury, aby w prak¬ tyce mozna bylo uniknac równoczesnego ulatniania sie cynku.Przytaczamy tu jeden przyklad wyko- natoia pomyslu iw! praktyce. Przy próbie na wielka skale udalo sie zapomoca opisane¬ go procesu, przy ciaglym dowozie materja- lu, a bez dodatków, tak dalece oczyscic pyl o zawartosci 59,5% Zn, 6,8% Pb, 5,1% S, ze opadajacy, spieczony produkt wyka¬ zywal juz tylko 0,03% Pb i 0,43% S obok 73,8% Zn. PL PLThe invention relates to a process for the preparation of zinc-containing volatile dust for further processing into pure zinc. In many metallurgical processes, volatile zinc-containing dust is produced, the direct conversion of which to zinc by a distillation process is low-cost due to the low density of the dust and the high content of foreign impurities, such as, for example, As, Sb, Sn, Pb, Cd. , Cl, S or also S03 and so on. The method, which is the subject of the invention, aims to remove the contents of foreign follicles and consists in the fact that the material is fed continuously to a flame furnace, e.g. a rotary tubular furnace and exposes it amidst the constant movement on the sole of this furnace to the action of such a high temperature that the sintering of the material is associated with its purification of harmful components by means of the evaporation of these. The result is a sintered and purified zinc oxide which is suitable for further processing into pure zinc. With foreign volatilization, it is possible, if necessary, to approach almost the temperature of the volatilization of zinc. If necessary, in order to facilitate the cleaning process by creating volatile admixtures, small amounts of additional materials can be added to the material, already In the Papé process (German Patent No. 214,912) we find the idea of sintering to facilitate transport, while the removal of foreign impurities in the process was neither intended nor achieved. The dust that falls during the volatilization process and is present in the condensing equipment can be led, for example by means of transport equipment, to a further, smaller furnace, where it is further processed and cleaned immediately after the dust extraction process. The furnace can be operated in such a way that, even without the addition of reducing carbon, removal of the contaminants, in particular S and Pb, can be achieved to a large extent. Therefore, it is only necessary to decide whether the dust already contains volatile forms, or combinations of foreign admixtures, or whether it is necessary to create them only with the help of piles of additions. For this purpose, reducing agents, chlorides and the like can be used in a known manner (in essence), provided that they are not already present in the starting material itself. In each case, however, the amount of additives and the amount of temperature must be regulated in such a way that, in practice, simultaneous zinc volatilization can be avoided. Here is one example of the idea and! practice. During the large-scale trial, the described process was successfully followed, with a continuous supply of material, and without additives, to clean the dust with a content of 59.5% Zn, 6.8% Pb, 5.1% S, with the falling the sintered product already had only 0.03% Pb and 0.43% S in addition to 73.8% Zn. PL PL

Claims (1)

1. Zastrzezenie patentowe. Sposób przygotowywania lotnego pylu, zawierajacego cynk do dalsizego przerobu na cynk, znamienny tern, ze materjal do¬ prowadza sie w sposób ciagly do pieca plo¬ miennego, nip. do obrotowego pieca rurowe¬ go, gdzie poruszajac go stale na podeszwie pieca, wystawia sie na dzialanie wysokiej temperatury, kitóra dochodzi prawie do temperatury ulatniania sie cynku, przyczem uzyskuje sie obok spiekania materjalu tak¬ ze oczyszczenie go od sizfkodliwych domie¬ szek obcych, np, As, Sb, Sn, Cd, Pb, Cl, S, SOq i i d., dodajac jednoczesnie w razie potrzeby dirobne ilosci matenjalów dodat¬ kowych celem ulatwienia procesu oczy¬ szczania przez tworzenie lotnych postaci tych skladników ubocznych. Fried. Krupp Grusonwerk Aktiengesellschaft Zastepca: M. Skrzypkowski, rzecznik patentowy. Druk L. Boguslawskiego. Warszawa. PL PL1. Patent claim. A method of preparing a volatile zinc-containing dust for further processing into zinc, characterized by the fact that the material is fed continuously to the flame furnace, n and p. to rotary tubular furnace, where, by constantly moving it on the furnace sole, it is exposed to the action of high temperature, which reaches almost the temperature of zinc volatilization, whereby apart from sintering the material, it is also cleaned of harmful foreign particles, e.g. , As, Sb, Sn, Cd, Pb, Cl, S, SOq, and d., Simultaneously adding, if necessary, small amounts of additional materials to facilitate the purification process by forming volatile forms of these by-components. Fried. Krupp Grusonwerk Aktiengesellschaft Deputy: M. Skrzypkowski, patent attorney. Print by L. Boguslawski. Warsaw. PL PL
PL8060A 1926-12-16 Method for preparing volatile zinc-containing dust for further processing. PL8060B1 (en)

Publications (1)

Publication Number Publication Date
PL8060B1 true PL8060B1 (en) 1927-12-31

Family

ID=

Similar Documents

Publication Publication Date Title
DE3220609A1 (en) METHOD FOR PRODUCING RAW COPPER FROM A COPPER ORE MATERIAL
DE2001450A1 (en) A process to be used in connection with the smelting of sulphide ores
DE2918316C2 (en) Process for roasting and chlorinating fine-grained iron ores and / or concentrates containing non-ferrous metals
PL8060B1 (en) Method for preparing volatile zinc-containing dust for further processing.
FR2429841A1 (en) PROCESS FOR THE SELECTIVE REMOVAL OF IMPURITIES FROM COMPLEX ORES, MIXED ORES, SULPHID CONCENTRATES
US2775509A (en) Selenium dioxide volatilization process
US2064495A (en) Method and apparatus for recovering vaporized metal compounds
Spedden et al. Acid bake-leach-flotation treatment of offgrade molybdenite
US4039173A (en) Aluminum dross recovery method
US599310A (en) Henry robert angel
DE590505C (en) Process for the extraction of lead, antimony or bismuth
US1940912A (en) Treatment of ores
DE2303902A1 (en) METHOD FOR PROCESSING TIN AND ISMUTAL MATERIALS
US1784490A (en) Process for the recovery of the tin contained in the residues of tinplate manufacture
SU947209A1 (en) Method for removing copper from slags of lead batch melting
CH335859A (en) Process for the extraction of lead
SU711132A1 (en) Method of processing copper-containing ferrous materials
US1799278A (en) Treatment of zinc-bearing material
DE1056838B (en) Process for the direct extraction of fine or ultra-fine lead from lead-containing materials
DE121324C (en)
DE1132734B (en) Process for the extraction of metallic manganese from metallurgical dusts, slag and ores
DE640732C (en) Process for separating low-ash coal from ash-rich
GB2150549A (en) Process for the separate recovery of metal chlorides from complex ores etc
DE2162077B2 (en) METHOD FOR REMOVING CONTAMINATION FROM COPPER SULFIDE OR CONCENTRATES OF COPPER SULFIDE
GB211895A (en) Process of splitting up ores and metallurgical products