PL801B1 - coal in acid furnaces. - Google Patents

coal in acid furnaces. Download PDF

Info

Publication number
PL801B1
PL801B1 PL801A PL80120A PL801B1 PL 801 B1 PL801 B1 PL 801B1 PL 801 A PL801 A PL 801A PL 80120 A PL80120 A PL 80120A PL 801 B1 PL801 B1 PL 801B1
Authority
PL
Poland
Prior art keywords
iron
carbon
coal
fire
old
Prior art date
Application number
PL801A
Other languages
Polish (pl)
Filing date
Publication date
Application filed filed Critical
Publication of PL801B1 publication Critical patent/PL801B1/en

Links

Description

Do sporzadzania stali lub zelaza zlewne¬ go ze starego zelaza (oldipiadków) srodkaimi weglowemi propolnowano juz roizunaite' spo¬ soby. Jedna grupa tych sposobów zastoso- wuje z&siadowa wyprawe pieca, druga kwah sna. Przy zias.adowym sposobie zastosowano juz doimieiszke wapnia lub kaimienia wapien¬ nego, w celu usuniecia fosforu, a czesciowo takze siarki. Dla kwaisnegoi pnoiceisu mie sto¬ sowano dotychczas ziasiadowych domieszek, gdyz domieszki te niszcza wyprawe pieca..Próby zniierziajace do topiefmia odpadków w kwasnych' piecach, nie przyniosly jednak zadnego1 praktycznego' wyniku, bo przez, dio- tychciziaisiowe1 metoidy nietylko wyprawa, ogni¬ ska, ale takze sklepienie pieca bardzo silnie bylo atakowane: dlatego tez potrzeba bylo dlugich przerw w robloclie nia naprawieffiie oignilskaj i scian pieca, które uniemozliwialy oiagloisc procesu mafrtiinioiwskiieigoi.Przyczyna tych szkodliwych dzialan le¬ zy, z jednej sitromy w wyzeraniu podwalimy ogniska przez, odpadki, a z drugiej strony w powsitaiwaniu gestoplynnych zuzli, które wymagaja dlugiego szarzowania, przeiz co wywieraja szkodliwe dlzialaniai temperatury na sklepianie. Róiwniez w praktyce zachodzi szczególna potrzeba: ekonomicznego zastoso¬ wania beizisurowcowegoi sposobu w kwaisnyim piecu, albowiem dla kwasnych pieców, w których wykluczone jest odsialrkoiwanie i odlfoisforowainie, tezebafoy uzywalo czystego- i przez to drogiego surowca1..Na poldstawie zgoldJnych prób znaleziono,ze mimo to mozliweni jest prze/prowadzenie topienia odpadków w kwiasnym piecu, co stoiowi prze!imiot niniejszego wylnialazku i polega na tern, ze wprowadza sie ma ogni¬ sko kwasnego pieca ubogi w siarke i forsfor srodek weglowy (np. petrolkoks, wegiel drzewny i t. p.), ila tein srodek weglowy daje sie stare zelazo, a zas ma to malo ilosci ta¬ kich topników (np. kamien wapniowy, p&r , lomo wapno i t. p.), które czynia zuzel rzad¬ ka przyspieszaja oldweglemie i spro¬ wadzaja kapiel do pdtirtobnej teimpeiratury.Taki, szczególnie zrnierziajacy do tego celu sposób jest nastepujacy: Pieic kwaisny, którego podwalina 'zrobio¬ na jest iz piaJsiku kwarcowego, izajsila sie, bez szczególnych zabezpieczen przeciw stratom srodka weglowego, a wiec przy ewentualnie otwairtym dostepie gaiziu i powietrza, srod¬ kiem weglowym (np. petroilkofcs, wegiel drzewny i t. p.). Srodek weglowy stosuje siie w formie kawalków, od wielkosci orzecha, aiz do wielkosci piesci. Uzycie srojdków weglo¬ wych we wspoimniainej foirmde okazalo sie bardzo odpowiedniem, albowiem srodek uzy¬ ty w formie mialu isipiaila sie, a przez to spa- lamle i ulatniantó sie powstaja straty, które moglyby spowodowac brak wegla w, cza&ie najwiekszej zdolnosci piadilalnfilamiial go p.rzeiz zelazo. Na srodek weglowy kladzie sie naj¬ lzejsze stare zelazo, azeby powieirtzohnia dzia- lamia byla duza i azeby zelaizo równioczeisnie octhronic przed spaleniem. Na te warstwe uimieszicza sie w stosunkowo' malych ilo¬ sciach takie topniki (np. kamien wapienny, palone wapno i t. p.), które czyiriia zuzel rzfadkoplyniniyim i przyspiesziaja odweglenie.Wreszcie na topniki sypie sie reszte grub¬ szych odpadków. Azeby, w kwasnym pieicu mjozna bylo szarzowac italkie- miekkie^ zelaro zlewlne,, belz atakowamia podwaliny ogniska, dorziuca. sie na warstwe siroidka weglowego je^zóze odpadków zelaza, ubogich w wegiel i krzeimi (np. odpadków dlrutu walcowane¬ go, gwozdzi i t. p.).Wylozenie ogniska chronione jest przed . szkodliweimi dzialaniami wstawka lezaca pod topnikami. Te topniki Zr pozoistalosciiaimi kolksu, wzralstajacemi w pózniejiszyim prze¬ biegu prcKcesu. topienia, wcholdiza w reakcje, przez co óisiajga sie Tzadkoplynnosc z po¬ czatku gestych zuzli, iszyfoki proces oidwe- glania i sizybkie pobieranie ciepla prz^z ka¬ piel stali. Rz&dfcoplyniniosc zuzli, w przeci- wienisitiwie: do gesitych zuzM, tworzacych sie przyv imnych beizisuiiowciowyich spoisobach, sprawia to, ze kapiel moze latwiej przyj¬ mowac goraco, a to nie dziMa, tak silnie ma 'sklepienie piieca, przez cio osiaga sie wiieksiza trwalosc sklepienia. Pomilnawisizy wyzej wsponumialne techniicizlne zalety sposobu, stwa¬ rza on takze osiagniecie wysofcowartoscio- wego koncowego,._.produktu^ .^bowiecni ten,, nie zawierajac sizfcodliwych Eanieczyisizicizen, posiada wyzsza walrtasc. Fosfor i sianka, które doistalyby sie wraiz z . suiriowceim do kapieli stalowej, odpadaja pirtey ntiniilejsfzym sposobie, z drugiej strony, o ile te .obce pier- wialsttoi trafilyby do .kapieli z otd]piaJdJkajmfii, to zostaja one czescflowo zwiaizalnei zasadiowemi 'topnikami, wzglednie dolstaja sie do zuzli.Dla niilniejiszego spoisobu jest to znamien¬ ne, ze wapno nie klaJdzie sie, jak przy zasa¬ dowym procesie, na podwalinie ogniska, lecz na grubych odpaJdkaioh i przykrywa sie go znowu grubettni odpadkalmi tak, ze wapno nie moze 'zetknac sie z, podwalina pieica, ma- toaniasit zobojetnia sie przeiz reakcje z lekkie- mi, zawierajacemi fcwais krzemiowy topnikai- mi, podnoslzaceimi, sie wgóre podczas prze¬ biegu procesu topienia., i cizyhi je rzadko- plynnemi. PL PLVarious methods have already been proposed by means of carbonaceous materials for the preparation of steel or cast iron from old iron. One group of these methods is used by the stove's expedition, the other by the acid dreams. In any of these methods, calcium or limestone had already been applied to remove phosphorus, and partly also sulfur. So far, for acidic and pnoiceis, there have been used grassland admixtures, because these admixtures are destroyed by the furnace expedition. The attempts to melt waste in acid furnaces, however, did not bring any practical result, because due to the diacetics and metoids, not only rock expeditions , but also the furnace vault was very strongly attacked: therefore, long breaks were needed in the work to repair the furnace wall and the furnace wall, which made it impossible to achieve a good image of the mafrtiinioivskiie process. on the other hand, in the celebration of liquid bad things, which require a long graying, thus exerting harmful tensions and temperatures on the vault. There is also a special need in practice: the economical use of the raw material and the acid-based method in the acid furnace, because for acid furnaces, in which desialination and de-deformation is excluded, tezebafoy used a pure - and thus expensive raw material1 .. On the basis of numerous nevertheless it is possible to melt the waste in a flower furnace, which is the basis of the present invention and consists in introducing a low-sulfur and forphoric carbon dioxide (e.g. petrolcox, charcoal, etc.) in an acid furnace, How much carbon is used to give old iron, and this has a small amount of such fluxes (e.g., limestone, p & r, lomo lime, etc.), which make the iron thin, accelerate the oldweglemie and bring the bath to a looped theory. Such a method, particularly conducive to this purpose, is as follows: Sour cream, the base of which is made of quartz sand, has come up, without any particular effort. protection against carbon losses, i.e. with open gas and air access, with carbon dioxide (e.g. petroilkofcs, charcoal, etc.). The charcoal is used in the form of chunks, from the size of a nut up to the size of a caress. The use of coal pots in the aforementioned foirmde turned out to be very appropriate, because the agent used in the form of pulverized powder and burned, and thus burned and volatilized, losses arise that could result in a lack of carbon in the body, while the greatest ability to fill it with flammability. iron and iron. The lightest old iron is put on the charcoal so that the air is large and the iron is simultaneously octhronic before burning. This layer is mixed in relatively small amounts with such fluxes (e.g. limestone, burnt lime, etc.), which make the slack thinner and accelerate dehydration. Finally, the rest of the coarse waste is poured onto the fluxes. In order that in the acid bath it was possible to grayish the Italian soft, catchy iron, the beams attack the foundations of the fire, the basin. on the carbon siroid layer, the scrap iron, low in carbon and silicate (e.g. scrap rolled wire, nails, etc.) is deposited. the insertion under the fluxes. These Zr fluxes were colic residual fluxes, which grew later in the course of the process of success. melting, absorbed into the reaction, which results in Tadulidity from the beginning of thick sloughs, and a quick process of stimulation and rapid absorption of heat from the steel bath. The smoothness of slips, on the contrary: to the dense slumps that are formed at the names of beisisiiowciowciowciowcii spoisobach, this makes the bath easier to receive hot, and it is not surprising that it has such a strong vault, through the body achieves the durability of the vault . Notwithstanding the above-mentioned collective technical advantages of the method, it also created the achievement of a high-quality final product. ^. ^. This beaver, without the harmful Eanieczyisizicizen, has a higher value. Phosphorus and haystack that would impress with. suiriowceim to steel bath, they fall off pirtey in the best way, on the other hand, if these foreign elements would end up in. it is significant that the lime does not clump, as in the case of the basic process, on the foundation of the fire, but on the thick chunks, and it is again covered with thick debris so that the lime cannot come into contact with the foundation of the fire, He becomes inert to react with light, silica-containing floating fluxes, which move up during the melting process, and dry them rarely. PL PL

Claims (3)

1. Zastrzezenia patentowe. 1. Sposób wytwarzania sitali lub zelatza zlewnego ^ze starego zelateiwa srodkami we- gloweimi w kwasnym pieicu, na ognisku któ¬ rego umieszczony jest ^srodek weglowy sto¬ sunkowo ubdgi w siarke i foslor (np. petiriol- koks, wegiel dnzeiwny i t. p.), a na tenze snodek nalozone stare zelaziwo, tern zna- — 2 —miiemny, ze ma to sitaire zelaiziiiwo, 'dajje sie, od¬ powiednio zelaaitwein przykryte topniki (uiip. kaimien waipieinlny, palone waipno) w malej ilosci, o takiej maturze, azeby spowodowaly rziadlkoplynny zuzel i pnzylspieszyly odwe- glenie i odebranie ciepla pirzeiz kapiel slalo^ wa, nfe stykajac ma a podrwialima pieioa.1. Patent claims. 1. The method of producing sitala or drainage gel from old gelatin with carbonaceous agents in an acidic oven, on the fire of which is placed carbonaceous agent relatively bound to sulfur and phosphorus (e.g. petiriol-coke, bottom carbon, etc.) , and on this snodek old iron is put on it, tern significant - 2 - dark, that it has a iron sitaire, 'it is possible to get, respectively, zelaaitwein covered fluxes (uiip. kaimien waipieinlny, roasted waipno) in a small amount, of such maturity, so that they would cause liquid decay and rush to remove the heat and take away the heat of the feathers, and to bathe slalo ^ wa, nfe touching a little, a broken tree 2. Sposób, podlug ziafejttrzieizeliiiai 1, tern znamienny, ze ma warsitwe srodka weglowe¬ go daje sie odpadki zelalza, ubogie w wegiel i Krzem (mjp. odpadki drutu walcowanego, gwozdzi i t. p.) w tym celu, aJzeiby mozna bylo szarzowac takze miekkie, drobino ska- walkowane, zelazo ziewnie w kwajsmej wy¬ prawie, bez misiziczemia poidlwiaiUny ogmaiska.2. The method, the base of ziaanniettrzieizeliiiai 1, characterized by the fact that it has a carbon base, it gives iron waste, low in carbon and silicon (e.g. waste of rolled wire, nails, etc.) for this purpose, so that the glass could also be grayed soft, defect, iron yawning in high acidity, without the mischievousness of the fire. 3. Spoaófo, podlug zaJstrzeizenia 1, tern znamienny, ze smoldlki weglowe wklalda sie do pieca w grubej formie (inp. w formie wielkosci orzecha ajz do wielkosci piesci) przeiz co srodki ite, w chwili, maijiwiejklsizej zidol- nosci pochlaniania wegla przez rozgrzane zelaizo, dzialaja doweglajjaco: Paul Brandl. Zastepca: M. K r y z a n, rzecznik patentowy. ZAKLGRAF.K0ZIANSK1CH W KRAKIWIE PL PL3. Spoófo, along the ground of the straits 1, the area characterized by the fact that the coal smolders are put into the furnace in a thick form (e.g. in the form of a nut or up to the size of the caulk), by means of which ite means, at the moment, maiji lighter pots - absorption of the heated coal by the carbon , working for navigation: Paul Brandl. Deputy: M. K r y z a n, patent attorney. ZAKLGRAF.K0ZIANSK1CH IN KRAKOW PL PL
PL801A 1920-09-07 coal in acid furnaces. PL801B1 (en)

Publications (1)

Publication Number Publication Date
PL801B1 true PL801B1 (en) 1924-11-29

Family

ID=

Similar Documents

Publication Publication Date Title
PL801B1 (en) coal in acid furnaces.
US1716527A (en) Manufacturing process for aluminous cements
US2211133A (en) Method of producing casting molds
US1867641A (en) Manufacture of brick
US2043642A (en) Building brick
DE409347C (en) Process for the production of iron or steel that is largely deoxidized, similar to welding iron
US1585184A (en) Artificial stone and method of making the same
DE471612C (en) Protective covering for permanent molds
Hemming Plastics and molded electrical insulation
AT82433B (en) Process, ceramic structures, etc. Like. To imitate in slag casting.
DE157876A (en)
DE281349C (en)
AT109996B (en) Process for the production of castings in permanent metal molds.
US3043040A (en) Method of transforming new bricks into bricks which simulate aged bricks
AT150003B (en) Process for producing a gas-tight mortar, in particular for lining chimneys.
DE533231C (en) Process for the production of cellular concrete o.
DE647286C (en) Process for the production of fire-resistant, tough and tough concrete mixes
DE564041C (en) Process for the production of a heat-retaining, porous and water-repellent compound
DE392949C (en) Process for the production of artificial and work stones from molten slag
SU150400A1 (en) Method of making refractory mass
US1883442A (en) Method of making brick and the like
SU599910A1 (en) Solution for strengthening ceramic shell moulds
DE864377C (en) Process for the production of molded parts from melted slag
US2104353A (en) Composition of matter for artificial stone
US140668A (en) Improvement in artificial marble