PL7716B3 - Sposób otrzymywania metanolu lub zawierajacych tlen zwiazków organicznych. - Google Patents
Sposób otrzymywania metanolu lub zawierajacych tlen zwiazków organicznych. Download PDFInfo
- Publication number
- PL7716B3 PL7716B3 PL7716A PL771626A PL7716B3 PL 7716 B3 PL7716 B3 PL 7716B3 PL 7716 A PL7716 A PL 7716A PL 771626 A PL771626 A PL 771626A PL 7716 B3 PL7716 B3 PL 7716B3
- Authority
- PL
- Poland
- Prior art keywords
- oxygen
- organic compounds
- containing organic
- obtaining methanol
- carbon monoxide
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title description 3
- 239000001301 oxygen Substances 0.000 title description 3
- 229910052760 oxygen Inorganic materials 0.000 title description 3
- 150000002894 organic compounds Chemical class 0.000 title description 2
- 239000007789 gas Substances 0.000 claims description 8
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229940087654 iron carbonyl Drugs 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 238000010531 catalytic reduction reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- -1 for example Chemical class 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Description
Najdluzszy czas trwania patentu do 21 grudnia 1941 r.W patencie Nr 6598 opisano sposób o- trzymywania zawierajacych tlen zwiazków organicznych zapomoca redukcji katalitycz¬ nej tlenku wegla wodorem przy tempera¬ turze i cisnieniu podwyzszonem. Sposób polega na tern, ze reakcje prowadzi sie w przyrzadach, których czesci aparatury, sty¬ kajace sie z tlenkami wegla, sa zaopatrzo¬ ne w wykladzine, wykonana z miedzi, srebra lub glinu, ze stopu tych metali, ze stali, zawierajacej znaczne ilosci chromu, manganu, wolframu, wanadu lub molibde¬ nu, lub tez czesci te pokrywa sie metalami powyzszemi lub zaopatruje w powloke chromowa, manganowa, wolframowa, wana¬ dowa lub molibdenowa, przyczem czesci a- paratury nienarazone na temperature podwyzszona i stykajace sie z tlenkiem we¬ gla moga byc wykonane z metalu nisko- topliwego, jak np. cyny, cynku lub olowiu i L d., ze stopów tych metali lub mozna je pokryc odpornem tworzywem niemeta¬ licznemu Obecnie wykryto, iz z tlenku wegla mozna otrzymac zawierajace tlen zwiazki organiczne równiez bez niedogodnosci, o których mowa w patencie powyzszym, sko¬ ro reakcje prowadzic w przyrzadach w tensposób, zeby zawierajacy tlenek wegla gaz przy stosowaniu suchej mieszaniny gazo¬ wej stykal sie z zelazem, niklem lub ko¬ baltem w mniej rozgrzanych lub zimnych czesciach przyrzadu. Rozumie sie, ze ga¬ zy musza byc pozbawione substancyj za¬ truwajacych kontakt, szczególnie zas nie moga zawierac lotnych zwiazków metalo^ wych, jak np. karbonylku zelaza i t. d.Gazy n^ozna suszyc w sposób dowolny, np. przepuszczajac je pod cisnieniem przy którym sie przeprowadza reakcja przez chlorek wapnia lub tez przemywajac je al¬ koholem, np. alkoholem metylowym. Wy¬ suszona w ten sposób mieszanina gazowa, skladajaca sie z 75% wodoru, 20% tlenku wegla, 5% azotu i metanu, przy cisnieniu 200 atm, nawet w temperaturze okolo 150° nie tworzy na powierzchni zelaznej karbo¬ nylku zelaza. Sklonnosc tworzenia sie karbonylku zelaza wogóle zwieksza sie w miare zwiekszania sie zawartosci wegla w zelazie. Zawarty w gazach swiezych kar¬ bonylek zelaza korzystniej jest usunac za- pomoca przepuszczenia gazu przez war¬ stwe wegla aktywowanego. PL PL
Claims (1)
1. Zastrzezenie patentowe. Odmiana sposobu wedlug patentu Nr 6598, znamienna tern, ze reakcje prowadzi sie w przyrzadach odpowiecjnich w ten sposób, iz gazy, zawierajace tlenek wegla, stykaja sie z zelazem, niklem lub kobaltem, w czesciach przyrzadu mniej goracych lub zimnych, przyczem stosuje sie wysu¬ szona mieszanine gazowa. I. G. Farbenindustrie Aktiengesellschaft. Zastepca: M. Skrzypkowski, rzecznik patentowy. Druk L. Boguslawskiego, Warszawa. PL PL
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL7716B3 true PL7716B3 (pl) | 1927-07-30 |
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