PL4936B1 - A method of producing gasoline and purifying hydrocarbon mixtures. - Google Patents

A method of producing gasoline and purifying hydrocarbon mixtures. Download PDF

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Publication number
PL4936B1
PL4936B1 PL4936A PL493624A PL4936B1 PL 4936 B1 PL4936 B1 PL 4936B1 PL 4936 A PL4936 A PL 4936A PL 493624 A PL493624 A PL 493624A PL 4936 B1 PL4936 B1 PL 4936B1
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PL
Poland
Prior art keywords
pressure
hydrocarbon mixtures
liquid
compounds
producing gasoline
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Application number
PL4936A
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Polish (pl)
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Publication date
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Publication of PL4936B1 publication Critical patent/PL4936B1/en

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Wynalazek niniejszy dotyczy uzyski¬ wania z mieszanin gazów weglowodorowych latwo (skraplajacych sie (skladników tychze i ma na celu wytwarzanie plynów weglo¬ wodorowych trwalych w temperaturach zwyklych i pod zwyklein ciilsnliieniem, aby moiznk je bylo przechowywac i przewozic bez znaczniejszych strat i o takim ukladzie, alby jeden tylko zwiazek chemiczny stano¬ wil glówny skladnik ,plyinu i pozostalosci gazowej pierwotnej mieszaniny, z jakiej plyn ten wytworzono. Tak naprzyklad, je¬ zeli mieszanine (gazcwa .stanowi gaz natu¬ ralny, zawierajacy metan, etan, propan i butan oraz w wiekszej ilosci weglowodory o budowie .czajsteczkowej bardziej zlozo¬ nej, a plynem wytwarzanym ma byc gazo:- lina o zwyklych wlasnosciach, ,plyn polwi- nien zawierac tylka wlslzystek butan i zwiazki o wiekszym ciezarze czasteczko¬ wym, albo butan jpowinien byc podzielony pomiedzy plyn i ipozoisitalolsc gazowa. W tym ostatnim wypadku butan (powilnie!n sta¬ nowic jedyny zjwiazek Wspólny obu frak- cyj, (podczas, gdy w pierwiszym riie posia¬ daja one zadnego wisipóikiego zwiazku. Usi¬ lowano dotychczas osiagnac wskazane re¬ zultaty zapomoca procesów, polegajacych na oczyszczaniu frakcji plynnej. , Wynalazek rikiiejiszy dotyczy odmiany znane/j metody, w któlrej oczyszczanie frak¬ cji iplynnej uskutecznia sie pod cisnieniem nizlszem od atjmoisiferycznegol, W przykladzie wykonania jednego ze sposobów dawniejszych kociol kolulmny rektyfikacyjnej utrzymuije sie w tempera-turze ^ofccio 2S°Oa ai wytWotarzotna .benzyna posiada/ w teif temperatuirze cisnieinie par (bezwzglednie) okota 1,5 altim. Aczkolwiek cisniemie pary plynu itego pitfzekraoza jed¬ na atmosfere (ibezwzigl^dkia) w teimperaifti- rze zewtnetrznejy panujacej przez zmacana czesc roku, plyn ten mozna] jedmak pirze- woizic w opatteoinycih otulina cysteirnach nawet latem, chociaz w upaly zachodzi u- stawilczzna strata materjalu, od|powiadaja- ca tej ilosci, iplyniu, jaka moze byc odparo¬ wana cieplem pitfzechodzaeem przez scian¬ ki cystenny; ptfzy odpowiedniej izolacji straty te nie sa znaczne. Dla izmtniejlsizemliia cisnietaia pary benzyny pdnizej cisnienia atmosferyczniego i zapobiezenia przeto jej wrzeniu, nalezy obnizyc jej temperature do 16° C lub jesizcze mmiej. Gdy temperatura kotla aparatu rektyfikacyjnego jest nizsza od tempetratury atmosfery, produkt .wyply¬ wajacy z kotla nalezy dostatecznie ochla¬ dzac siztuczniiie, inaczej bowiem bedzie on wrzal, co powoduje znaczne straty, przy- czem teimiper^tuira jego podczas wtaenia spada, Aczkolwiek istraty z cysterny zmniejszaja sie podczas chlodów, jadna- Ikowoz kwestja obnizki temperatury gazoli- Iny ponizej jej puniktu wlrzenia pod cisnie- Iniem atmtostferycztyem posiada doniosle iznaczenie dla wsizysitkibh pór roku, celem izmmiejisizenia lwiskazana .truldnosc mozna zupelnie usunac iprizez oczyszczanie imaterjalu pod zmniej- tezonem cisnielniem. Pozwala to oczywiscie fetoisowac w kotlach temperature nizsza, (jak to widac ma fig. 1 zalaczjonego rysunku, Iwyobrazajacej wykres temperatury i ci- sniieniiia pary typowej gaiztoliny z gazu zle- lmnego pr zyczem w wykresie tym rzedne (wyrazaja w atm cislnienie w kolumnie, a fcdcfete — temperaittury w isJtopniach Celsju¬ sza, Nalezy zaznaczyc, ,ze iskotrc cisnienie Kv kolumnie .spadlnie ponizelj jednej atimio- sf-ery (bezfwzigjedlnie p^oniiizelj iziera cisnien na Iwyifercfsie), wyftWarza sie plyn, który mozna bezposrednio spuiszcziaic do naczyn 'Otwar- (Lych bez obawy strat parowania wsjkuitek Iwirzenia, i ze w miare dalszego ispadku ci- (slnifenia wytwarza sie plyn, o tym samym {zawsze skladnie i temperaturze tak ni- (skiej), zte przy bezposredniem przelewaniu Igo do opatrzonych otullina ciepliia cystern lnie zachodzi jakiekolwiek dostrfzegalttie pa¬ kowanie przez czas dluzszy, nawet gdy (temperatura atmosfery przekracza tempe- teatulre wrzenia plynu, \ Pnoces teri mozma prowadzic w najjrote- maitlszych aparatach, naprzylklaid we wiska- .zanym na fig. 2. Tuta)j kolumna tfektyfika- ?cyj|na 1 posiada kociol 2 zaopatrzony w tw^ezownice grzejna 3, manometr 4 i rury 5, (6 i 7, z których pierwsza dopirolwadza ciecz Ido kotla, druga — pare do kolumny, a [trzecia sluzy do tspu|sziczajnia gotowego pro¬ duktu. Podlegajaca! przeróbce mieszanina 'Weglowodorowa djoplywa przewodem 8 (przedewiszysitkiem do chlodnicy 9 nastejp- taiie poprzez lapke 10, pompe 11 i chlodni¬ ce poisreidlnia 12, lapke 13, pompe 14, chlod- Iniice konlcowa }5, naczynie 16 i parze wód J7 •ciecz splywa do czesbi górniej (kolumny pod 'cSfstóeniiem dkolo napfzyklad 56 kg, Plyn, gromadzacy sie w lapce 10 splywa prze- fwodefm 18 pod cis-nieniem lokolo 0,3 aitm (na dnio kolumny, a plyn z lapki 13 plrtzewo1- dem 19 .na poziom postedni kolumny pod taisnieniem naprzyklad .1,3 atm. Pozadana tóedopreznosc w kohumnie utrzymuje prze- fwiettfznik 20. Manorndtr 21 wtekazuije ci¬ snienie okolo 13 cm siupa rteci, a mainio- toetr 22 cisnienie 0,3 a|tm. Gaz wyzyskany, bdciagany z wierzcholka kolumny prze- wliietrzniilkiiiem 20, odlpllywia iczesciowio prze- lwodem 23 .nazewlnatlrz, czeslciowo zas ruta Q4 napowrót do obiegu, Spofcób i sikuitek idzialatnia aparatu sa zrozulmiale i nie wy- fmaigaja zadnych blilziszych wyjasnien. PLThe present invention relates to the easy preparation of liquefied hydrocarbon gases (condensable components) from mixtures of hydrocarbon gases and is intended to produce hydrocarbon fluids stable at ordinary temperatures and under pressure, so that they can be stored and transported without significant losses and in such an arrangement as to only one chemical compound is the major constituent of the fluid, and the residual gaseous material of the original mixture from which the fluid was made. For example, if the mixture (gas is a natural gas containing methane, ethane, propane and butane, and more the amount of hydrocarbons with a more complex molecular structure, and the liquid to be produced is to be a gas: - a rope with ordinary properties, the liquid half-liquid should contain only butane strands and compounds with a higher molecular weight, or the butane should be divided between the liquid and and gas. In the latter case, butane (urgently to be the only common compound of both factions (while when in the first region they have no connection. Hitherto, attempts have been made to achieve the indicated results by means of processes consisting in cleaning the liquid fraction. The invention of the rickshaw relates to a variant of the known method, in which the purification of the liquid fraction is effective under a pressure lower than that of the atmoisiform. In an example of an embodiment of one of the earlier methods, the rectification colloidal boiler is maintained at a temperature of 2 ° C. has / in teif temperatuirze a pressure of par (absolute) about 1.5 altim. Although the vapor pressure of this fluid is pressed against the atmosphere (and without a lift) in the external teimperaift, which prevails during the cloudy part of the year, this fluid can be, however, feathers - to be sucked in the covered cysts, wet cysts, even in the summer corresponding to that amount, the effect that can be vaporized by heat pitting through the walls of the cystenine; With adequate insulation, these losses are not significant. In order to reduce the pressure of the gasoline vapor below atmospheric pressure and thus prevent its boiling, its temperature should be reduced to 16 ° C or even lower. When the temperature of the boiler of the rectification apparatus is lower than the temperature of the atmosphere, the product flowing out of the boiler must be sufficiently cooled down with plasticization, otherwise it will boil, which causes considerable losses, and the teimiper of its temperature decreases during the injection. cisterns decrease during cold weather, eat- Ikowoz, the issue of lowering the temperature of gasoline below its boiling point under pressure- Iniem atmtostferycztyem is of great importance for the villages of several seasons, in order to minimize the pressure of the lion, it is possible to completely reduce the pressure and remove it completely. This, of course, allows for a lower temperature in the boilers (as can be seen in Fig. 1 of the enclosed drawing, I depicting the graph of temperature and vapor pressure of a typical gaiztoline from bad gas, in this graph it is orderly (they express the pressure in the column, and fcdcfete - temperaittury in iMelt Celsju¬sza, It should be noted that the pressure of the Kv column drops shortly below one atimiosphere (infinitely flames and takes the pressure on Iwyifercfsie), it can destroy the liquid immediately. - (Lych without fear of evaporation losses in the Iwirzenie capsule, and that as a result of a further fall in c- (slnifenia, a fluid is produced, with the same (always consistently and so low) temperature, yellow when Igo is directly poured into the tankers with thermal insulation provided there is any proof of long-term packing, even when (the temperature of the atmosphere exceeds the boiling point of the liquid, \ Pnoces teri may conduct a in the viscous apparatus shown in Fig. 2. Here, the tectification column 1 has a boiler 2 equipped with your heating coil 3, pressure gauge 4 and pipes 5, (6 and 7, the first of which leads the liquid to the boiler, the second - to the column, and the third is used to drain the finished product. Subject! The mixture is processed through the line 8 (pre-sewer to the cooler 9, then through the trap 10, pump 11 and the cooler 12, trap 13, pump 14, final cooler} 5, vessel 16 and steam J7 • the liquid flows to the upper section (columns under the cap around 56 kg, the liquid that accumulates in the trap 10 flows through the tube 18 under the pressure of 0.3 aitm (at the bottom of the column, and the liquid from the lip 13 and the left side 19. the column's postedni level under a pressure of, for example, 1.3 atm. The desired pressure in the cohumum maintains the air pressure factor of 20. Manorndtr 21 will add a pressure of about 13 cm of mercury, and the main pressure of 0.3 a | tm. Taken from the top of the column, it is airborne 20, it drags and partially through the conduit 23 externally, partially returns the Q4 route to circulation, the procedure and the pellets and the breathing room of the apparatus are sophisticated and do not flare up any blandness.

Claims (2)

Zastrzezenia patentowe. 1. Sposób wytwarzania ga^oliny z ga¬ zu ziemnego lufo podobnych mu mieiszanin - 2 —weglowacterolwych zapoiimoca kondensacji iskraplajacych sie zwiazków oraz oczy¬ szczania tychze celem oddzielenia od nich 'zwiazków zbyit lotnych, w rodzaju naiprzy- szczanie uskutecznia sie po|d cisnieniem fpoinizej atmosferycznego, co hatmuije paro¬ wanie gazoliny po odprowadzeniu jej z a- 'paraftu rektyfikacyjnego; 2, Sposób wedlug zastrz, 1, znaJmien- tei-e z aparatu rektyfikacyjnego bezposred¬ nio do opatrzonego otulina cieplna zbior¬ nika, Carbide and Carbon Chemicals Corporation. Zastepca?: M. Skrzyipkowiski, rzecznik patentowy. ^i^-_ fA 14 IZ 8 6 ? O -? -A L / / -ZS* €• '2.&a CO* ?7.S° *S° 4C.S* <&?*Do opisu patentowego Nr 4936. Ark.Patent claims. 1. The method of producing gas from natural gas or similar mixtures of carbonaceous organic compounds to prevent condensation of sparkling compounds and to purify them in order to separate volatile compounds from them, in the form of fastening, is effective under pressure atmospheric pressure, which ignores the evaporation of gasoline after it has been drained from the rectification paraffin; 2, The method of claim 1, alternating from the rectification apparatus directly to the provided thermal jacket of the vessel, Carbide and Carbon Chemicals Corporation. Deputy ?: M. Skrzyipkowiski, patent attorney. ^ i ^ -_ fA 14 IZ 8 6? ABOUT -? -A L / / -ZS * € • '2. & a CO *? 7.S ° * S ° 4C.S * <&? * To patent specification No. 4936. Sheet. 2. Druk L« Boguslawskiego, Warszawa. PL2. Print by L «Boguslawski, Warsaw. PL
PL4936A 1924-10-28 A method of producing gasoline and purifying hydrocarbon mixtures. PL4936B1 (en)

Publications (1)

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PL4936B1 true PL4936B1 (en) 1926-07-31

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