PL448582A1 - Sposób otrzymywania 1,1'-bis-(E)-(α,β-nienasyconych) karbonylowych pochodnych ferrocenu - Google Patents

Sposób otrzymywania 1,1'-bis-(E)-(α,β-nienasyconych) karbonylowych pochodnych ferrocenu

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Publication number
PL448582A1
PL448582A1 PL448582A PL44858224A PL448582A1 PL 448582 A1 PL448582 A1 PL 448582A1 PL 448582 A PL448582 A PL 448582A PL 44858224 A PL44858224 A PL 44858224A PL 448582 A1 PL448582 A1 PL 448582A1
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PL
Poland
Prior art keywords
ferrocene
unsaturated
bis
obtaining
carbonyl derivatives
Prior art date
Application number
PL448582A
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English (en)
Inventor
Włodzimierz Buchowicz
Mikołaj Ośmiański
Original Assignee
Politechnika Warszawska
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Politechnika Warszawska filed Critical Politechnika Warszawska
Priority to PL448582A priority Critical patent/PL448582A1/pl
Publication of PL448582A1 publication Critical patent/PL448582A1/pl

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)

Abstract

Przedmiotem zgłoszenia jest sposób otrzymywania 1,1′-bis-(Ε)-(α,β-nienasyconych) karbonylowych pochodnych ferrocenu charakteryzujący się tym, że przygotowuje się mieszaninę 1,1'-diformyloferrocenu oraz ketonu w rozpuszczalniku organicznym w stosunku molowym 1:2, następnie mieszaninę reakcyjną schładza się do temperatury 0°C i dodaje się zasadę, a całość miesza się w temperaturze pokojowej w czasie 1,5 - 24 h, po czym do mieszaniny reakcyjnej dodaje się roztwór kwasu solnego o stężeniu 0,8 - 1,2 M, zaś czysty produkt wyodrębnia się na drodze ekstrakcji oraz chromatografii kolumnowej.
PL448582A 2024-05-16 2024-05-16 Sposób otrzymywania 1,1'-bis-(E)-(α,β-nienasyconych) karbonylowych pochodnych ferrocenu PL448582A1 (pl)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL448582A PL448582A1 (pl) 2024-05-16 2024-05-16 Sposób otrzymywania 1,1'-bis-(E)-(α,β-nienasyconych) karbonylowych pochodnych ferrocenu

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL448582A PL448582A1 (pl) 2024-05-16 2024-05-16 Sposób otrzymywania 1,1'-bis-(E)-(α,β-nienasyconych) karbonylowych pochodnych ferrocenu

Publications (1)

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PL448582A1 true PL448582A1 (pl) 2025-01-07

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PL448582A PL448582A1 (pl) 2024-05-16 2024-05-16 Sposób otrzymywania 1,1'-bis-(E)-(α,β-nienasyconych) karbonylowych pochodnych ferrocenu

Country Status (1)

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PL (1) PL448582A1 (pl)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114671917A (zh) * 2022-01-10 2022-06-28 广东以色列理工学院 一种姜黄素类似物和制备方法及其在抗癌细胞增殖药物中的应用

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114671917A (zh) * 2022-01-10 2022-06-28 广东以色列理工学院 一种姜黄素类似物和制备方法及其在抗癌细胞增殖药物中的应用

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
AKIRA KASAHARA ET AL.: "Bulletin of the Chemical Society of Japan, Volume 45, Issue 3, March 1972, Pages 895–900, https://doi.org/10.1246/bcsj.45.895, abstract", THE PALLADIUM-CATALYZED FERROCENYLATION OF OLEFINS, DOI: Published: 27 March 2006, https://academic.oup.com/bcsj/article-abstract/45/3/895/7373101 *
SARHAN, ABDELWARETH A. O. ET AL.: "Monatshefte fuer Chemie (2009), 140(3), 315-323, DOI: 10.1007/s00706-008-0025-2", SYNTHESIS, CYCLIC VOLTAMMETRY, AND UV-VIS STUDIES OF FERROCENE-DITHIAFULVALENES AS ANTICIPATED ELECTRON-DONOR MATERIALS *

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