PL404175A1 - Nowa pochodna bis (2,2'-bitienylo) metanu i sposób jej wytwarzania, warstwa molekularnie wdrukowanego polimeru, sposób jej wytwarzania i jej zastosowanie do selektywnego wykrywania i oznaczania związków nitroaromatycznych - Google Patents

Nowa pochodna bis (2,2'-bitienylo) metanu i sposób jej wytwarzania, warstwa molekularnie wdrukowanego polimeru, sposób jej wytwarzania i jej zastosowanie do selektywnego wykrywania i oznaczania związków nitroaromatycznych

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PL404175A1
PL404175A1 PL404175A PL40417513A PL404175A1 PL 404175 A1 PL404175 A1 PL 404175A1 PL 404175 A PL404175 A PL 404175A PL 40417513 A PL40417513 A PL 40417513A PL 404175 A1 PL404175 A1 PL 404175A1
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Poland
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layer
methane
bitienyl
production
bis
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PL404175A
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English (en)
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PL223094B1 (pl
Inventor
Tan-Phat Huynh
Marta Sosnowska
Janusz Sobczak
K.C. Chandra Bikram
Vladimir N. Nesterov
Francis D'souza
Włodzimierz Kutner
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Instytut Chemii Fizycznej Polskiej Akademii Nauk
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Priority to PL404175A priority Critical patent/PL223094B1/pl
Priority to GB1409820.6A priority patent/GB2548540B/en
Publication of PL404175A1 publication Critical patent/PL404175A1/pl
Publication of PL223094B1 publication Critical patent/PL223094B1/pl

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    • C08F234/00—Copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain and having one or more carbon-to-carbon double bonds in a heterocyclic ring
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Abstract

Przedmiotem wynalazku jest nowa pochodna bis(2,2'-bitienylo)metanu, obejmująca bis(2,2'-bitienylo)-(4-aminofenylo)metan oraz sposób jej wytwarzania, polegający na tym, że wyjściowy roztwór 2,2'-bisbitiofenu i 4-acetaminobenzaldehydu w glikolu etylenowym poddaje się reakcji z kwasem nadchlorowym, w temperaturze w zakresie od 40 do 90°C. Ponadto wynalazek dotyczy warstwy molekularnie wdrukowanego polimeru (MIP) za pomocą związków nitroaromatycznych oraz sposobu jej wytwarzania, obejmującego etapy: (a) przygotowuje się roztwór, zawierający bis(2,2'-bitienylo)-(4-aminofenylo)metan jako monomer funkcyjny, tris([2,2'-bitiofen]-5-ylo)metan jako monomer sieciujący i związek nitroaromatyczny (NT) jako szablon, w rozpuszczalniku lub mieszaninie rozpuszczalników, w którym powstaje kompleks pre-polimeryzacyjny typu ?-? podstawnika aminofenylowego monomeru funkcyjnego z pierścieniem aromatycznym związku nitroaromatycznego (NT), (b) otrzymany kompleks pre-polimeryzacyjny poddaje się elektropolimeryzacji, osadzając go na elektrodzie, jako warstwę molekularnie wdrukowanego polimeru z wdrukowanym szablonem związku nitroaromatycznego (MIP-NT), (c) wdrukowany, w etapie (b), szablon związku nitroaromatycznego (NT) wyekstrahowuje się z tej warstwy MIP-NT, w wyniku czego powstaje warstwa MIP z nieobsadzonymi wdrukowanymi wnękami molekularnymi. Wynalazek dotyczy też zastosowania tej warstwy wdrukowanego polimeru, jako elementu rozpoznającego czujnika chemicznego do selektywnego wykrywania i oznaczania związków nitroaromatycznych, zwłaszcza takich jak 2,4,6-trinitrofenol (TNP), 2,4,6-trinitrotoluen (TNT), 1,3,5-trinitrobenzen (TNB) i 2,4-dinitrotoluen (DNT).
PL404175A 2013-06-03 2013-06-03 Nowa pochodna bis(2,2'-bitienylo)metanu i sposób jej wytwarzania, warstwa molekularnie wdrukowanego polimeru, sposób jej wytwarzania i jej zastosowanie do selektywnego wykrywania i oznaczania związków nitroaromatycznych PL223094B1 (pl)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PL404175A PL223094B1 (pl) 2013-06-03 2013-06-03 Nowa pochodna bis(2,2'-bitienylo)metanu i sposób jej wytwarzania, warstwa molekularnie wdrukowanego polimeru, sposób jej wytwarzania i jej zastosowanie do selektywnego wykrywania i oznaczania związków nitroaromatycznych
GB1409820.6A GB2548540B (en) 2013-06-03 2014-06-03 Bis(2,2-bithienyl)methane derivate; molecularly imprinted polymer film; and associated methods of production and use thereof

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PL404175A PL223094B1 (pl) 2013-06-03 2013-06-03 Nowa pochodna bis(2,2'-bitienylo)metanu i sposób jej wytwarzania, warstwa molekularnie wdrukowanego polimeru, sposób jej wytwarzania i jej zastosowanie do selektywnego wykrywania i oznaczania związków nitroaromatycznych

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PL404175A1 true PL404175A1 (pl) 2014-12-08
PL223094B1 PL223094B1 (pl) 2016-10-31

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL446124A1 (pl) * 2023-09-16 2025-03-17 Uniwersytet Śląski W Katowicach 2-(2-tienyloetynylo)-3-(2-tienylo)-1,4-dimetylonaftalen oraz sposób jego otrzymywania

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110038532A (zh) * 2018-01-16 2019-07-23 南京理工大学 吸附2,4-二硝基甲苯的分子印迹纳米纤维膜及其制备方法
CN115677530B (zh) * 2022-10-25 2023-12-29 昆明学院 一种卤代希夫碱Zn(II)配合物Zn-χ-L及其制备方法与应用
CN118771540B (zh) * 2024-06-14 2025-11-04 南京大学 一种分子印迹聚合物电催化极板及其制备方法与应用

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101738423A (zh) * 2008-11-13 2010-06-16 华东师范大学 一种分子印迹聚合物/碳纳米管/基底电极修饰电极及其应用
US20140220704A1 (en) * 2011-08-03 2014-08-07 The Johns Hopkins University Articles comprising templated crosslinked polymer films for electronic detection of nitroaromatic explosives
PL220926B1 (pl) * 2012-02-29 2016-01-29 Inst Chemii Fizycznej Polskiej Akademii Nauk Pochodne tiofenu, molekularnie wdrukowany polimer zawierający spolimeryzowaną pochodną tiofenu i zastosowanie tego polimeru do selektywnego oznaczania i kontrolowanego uwalniania adenozyno-5'-trifosforanu (ATP)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL446124A1 (pl) * 2023-09-16 2025-03-17 Uniwersytet Śląski W Katowicach 2-(2-tienyloetynylo)-3-(2-tienylo)-1,4-dimetylonaftalen oraz sposób jego otrzymywania
PL248626B1 (pl) * 2023-09-16 2026-01-05 Uniwersytet Śląski W Katowicach 2-(2-tienyloetynylo)-3-(2-tienylo)-1,4-dimetylonaftalen oraz sposób jego otrzymywania

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GB2548540A (en) 2017-09-27
GB2548540B (en) 2020-03-04
PL223094B1 (pl) 2016-10-31
GB201409820D0 (en) 2014-07-16

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