PL3570B1 - A method of producing objects from metals with a high melting point, such as tungsten, in the form of rods, blocks or other, consisting of very large crystals. - Google Patents

A method of producing objects from metals with a high melting point, such as tungsten, in the form of rods, blocks or other, consisting of very large crystals. Download PDF

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Publication number
PL3570B1
PL3570B1 PL3570A PL357025A PL3570B1 PL 3570 B1 PL3570 B1 PL 3570B1 PL 3570 A PL3570 A PL 3570A PL 357025 A PL357025 A PL 357025A PL 3570 B1 PL3570 B1 PL 3570B1
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PL
Poland
Prior art keywords
rods
tungsten
melting point
metals
blocks
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Application number
PL3570A
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Polish (pl)
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Publication date
Application filed filed Critical
Publication of PL3570B1 publication Critical patent/PL3570B1/en

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Description

Wynalazek odnosi sie do sposobu wy¬ robu przedmiotów w postaci pretów, klo¬ ców lub innej, skladajacych sie z bardzo wielkich krysztalów, z takich metali, o wy¬ sokim punkcie topliwosci, jak wolfram.Podlug znanego sposobu wyrabia sie prety wolframowe przez prasowanie proszku wol¬ framowego; tak otrzymamy pret ogrzewa sie do temperatury okolo 1000°, a dalej zapo- moca pradu elektrycznego, przez czas ja¬ kis, do temperatury lezacej tuz ponizej je¬ go punktu topliwosci, przez co pret nabie¬ ra takiego stopnia zwartosci, ze mozna go obrabiac mechanicznie.Prety tak otrzymane wykalzuja bardzo drobna strukture krystaliczna. Niekiedy jednak nalezy wykonac prety, których struktura krystaliczna nie jest drobna, a sklada sie z krysztalów o wielkosci wspól¬ miernej, a nawet wiele wieksizej, anizeli srednica preta. Celem ulatwienia tworze¬ nia sóe wielkich krysztalów proponowano juz przeprowadzanie procesu spiekania sie w atmosferze zawierajacej male ilosci pa¬ ry wodnej luib tleniu. Fiinma zglaszajaca wykryla jednak, ze mozna i w inny spoisób otrzymac prety skladajace sie z bardzo wielkich krysztalów. Okazalo sie mianowi¬ cie, ze cisnienie, pod którem prasuje sie prosizek metaliczny, ma bardzo wielki wplyw nai przyrost krysztalów pod¬ czas procesu spiekania i, ze w szczególno¬ sci istnieje pewnie okreslone cisnienie, pod którem prasojwiatno proszek wolframowy aS mianowicie teikfe, ze cdpowiaidja mu, pod¬ czas pnocesiU' spiekania, miaximum przyro^ yifJkryszftaló^ |f ^rzyn^yw|&^ sie z bardzo wielkich krysztalów pretowi, klocy i t- d, z wysiofco topliiwejgo melallu, jak wolframu, polega na tern, ze proszek metaliczny pra¬ suje sie pod talkfam cisnieniem', azeby przy spiekaniu powstawaly krysiztlaly, których wymiary przewyzsza!ja 1 cm.Przyklad wykonania, opisany ponizej, dokladnie -wyjasnia ten wynailiazek.Wychodzac z prosizku wolfnairnowlegK), skladaj apego siie z ziarn o wielkosci w 8% od 10 — 20 mikroniów, iw; 35% od 1 — 10 mikronów, w 26% od 3 —'6 nAronów i w 31% ponizej 3 mikronów, otrzymuje sie, po procesie spiekania, pret o strukturze krystailJczniej bardzo drobnej, jezeli sie prasowalo pod cisnienieim 340 kg na cm2 i o grubszej strukturze krystalicznej z po¬ jawiajacym sile tu i owdzie wiekszym krysiztalem, jezeli prasowano pod cisnie- niem 680 k|g na cm2, zajs krysiztialy o maJ- ksymialnej wielkosici (w wymiarach centy¬ metrów), jezeli sie prasowalo pod cisnie¬ niem 884 kg na cni2; natomiast przy cisnie¬ niu 1020 kg na cm2 wielkosc krysztalów znowu spada, a przy cisnilenSu 1224 kg na cm2 struktura krystaliczna jest jeszcze drobniejsza. Na krzywej przedstawiajacej wielkosc krysztalów, jako funkcje cisnie¬ nia przy praisowaniu, maximum lezy w o- kolicy 884 kg mai c*n2. Maadimium to zalez¬ ne jest od rodizaju proszku wolframowego, jakiego sie uzywa do wyrobu; jest jednak rzecza laltwa oznaczyc dla kazdego rodza¬ ju proszku metalowego maxiimum wielko¬ sci krysztallu nia wyzej wspomnilalnej krzy¬ wiej.Podlug opisanego spoaobu mozna otrzy¬ mywac wyroby w postaci pretów lub innej, zawierajace krysztaly o znacznej dlugosci. PLThe invention relates to a process for the production of rods, blocks or other objects, consisting of very large crystals, of metals with a high melting point, such as tungsten. In a known process, tungsten rods are made by compressing the powder. tungsten; in this way, the rod is heated to a temperature of about 1000 °, and then by an electric current, for some time, to a temperature just below its melting point, so that the rod becomes so compact that it can be processed mechanically. The thus obtained particles show a very fine crystal structure. Sometimes, however, it is necessary to make bars, the crystal structure of which is not fine, and consists of crystals of a commensurate size, and even much larger than the diameter of the bar. It has already been proposed to carry out the sintering process in an atmosphere containing a small amount of water vapor or smoldering to facilitate the formation of salt of large crystals. The submitter has discovered, however, that it is possible to obtain rods consisting of very large crystals in another way. It turned out that the pressure under which the metallic piglet is pressed has a very great effect on the crystal growth and growth during the sintering process and that, in particular, there is a certain pressure under which the tungsten powder is very bright, namely the cdpowiaidja mu, during midnight sintering, the miaximum increment of ^ yifJcrystalline ^ | f ^ f ^ y ^ yw | & ^ is made of very large crystals, rods, logs, etc. The metallic powder is pressed under pressure, so that when sintering, crystals are formed, the dimensions of which exceed 1 cm. An example of execution, described below, exactly - explains this exaggeration. in 8% from 10-20 microns, and in; 35% from 1 - 10 microns, in 26% from 3-6 nArons and in 31% below 3 microns, after the sintering process, a rod with a crystalline structure is obtained, even very fine, if pressed under a pressure of 340 kg per cm2 and with a coarser structure crystalline with an exhilarating force here and there, more crystalline, if pressed under a pressure of 680 kg per cm2, crystallites of a maximum size (in centimeters), if pressed under a pressure of 884 kg per cm2 cni2; whereas, at a pressure of 1020 kg per cm 2, the crystal size drops again, and at a pressure of 1224 kg per cm 2, the crystal structure is even finer. In the curve showing the size of the crystals as a function of pressure during pressing, the maximum lies in the circle of 884 kg ma and c * n2. This maadimium depends on the type of tungsten powder that is used in the product; However, it is a matter of course for each type of metal powder to determine the maximum crystal size of the above-mentioned curve. By the method described, it is possible to obtain products in the form of rods or other products, containing crystals of considerable length. PL

Claims (1)

1. Zastrzezenie patentowe. Sposób wyrobu przedmiotów w postaci pretów, kloców lub innej, skladajacych sie z bardzo wielkich krysztalów, z takich me¬ tali o wysokim punkcie topliwosci jak wol¬ fram, znamienny tern, ze proszek metalicz¬ ny prasuje sie pod takiem cisnieniem, aze¬ by przy spiekaniu powstawaly krysztaly o wymiaralchi wiekszych niz 1 cm. N. V. Philips' Gloeilampenfabrieken Zastepca: W. Suchowiak, rzecznik patentowy Druk L. Boguslawskiego, Warszawa. PL1. Patent claim. A method of making objects in the form of rods, blocks or other, consisting of very large crystals, from metals with a high melting point such as tungsten, characterized by the fact that the metallic powder is pressed under such pressure as to by sintering, crystals with dimensions greater than 1 cm were formed. N. V. Philips' Gloeilampenfabrieken Deputy: W. Suchowiak, patent attorney Druk L. Boguslawski, Warsaw. PL
PL3570A 1925-04-18 A method of producing objects from metals with a high melting point, such as tungsten, in the form of rods, blocks or other, consisting of very large crystals. PL3570B1 (en)

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PL3570B1 true PL3570B1 (en) 1926-01-30

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