PL3558512T3 - Sposób ciągłej syntezy elastomeru dienowego z inicjatorem amidkiem litu - Google Patents

Sposób ciągłej syntezy elastomeru dienowego z inicjatorem amidkiem litu

Info

Publication number
PL3558512T3
PL3558512T3 PL17816896T PL17816896T PL3558512T3 PL 3558512 T3 PL3558512 T3 PL 3558512T3 PL 17816896 T PL17816896 T PL 17816896T PL 17816896 T PL17816896 T PL 17816896T PL 3558512 T3 PL3558512 T3 PL 3558512T3
Authority
PL
Poland
Prior art keywords
diene elastomer
lithium amide
continuous synthesis
amide initiator
initiator
Prior art date
Application number
PL17816896T
Other languages
English (en)
Inventor
Charlotte Dire
Marie-Hélène DESSENDIER
Original Assignee
Compagnie Générale Des Etablissements Michelin
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Compagnie Générale Des Etablissements Michelin filed Critical Compagnie Générale Des Etablissements Michelin
Publication of PL3558512T3 publication Critical patent/PL3558512T3/pl

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/04Polymerisation in solution
    • C08F2/06Organic solvent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053Details of the reactor
    • B01J19/0066Stirrers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18Stationary reactors having moving elements inside
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • C08C19/22Incorporating nitrogen atoms into the molecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • C08C19/30Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
    • C08C19/42Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
    • C08C19/44Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06Butadiene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/01Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/42Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using short-stopping agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/44Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F36/06Butadiene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • B01J2219/00027Process aspects
    • B01J2219/00033Continuous processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • B01J2219/00027Process aspects
    • B01J2219/0004Processes in series
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00164Controlling or regulating processes controlling the flow
    • B01J2219/00166Controlling or regulating processes controlling the flow controlling the residence time inside the reactor vessel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00274Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
    • B01J2219/00277Apparatus
    • B01J2219/00279Features relating to reactor vessels
    • B01J2219/00306Reactor vessels in a multiple arrangement
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00274Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
    • B01J2219/00718Type of compounds synthesised
    • B01J2219/0072Organic compounds
    • B01J2219/00736Non-biologic macromolecules, e.g. polymeric compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
PL17816896T 2016-12-21 2017-12-20 Sposób ciągłej syntezy elastomeru dienowego z inicjatorem amidkiem litu PL3558512T3 (pl)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1663002A FR3060578A1 (fr) 2016-12-21 2016-12-21 Procede de synthese en continu d'elastomere dienique avec initiateur amidure de lithium
EP17816896.9A EP3558512B1 (fr) 2016-12-21 2017-12-20 Procédé de synthèse en continu d'élastomère diénique avec initiateur amidure de lithium
PCT/EP2017/083894 WO2018115165A1 (fr) 2016-12-21 2017-12-20 Procédé de synthèse en continu d'élastomère diénique avec initiateur amidure de lithium

Publications (1)

Publication Number Publication Date
PL3558512T3 true PL3558512T3 (pl) 2022-01-10

Family

ID=58347610

Family Applications (1)

Application Number Title Priority Date Filing Date
PL17816896T PL3558512T3 (pl) 2016-12-21 2017-12-20 Sposób ciągłej syntezy elastomeru dienowego z inicjatorem amidkiem litu

Country Status (7)

Country Link
US (1) US11059914B2 (pl)
EP (1) EP3558512B1 (pl)
JP (1) JP7073381B2 (pl)
KR (1) KR102474316B1 (pl)
FR (1) FR3060578A1 (pl)
PL (1) PL3558512T3 (pl)
WO (1) WO2018115165A1 (pl)

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4843120A (en) * 1986-09-29 1989-06-27 The Goodyear Tire & Rubber Company Rubber composition
US5272220A (en) * 1992-09-14 1993-12-21 The Goodyear Tire & Rubber Company Process for preparing styrene-isoprene-butadiene rubber
US5405927A (en) * 1993-09-22 1995-04-11 The Goodyear Tire & Rubber Company Isoprene-butadiene rubber
JP3625919B2 (ja) * 1995-10-16 2005-03-02 株式会社ブリヂストン 重合体の製造方法
US6313216B1 (en) * 2000-09-01 2001-11-06 The Goodyear Tire & Rubber Company Synthesis of styrene-isoprene rubber
US6515087B2 (en) * 2000-12-14 2003-02-04 The Goodyear Tire & Rubber Company Synthesis of elastomers having low hysteresis
JP4655706B2 (ja) 2005-03-17 2011-03-23 住友化学株式会社 変性ジエン系重合体ゴム及びその製造方法
ITMI20060385A1 (it) * 2006-03-03 2007-09-04 Polimeri Europa Spa Procedimento in continuo per la preparazione di copolimeri randon dieni coniugati-vinil areni
JP5756248B2 (ja) * 2008-04-28 2015-07-29 株式会社ブリヂストン タイヤ
TW201211083A (en) * 2010-06-15 2012-03-16 Styron Europe Gmbh Low vinyl styrene-butadiene polymers and methods of making the same
US20120245275A1 (en) 2011-01-24 2012-09-27 Sumitomo Chemical Company, Limited Process for producing conjugated diene-based polymer, conjugated diene-based polymer, and conjugated diene-based polymer composition
ES2596368T3 (es) * 2012-03-20 2017-01-09 Trinseo Europe Gmbh Composiciones de polímeros modificados
HUE033462T2 (en) * 2012-09-14 2017-12-28 Trinseo Europe Gmbh Amino silane modified polymers
FR3009556B1 (fr) 2013-08-08 2015-07-31 Michelin & Cie Procede de synthese en continu d'un elastomere dienique modifie, installation pour sa mise en oeuvre.
FR3009560B1 (fr) 2013-08-08 2018-01-05 Compagnie Generale Des Etablissements Michelin Elastomere dienique modifie par couplage porteur de fonctions silanol, son procede de synthese et composition de caoutchouc le comprenant.
FR3009557B1 (fr) 2013-08-09 2015-09-11 Michelin & Cie Elastomere dienique modifie comprenant un elastomere dienique couple par un compose aminoalcoxysilane et fonctionnalise amine en extremite de chaine et composition de caoutchouc le comprenant
FR3011241B1 (fr) 2013-09-27 2015-10-23 Michelin & Cie Elastomere dienique tribloc dont le bloc central est un bloc polyether et fonctionnalise amine en extremite de chaine
FR3012454B1 (fr) 2013-10-30 2015-12-18 Michelin & Cie Elastomere dienique modifie comprenant majoritairement un elastomere dienique couple par un compose alcoxysilane portant un groupe epoxyde et fonctionnalise amine en extremite de chaine
KR101865796B1 (ko) * 2017-01-03 2018-06-11 주식회사 엘지화학 변성 공액디엔계 중합체 및 이를 포함하는 고무 조성물

Also Published As

Publication number Publication date
JP7073381B2 (ja) 2022-05-23
EP3558512B1 (fr) 2021-07-21
EP3558512A1 (fr) 2019-10-30
US20190352432A1 (en) 2019-11-21
US11059914B2 (en) 2021-07-13
WO2018115165A1 (fr) 2018-06-28
KR20190100947A (ko) 2019-08-29
JP2020514454A (ja) 2020-05-21
FR3060578A1 (fr) 2018-06-22
KR102474316B1 (ko) 2022-12-08

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