PL3546B1 - A method of obtaining turpentine, resin glue and other products from pine trunks. - Google Patents
A method of obtaining turpentine, resin glue and other products from pine trunks. Download PDFInfo
- Publication number
- PL3546B1 PL3546B1 PL3546A PL354623A PL3546B1 PL 3546 B1 PL3546 B1 PL 3546B1 PL 3546 A PL3546 A PL 3546A PL 354623 A PL354623 A PL 354623A PL 3546 B1 PL3546 B1 PL 3546B1
- Authority
- PL
- Poland
- Prior art keywords
- turpentine
- obtaining
- pine
- products
- resin acids
- Prior art date
Links
- 239000011347 resin Substances 0.000 title claims description 12
- 229920005989 resin Polymers 0.000 title claims description 12
- 241000779819 Syncarpia glomulifera Species 0.000 title claims description 11
- 239000001739 pinus spp. Substances 0.000 title claims description 11
- 229940036248 turpentine Drugs 0.000 title claims description 11
- 238000000034 method Methods 0.000 title claims description 10
- 239000003292 glue Substances 0.000 title claims description 9
- 235000008331 Pinus X rigitaeda Nutrition 0.000 title claims description 5
- 235000011613 Pinus brutia Nutrition 0.000 title claims description 5
- 241000018646 Pinus brutia Species 0.000 title claims description 5
- 239000002253 acid Substances 0.000 claims description 7
- 150000007513 acids Chemical class 0.000 claims description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 5
- 238000000926 separation method Methods 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 238000001704 evaporation Methods 0.000 claims description 2
- 230000008020 evaporation Effects 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000000243 solution Substances 0.000 claims 2
- 239000007864 aqueous solution Substances 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 239000000565 sealant Substances 0.000 claims 1
- 239000007788 liquid Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 241000514695 Halocarpus bidwillii Species 0.000 description 1
- 241000282320 Panthera leo Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Description
V Wszelkie dotychczas stosowalne sposoiby otrzymywania zywicy z pni .sosnowych, po¬ legajace na wyciaganiu benzyna lub benzo¬ lem, okalzialy isie w praktyce zawodnenii, po- nijewaz najcenniejszy produkt, t, j. terpen¬ tyna zostaje zanieczyszczona plynem wy¬ ciagajjacym w tak znacznym stopniu, ze na¬ wet bardzo staranna rektyfikacja nie po¬ zwala naj calkowite oddzielenie plynu wy¬ ciagajacego od teifpenjtyny. Ottrzymywana przez wyciaganie zywice (kalafonje) trzeba poddac dalszej przeróbce, chcajc z niej o- trzymac klej zywiczny papierniczy.Sposób nizej opisany pozwala otrzymy¬ wac w przeciagu 5-u godzin z drzewa pni sosnowych klej papierniczy oraz terpenty¬ ne odrazai idealnie czysta i bezbarwna. Po¬ lega on na tern, ze odpowiednio mechanicz¬ nie przygotowane drzewo umieszcza ®va w dyfuzorze w roizczynie sody i gotuje pod cisnieniem do chwili zupelnego wydzielenia sie terpentyny, która odprowadza sie.do Sipecjalnych aparatów, w celu oddzielenia jej od wody. Otrzymany w ten sposób produkt jest odrazu idealnie czysty i bezbarwny.Wydajnosc terpentyny otrzymywanej tym sposobem jest znaiczmie wiiekszai, niz przy destylacji para, a to z tej przyczyny, ze so¬ da, wiazac kwasy zywiczne, ulatwila wy¬ dzielenie sie z zywicy terpentyny. Drzewo smolne, gotowane w rozczynie lugu siodlowe¬ go (NaOH), wydzieli wprawdzie równiez te same ilosci terpentyny, z ta jednak róznica, ze otrzymana terpentyna bedzie miala za¬ pach nader przykry, czego o terpentynie, o- trzymanej niniejszym sposobem, powiedziecnie mjazaa. Po zupelmem wydzieleniu sie terpentyny,, opróznial sie dyfuizor z plynu. ciernno4):ronzowegjo, zawierajacego lgwiasy zywiczne jiuz nalezycie zwiazane oraz roz¬ puszczane czesciowo lnlkruisitacje drzewne.Do plynu tego dodaje sie mozliwie stezony roztwór lugu potasowego lub sodowego, któ¬ ry, jako siilaiiejszai zasaida od sody, naftych- miiatsit scina juz poprzednio zwiajzane kwasy zywiczne, które, jako ciezsze od plynu, o- padaja na d*u zfeiforafliba.W ten sposób unika -sie uciazliwej de- kantacji zwiazanych .sanna tylko soda kwa¬ sów zywicznych, które sie wtedy przedsta- wiajja miulowato,, i skutkiem tego zle sie de- kantuja.Sposób opisany ussuwal powyzsza niedo¬ kladnosc i dajje moznosc otrzymywania od- razu produktiu czystego, poniewaz sciety Lu¬ giem klej zywiczny zawiera bamdzo malo do¬ mieszki plynu, z którego sie go wytraca. A- zeby usunac resztki plynu, pozostajacego po dekaoiiowajniiiu,,, nalezy klej malezycie od¬ wirowac. Po odwirowaniu nalezy go zobo¬ jetnic ii ewenttuailnie bielic.Pozostale wylugowane drzewo przedsta¬ wia znakomity surowiec do mechanicznej fa¬ brykacji tektury drzewnej. Nalezy je w tym celu przepuscic przez mlyny i prasowac.Plyn, z któregjo wytracono klej zywicz¬ ny, zawiera znaczne ilosci sody; sode te na¬ lezy przez parowanie oddzielic. Zbierajaca sie przy tym procesie w parowniku hromzo- wia masa, krzepnaca w temperaturze poko¬ jowej (rozpuszczone inkrustacje i t. d.), ma wlasciwosc fozpusizczainia sie w wodzie, to¬ pi sie w cieple i jest przytem latwopalna.Wlasciwosci te pozwalaja ja uzyc, jako do¬ mieszke, zamiast drogiego kleju do ciem¬ nych farb „klejowych" hub do wyrobu laku.Sposób wyzej opisany odznacza; sie szyb¬ koscia oraz tern, ze nie pozostawia zadnych nieuzytków* PLV Any hitherto applicable methods of obtaining resin from pine trunks, involving the extraction of gasoline or benzol, have proved to be unreliable in practice, because the most valuable product, i.e. terpentin, becomes contaminated with the liquid pulling it. to a large extent that even a very careful rectification does not allow for complete separation of the extracting fluid from the teifpenithin. Resin (rosin) obtained by removing it must be further processed, in order to obtain paper resin glue from it. The method described below allows to obtain paper glue and turpentine from pine trunks within 5 hours, which is perfectly clean and colorless . It is based on the fact that a suitably mechanically prepared tree is placed in a diffuser in a baking soda solution and boiled under pressure until turpentine is completely released, which is drained into special devices in order to separate it from the water. The product obtained in this way is immediately perfectly clear and colorless. The yield of turpentine obtained in this way is significantly greater than that of steam distillation, and this is because sodium, by binding the resin acids, facilitates the separation of turpentine from the resin. Tarwood, boiled in a solution of saddle (NaOH), will also give off the same amounts of turpentine, with the difference, however, that the resulting turpentine will have a very unpleasant smell, which the turpentine in this method was told . After the turpentine was released, the diffuser emptied of the liquid. thornness4): ronzowegjo, containing resinous lions jiuz duly bound and partially dissolved solid wood cruisitations. To this liquid is added possibly a concentrated solution of potassium or sodium liquor, which, as a strength and binds it with the previously bound kerosene acids, resins, which, as they are heavier than liquid, fall on the bottom of the feiforaflib, thus avoiding the burdensome decantation of only soda of the resin acids, which then appear softly and thus They decompose badly. The method described above eliminates the above-mentioned incoherence and makes it possible to obtain a pure product immediately, because the resinous glue, which is cut off, contains very little admixture of the liquid from which it is drawn off. In order to remove the remnants of the liquid that remains after decaying, the glue should be centrifuged slightly. After centrifugation, it should be whitewashed and possibly whitewashed. The remaining leached tree is an excellent raw material for mechanical corrugation of wood cardboard. To do this, they must be passed through mills and pressed. The liquid from which the resin glue has been lost, contains considerable amounts of soda; These soda should be separated by evaporation. The mass that accumulates in the evaporator during this process, solidifies at room temperature (dissolved incrustations, etc.), has the property of phosphorus in water, melts in warmth and is also flammable. These properties allow it to be used as a hub, instead of the expensive glue for dark glue paints, a hub for the production of lacquer. The method described above is quick and easy, so that it does not leave any waste.
Claims (3)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL3546B1 true PL3546B1 (en) | 1926-01-30 |
Family
ID=
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2057117A (en) | Process of making vanillin | |
| DE2202707B2 (en) | Process for the extraction and further processing of organic substances from the waste liquors resulting from the digestion of lignocellulose-containing material | |
| KR20010006114A (en) | Separating Lignin Solids and Black Liquor | |
| PL3546B1 (en) | A method of obtaining turpentine, resin glue and other products from pine trunks. | |
| CN104356946A (en) | Method for leaching rosin and heavy oil by crushing rosin residues | |
| CN101589134B (en) | Additives for increasing the separation yield of tall oil soap in black liquor | |
| US930274A (en) | Method of treating wood during distillation. | |
| CN1073352C (en) | Solid resin soap emulsifiable concentrate and its production | |
| CN104211596A (en) | Preparation method of rosin acid | |
| Baumassy | Pine Chemicals Industry Global Overview and Trends | |
| Nolte et al. | Grapefruit seed oil manufacture and physical properties | |
| US4256628A (en) | Sulfur-free acidulation of tall oil soap | |
| US2891046A (en) | Methods of processing and refining crude chemical fractions obtained from bark | |
| Palmer | Turpentine and rosin from wood wastes by the steam and solvent process | |
| WO2004074415A1 (en) | Crude tall oil recovery in alkaline pulp mills | |
| US2880216A (en) | Process of separating a crude composition obtained from bark into its component parts | |
| US3138580A (en) | Process for recovery of fat-resin constituents from black liquor | |
| US3560536A (en) | Fractionation of alkaline extracts of tree barks | |
| FI115228B (en) | Procedure for streamlining soap removal from black liquor | |
| US2395283A (en) | Method of treating crude kraft soap | |
| DE234223C (en) | ||
| Bray et al. | List of References to the Literature on Tall Oil (tallol, Liquid Rosin, Pine Oil Or Black Liquor Soap) | |
| Penninger | Extraction of oily matter from spent bleaching earth with water at elevated temperature and pressure | |
| US903471A (en) | Process of producing terpenes from wood. | |
| DE1517212C (en) | Process for the recovery of chemicals |