PL25614B1 - Method for producing zinc from metallic zinc dust. - Google Patents
Method for producing zinc from metallic zinc dust. Download PDFInfo
- Publication number
- PL25614B1 PL25614B1 PL25614A PL2561436A PL25614B1 PL 25614 B1 PL25614 B1 PL 25614B1 PL 25614 A PL25614 A PL 25614A PL 2561436 A PL2561436 A PL 2561436A PL 25614 B1 PL25614 B1 PL 25614B1
- Authority
- PL
- Poland
- Prior art keywords
- zinc
- dust
- metal
- metallic
- producing
- Prior art date
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- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims description 12
- 239000011701 zinc Substances 0.000 title claims description 9
- 229910052725 zinc Inorganic materials 0.000 title claims description 8
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 239000002184 metal Substances 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 3
- 210000005045 desmin Anatomy 0.000 claims 1
- 239000000428 dust Substances 0.000 description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- 239000004484 Briquette Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- -1 for example Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- HSYFJDYGOJKZCL-UHFFFAOYSA-L zinc;sulfite Chemical compound [Zn+2].[O-]S([O-])=O HSYFJDYGOJKZCL-UHFFFAOYSA-L 0.000 description 1
Description
W przypadku przerabiania pylu, np. py- talowy plucze sie kwasem, np. kwasem sol- lu cynkowego na cynk, przylegajace tlenki nym albo siarkowym, przez co z jednej utrudniaja spajanie sie czesto mikroskopij- stromy usuwa sie przylegajacy tlenek, z dru- nie malych czastek metalowych przy sta- giej zas pyl metalowy zamienia sie cze¬ pianiu w takim stopniu, ze wydajnosc wy- sciowo w gabke metalowa. Te gabke meta- nosi zaledwie 60 — 80% w stosunku do py- Iowa w stanie mokrym prasuje sie na bry¬ lu metalowego. Wszystkie uzywane dotych- kiety, dzieki czemu zapobiega sie utlenia- czas sposoby polegaja na tym, ze usuwa niu metalu przez zmniejszenie do minimum sie najpierw wlasnie ten tlenek albo me- ilosci powietrza, zawartego miedzy po- chanicznie, albo tez za pomoca salmiaku szczególnymi czastkami metalu. Tak otrzy- (NH^Cl), wskutek czego pozostale czastki mane brykiety metalowe stapia sie pod metalowe latwiej lacza sie przy stapianiu, przykrywajaca warstwa topnika, np. sal- Wedlug wynalazku niniejszego pyl me- miaku.Potózej podamy jje&t przyklad wykona¬ nia1 sposobu wedlug wynalazku. Pyl cynko¬ wy, pochodzacy z destylacji cynku, opada¬ jacy- w mikroskop!jflie malych ziarnkach metalowych, zawiera okolo 5% Zn w po¬ staci tlenku cynku. Pyl ten zostaje w ka¬ dzi rozbeltany z woda, po czym do kadzi wpuszcza sie mieszajac kwas solny lub siar¬ kowy wzglednie inny kwas w ilosci, dosto¬ sowanej do ilosci tlenku cynkowego. Gdy ciecz jest juz prawie obojetna, pompuje sie ja do kadzi posredniej, a pozostala gabke metalowa wymywa sie i doprowadza do prasy brykietowej. Pozostala ciecz stosuje sie nastepnie do rozbeltania swiezego pylu.Nastepnie dodaje sie te sama ilosc kwasu jak poprzednio, pompuje znowu do kadzi posredniej, a pozostala gabke metalowa doprowadza do prasy i t. d. Ciecz jest uzy¬ wana tak dlugo, az osiagnie sie stezenie cynku, umozliwiajace uzycie-go do innych celów, np. do elektrolizy cynku, do wyrobu litoponu (bieli), chlorku cynku, lub doi wy¬ twarzania siarczynu cynku, tlenku cynku i t. d. Prasowane brykiety z gabki metalo¬ wej suszy sie, a nastepnie stapia pod przy¬ kryciem, np. salmiaku, w piecach stosowa¬ nych normalnie do przetapiania cynku.Roztopiony metal odlewa sie do form. PLIn the case of processing dust, for example, dust is rinsed with an acid, for example with the acid of zinc salt to zinc, adhering oxides of nium or sulfuric acid, which impede bonding from one of them, often microscopic, the adhering oxide is removed from the other of small metal particles, but the metal dust is transformed into foam to such an extent that the efficiency is limited to a metal sponge. This metal sponge is only 60-80% of the dust in a wet state and is pressed on a metal body. All the previously used methods, thanks to which oxidation is prevented, are based on the fact that the removal of the metal by minimizing this oxide first or the amount of air contained between mechanically, or with the help of ammonium chloride with special particles metal. In this way, (NHCl) is obtained, as a result of which the remaining particles of mane metal briquettes melt under the metal briquettes more easily fuse on fusing, the covering flux layer, e.g. sal- According to the present invention, flour dust. Then we will give an example of the implementation of the method according to the invention. The zinc dust from the distillation of zinc falling under the microscope as small metal grains contains about 5% of Zn in the form of zinc oxide. This dust is pelleted with water in the tank, and then, by stirring, hydrochloric or sulfuric acid, or another acid, in an amount adjusted to that of zinc oxide, is introduced into the tank. When the liquid is almost inert, it is pumped to the tundish, and the remaining metal sponge is washed away and fed to the briquette press. The remaining liquid is then used to defuse the fresh dust, then the same amount of acid is added as before, it is pumped again into the tundish and the remaining metal sponge is fed to the press and hence the liquid is used until a zinc concentration is reached that allows used for other purposes, e.g. for the electrolysis of zinc, for the production of lithopone (whiteness), zinc chloride, or for the production of zinc sulphite, zinc oxide, etc. Pressed briquettes of metal sponge are dried and then melted under By covering, for example, ammonium chloride in furnaces normally used for remelting zinc. The molten metal is poured into molds. PL
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL25614B1 true PL25614B1 (en) | 1937-11-30 |
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