PL220424B1 - Compositions for hair and body wash - Google Patents

Description

The present invention relates to an anhydrous oil-lanolin body and hair cleansing composition containing ozonated olive oil. The subject of the invention includes, but is not limited to, soaps, body and hair shampoos, bath oils and body wash gels.

Therapeutic and care compositions for washing the body and hair are known.

From the Polish patent description No. PL174919 there is known a bar of soap containing 44% to 86.5% by weight of fatty acid soap; 5% to 30% by weight of a polyalkylene glycol; 2.5% to 20% by weight of a C ₆ -C ₂₂ fatty acid and 6% to 20% by weight of water, wherein the ratio of the amount of polyalkylene glycol and fatty acid is from 1: 3 to 3: 1. The disadvantage of this composition, containing a significant amount of fatty acids, is that the product is somewhat rough.

European Patent No. EP1713438 discloses a medicated soap produced on the basis of the synergy between glycerin and sapropel in the process of separating fatty acids from tallow and coconut oil. This soap contains, in addition to the known ingredients necessary for the preparation of solid cube compositions, glycerin and sapropel and as a principal ingredient olive oil in an amount of 48% to 66%; as a foaming agent, coconut oil in an amount of 30% to 42%; as a hardener, castor oil in an amount of 2% to 8% and is catalyzed by beeswax in an amount of 2% to 5% and additives to support its therapeutic effect, such as additives introducing sodium or potassium. The drawback of the medicated soap according to EP 1713438 is the complicated production process and the limited scope of its use only for the treatment of specific skin diseases.

Polish patent description No. PL164195 describes a liquid cleansing cosmetic preparation consisting of 10% to 22% by weight of anionic active agents; 2% to 8% by weight of non-ionic agents containing 1.8% to 6% by weight of C10-C16 alcohols ethoxylated with 2.5 to 10 ethylene oxide groups, in which the C12-C14 alcohol content is at least 75% and 0.15% to 6% by weight of ethoxylated lanolin alcohols; 1.5% to 4% by weight of evaporated salt; 0.02% to 0.5% by weight of preservatives; 0.001% to 0.03% by weight of dyes; 0.1% to 0.7% by weight of perfume compositions and optionally up to 5% by weight of fatty acid ethoxylates or ricic acid triglyceride. By selecting the appropriate ingredients showing synergistic action, only the drying effect of the preparation on human skin was reduced.

There is known from the Polish patent description No. PL187715 a body wash, consisting of sodium salt of ethoxylated lauryl alcohol sulphate in an amount from 10% to 14% by weight; coconut fatty acid amide alkylbetaines in an amount of from 3% to 6% by weight; coconut oil acid diethanolamide in an amount of 0.5% to 2% by weight; polyoxyethylene ester of coconut acids in an amount from 0.5% to 4% by weight; 5-ureidohydantoin in an amount from 0.1% to 5% by weight; preservative; a pH regulator to a value from 5 to 7.5; viscosity regulator and water. It also contains a mixture of natural essential oils and an adduct of ethylene oxide with hydrogenated castor oil in an amount of 0.3% to 3% by weight. The oil mixture consists of at least one oil from the group consisting of tea tree oil, canang oil, neroli oil, sandalwood oil, slang oil, hyssop oil and cypress oil in an amount from 1% to 60% by weight, and at least one oil from the group consisting of lavender oil, rosemary oil, clary sage oil, rose oil, rosewood oil, geranium oil, lemon oil, basil oil in an amount from 1% to 60% by weight. The disadvantage of the body wash according to the patent No. PL187715 is the low therapeutic effect and the inability to have a mild bactericidal and fungicidal effect on the skin and hair.

A cleaner for external use is known from the Japanese patent application No. JP2009001575, containing ozone dissolved in a glycerol solution with an initial concentration of not less than 85 ppm, which does not disturb the skin mucosa. The disadvantage of the invention described in this application is that the concentration of ozone in the glycerol solution is too high, preventing the direct contact of this agent on the skin for a longer period of time, which eliminates the possibility of its use in cosmetic products.

It is known from the Japanese application of the invention No. JP2007186623 ozone soap containing an addition of vegetable ozone oil in an amount of 25% to 50% by weight, which is a fully saturated substance in ozone, and therefore its concentration significantly exceeds the value of 300 ppm. Such a high concentration of ozone in the oil allows only limited direct contact of this soap on the skin, which

It allows its use only as a pharmaceutical antibacterial product to a limited extent.

It is known from the Japanese patent application No. JP2009091489 a soap containing ozonated oil and a method of its production. This invention relates in particular to a method of mixing a pre-prepared bar or liquid soap with an ozone containing oil in connection with specific line equipment, and the end product is a medicated pharmaceutical soap with a limited use range.

UK-known application of the invention No. GB790075 describing soluble mineral, vegetable, animal oils for use in the cosmetics industry, as well as Italian patent application No. IT1183342 relating to detergent compositions disclose formulations of cosmetic products and detergents used in these formulations. The formulas disclosed in these inventions do not contain the addition of ozonated oils with a specific concentration and the percentage of this oil in the composition for washing the body and hair.

However, no prior art cosmetic blend containing ozonated oil has an optimal ozonated oil addition to provide the cosmetic user with a safe ozone content in the final product and to take advantage of its skin properties. Moreover, all known compositions have an addition of water which is disadvantageous in ozonated skin protection and care compositions.

The essence of a body and hair washing composition comprising, on a cosmetically acceptable support, a washing system comprising one or more surfactants selected from anionic, amphoteric nonionic and cationic surfactants and mixtures thereof, and a conditioning system comprising at least one cationic polymer and at least one silicone insoluble is an anhydrous oil-lanolin composition containing ozonized olive oil with an ozone concentration of 1 to 70 ppm in an amount of 1 to 7% by weight, the ozone concentration in the composition being from 1 ppm to 20 ppm and four or more selected ingredients with:

- titanium dioxide

- polyoxypropylene and polyoxyethylene cetyl ether

- sweet almond oil

- a mixture of hydrogels of sodium salts of higher C12-C20 fatty acids

- a mixture of sodium laurate sulphate, laurate and diethanolamine or

- a mixture of sodium salt of ethoxylated lauryl alcohol sulphate with laurate and diethanolamine

- mixture of higher C ₁₂ -C ₁₈ fatty acids, which is a compound of alkylamidopropyl dimethylaminobetaine

- pharmaceutical glycerin 99.5

- mixture of C ₁₂ -C ₁₄ alkyl ether sulfate ethoxylated with 2 moles of ethylene oxide with fatty acid amide and with aliphatic alcohol ethoxylate with ethylene glycol

- (R) -2,4-dihydroxy-N- (3-hydroxypropyl) -3,3-dimethylbutyramide

- a mixture of gasoline alcohol with 5-chloro-2-methyl-2H-isothiazol-3-one and with 2-methyl-2H-isothiazol-3-one

- a cationic copolymer consisting of a mixture of 30 moles of diallyl dimethylammonium chloride and 70 moles of acrylamide

- ethylene oxide / polypropylene oxide block copolymer

- 10: 1 aloe vera gel concentrate

- a mixture of polyoxyethylene glycol with polyoxyethylated glycerin esters and coconut oil fatty acid

- borage oil

- hemp oil

- 0.10-1.30 wt.%

- 0.20-2.00 wt.%

- 0.10-1.00 wt.%

- 0.10-96.00 wt.%

- 5.00-40.00 wt.%

- 5.00-40.00 wt.%

- 5.00-20.00 wt.%

- 5.00-36.90 wt.

- 2.00-5.00 wt.%

- 2.00-5.00 wt.%

- 0.02-0.10 wt.%

- 0.05-4.00 wt.%

- 0.05-3.00 wt.%

- 0.05-5.00 wt.%

- 2.00-5.00 wt.%

- 0.05-2.00 wt.%

- 0.05-2.00 wt.%

PL 220 424 B1

- soybean oil

- castor oil

- anhydrous lanolin

- mixture of ascorbyl palmitate with tocopherol, with ascorbic acid and with citric acid

- 2.00-15.00 wt.%

- 5.00-25.00 wt.%

- 0.50-2.00 wt.%

- 0.05-0.20 wt.%

The oil-lanolin composition for washing the body and hair according to the invention is based on a basic ozonated olive oil base with the addition of known detergents, preferably in the form of super-pure lanolin, available under the name Medilan, and known foaming agents, preferably in the form of super-pure wax paraffin-polyethylene, available under the name CordabaseSQ.

For the purposes of the present invention, a special selection of lanolin, polyethylene paraffin wax, vegetable oils was selected for the composition of a body and hair washing composition containing the addition of ozonated olive oil as defined by the present invention, the active ozone content in these compositions at the level of 1 to 20 ppm. for which adequate quantities of ozonated olive oil have been determined. The main washing base is a specially selected mixture of non-ionic, anionic and amphoteric surfactants, most of which do not contain added water, or the proportion of water in the compositions of these compositions is negligible and does not exceed a few percent by weight. These specially selected mixtures allow the incorporation of a relatively large amount of various types of natural vegetable oils into the composition without the effect of phase separation. As a result of such a composition of the compositions according to the invention, homogeneous, concentrated emulsion-gel systems are obtained in all the compositions included in the present invention. These concentrated mixtures of surfactants and vegetable oils during application, i.e. diluting them with water, create specific emulsion systems which, despite the high concentration of oils, have excellent foaming properties, and after use leave a permanent oil film on the skin and hair, which nourishes and cares for the skin for a long time. and hair.

The anhydrous composition for washing the body and hair is in the form of solid soap, gel soap for washing hands of the whole body, shampoo for washing and conditioning hair, various types of bath oils.

The most commonly produced cube-shaped solid soap contains:

- ozonated olive oil with a content of ____ 70 ppm ozone in the amount of titanium dioxide polyoxypropylene and polyoxyethylene cetyl ether sweet almond oil a mixture of hydrogels, sodium salts of higher C12-C20 fatty acids

- 1.00-3.00 wt.%

- 0.10-0.30 wt.%

- 0.20-2.00 wt.%

- 0.10-1.00 wt.%

- 0.10-99.00 wt.%

A liquid oil-lanolin composition for washing the body and hair contains

- ozonated olive oil with ____ 70 ppm ozone in quantity

- a mixture of sodium laurate sulphate, diethanolamine laurate

- mixture of higher C ₁₂ -C ₁₈ fatty acids, which is a compound of alkylamidopropyl dimethylaminobetaine

- pharmaceutical glycerin 99.5

- a mixture of C12-C14 alkyl ether sulfate ethoxylated with moles of ethylene oxide with fatty acid amide and with aliphatic alcohol ethoxylate ethylene glycol

- (R) -2,4-dihydroxy-N- (3-hydroxypropyl) -3,3-dimethylbutyramide

- 1.00-7.00 wt.%

- 5.00-40.00 wt.%

- 5.00-20.00 wt.%

- 5.00-36.90 wt.

- 2.00-5.00 wt.%

- 2.00-5.00 wt.%

PL 220 424 B1

- a mixture of gasoline alcohol with 5-chloro-2-methyl-2H-isothiazol-3-one and with 2-methyl-2H-isothiazol-3-one

- cationic copolymer consisting of a mixture of moles of diallyl dimethylammonium chloride and 70 moles of acrylamide

- ethylene oxide / polypropylene oxide block copolymer

- 10: 1 aloe vera gel concentrate

- a mixture of polyoxyethylene glycol with polyoxyethylene glycerol esters and coconut oil fatty acid

- borage oil

- hemp oil

- soybean oil

- castor oil

- anhydrous lanolin

- mixture of ascorbyl palmitate with tocopherol, with ascorbic acid and with citric acid

- 0.02-0.10 wt.%

- 0.05-4.00 wt.%

- 0.05-3.00 wt.%

- 0.05-5.00 wt.%

- 2.00- 5.00 wt.%

- 0.05- 2.00 wt.%

- 0.05- 2.00 wt.%

- 2.00-15.00 wt.%

- 5.00-25.00 wt.%

- 0.50- 2.00 wt.%

- 0.05-0.20 wt.%

The advantage of the oil-lanolin composition for washing the body and conditioning hair with the addition of ozonated olive oil is its combined caring, protective, washing and conditioning effect, with simultaneous antibacterial action on the skin and hair, derived from the active ozone contained in olive oil. A properly selected amount of ozonated olive oil causes the release of active ozone during the application of the composition to the skin and hair and contact with water, which dissolves in this water 15 times faster than oxygen, supporting the washing process with intensive care, bactericidal and fungicidal action on the washed the surface of the skin or hair. A composition for washing the body and hair containing the released active ozone has a dermatological benefit on the skin of the human body irritated by synthetic detergents used in similar products. The composition according to the invention can be used in various forms, such as solid soaps, shampoos, shower gels, various oils, and as bath additives. The ozone present in the composition according to the invention has a bactericidal effect even at low concentrations, not exceeding 5 ppm, not only directly neutralizing the bacteria present on the skin and hair, but also positively influencing the immune system of the body. It is also advantageous that the addition of ozone olive oil with an ozone concentration of 1 to 70 ppm in an amount of 1 to 7% by weight, in addition to its normal cosmetic properties, also results in certain therapeutic properties. The ozone released during the use of the composition according to the invention affects the nutrition of tissues and revitalizes them.

Examples:

The oil-lanolin composition according to the invention has been shown in the following examples:

P r z k ł a d 1

Solid soap

According to the invention described earlier, a solid soap was prepared with the following composition:

- ozonated olive oil with an ozone content of 70 ppm, in an amount - 2.50 wt.%.

- titanium dioxide - 0.20 wt.%

- polyoxypropylene and polyoxyethylene cetyl ether - 1.00 wt.%

- sweet almond oil - 0.50 wt.%

- a mixture of hydrogels of sodium salts of higher fatty acids C ₁₂ C ₂₀ - 95.80 wt.

Individual raw materials were weighed into the mixer in accordance with the above-mentioned recipe, and then the mixing process was carried out at constant mixer speed for about 5 minutes. After mixing, the refiner was turned on, in which the initial embossing and cutting of the soap mass into chips took place,

After that, the pelothesis was turned on to press and heat the resulting chips, from which a uniform web of soap mass was formed. When the soap mass had reached a temperature of 80 ° C, it was cut into individual cubes which contained 1.4 ppm ozone upon cooling to room temperature.

P r z k ł a d 2

Shampoo for washing and conditioning the hair. A shampoo was prepared with the following composition: a) ozonated olive oil, 70 ppm ozone content, a mixture of sodium laurate sulphate, laurate and diethanolamine mixture of higher C12-C18 fatty acids, which is a compound of alkylamidopropyl dimethylaminobetaines [cocamidopropyl ] pharmaceutical glycerin 99.5 mixture C12-C14 alkyl ether sulphate ethoxylated with moles of ethylene oxide with fatty acid amide and with aliphatic alcohol ethoxylate ethylene glycol (R) -2,4-dihydroxy-N- (3-hydroxypropyl) -3,3-dimethylbutyramide mixture gasoline alcohol with 5-chloro-2-methyl-2H-isothiazol-3-one and 2-methyl-2H-isothiazol-3-one cationic copolymer consisting of a mixture of moles of diallyl dimethylammonium chloride and 70 moles of acrylamide

i) ethylene oxide / polypropylene oxide block copolymer

b)

c)

d)

e)

f)

g)

h)

- 7.00 wt.%

- 20.00 wt.%

- 20.00 wt.%

- 36.90 wt.%

- 5.00 wt.% - 5.00 wt.%

- 0.10 wt.%

- 4.00 wt.%

- 2.00 wt.%

The ingredients were dosed in the amounts indicated above into the mixer, which was started at low speed, in the following order:

1. Component h),

2. Component i),

3. Component a),

4. Component f),

5. Component g),

6. Component b),

7. Component d)

8. Component e),

9. Component c).

The mixing was carried out for 30 minutes in such a way that the mixture did not become airless under vacuum conditions, with a vacuum value of 0.048 MPa. After visual inspection of the homogeneity of the obtained mixture, the mixer was stopped and drained.

The obtained shampoo had the consistency of a thick gel of white color with pearl iridescence, containing 5 ppm of ozone.

P r o x l a d 3 Liquid soap.

A liquid soap is made with the following composition:

(a) ozonated olive oil with an ozone content of 70 ppm

b) a mixture of sodium laurate sulfate, laurate and diethanolamine

c) a mixture of higher C ₁₂ -C ₁₈ fatty acids which is an alkylamidopropyl dimethylaminobetaine compound

d) pharmaceutical glycerin 99.5

- 7.00 wt.%

- 20.00 wt.%

- 20.00 wt.%

- 36.90 wt.%

PL 220 424 B1

e) a mixture of C12-C14 alkyl ether sulfate ethoxylated with 2 moles of ethylene oxide with fatty acid amide and with aliphatic alcohol ethoxylate ethylene glycol

f) (R) -2,4-dihydroxy-N- (3-hydroxypropyl) -3,3-dimethylbutyramide

g) a mixture of petrol alcohol with 5-chloro-2-methyl-2H-isothiazol-3-one and with 2-methyl-2H-isothiazol-3-one

h) cationic copolymer consisting of a mixture of moles of diallyl dimethylammonium chloride and 70 moles of acrylamide

i) 10: 1 aloe vera gel concentrate

- 5.00 wt.%

- 5.00 wt.%

- 0.10 wt.%

- 4.00 wt.%

- 2.00 wt.%

The ingredients were dosed in the amounts indicated above into the mixer, which was started at low speed, in the following order:

1. Component h),

2. Component i),

3. Component a),

4. Component f),

5. Component g),

6. Component e),

7. Component d),

8. Component h),

9. Component c).

Mixing was carried out for 30 minutes in such a way that the mixture did not become airless under vacuum conditions with a vacuum value of 0.050 MPa. After visual inspection of the homogeneity of the resulting mixture, the blender was stopped and drained.

The obtained liquid soap had the consistency of a thick gel of white color with pearl iridescence, containing 5 ppm of ozone.

P r z k ł a d 4

Bath oil in the tub.

A bath oil was prepared with the following composition: a) ozonated olive oil with a content of 70 ppm ozone in the amount of a mixture of sodium salt of oxyethylated lauryl alcohol sulphate with laurate and diethanolamine mixture of polyoxyethylene glycol with polyoxyethylated esters of glycerin and with fatty acid coconut oil borage oil Hemp oil soybean oil castor oil anhydrous lanolin ethylene oxide / polypropylene oxide block copolymer mixture of ascorbyl palmitate with tocopherol, with ascorbic acid and with citric acid (R) -2,4-dihydroxy-N- (3-hydroxypropyl) -3,3- dimethylbutyramide

The following amounts were introduced into the mixer, which was started at low speed:

1. Component h),

2. Component c),

3. Component f),

- 7.00 wt.%

b)

c)

d)

e)

f)

g)

h)

and)

j)

k)

- 40.00 wt.%

- 5.00 wt.%

- 2.00 wt.%

- 2.00 wt.%

- 15.00 wt.%

- 20.00 wt.%

- 2.00 wt.%

- 3.00 wt.%

- 0.40 wt.%

- 3.60 wt.%

The mixer was then heated to a temperature of about 60 ° C with the contents of these three components. The temperature was kept at 60 ° C while stirring until the lanolin was completely dissolved. The dissolution efficiency was assessed visually by taking a sample of the fluid from the mixer. After achieving homogeneity in the mixed liquid, without visible particles of undissolved medilane, and after the mixture was fully homogenized, the process of cooling the mixture to room temperature in the mixer was started while stirring. When the content of the mixer was cooled to 35 ° C, dosing of the remaining components of the composition was started to the mixer, which was still rotating at low speed, while the cooling process was still taking place, in the following order:

4. Component a),

5. Component b),

6. Component d),

7. Component e),

8. Component f),

9. Component g),

10. Component i),

11. Component j),

12. Component k).

After dispensing all of the remaining ingredients, all of the composition in the mixer was mixed thoroughly for about 20 minutes. At the end of mixing, when the temperature of the composition under the blender had dropped to room temperature, a sample of the oil was taken from the blender to visually assess the homogenization of the mixture, and the mixing process was complete.

The obtained oil for bathing in a bathtub contains 5 ppm of ozone.

Claims (3)

A body and hair wash composition comprising, on a cosmetically acceptable support, a washing system comprising one or more active agents selected from anionic, amphoteric, nonionic and cationic surfactants and mixtures thereof, and a conditioning system comprising at least one cationic polymer and at least one an insoluble silicone characterized in that it is an anhydrous oil-lanolin composition containing ozonated olive oil with an ozone concentration of 1 to 70 ppm in an amount of 1% to 7% by weight, the ozone concentration in the composition being from 1 ppm to 20 ppm; and four or more ingredients selected from: - titanium dioxide - 0.10-1.30 wt.% - polyoxypropylene and polyoxyethylene cetyl ether - 0.20-2.00 wt.% - sweet almond oil - 0.10-1.00 wt.% - mixture of hydrogels of sodium salts of higher C12-C20 fatty acids - 0.10-96.00 wt.% - a mixture of sodium laurate sulphate, laurate and diethanolamine - 5.00-40.00% by weight or - a mixture of sodium salt of ethoxylated lauryl alcohol sulphate with laurate and diethanolamine - a mixture of higher C ₁₂ -C ₁₈ fatty acids, which is a compound of alkylamidopropyl dimethylaminobetaine - pharmaceutical glycerin 99.5 - mixture of C ₁₂ -C ₁₄ alkyl ether sulfate ethoxylated with 2 moles of ethylene oxide with fatty acid amide and with aliphatic alcohol ethoxylate with ethylene glycol - (R) -2,4-dihydroxy-N- (3-hydroxypropyl) -3,3-dimethylbutyramide - 5.00-40.00 wt.% - 5.00-20.00 wt.% - 5.00-36.90 wt. - 2.00-5.00 wt.% - 2.00-5.00 wt.% PL 220 424 B1 - a mixture of petrol alcohol with 5-chloro-2-methyl-2H-isothiazol-3-one and with 2-methyl-2H-isothiazol-3-one - a cationic copolymer consisting of a mixture of 30 moles of diallyl dimethylammonium chloride and 70 moles of acrylamide - ethylene oxide / polypropylene oxide block copolymer - 10: 1 aloe vera gel concentrate - a mixture of polyoxyethylene glycol with polyoxyethylated glycerol esters and coconut oil fatty acid - borage oil - hemp oil - soybean oil - castor oil - anhydrous lanolin - a mixture of ascorbyl palmitate with tocopherol, with ascorbic acid and with citric acid 2. A composition according to claim 1 The solid soap of claim 1, wherein the solid soap comprises: - ozonated olive oil with an ozone content of 70 ppm - titanium dioxide - polyoxypropylene and polyoxyethylene cetyl ether - sweet almond oil - a vegetable soap base consisting of a mixture of hydrogels and sodium salts of higher C12-C20 fatty acids, the ozone content in the composition being from 1 ppm to 2 ppm. - 0.02-0.10 wt.% - 0.05-4.00 wt.% - 0.05-3.00 wt.% - 0.05-5.00 wt.% - 2.00-5.00 wt.% - 0.05-2.00 wt.% - 0.05-2.00 wt.% - 2.00-15.00 wt.% - 5.00-25.00 wt.% - 0.50-2.00 wt.% - 0.05-0.20 wt.% - 1.00-3.00 wt.% - 0.10-0.30 wt.% - 0.20-2.00 wt.% - 0.10-1.00 wt.% - 0.10-96.00 wt.% 3. A composition according to p. The method of claim 1, wherein the liquid oil-lanolin composition for washing the body and hair comprises ozonated olive oil with a content of 70 ppm ozone in an amount of 1.00% to 7.00% by weight and 5 or more ingredients selected from: - a mixture of sodium laurate sulphate, laurate 1 diethanolamine - 5.00-40.00 wt.% or - a mixture of sodium salt of ethoxylated lauryl alcohol sulphate with laurate and diethanolamine - 5.00-40.00% by weight - a mixture of higher C ₁₂ -C ₁₈ fatty acids being an alkylamidopropyl dimethylaminobetaine compound - 5.00-20.00 wt. - pharmaceutical glycerin 99.5 - 5.00-36.90% by weight mixture of C ₁₂ -C ₁₄ alkyl ether sulfate ethoxylated 2 moles of ethylene oxide with fatty acid amide and aliphatic alcohol ethoxylated with ethylene glycol - 2.00-5.00 wt.%. - (R) -2,4-dihydroxy-N- (3-hydroxypropyl) -3,3-dimethylbutyramide - 2.00-5.00 wt. - mixture of petrol alcohol with 5-chloro-2-methyl-2H-isothiazol-3-one and with 2-methyl-2H-isothiazol-3-one - 0.02-0.10% by weight - a cationic copolymer consisting of a mixture of 30 moles of diallyl dimethylammonium chloride and 70 moles of acrylamide - 0.05-4.00% by weight. - ethylene oxide / polypropylene oxide block copolymer - 0.05-3.00 wt.% - aloe vera juice gel concentrate 10: 1 - 0.05-5.00 wt.% PL 220 424 B1 - 2.00- 5.00 wt.% - 0.05- 2.00 wt.% - 0.05- 2.00 wt.% - 2.00-15.00 wt.% - 5.00-25.00 wt.% - 0.50- 2.00 wt.% mixture of polyoxyethylene glycol with polyoxyethylated glycerol esters and fatty acid coconut oil borage oil hemp oil soybean oil castor oil anhydrous lanolin mixture of ascorbyl palmitate with tocopherol, with ascorbic acid and citric acid - 0.05-0.20 wt.%, with wherein the ozone content of these compositions is from 3 ppm to 20 ppm.