PL203550B1 - The use of strobilurins for the production of the agent - Google Patents

The use of strobilurins for the production of the agent

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Publication number
PL203550B1
PL203550B1 PL358784A PL35878401A PL203550B1 PL 203550 B1 PL203550 B1 PL 203550B1 PL 358784 A PL358784 A PL 358784A PL 35878401 A PL35878401 A PL 35878401A PL 203550 B1 PL203550 B1 PL 203550B1
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Poland
Prior art keywords
och
alkyl
alkylamino
cycloalkyl
nhch
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PL358784A
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Polish (pl)
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PL358784A1 (en
Inventor
Köhle Harald
Conrath Uwe
Seehaus Kai
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Basf Aktiengesellschaft
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Priority claimed from PCT/EP2001/004889 external-priority patent/WO2001082701A1/en
Publication of PL358784A1 publication Critical patent/PL358784A1/en
Publication of PL203550B1 publication Critical patent/PL203550B1/en

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/52Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing groups, e.g. carboxylic acid amidines
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/541,3-Diazines; Hydrogenated 1,3-diazines
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof

Description

Opis wynalazku Przedmiotem wynalazku jest zastosowanie strobiluryn do wytwarzania srodka do wzbudzania oporno sci na wirusy w ro slinach. Du za liczba przedstawicieli wysoce zró znicowanej grupy wirusów ro slinnych (fitofagów) jest zdolna do atakowania ro slin o znaczeniu gospodarczym; objawy uszkodze n obejmuj a zakres od zmian morfologicznych do zamarcia ro slin. Z powodu ró znorodnych dróg przenoszenia wirusów (np. mechanicznie przez uszkodzenie, przez nasiona i py lek, lub przez wektory, takie jak nicienie i owady), problemów z diagnoz a i braku odpowiednich substancji czynnych zwalczanie takich wirusów jest nadzwyczaj trudne, a zatem pierwszoplanowe staj a si e dzia lania prewencyjne i fitosanitarne. Tak wi ec unikni ecie chorób wirusowych u ro slin jest wa znym celem w rolnictwie. W poszukiwaniu sposobów unikni ecia chorób wirusowych u ro slin opracowano ju z przeciwwiru- sowe substancje czynne, z których pewne s a zbli zone do kwasów nukleinowych. Jednak ze niektóre z tych substancji powoduj a wytwarzanie mutantów i hamuj a metabolizm kwasów nukleinowych i bia lek w komórkach gospodarza, powoduj ac uszkodzenia. W warunkach polowych takie materia ly wywieraj a tylko niewielkie rzeczywiste dzia lanie zwalczaj ace. Skomplikowanym podej sciem jest wykorzystanie lub stymulowanie w lasnych si l obronnych ro slin. W DE-A 3934761 zaproponowano stosowanie polilizyny i kwasów alkilodietylenotriamino- octowych dla unikni ecia chorób wirusowych u ro slin. W EP-A 420803 opisano uodporniaj ace dzia lanie pochodnych benzo-1,2,3-tiazolu przeciw ró znym fitopatogennym mikroorganizmom. Z WO-A 96/37493 znane jest podobne dzia lanie pirydylotiazoli. W DD 280030 zaproponowano pochodne kwasu sulfonowego jako srodki do aktywacji oporno- sci ro slin uprawnych i u zytkowych. Jednak ze dzia lanie takich substancji jest w wielu przypadkach niewystarczaj ace. Celem wynalazku by lo zatem dostarczenie substancji czynnych do wytwarzania srodków, które mog lyby by c szeroko stosowane, bez uszkadzania ro slin, i które powodowa lyby skuteczne uodpornie- nie przeciw chorobom wirusowym u ro slin. Odkryto, ze cel ten osi agni eto dzi eki zastosowaniu poni zej zdefiniowanych strobiluryn o ogól- nym wzorze I. Zastosowane substancje czynne s a znane jako fungicydy, a w pewnych przypadkach tak ze jako insektycydy (EP-A 178826; EP-A 253213; WO-A 93/15046; WO-A 95/18789; WO-A 95/21153; WO-A 95/21154; WO-A 95/24396; WO-A 96/01256; WO-A 97/15552). Jednak ze dotych- czas nie podano zadnej sugestii co do mo zliwo sci wywierania przez te substancje czynne dzia lania stymuluj acego w lasny uk lad immunologiczny ro slin przeciw wirusom. Zatem wynalazek dotyczy zastosowania strobiluryn o ogólnym wzorze I w którym X oznacza atom chlorowca, C 1 -C 4 -alkil lub trifluorometyl; m oznacza 0 lub 1; Q oznacza C(=CH-CH 3 )-COOCH 3 , C(=CH-OCH 3 )-COOCH 3 , C(=N-OCH 3 )-CONHCH 3 , C(=N- OCH 3 )-COOCH 3 lub N(-OCH 3 )-COOCH 3 ; A oznacza -O-B, -CH 2 O-B, -CH 2 O-N=C(R 1 )-B lub -CH 2 O-N=C(R 1 )-C(R 2 )=N-OR 3 , gdzie B oznacza fenyl, pirydyl, pirymidynyl, pirazolil lub triazolil, przy czym te uk lady pier scieniowe s a podstawione jedn a lub dwiema grupami R a ; R a oznacza grup e cyjanow a, grup e nitrow a, grup e aminow a, aminokarbonyl, aminotiokarbonyl, atom chlorowca, C 1 -C 6 -alkil, C 1 -C 6 -chlorowcoalkil, C 1 -C 6 -alkilokarbonyl, C 1 -C 6 -alkilosulfonyl, C 1 -C 6 - -alkilosulfinyl, C 3 -C 6 -cykloalkil, C 1 -C 6 -alkoksyl, C 1 -C 6 -chlorowcoalkoksyl, C 1 -C 6 -alkiloksykarbonyl, gru- p e C 1 -C 6 -alkilotio, grup e C 1 -C 6 -alkiloaminow a, grup e di-C 1 -C 6 -alkiloaminow a, C 1 -C 6 -alkiloamino- karbonyl, di-C 1 -C 6 -alkiloaminokarbonyl, C 1 -C 6 -alkiloaminotiokarbonyl, di-C 1 -C 6 -alkiloaminotiokarbonyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkenyloksyl, fenyl, fenoksyl, benzyl, benzyloksyl, 5- lub 6-cz lonowy heterocyklil, 5- lub 6-cz lonowy heteroaryl, 5- lub 6-cz lonowy heteroaryloksyl, C(=NOR a )-OR ß lub OC(R a ) 2 - C(R ß )=NOR ß przy czym te grupy cykliczne s a ewentualnie podstawione 1-3 grupami R b :PL 203 550 B1 3 R b oznacza grup e cyjanow a, grup e nitrow a, atom chlorowca, grup e aminow a, aminokarbonyl, aminotiokarbonyl, C 1 -C 6 -alkil, C 1 -C 6 -chlorowcoalkil, C 1 -C 6 -alkilosulfonyl, C 1 -C 6 -alkilosulfinyl, C 3 -C 6 - -cykloalkil, C 1 -C 6 -alkoksyl, C 1 -C 6 -chlorowcoalkoksyl, C 1 -C 6 -alkoksykarbonyl, grup e C 1 -C 6 -alkilotio, grup e C 1 -C 6 -alkiloaminow a, grup e di-C 1 -C 6 -alkiloaminow a, C 1 -C 6 -alkiloaminokarbonyl, di-C 1 -C 6 -alkilo- aminokarbonyl, C 1 -C 6 -alkiloaminotiokarbonyl, di-C 1 -C 6 -alkiloaminotiokarbonyl, C 2 -C 6 -alkenyl, C 2 -C 6 - -alkenyloksyl, C 3 -C 6 -cykloalkil, C 3 -C 6 -cykloalkenyl, fenyl, fenoksyl, grup e fenylotio, benzyl, benzyloksyl, 5- lub 6-cz lonowy heterocyklil, 5- lub 6-cz lonowy heteroaryl, 5- lub 6-cz lonowy heteroaryloksyl lub C(=NOR a )-OR ß ; R a i R ß oznaczaj a atom wodoru lub C 1 -C 6 -alkil; R 1 oznacza atom wodoru, grup e cyjanow a, C 1 -C 4 -alkil, C 1 -C 4 -chlorowcoalkil, C 3 -C 6 -cykloalkil lub C 1 -C 4 -alkoksyl; R 2 oznacza C 1 -C 6 -alkil, C 2 -C 10 -alkenyl lub C 3 -C 6 -cykloalkil, przy czym te grupy s a ewentualnie podstawione jedn a lub dwiema grupami R b ’; gdzie R b' oznacza C 1 -C 6 -alkil, C 3 -C 6 -cykloalkil, C 1 -C 6 -alkoksyl, C 1 -C 6 -chlorowcoalkoksyl, benzyl, fenyl lub fenoksyl; albo R 2 oznacza fenyl ewentualnie podstawiony jedn a lub dwiema grupami R a ; a R 3 oznacza C 1 -C 6 -alkil, C 2 -C 10 -alkenyl lub C 2 -C 10 -alkinyl; do wytwarzania srodka do wzbudzania oporno sci na wirusy w ro slinach. Korzystnie w odniesieniu do powy zszego rozwi azania stosuje si e substancj e czynn a o ogólnym wzorze II w którym T oznacza N lub CH; x oznacza 0, 1 - 3; y oznacza 0 lub 1; R a ’ ma powy zej podane znaczenie odno snie R a ; a R b ma powy zej podane znaczenie. Korzystnie w odniesieniu do powy zszego rozwi azania stosuje si e substancj e czynn a o wzorze III w którym V oznacza OCH 3 lub NHCH 3 ; Y oznacza N, a R a ma powy zej podane znaczenie. Korzystniej w odniesieniu do powy zszego rozwi azania stosuje si e substancj e czynn a wybran a z grupy zwi azków I-5, III-4 i VII-1PL 203 550 B1 4 Dobra zgodnosc substancji czynnych o wzorze I z ro slinami przy st ezeniu potrzebnym dla zwal- czenia chorób ro slin umo zliwia nanoszenie na nadziemne cz esci ro slin, jak równie z na nanoszenie na rozsady, nasiona i na gleb e. Zgodnie z zastosowaniem wed lug wynalazku substancja czynna jest pobierana przez ro slin e albo przez powierzchni e li sci, albo przez korzenie ro sliny i rozprzestrzenia si e w soku ro slinnym w ca lej ro slinie. Zatem dzia lanie ochronne po zastosowaniu substancji czynnych o wzorze I zgodnie z wynalaz- kiem wyst epuje nie tylko w cz esciach ro slin opryskanych bezpo srednio, gdy z podnosi si e oporno sc przeciw chorobom wirusowym w ca lej ro slinie. W korzystnej postaci wykonania wynalazku preparatem substancji czynnej o wzorze I traktuje sie nadziemne cz esci ro slin. W cytowanych na pocz atku publikacjach opisano sposoby syntezy substancji czynnych stoso- wanych zgodnie z wynalazkiem. Szczególnie korzystne zgodnie z wynalazkiem stosuje si e substancje czynne maj ace podstaw- niki o ni zej podanym znaczeniu, w ka zdym przypadku osobno, jak i w po laczeniach. Szczególnie korzystne zgodnie z wynalazkiem stosuje si e substancje czynne o wzorach II - VIII, w których V oznacza OCH 3 lub NHCH 3 , Y oznacza CH lub atom azotu, a T i Z niezale znie oznaczaj a CH lub atom azotu. Korzystnymi substancjami czynnymi o wzorze I, w którym Q oznacza N(-OCH 3 )-COOCH 3 , s a zwi azki opisane w WO-A 93/15046 i WO-A 96/01256. Korzystnymi substancjami czynnymi o wzorze I, w którym Q oznacza C(=CH-OCH 3 )-COOCH 3 , s a zwi azki opisane w EP-A 178826 i EP-A 278595. Korzystnymi substancjami czynnymi o wzorze I, w którym Q oznacza C(=N-OCH 3 )-COOCH 3 , s a zwi azki opisane w EP-A 253213 i EP-A 254426. Korzystnymi substancjami czynnymi o wzorze I, w którym Q oznacza C(=N-OCH 3 )-CONHCH 3 , s a zwi azki opisane w EP-A 398692, EP-A 477631 i EP-A 628540. Korzystnymi substancjami czynnymi o wzorze I, w którym Q oznacza C(=CH-CH 3 )-COOCH 3 , s a zwi azki opisane w EP-A 280185 i EP-A 350691. Korzystnymi substancjami czynnymi o wzorze I, w którym A oznacza -CH 2 O-N=C(R 1 )-B, s a zwi azki opisane w EP-A 460575 i EP-A 463488. Korzystnymi substancjami czynnymi o wzorze I, w którym A oznacza -O-B, s a zwi azki opisane w EP-A 382375 i EP-A 398692. Korzystnymi substancjami czynnymi o wzorze I, w którym A oznacza -CH 2 O-N=C(R 1 )-C(R 2 )=N-OR 3 , s a zwi azki opisane w WO-A 95/18789, WO-A 95/21153, WO-A 95/21154, WO-A 97/05103 i WO-A 97/06133. Szczególnie korzystne s a substancje czynne o wzorze I, w którym Q oznacza N(-OCH 3 )-COOCH 3 , A oznacza CH 2 -O-B, a B oznacza 3-pirazolil lub 1,2,4-triazolil, przy czym grupa B jest podstawiona jednym lub dwoma podstawnikami wybranymi z grupy obejmuj acej atom chlorowca, metyl i trifluorometyl oraz fenyl i pirydyl, a zw laszcza 2-pirydyl, podstawione 1-3 grupami R b . Te substancje czynne s a opisane wzorem II. Innymi szczególnie korzystnymi substancjami czynnymi s a zwiazki o wzorze II'.PL 203 550 B1 5 Ze wzgl edu na ich w la sciwo sci u zytkowe szczególnie korzystne s a zwi azki podane w tabelach. T a b e l a I Nr T (R a' ) y Pozycja grupy fenylowej podstawionej (R b ) x (R b ) x Odno snik literaturowy I-1 N - 1 2,4-Cl 2 WO-A 96/01256 I-2 N - 1 4-Cl WO-A 96/01256 I-3 CH - 1 2-Cl WO-A 96/01256 I-4 CH - 1 3-Cl WO-A 96/01256 I-5 CH - 1 4-Cl WO-A 96/01256 I-6 CH - 1 4-CH 3 WO-A 96/01256 I-7 CH - 1 H WO-A 96/01256 I-8 CH - 1 3-CH 3 WO-A 96/01256 I-9 CH 5-CH 3 1 3-CF 3 WO-A 96/01256 I-10 CH 1-CH 3 5 3-CF 3 WO-A 99/33812 I-11 CH 1-CH 3 5 4-Cl WO-A 99/33812 I-12 CH 1-CH 3 5 - WO-A 99/33812 T a b e l a II Nr V Y R a Odno snik literaturowy II-1 OCH 3 N 2-CH 3 EP-A 253213 II-2 OCH 3 N 2,5-(CH 3 ) 2 EP-A 253213 II-3 NHCH 3 N 2,5-(CH 3 ) 2 EP-A 398692 II-4 NHCH 3 N 2-Cl EP-A 398692 II-5 NHCH 3 N 2-CH 3 EP-A 398692 II-6 NHCH 3 N 2-CH 3 , 4-OCF 3 EP-A 628540 II-7 NHCH 3 N 2-Cl, 4-OCF 3 EP-A 628540 II-8 NHCH 3 N 2-CH 3 , 4-OCH(CH 3 )-C(CH 3 )=NOCH 3 Zg l. DE 10002661.3 II-9 NHCH 3 N 2-Cl, 4-OCH(CH 3 )-C(CH 3 )=NOCH 3 Zg l. DE 10002661.3 II-10 NHCH 3 N 2-CH 3 , 4-OCH(CH 3 )-C(CH 2 CH 3 )=NOCH 3 Zg l. DE 10002661.3 II-11 NHCH 3 N 2-Cl, 4-OCH(CH 3 )-C(CH 3 )=NOCH 2 CH 3 Zg l. DE 10002661.3PL 203 550 B1 6 T a b e l a III Nr V Y T R a Odno snik literaturowy III-1 OCH 3 CH N 2-OCH 3 , 6-CF 3 WO-A 96/16047 III-2 OCH 3 CH N 2-OCH(CH 3 ) 2 , 6-CF 3 WO-A 96/16047 III-3 OCH 3 CH CH 5-CF 3 EP-A 278595 III-4 OCH 3 CH CH 6-CF 3 EP-A 278595 III-5 NHCH 3 N CH 3-Cl EP-A 398692 III-6 NHCH 3 N CH 3-CF 3 EP-A 398692 III-7 NHCH 3 N CH 3-CF 3 , 5-Cl EP-A 398692 III-8 NHCH 3 N CH 3-Cl, 5-CF 3 EP-A 398692 T a b e l a IV Nr V Y R 1 B Odno snik literaturowy IV-1 OCH 3 CH CH 3 (3-CF 3 )C 6 H 4 EP-A 370629 IV-2 OCH 3 CH CH 3 (3,5-Cl 2 )C 6 H 3 EP-A 370629 IV-3 NHCH 3 N CH 3 (3-CF 3 )C 6 H 4 WO-A 92/13830 IV-4 NHCH 3 N CH 3 (3-OCF 3 )C 6 H 4 WO-A 92/13830 IV-5 OCH 3 N CH 3 (3-OCF 3 )C 6 H 4 EP-A 460575 IV-6 OCH 3 N CH 3 (3-CF 3 )C 6 H 4 EP-A 460575 IV-7 OCH 3 N CH 3 (3,4-Cl 2 )C 6 H 3 EP-A 460575 IV-8 OCH 3 N CH 3 (3,5-Cl 2 )C 6 H 3 EP-A 463488 T a b e l a VPL 203 550 B1 7 Nr V R 1 R 2 R 3 Odno snik literaturowy V-1 OCH 3 CH 3 CH 3 CH 3 WO-A 95/18789 V-2 OCH 3 CH 3 CH(CH 3 ) 2 CH 3 WO-A 95/18789 V-3 OCH 3 CH 3 CH 2 CH 3 CH 3 WO-A 95/18789 V-4 NHCH 3 CH 3 CH 3 CH 3 WO-A 95/18789 V-5 NHCH 3 CH 3 4-F-C 6 H 4 CH 3 WO-A 95/18789 V-6 NHCH 3 CH 3 4-Cl-C 6 H 4 CH 3 WO-A 95/18789 V-7 NHCH 3 CH 3 2,4-C 6 H 3 CH 3 WO-A 95/18789 V-8 NHCH 3 Cl 4-F-C 6 H 4 CH 3 WO-A 98/38857 V-9 NHCH 3 Cl 4-Cl-C 6 H 4 CH 2 CH 3 WO-A 98/38857 V-10 NHCH 3 CH 3 CH 2 C(=CH 2 )CH 3 CH 3 WO-A 97/05103 V-11 NHCH 3 CH 3 CH=C(CH 3 ) 2 CH 3 WO-A 97/05103 V-12 NHCH 3 CH 3 CH=C(CH 3 ) 2 CH 2 CH 3 WO-A 97/05103 V-13 NHCH 3 CH 3 CH=C(CH 3 )CH 2 CH 3 CH 3 WO-A 97/05103 T a b e l a VI Nr V Y R a Odno snik literaturowy VI-1 NHCH 3 N 3-CH 3 EP-A 398692 VI-2 NHCH 3 N 2-NO 2 EP-A 398692 VI-3 NHCH 3 N 4-NO 2 EP-A 398692 VI-4 NHCH 3 N 4-Cl EP-A 398692 VI-5 NHCH 3 N 4-Br EP-A 398692 T a b e l a VIIPL 203 550 B1 8 Nr V Y T R a Odno snik literaturowy VII-1 OCH 3 CH N 6-O-(2-CN-C 6 H 4 ) EP-A 382375 VII-2 OCH 3 CH N 6-O-(2-Cl-C 6 H 4 ) EP-A 382375 VII-3 OCH 3 CH N 6-O-(2-CH 3 -C 6 H 4 ) EP-A 382375 VII-4 NHCH 3 N N 6-O-(2-Cl-C 6 H 4 ) GB-A 2253624 VII-5 NHCH 3 N N 6-O-(2,4-Cl 2 -C 6 H 3 ) GB-A 2253624 VII-6 NHCH 3 N N 6-O-(2-CH 3 -C 6 H 4 ) GB-A 2253624 VII-7 NHCH 3 N N 6-O-(2-CH 3 ,3-Cl-C 6 H 3 ) GB-A 2253624 VII-8 NHCH 3 N N 2-F, 6-O-(2-CH 3 -C 6 H 4 ) WO-A 98/21189 VII-9 NHCH 3 N N 2-F, 6-O-(2-Cl-C 6 H 4 ) WO-A 98/21189 VII-10 NHCH 3 N N 2-F, 6-O-(2-CH 3 ,3-Cl-C 6 H 3 ) WO-A 98/21189 Szczególnie korzystne s a substancje czynne I-5 (nazwa zwyczajowa: piraklostrobina), III-4 (nazwa zwyczajowa: pikoksystrobina), IV-6 (nazwa zwyczajowa: trifloksystrobina) i VII-1 (nazwa zwy- czajowa: azoksystrobina). Zwi azki I podwy zszaj a oporno sc ro slin na wirusy. Maj a one szczególne znaczenie w zwalczaniu wirusów w ró znych ro slinach uprawnych, takich jak tyto n, j eczmie n, ogórki, ziemniaki i buraki, jak rów- nie z w nasionach tych ro slin. Nadaj a si e one szczególnie do zwalczania nast epuj acych chorób ro slin: w tytoniu, wirusa mozaiki tytoniu i wirusa nekrozy tytoniu, w fasoli, wirusa zwyk lej mozaiki fasoli i wirusa zó ltej mozaiki fasoli, w jeczmieniu, wirusa paskowanej mozaiki i zó ltej kar lowato sci jeczmienia, w ogórkach, wirusa zielonej mozaiki ogórków i wirusa mozaiki ogórka, w ziemniakach, wirusa choroby X i wirusa choroby Y ziemniaka, w burakach, wirusa rizomanii i wirusa lagodnej zó ltaczki buraka. Zwi azki I stosuje si e przez nanoszenie na zagro zone wirusem ro sliny, nasiona lub gleb e sku- tecznej ilo sci substancji czynnych. Nanoszenie mo zna prowadzi c zarówno przed zara zeniem, jak i po zara zeniu wirusami ro slin lub nasion. W korzystnej postaci wykonania nanoszenie na ro sliny prowadzi si e przed zara zeniem. Obser- wuje si e wtedy wyra znie zmniejszon a sk lonno sc ro sliny do chorób wirusowych. Dawki nanoszenia przy stosowaniu w celu ochrony ro slin wynosz a, w zale zno sci od rodzaju pa- togenów i gatunków ro slin, 0,01 - 2,0 kg substancji czynnej na hektar. Przy zaprawianiu nasion ilosc substancji czynnej wynosi na ogó l 0,001 - 0,1 g, a korzystnie 0,01 - 0,05 g, substancji czynnej na kilogram nasion. Zwi azkom o wzorze I mo zna nadawa c posta c preparatów zwykle stosowanych w przypadku fungicydów, takich jak roztwory, emulsje, zawiesiny, py ly, proszki, pasty i granulaty. Posta c u zytkowa zale zy od celu stosowania i w ka zdym przypadku powinna ona zapewnia c dok ladne i równomierne rozprowadzenie zwi azku wed lug niniejszego wynalazku. Preparaty wytwarza si e znanym sposobem, np. przez polaczenie substancji czynnej z rozpusz- czalnikami i/lub no snikami, ewentualnie z u zyciem srodków emulguj acych i dysperguj acych, przy czym w przypadku wody jako rozpuszczalnika mo zna stosowa c tak ze inne rozpuszczalniki organiczne jako wspó lrozpuszczalniki. Jako substancje pomocnicze stosuje si e te zwykle stosowane w przypadku fungicydów. Preparaty zawieraj a na ogó l 0,01 - 95% wag., korzystnie 0,1 - 90% wag. substancji czyn- nej. Substancje czynne stosuje si e jako zwi azki o czysto sci 90% - 100%, a korzystnie 95% - 100% (wed lug widm NMR). P r z y k l a d y preparatów: I. 5 cz esci wagowych zwi azku wed lug wynalazku zmieszano dok ladnie z 95 cz esciami wago- wymi drobno zmielonego kaolinu. Otrzymano w ten sposób preparat do opylania zawieraj acy 5% wag. substancji czynnej. II. 30 cz esci wagowych zwi azku wed lug wynalazku zmieszano z mieszanin a 92 cz esci wago- wych sproszkowanego zelu krzemionkowego i 8 cz esci wagowych oleju parafinowego rozpylonego naPL 203 550 B1 9 powierzchni tego zelu krzemionkowego. Otrzymano w ten sposób preparat substancji czynnej o do- brych w la sciwo sciach adhezyjnych (zawarto sc substancji czynnej 23% wag.). III. 10 czesci wagowych zwi azku wed lug wynalazku rozpuszczono w mieszaninie 90 cz esci wa- gowych ksylenu, 6 cz esci wagowych adduktu 8-10 moli tlenku etylenu i 1 mola N-monoetanoloamidu kwasu oleinowego, 2 cz esci wagowych dodecylobenzenosulfonianu wapnia i 2 cz esci wagowych ad- duktu 40 moli tlenku etylenu i 1 mola oleju rycynowego (zawarto sc substancji czynnej 9% wag.). IV. 20 cz esci wagowych zwi azku wed lug wynalazku rozpuszczono w mieszaninie 60 cz esci wa- gowych cykloheksanonu, 30 cz esci wagowych izobutanolu, 5 cz esci wagowych adduktu 7 moli tlenku etylenu i 1 mola izooktylofenolu i 5 cz esci wagowych adduktu 40 moli tlenku etylenu i 1 mola oleju rycynowego (zawarto sc substancji czynnej 16% wag.). V. 80 cz esci wagowych zwi azku wed lug wynalazku zmieszano dok ladnie z 3 cz esciami wa- gowymi diizobutylonaftaleno- a-sulfonianu sodu, 10 cz esciami wagowymi soli sodowej kwasu ligno- sulfonowego z posiarczynowego lugu odpadowego i 7 cz esciami wagowymi sproszkowanego zelu krzemionkowego, po czym mieszanin e zmielono w m lynku m lotkowym (zawarto sc substancji czyn- nej 80% wag.). VI. 90 czesci wagowych zwi azku wed lug wynalazku zmieszano z 10 cz esciami wagowymi N-metylo- a-pirolidonu i otrzymano roztwór odpowiedni do u zycia w postaci mikrokropel (zawartosc substancji czynnej 90% wag.). VII. 20 cz esci wagowych zwi azku wed lug wynalazku rozpuszczono w mieszaninie 40 cz esci wag. cykloheksanonu, 30 cz esci wag. izobutanolu, 20 cz esci wag. adduktu 7 moli tlenku etylenu i 1 mola izooktylofenolu, 10 cz esci wagowych adduktu 40 moli tlenku etylenu i 1 mola oleju rycynowe- go. Po wlaniu roztworu do 100000 cz esci wagowych wody, otrzymano wodn a dyspersj e zawieraj ac a 0,02% wag. substancji czynnej. VIII. 20 czesci wagowych zwi azku wed lug wynalazku zmieszano dok ladnie z 3 cz esciami wa- gowymi diizobutylonaftaleno- a-sulfonianu sodu, 17 cz esciami wagowymi soli sodowej kwasu lignosul- fonowego z lugu posiarczynowego i 60 cz esciami wagowymi sproszkowanego zelu krzemionkowego, po czym mieszanin e zmielono w m lynku m lotkowym. Po dok ladnym rozprowadzeniu mieszaniny w 20000 cz esciach wagowych wody otrzymano mieszanin e opryskow a zawieraj ac a 0,1 wag. substancji czynnej. Wodne postacie u zytkowe mo zna wytwarza c z koncentratów do emulgowania, past lub proszków zwil zalnych (proszki do oprysku, dyspersje na bazie oleju) przez dodanie wody. Przy wytwarzaniu emulsji, past lub dyspersji na bazie oleju, te substancje jako takie lub rozpuszczone w oleju albo w rozpuszczalniku, mo zna homogenizowa c w wodzie z u zyciem srodka zwil zaj acego, srodka zwi ekszaj acego przyczepno sc, dyspergatora lub emulgatora. Mo zna tak ze wytwarza c koncentraty z lo zone z substancji czynnej, srodka zwil zaj acego, srodka zwi ekszaj acego przyczepno sc, dyspergatora lub emulgatora oraz, w razie potrzeby, rozpuszczalnika lub oleju, przy czym takie koncentraty nadaj a si e do rozcie nczania wod a. St ezenie substancji czynnej w gotowych do u zycia preparatach mo ze si e zmienia c w szerokim zakresie. Wynosi ono na ogó l 0,0001 - 10%, a korzystnie 0,01 - 1%. Substancje czynne mo zna tak ze stosowa c z dobrym skutkiem z u zyciem metody ultrama loobj e- to sciowej (ULV), co umo zliwia nanoszenie preparatów o st ezeniu substancji czynnej powy zej 95% wag. lub nawet samej substancji czynnej bez dodatków. Do substancji czynnych mo zna dodawa c ró zne typy olejów, herbicydy, inne fungicydy, inne srodki zwalczaj ace szkodniki, bakteriocydy, ewentualnie dopiero bezpo srednio przed u zyciem (mieszanka zbior- nikowa). Srodki te mo zna miesza c ze srodkami wed lug wynalazku w stosunku wagowym od 1:10 do 10:1. Uwag e dotycz ac a dzia lania substancji czynnych o wzorze I wzbudzaj acych oporno sc na wirusy mo zna umie scic na opakowaniu lub na ulotkach dolaczonych do produktu. T e uwag e mo zna tak ze umie sci c na preparatach, które stosuje si e w kompozycji z substancjami czynnymi o wzorze I. Zdolno sc wzbudzania oporno sci mo ze by c wskazaniem do uzyskania urz edowego dopuszcze- nia substancji czynnych o wzorze I do obrotu. Dzia lanie zwi azków o ogólnym wzorze I mo zna wykaza c w nast epuj acych próbach: Przyk lady stosowania, wzbudzanie oporno sci na wirusy Materia l ro slinny Dla celów prób hodowano ro sliny tytoniu (Nicotiana tabacum cv. Xanthi-nc) w temperaturze 25°C, przy wilgotno sci 59% i przy swietle dziennym przez 16 godzin (150-200 µM kwantów/s -1 /m -2 ) przez 4-5 tygodni w ziemi doniczkowej (ziemia standardowa typu ED 73). Cz es c ro slin jeden raz w tygodniu zasilano nawozami, dodaj ac do wody przy podlewaniu odpowiedni a dawk e handlowego nawozu do kwiatów domowych (10% azotu ogó lem, 9% fosforanu, 7% potasu).PL 203 550 B1 10 Nanoszenie substancji czynnej Stosowano sformu lowane substancje czynne w postaci granulatów dyspergowalnych w wodzie zawieraj acych 20% substancji czynnej. Zastosowane w próbach st ezenia (0,01 - 10 mM) przeliczono na zawarto sc substancji czynnej. Dla unikni ecia rozprowadzenia substancji czynnej w ca lej ro slinie, lodygi ro slin usuwano powy zej miejsca naniesienia na li sc za pomoc a sterylnego skalpela. Po naniesieniu substancji czynnej, a nast epnie po zaka zeniu wirusem, ro sliny pozostawiono w komorze wzrostowej. Okre slenie infekcji wirusowej i oporno sci (wed lug Malamy i inni, SCIENCE, tom 250, str. 1002- 1004 (1990)): Ró zne wst epnie potraktowane ro sliny tytoniu zara zono wirusem mozaiki tytoniu (TMV, szczep U1). W tym celu podstawowy roztwór szczepu wirusa z 50 mM buforu fosforanowego (pH 7) rozcie n- czono do ko ncowego st ezenia 1 µg bia lka pokrytego TMV/ml. Infekcj e spowodowano przez lagodne pocieranie umoczonym w roztworze TMV banda zem gazowym li sci, których powierzchnie posypano w eglikiem krzemu. Po zaka zeniu w eglik krzemu sp lukano z li sci lagodnym strumieniem wody i ro sliny umieszczono w wy zej opisanych warunkach. Infekcj e TMV przeprowadzono w 1 dzie n po naniesieniu. W piec do siedmiu dni po zara zeniu okre slono srednic e 10 - 20 uszkodze n na li sciach. Srednica uszkodzenia jest miar a nabytej oporno sci ro slin, przy czym najmniejsze uszkodzenia odpowiadaj a najwy zszej nabytej oporno sci. P r z y k l a d stosowania 1 Poszczególne li scie ro slin przedziurawiono ig la do wstrzykniec w kilku miejscach i w miejscach nak lucia wstrzykni eto strzykawk a wodny roztwór substancji czynnej (wstrzykni eta ilosc 2-5 ml/lisc). Nierozpuszczalne sk ladowe cz esci roztworu substancji czynnej oddzielono uprzednio albo drog a se- dymentacji, albo drog a krótkotrwa lego odwirowania (3 minuty przy 5000 g). W przypadku ro slin kontro- lnych do li sci wstrzykni eto wod e. Po 7 dniach srednic e spowodowanych przez TMV uszkodze n na li sciach okre slono w milime- trach [mm]. W tym te scie ro sliny potraktowane 1 mM substancji czynnej I-5 z tabeli I wykaza ly uszkodzenia srednio 2,35 mm, a ro sliny potraktowane przy st ezeniu 2,5 mM wykaza ly uszkodzenia 1,8 mm, pod- czas gdy ro sliny kontrolne potraktowane czyst a wod a wykaza ly uszkodzenia 3,55 mm. P r z y k l a d stosowania 2 Jedn a po low e traktowanego li scia nas aczono roztworem substancji czynnej (wytworzonym jak w przyk ladzie 1), podczas gdy drug a po low e li scia nas aczono wod a. Taki sposób post epowania powi- nien wykluczy c ró znice przy reakcji pomi edzy ró znymi liscmi i umo zliwi c bezpo srednie okre slenie efek- tu dzia lania substancji czynnej. Po 5 dniach srednic e spowodowanych przez TMV uszkodze n na li sciach okre slono w milime- trach [mm]. W tym te scie strefy li scia potraktowane 0,5 i 1 mM substancji czynnej I-5 z tabeli I wykaza ly uszkodzenia srednie odpowiednio 2,75 mm i 2,85 mm, a niepotraktowane strefy li scia mia ly uszko- dzenia 4,15 mm i 4,25 mm, podczas gdy ro sliny potraktowane czyst a wod a jako ro sliny kontrolne wy- kaza ly uszkodzenia 3,2 mm i 3,35 mm. P r z y k l a d stosowania 3 Po lówki li sci oko lo 5-tygodniowych ro slin tytoniu (odmiana Xanthi-nc) nas aczono 1 mM roztworu substancji czynnej w 1% wodnym roztworze etanolu. Po lówki li sci ro slin kontrolnych nas aczono 1% wodnym roztworem etanolu. Zara zenie TMV przeprowadzono w 1 dzie n po naniesieniu; ro sliny oceniono po nast epnych 5 dniach. Przedstawiono srednie warto sci obumar lych zara zonych wirusem powierzchni li sci (uszkodzenia) w miejscu infekcji na potraktowanych substancj a czynn a lub niepotraktowanych po lówkach li sci (ro sliny kontrolne). Powierzchnia uszkodze n w porównaniu do ro slin kontrolnych: Substancja czynna Powierzchnia w procentach I-5 53,0% II-3 68,1% III-4 60,3% IV-6 76,1% VII-1 62,1%PL 203 550 B1 11 P r z y k l a d stosowania 4 Prób e przeprowadzono jak w przyk ladzie stosowania 3, z tym, ze zara zenie przeprowadzono w 2 dni po naniesieniu i ro sliny oceniono po nast epnych 5 dniach. Powierzchnia uszkodze n w porównaniu do ro slin kontrolnych: Substancja czynna Powierzchnia w procentach II-3 62,7% III-4 78,4% VII-1 70,4% P r z y k l a d stosowania 5 Oprysk li sci roztworami substancji czynnej Z u zyciem uniwersalnego srodka zwil zaj acego rozpuszczono 2 mM substancji czynnej w wodzie w stosunku 1:1 (wag./wag.) i opryskano po lówki li scia 5-tygodniowych ro slin tytoniu (odmiana Xanthi- nc) (po lówki ro slin kontrolnych opryskano jedynie rozpuszczonym srodkiem zwil zaj acym). Zara zenie TMV przeprowadzono w 5 dni po naniesieniu, a oceny dokonano po dalszych 4 dniach. Przedstawiono srednie warto sci obumar lych zara zonych wirusem powierzchni li sci (uszko- dzenia) w miejscu infekcji na potraktowanych substancj a czynn a lub niepotraktowanych po lówkach li sci (ro sliny kontrolne). Powierzchnia uszkodze n w porównaniu do ro slin kontrolnych: Substancja czynna Powierzchnia w procentach II-3 49,6% III-4 73,6% VII-1 68,3% PL PLDescription of the invention The present invention relates to the use of strobilurins for the production of an agent for inducing resistance to viruses in plants. A large number of representatives of the highly diverse group of plant viruses (phytophages) are capable of attacking plants of economic importance; the symptoms of leg injuries range from morphological changes to plant death. Due to the various pathways of virus transmission (e.g. mechanically by damage, by seed and drug dust, or by vectors such as nematodes and insects), diagnosis problems and the lack of suitable active substances, the control of such viruses is extremely difficult, and therefore the priority is there are preventive and phytosanitary measures. Thus, the avoidance of viral diseases in plants is an important goal in agriculture. In the search for ways to avoid viral diseases in plants, antiviral active substances, some of which are closely related to nucleic acids, have already been developed. However, some of these substances cause the production of mutants and inhibit the metabolism of nucleic acids and protein in the host cells, causing damage. Under field conditions, such materials have only little actual control effect. A complicated approach is to use or stimulate the forest defense forces of plants. DE-A 3934761 proposes the use of polylysine and alkyl diethylene triamine acetic acids to avoid viral diseases in plants. EP-A 420803 describes the immunizing effect of benzo-1,2,3-thiazole derivatives against various phytopathogenic microorganisms. A similar effect of pyridylthiazoles is known from WO-A 96/37493. In DD 280030, sulfonic acid derivatives are proposed as agents for activating resistance in crops and crops. However, the action of such substances is in many cases insufficient. It was therefore an object of the invention to provide active compounds for the production of agents which can be widely used without damaging the plants and which can provide effective immunity against plant viral diseases. It has been found that this aim is achieved by the use of strobilurins of the general formula I below defined. The active substances used are known as fungicides and in some cases also as insecticides (EP-A 178826; EP-A 253213; WO-). A 93/15046; WO-A 95/18789; WO-A 95/21153; WO-A 95/21154; WO-A 95/24396; WO-A 96/01256; WO-A 97/15552). However, no suggestion has been made so far as to the possibility that these active substances may have a stimulating effect on the plant's own immune system against viruses. The invention therefore relates to the use of strobilurins of general formula I in which X is halogen, C 1 -C 4 -alkyl or trifluoromethyl; m is 0 or 1; Q is C (= CH-CH 3) -COOCH 3, C (= CH-OCH 3) -COOCH 3, C (= N-OCH 3) -CONHCH 3, C (= N- OCH 3) -COOCH 3 or N (-OCH 3) -COOCH 3; A is -OB, -CH 2 OB, -CH 2 ON = C (R1) -B or -CH 2 ON = C (R1) -C (R2) = N-OR 3, where B is phenyl, pyridyl, pyrimidinyl, pyrazolyl or triazolyl, which ring systems are substituted with one or two groups R a; R a is cyano, e nitro, amino, aminothiocarbonyl, aminothiocarbonyl, halogen, C 1 -C 6 -alkyl, C 1 -C 6 -halogenalkyl, C 1 -C 6 -alkylcarbonyl, C 1 -C 6 -alkylsulfonyl, C 1 -C 6 -alkylsulfinyl, C 3 -C 6 -cycloalkyl, C 1 -C 6 -alkoxy, C 1 -C 6 -halogenalkoxy, C 1 -C 6 -alkyloxycarbonyl, pe C 1 -C 6 -alkylamino, C 1 -C 6 -alkylamino, C 1 -C 6 -alkylamino, C 1 -C 6 -alkylamino-carbonyl, di-C 1 -C 6 -alkylaminocarbonyl, C 1 -C 6 -alkylaminothiocarbonyl, di-C 1 -C 6 -alkylaminothiocarbonyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkenyloxy, phenyl, phenoxy, benzyl, benzyloxy, 5- or 6- one piece heterocyclyl, 5- or 6-piece heteroaryl, 5- or 6-piece heteroaryloxy, C (= NOR a) -OR ß or OC (Ra) 2 - C (R ß) = NOR ß where cyclic groups are optionally substituted with 1-3 groups R b: PL 203 550 B1 3 R b is cyano, e nitro, halogen, amino, aminothiocarbon yl, C 1 -C 6 -alkyl, C 1 -C 6 -haloalkyl, C 1 -C 6 -alkylsulfonyl, C 1 -C 6 -alkylsulfinyl, C 3 -C 6 -cycloalkyl, C 1 -C 6 -alkoxy , C 1 -C 6 -halogenalkoxy, C 1 -C 6 -alkoxycarbonyl, C 1 -C 6 -alkylthio, C 1 -C 6 -alkylamino, E di-C 1 -C 6 -alkylamino , C 1 -C 6 -alkylaminocarbonyl, di-C 1 -C 6 -alkylaminocarbonyl, C 1 -C 6 -alkylaminothiocarbonyl, di-C 1 -C 6 -alkylaminothiocarbonyl, C 2 -C 6 -alkenyl, C 2 - C 6 -alkenyloxy, C 3 -C 6 -cycloalkyl, C 3 -C 6 -cycloalkenyl, phenyl, phenoxy, phenylthio, benzyl, benzyloxy, 5- or 6-membered heterocyclyl, 5- or 6-membered heteroaryl, 5- or 6-membered heteroaryloxy or C (= NOR a) -OR ß; R a and R 6 are a hydrogen or C 1 -C 6 -alkyl; R 1 is hydrogen, C cyano, C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 3 -C 6 cycloalkyl or C 1 -C 4 alkoxy; R 2 is C 1 -C 6 alkyl, C 2 -C 10 alkenyl or C 3 -C 6 cycloalkyl, which groups are optionally substituted with one or two Rb 'groups; where R b 'is C 1 -C 6 alkyl, C 3 -C 6 cycloalkyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkoxy, benzyl, phenyl or phenoxy; or R2 is phenyl optionally substituted with one or two R a groups; and R 3 is C 1 -C 6 -alkyl, C 2 -C 10 -alkenyl or C 2 -C 10 -alkynyl; for the production of an agent for inducing resistance to viruses in plants. Preferably, in relation to the above embodiment, an active ingredient of general formula II is used in which T is N or CH; x is 0,1 - 3; y is 0 or 1; Ra 'has the meaning given above for Ra; and R b has the meaning given above. Preferably, in relation to the above embodiment, an active ingredient of formula III is used in which V is OCH 3 or NHCH 3; Y is N and Ra is as defined above. More preferably with regard to the above embodiment, an active ingredient selected from the group of compounds I-5, III-4 and VII-1PL 203 550 B1 is used. For the control of plant diseases, it is possible to apply to the above-ground parts of plants as well as to seedlings, seeds and soil. , or through the roots of the plant, and it is distributed throughout the plant sap throughout the plant. Thus, the protective effect after the application of the active compounds of the formula I according to the invention occurs not only in the parts of the plants directly sprayed, since the resistance of the whole plant against viral diseases is increased. In a preferred embodiment of the invention, the above-ground parts of plants are treated with the preparation of an active compound of the formula I. The publications cited at the beginning describe methods for the synthesis of the active ingredients used according to the invention. In accordance with the invention, it is particularly preferred to use the active ingredients which have the substituents of the following meaning, in each case individually and in combination. Particularly preferred according to the invention are active compounds of the formulas II - VIII in which V is OCH 3 or NHCH 3, Y is CH or nitrogen and T and Z are independently CH or nitrogen. The preferred active compounds of formula I in which Q is N (-OCH 3) -COOCH 3 are the compounds described in WO-A 93/15046 and WO-A 96/01256. The preferred active compounds of formula I in which Q is C (= CH-OCH 3) -COOCH 3 are those described in EP-A 178 826 and EP-A 278595. Preferred active compounds of formula I in which Q is C (= N-OCH 3) -COOCH 3 are the compounds described in EP-A 253 213 and EP-A 254426. Preferred active compounds of formula I in which Q is C (= N-OCH 3) -CONHCH 3 are the compounds described in EP-A 398692, EP-A 477631 and EP-A 628540. Preferred active compounds of formula I, in which Q is C (= CH-CH 3) -COOCH 3, are those described in EP-A 280185 and EP-A 350691. Preferred active compounds of formula I, in which A is -CH 2 ON = C (R1) -B, are the compounds described in EP-A 460 575 and EP-A 463 488. of formula I in which A is -OB are the compounds described in EP-A 382 375 and EP-A 398 692. Preferred active compounds of formula I in which A is -CH 2 ON = C (R1) -C (R 2) = N-OR 3, these are the compounds described in WO-A 95/18789, WO-A 95/21153, WO-A 95/21154, WO-A 97 / 05103 and WO-A 97/06133. Particularly preferred are active compounds of formula I in which Q is N (-OCH 3) -COOCH 3, A is CH 2 -OB and B is 3-pyrazolyl or 1,2,4-triazolyl, wherein the group B is substituted with one or two substituents selected from the group consisting of halogen, methyl and trifluoromethyl, and phenyl and pyridyl, especially 2-pyridyl, substituted with 1-3 Rb groups. These active substances are described by formula II. Other particularly preferred active compounds are the compounds of formula II '. Due to their usefulness in use, the compounds given in the tables are particularly preferred. TABLE I No.T (R a ') y Position of the substituted phenyl group (R b) x (R b) x Literature reference I-1 N - 1 2,4-Cl 2 WO-A 96/01256 I-2 N - 1 4-Cl WO-A 96/01256 I-3 CH - 1 2-Cl WO-A 96/01256 I-4 CH - 1 3-Cl WO-A 96/01256 I-5 CH - 1 4-Cl WO-A 96/01256 I-6 CH - 1 4-CH 3 WO-A 96/01256 I-7 CH - 1 H WO-A 96/01256 I-8 CH - 1 3-CH 3 WO-A 96 / 01256 I-9 CH 5-CH 3 1 3-CF 3 WO-A 96/01256 I-10 CH 1-CH 3 5 3-CF 3 WO-A 99/33812 I-11 CH 1-CH 3 5 4- Cl WO-A 99/33812 I-12 CH 1-CH 3 5 - WO-A 99/33812 Table II VYR No. a Literature reference II-1 OCH 3 N 2-CH 3 EP-A 253213 II-2 OCH 3 N 2,5- (CH 3) 2 EP-A 253 213 II-3 NHCH 3 N 2,5- (CH 3) 2 EP-A 398 692 II-4 NHCH 3 N 2-Cl EP-A 398692 II-5 NHCH 3 N 2-CH 3 EP-A 398 692 II-6 NHCH 3 N 2-CH 3, 4-OCF 3 EP-A 628 540 II-7 NHCH 3 N 2-Cl, 4-OCF 3 EP-A 628 540 II- 8 NHCH 3 N 2-CH 3, 4-OCH (CH 3) -C (CH 3) = NOCH 3 Ag. DE 10002661.3 II-9 NHCH 3 N 2-Cl, 4-OCH (CH 3) -C ( CH 3) = NOCH 3 Death DE 10002661.3 II-10 NHCH 3 N 2-CH 3, 4-OCH (CH 3) -C (CH 2 CH 3) = NOCH 3 Dec. DE 10002661.3 II-11 NHCH 3 N 2-Cl, 4-OCH (CH 3) -C (CH 3) = NOCH 2 CH 3 Dec. DE 10002661.3PL 203 550 B1 6 Table III VYTR No. a Odno literature III-1 OCH 3 CH N 2-OCH 3, 6-CF 3 WO-A 96/16047 III-2 OCH 3 CH N 2-OCH (CH 3) 2, 6-CF 3 WO-A 96/16047 III-3 OCH 3 CH CH 5-CF 3 EP-A 278595 III-4 OCH 3 CH CH 6-CF 3 EP-A 278595 III-5 NHCH 3 N CH 3-Cl EP-A 398692 III-6 NHCH 3 N CH 3-CF 3 EP-A 398692 III-7 NHCH 3 N CH 3-CF 3, 5-Cl EP-A 398692 III-8 NHCH 3 N CH 3-Cl, 5-CF 3 EP-A 398692 Table IV No.VYR 1 B Literature reference IV-1 OCH 3 CH CH 3 (3-CF 3) C 6 H 4 EP-A 370 629 IV-2 OCH 3 CH CH 3 (3,5-Cl 2) C 6 H 3 EP -A 370629 IV-3 NHCH 3 N CH 3 (3-CF 3) C 6 H 4 WO-A 92/13830 IV-4 NHCH 3 N CH 3 (3-OCF 3) C 6 H 4 WO-A 92 / 13830 IV-5 OCH 3 N CH 3 (3-OCF 3) C 6 H 4 EP-A 460575 IV-6 OCH 3 N CH 3 (3-CF 3) C 6 H 4 EP-A 460 575 IV-7 OCH 3 N CH 3 (3,4-Cl 2) C 6 H 3 EP-A 460 575 IV-8 OCH 3 N CH 3 (3,5-Cl 2) C 6 H 3 EP-A 463488 Table VPL 203 550 B1 7 No. VR 1 R 2 R 3 Reference lit erature V-1 OCH 3 CH 3 CH 3 CH 3 WO-A 95/18789 V-2 OCH 3 CH 3 CH (CH 3) 2 CH 3 WO-A 95/18789 V-3 OCH 3 CH 3 CH 2 CH 3 CH 3 WO-A 95/18789 V-4 NHCH 3 CH 3 CH 3 CH 3 WO-A 95/18789 V-5 NHCH 3 CH 3 4-FC 6 H 4 CH 3 WO-A 95/18789 V-6 NHCH 3 CH 3 4-Cl-C 6 H 4 CH 3 WO-A 95/18789 V-7 NHCH 3 CH 3 2,4-C 6 H 3 CH 3 WO-A 95/18789 V-8 NHCH 3 Cl 4- FC 6 H 4 CH 3 WO-A 98/38857 V-9 NHCH 3 Cl 4-Cl-C 6 H 4 CH 2 CH 3 WO-A 98/38857 V-10 NHCH 3 CH 3 CH 2 C (= CH 2 ) CH 3 CH 3 WO-A 97/05103 V-11 NHCH 3 CH 3 CH = C (CH 3) 2 CH 3 WO-A 97/05103 V-12 NHCH 3 CH 3 CH = C (CH 3) 2 CH 2 CH 3 WO-A 97/05103 V-13 NHCH 3 CH 3 CH = C (CH 3) CH 2 CH 3 CH 3 WO-A 97/05103 Table VI No. VYR a Literature reference VI-1 NHCH 3 N 3-CH 3 EP-A 398692 VI-2 NHCH 3 N 2-NO 2 EP-A 398692 VI-3 NHCH 3 N 4-NO 2 EP-A 398692 VI-4 NHCH 3 N 4-Cl EP-A 398692 VI -5 NHCH 3 N 4-Br EP-A 398692 Table VIIPL 203 550 B1 8 No. VYTR a Literature reference VII-1 OCH 3 CH N 6-O- (2-CN-C 6 H 4) EP-A 382375 VII-2 OCH 3 CH N 6-O- (2-Cl-C 6 H 4) EP- A 382 375 VII-3 OCH 3 CH N 6-O- (2-CH 3 -C 6 H 4) EP-A 382 375 VII-4 NHCH 3 NN 6-O- (2-Cl-C 6 H 4) GB- A 2253624 VII-5 NHCH 3 NN 6-O- (2,4-Cl 2 -C 6 H 3) GB-A 2253624 VII-6 NHCH 3 NN 6-O- (2-CH 3 -C 6 H 4) GB-A 2253624 VII-7 NHCH 3 NN 6-O- (2-CH 3, 3-Cl-C 6 H 3) GB-A 2253624 VII-8 NHCH 3 NN 2-F, 6-O- (2- CH 3 -C 6 H 4) WO-A 98/21189 VII-9 NHCH 3 NN 2-F, 6-O- (2-Cl-C 6 H 4) WO-A 98/21189 VII-10 NHCH 3 NN 2-F, 6-O- (2-CH 3, 3-Cl-C 6 H 3) WO-A 98/21189 The active substances I-5 (common name: pyraclostrobin), III-4 (common name) are particularly preferred : picoxystrobin), IV-6 (common name: trifloxystrobin) and VII-1 (common name: azoxystrobin). Compounds I increase plant resistance to viruses. They are of particular importance in the control of viruses in various crops, such as tobacco, barley, cucumbers, potatoes and beets, as well as in the seeds of these plants. They are particularly suitable for combating the following plant diseases: in tobacco, tobacco mosaic virus and tobacco necrosis virus, in beans, bean mosaic virus and bean yellow mosaic virus, in barley, striped mosaic virus and yellow barley, in cucumbers, cucumber green mosaic virus and cucumber mosaic virus, in potatoes, X disease virus and potato disease Y virus, in beetroot, rhizomania virus and mild beetroot yellows virus. Compounds I are applied by applying an effective amount of active substances to plants, seeds or soil endangered with viruses. Application can be carried out both before and after infection by plant or seed viruses. In a preferred embodiment, the application to the plants is carried out prior to infection. It is then observed that the plant's susceptibility to viral diseases is significantly reduced. The application rates for plant protection application are, depending on the type of pathogens and plant species, 0.01-2.0 kg of active ingredient per hectare. In seed treatment, the amount of active ingredient is generally 0.001-0.1 g, preferably 0.01-0.05 g, of active ingredient per kilogram of seed. The compounds of formula I can be formulated in the form of preparations customary for fungicides, such as solutions, emulsions, suspensions, dusts, powders, pastes and granules. The use form depends on the purpose of use and in any case it should ensure a fine and even distribution of the compound according to the present invention. The formulations are prepared in a known manner, for example by combining the active ingredient with solvents and / or carriers, or with the use of emulsifying and dispersing agents, and in the case of water as the solvent, other organic solvents can also be used as co-solvents. The adjuvants used are those usually used for fungicides. The formulations generally contain from 0.01 to 95% by weight, preferably from 0.1 to 90% by weight. active ingredient. The active substances are used as compounds with a purity of 90% -100%, preferably 95% -100% (according to the NMR spectra). Examples of the formulations: I. 5 parts by weight of the compound according to the invention were intimately mixed with 95 parts by weight of finely ground kaolin. In this way, a dust composition containing 5 wt. active substance. II. 30 parts by weight of a compound according to the invention were mixed with a mixture of 92 parts by weight of powdered silica gel and 8 parts by weight of paraffin oil sprayed onto the surface of the silica gel. An active compound formulation with good adhesive properties (active compound content 23% by weight) was thus obtained. III. 10 parts by weight of the compound according to the invention are dissolved in a mixture of 90 parts by weight of xylene, 6 parts by weight of an adduct of 8-10 moles of ethylene oxide and 1 mole of oleic acid-N-monoethanolamide, 2 parts by weight of calcium dodecylbenzenesulfonate and 2 parts by weight of an additive of 40 moles of ethylene oxide and 1 mole of castor oil (active ingredient content 9% by weight). IV. 20 parts by weight of the compound according to the invention are dissolved in a mixture of 60 parts by weight of cyclohexanone, 30 parts by weight of isobutanol, 5 parts by weight of an adduct of 7 moles of ethylene oxide and 1 mole of isooctylphenol and 5 parts by weight of an adduct of 40 moles of ethylene oxide, and 1 mole of castor oil (active ingredient content 16% by weight). V. 80 parts by weight of the compound according to the invention are intimately mixed with 3 parts by weight of sodium diisobutylnaphthalene a-sulfonate, 10 parts by weight of sodium lignosulfonic acid from the sulfite waste liquor and 7 parts by weight of powdered silica gel and then the mixture is ground in millium zinc (active ingredient content 80% by weight). VI. 90 parts by weight of the compound according to the invention are mixed with 10 parts by weight of N-methyl-α-pyrrolidone to obtain a solution suitable for use in the form of microdroplets (active ingredient content 90% by weight). VII. 20 parts by weight of a compound according to the invention are dissolved in a mixture of 40 parts by weight. parts of cyclohexanone, 30 parts by weight parts of isobutanol, 20 parts by wt. of an adduct of 7 moles of ethylene oxide and 1 mole of isooctylphenol, 10 parts by weight of an adduct of 40 moles of ethylene oxide and 1 mole of castor oil. After pouring the solution into 100,000 parts by weight of water, an aqueous dispersion was obtained containing 0.02% by weight of water. active substance. VIII. 20 parts by weight of the compound according to the invention are intimately mixed with 3 parts by weight of sodium diisobutylnaphthalene a-sulfonate, 17 parts by weight of sodium lignosulfonic acid salt from sulfite liquor, and 60 parts by weight of powdered silica gel, and then the mixture is mixed with that was ground in ml of lotion. After the mixture was thoroughly distributed in 20,000 parts by weight of water, a spray mixture containing 0.1 wt. active substance. Aqueous use forms can be prepared from emulsifiable concentrates, pastes or wettable powders (sprayable powders, oil-based dispersions) by adding water. In the preparation of oil-based emulsions, pastes or dispersions, these substances can be homogenized as such or dissolved in oil or in a solvent in water using a wetting agent, adhesion promoter, dispersant or emulsifier. It is also possible to prepare concentrates composed of an active substance, a wetting agent, an adhesion promoter, a dispersant or an emulsifier and, if necessary, a solvent or oil, and such concentrates are suitable for diluting water. The active substance concentration in the ready-to-use preparations can vary widely. It is generally 0.0001-10% and preferably 0.01-1%. The active ingredients can also be used to good effect using the ultra-loosely-retained method (ULV), which makes it possible to apply formulations with an active ingredient concentration of more than 95% by weight. or even the active substance itself without additives. Various types of oils, herbicides, other fungicides, other pest control agents, bactericides can be added to the active substances, or only immediately before use (tank mix). These agents may be mixed with the agents according to the invention in a weight ratio of 1:10 to 10: 1. Information on the action of the active substances of formula I in inducing resistance to viruses can be made on the packaging or on the leaflets accompanying the product. This remark can also be made on preparations that are used in the composition with active substances of formula I. The ability to induce resistance may be an indication for obtaining official approval of the active substances of formula I on the market. . The action of compounds of general formula I can be demonstrated in the following tests: Examples of use, induction of resistance to viruses Plant material For the purposes of the tests, tobacco plants (Nicotiana tabacum cv. Xanthi-nc) were grown at 25 ° C C, at a humidity of 59% and under daylight for 16 hours (150-200 µM quanta / s -1 / m -2) for 4-5 weeks in potting soil (standard soil type ED 73). Part of the plant was fed once a week with fertilizers, adding an appropriate dose of commercial fertilizer for house flowers (10% total nitrogen, 9% phosphate, 7% potassium) to the water during watering. The formulated active ingredients were used in the form of water-dispersible granules containing 20% of active ingredient. The concentrations used in the tests (0.01 - 10 mM) were converted to the content of active substance. To avoid the distribution of the active ingredient throughout the plant, the stems of the plants were removed above the application site on the leaves with a sterile scalpel. After application of the active ingredient, and then after infection with the virus, the plants were left in the growth chamber. Determination of viral infection and resistance (according to Malama et al., SCIENCE, vol. 250, pp. 1002-1004 (1990)): Various pretreated tobacco plants have been infected with tobacco mosaic virus (TMV, strain U1). For this, the viral stock solution with 50 mM phosphate buffer (pH 7) was diluted to a final concentration of 1 µg TMV coated protein / ml. The infection was caused by gentle rubbing of a band of gas leaves soaked in TMV solution, the surfaces of which were sprinkled with silicon carbide. After contamination with silicon carbide, the leaves were loosened with a gentle stream of water, and the plants were placed under the conditions described above. Infection with TMV was performed 1 day after application. Five to seven days after infection, the mean diameter of 10 - 20 leg lesions on the leaves were determined. The lesion diameter is a measure of the plant acquired resistance, with the smallest damage being the highest acquired resistance. Application example 1 The individual plant leaves were punctured with an injection needle at several sites and at the injection sites with a syringe with an aqueous solution of the active substance (injected at a quantity of 2-5 ml / leaf). The insoluble components of the active compound solution were previously separated either by sedimentation or by short-term centrifugation (3 minutes at 5000 g). In the case of control plants, the leaves were injected with water. After 7 days, the diameter of the leaf damage caused by TMV was determined in millimeters [mm]. In this case, plants treated with 1 mM of the active ingredient I-5 from Table I showed lesions on average 2.35 mm, and plants treated with a concentration of 2.5 mM showed 1.8 mm lesions, while The control saliva was treated with clean water and showed damage of 3.55 mm. Application example 2 One half of the treated leaf is soaked with a solution of the active ingredient (prepared as in example 1), while the second half of the leaf is soaked with water. changes in the reaction between the different leaves and enables the direct determination of the effect of the active ingredient. After 5 days, the diameter of TMV-induced leg injuries on the leaves was determined in millimeters [mm]. In this area, the leaf zones treated with 0.5 and 1 mM of active ingredient I-5 from Table I showed average lesions of 2.75 mm and 2.85 mm, respectively, and the untreated leaf zones showed lesions of 4.15 mm and 4.25 mm, while plants treated with clean water as control plants showed damage of 3.2 mm and 3.35 mm. Application example 3 Halves of leaves of about 5-week-old tobacco plants (Xanthi-nc variety) were soaked in 1 mM solution of the active substance in 1% aqueous ethanol solution. The halves of the leaves of the control plants were soaked in 1% aqueous ethanol solution. Infection with TMV was carried out on day 1 after application; the plants were evaluated after the next 5 days. The mean values of dead leaf surfaces infected with the virus (lesions) at the infection site on the treated or untreated leaves (control plants) are shown. Damage area compared to control plants: Active substance Area in percent I-5 53.0% II-3 68.1% III-4 60.3% IV-6 76.1% VII-1 62.1% PL Application Example 4 A trial was carried out as in Application Example 3, except that the infection was carried out 2 days after application and the plants were evaluated after a further 5 days. Damage area compared to control plants: Active substance Area in percent II-3 62.7% III-4 78.4% VII-1 70.4% Application example 5 Spraying leaves with solutions of the active substance Using a universal agent the moisturizer was dissolved with 2 mM of the active substance in water in a 1: 1 ratio (w / w) and halves of leaves of 5-week-old tobacco plants (Xanthinc variety) were sprayed (halves of control plants were sprayed only with the dissolved agent wet the occupants). Infection with TMV was performed 5 days after application, and evaluation was done after a further 4 days. The mean values of dead leaf surfaces infected with virus (lesions) at the infection site on the treated or untreated leaves (control plants) are shown. Damage area compared to control plants: Active substance Area in percent II-3 49.6% III-4 73.6% VII-1 68.3% PL PL

Claims (4)

1. Zastrze zenia patentowe 1. Zastosowanie strobiluryn o ogólnym wzorze I w którym X oznacza atom chlorowca, C 1 -C 4 -alkil lub trifluorometyl; m oznacza 0 lub 1; Q oznacza C(=CH-CH 3 )-COOCH 3 , C(=CH-OCH 3 )-COOCH 3 , C(=N-OCH 3 )-CONHCH 3 , C(=N- OCH 3 )-COOCH 3 lub N(-OCH 3 )-COOCH 3 ; A oznacza -O-B, -CH 2 O-B, -CH 2 O-N=C(R 1 )-B lub -CH 2 O-N=C(R 1 )-C(R 2 )=N-OR 3 ; gdzie B oznacza fenyl, pirydyl, pirymidynyl, pirazolil lub triazolil, przy czym te uk lady pier scieniowe s a podstawione jedn a lub dwiema grupami R a ; R a oznacza grup e cyjanow a, grup e nitrow a, grup e aminow a, aminokarbonyl, aminotiokarbonyl, atom chlorowca, C 1 -C 6 -alkil, C 1 -C 6 -chlorowcoalkil, C 1 -C 6 -alkilokarbonyl, C 1 -C 6 -alkilosulfonyl, C 1 -C 6 - -alkilosulfinyl, C 3 -C 6 -cykloalkil, C 1 -C 6 -alkoksyl, C 1 -C 6 -chlorowcoalkoksyl, C 1 -C 6 -alkiloksykarbonyl, gru- p e C 1 -C 6 -alkilotio, grup e C 1 -C 6 -alkiloaminow a, grup e di-C 1 -C 6 -alkiloaminow a, C 1 -C 6 -alkiloamino- karbonyl, di-C 1 -C 6 -alkiloaminokarbonyl, C 1 -C 6 -alkiloaminotiokarbonyl, di-C 1 -C 6 -alkiloaminotiokarbonyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkenyloksyl, fenyl, fenoksyl, benzyl, benzyloksyl, 5- lub 6-cz lonowy heterocyklil, 5- lub 6-cz lonowy heteroaryl, 5- lub 6-cz lonowy heteroaryloksyl, C(=NOR a )-OR ß lub OC(R a ) 2 - -C(R ß )=NOR ß , przy czym te grupy cykliczne s a ewentualnie podstawione 1-3 grupami R b : R b oznacza grup e cyjanow a, grup e nitrow a, atom chlorowca, grup e aminow a, aminokarbonyl, aminotiokarbonyl, C 1 -C 6 -alkil, C 1 -C 6 -chlorowcoalkil, C 1 -C 6 -alkilosulfonyl, C 1 -C 6 -alkilosulfinyl, C 3 -C 6 -cy- kloalkil, C 1 -C 6 -alkoksyl, C 1 -C 6 -chlorowcoalkoksyl, C 1 -C 6 -alkoksykarbonyl, grup e C 1 -C 6 -alkilotio, grup ePL 203 550 B1 12 C 1 -C 6 -alkiloaminow a, grup e di-C 1 -C 6 -alkiloaminow a, C 1 -C 6 -alkiloaminokarbonyl, di-C 1 -C 6 -alkiloamino- karbonyl, C 1 -C 6 -alkiloaminotiokarbonyl, di-C 1 -C 6 -alkiloaminotiokarbonyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alke- nyloksyl, C 3 -C 6 -cykloalkil, C 3 -C 6 -cykloalkenyl, fenyl, fenoksyl, grup e fenylotio, benzyl, benzyloksyl, 5- lub 6-cz lonowy heterocyklil, 5- lub 6-cz lonowy heteroaryl, 5- lub 6-cz lonowy heteroaryloksyl lub C(=NOR a )-OR ß ; R a i R ß oznaczaj a atom wodoru lub C 1 -C 6 -alkil; R 1 oznacza atom wodoru, grup e cyjanow a, C 1 -C 4 -alkil, C 1 -C 4 -chlorowcoalkil, C 3 -C 6 -cykloalkil lub C 1 -C 4 -alkoksyl; R 2 oznacza C 1 -C 6 -alkil, C 2 -C 10 -alkenyl lub C 3 -C 6 -cykloalkil, przy czym te grupy s a ewentualnie podstawione jedn a lub dwiema grupami R b ’; gdzie R b ’ oznacza C 1 -C 6 -alkil, C 3 -C 6 -cykloalkil, C 1 -C 6 -alkoksyl, C 1 -C 6 -chlorowcoalkoksyl, benzyl, fenyl lub fenoksyl; albo R 2 oznacza fenyl ewentualnie podstawiony jedn a lub dwiema grupami R a ; a R 3 oznacza C 1 -C 6 -alkil, C 2 -C 10 -alkenyl lub C 2 -C 10 -alkinyl; do wytwarzania srodka do wzbudzania oporno sci na wirusy w ro slinach.1. Claims 1. The use of strobilurins of general formula I in which X is halogen, C 1 -C 4 -alkyl or trifluoromethyl; m is 0 or 1; Q is C (= CH-CH 3) -COOCH 3, C (= CH-OCH 3) -COOCH 3, C (= N-OCH 3) -CONHCH 3, C (= N- OCH 3) -COOCH 3 or N (-OCH 3) -COOCH 3; A is -O-B, -CH 2 O-B, -CH 2 O-N = C (R 1) -B or -CH 2 O-N = C (R 1) -C (R 2) = N-OR 3; wherein B is phenyl, pyridyl, pyrimidinyl, pyrazolyl or triazolyl, wherein said ring systems are substituted with one or two groups R a; R a is cyano, e nitro, amino, aminothiocarbonyl, aminothiocarbonyl, halogen, C 1 -C 6 -alkyl, C 1 -C 6 -halogenalkyl, C 1 -C 6 -alkylcarbonyl, C 1 -C 6 -alkylsulfonyl, C 1 -C 6 -alkylsulfinyl, C 3 -C 6 -cycloalkyl, C 1 -C 6 -alkoxy, C 1 -C 6 -halogenalkoxy, C 1 -C 6 -alkyloxycarbonyl, pe C 1 -C 6 -alkylthio, C 1 -C 6 -alkylamino, E di-C 1 -C 6 -alkylamino, C 1 -C 6 -alkylamino-carbonyl, di-C 1 -C 6 -alkylaminocarbonyl, C 1 -C 6 -alkylaminothiocarbonyl, di-C 1 -C 6 -alkylaminothiocarbonyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkenyloxy, phenyl, phenoxy, benzyl, benzyloxy, 5- or 6- one heterocyclyl, 5- or 6-membered heteroaryl, 5- or 6-membered heteroaryloxy, C (= NOR a) -OR ß or OC (Ra) 2 - -C (R ß) = NOR ß, with where these cyclic groups are optionally substituted with 1-3 Rb groups: Rb is cyano, e nitro, halogen, e amino, aminothiocarbonyl, C 1 -C 6 -alkyl, C 1 -C 6 -halogenalkyl, C 1 -C 6 -alkylsulfonyl, C 1 -C 6 -alkylsulfinyl, C 3 -C 6 -cycloalkyl, C 1 -C 6 -alkoxy, C 1 -C 6 -halogenoalkoxy, C 1 -C 6 -alkoxycarbonyl, C 1 -C 6 -alkylthio, C 1 -C 6 -alkylamino, C 1 -C 6 -alkylamino, C 1 -C 6 -alkylaminocarbonyl, di-C 1 -C 6 -alkylamino-carbonyl, C 1 -C 6 -alkylaminothiocarbonyl, di-C 1 -C 6 -alkylaminothiocarbonyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkenyloxy, C 3 -C 6 -cycloalkyl, C 3 -C 6 -cycloalkenyl, phenyl, phenoxy, phenylthio, benzyl, benzyloxy, 5- or 6-membered heterocyclyl, 5- or 6-membered heteroaryl , 5- or 6-membered heteroaryloxy or C (= NOR?) -OR ß; R a and R 6 represent a hydrogen or C 1 -C 6 alkyl; R 1 is hydrogen, C cyano, C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 3 -C 6 cycloalkyl or C 1 -C 4 alkoxy; R 2 is C 1 -C 6 alkyl, C 2 -C 10 alkenyl or C 3 -C 6 cycloalkyl, which groups are optionally substituted with one or two Rb 'groups; where R b 'is C 1 -C 6 alkyl, C 3 -C 6 cycloalkyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkoxy, benzyl, phenyl or phenoxy; or R2 is phenyl optionally substituted with one or two R a groups; and R 3 is C 1 -C 6 -alkyl, C 2 -C 10 -alkenyl or C 2 -C 10 -alkynyl; for the production of an agent for inducing resistance to viruses in plants. 2. Zastosowanie wed lug zastrz. 1, zgodnie z którym stosuje si e substancj e czynn a o ogólnym wzorze II w którym T oznacza N lub CH; x oznacza 0, 1 - 3; y oznacza 0 lub 1; R a' ma znaczenie podane w zastrz. 1 odno snie R a ; a R b ma znaczenie podane w zastrz. 1.2. Use according to claim According to claim 1, according to which an active ingredient of general formula II is used in which T is N or CH; x is 0,1 - 3; y is 0 or 1; R a 'has the meaning given in claim 1 as regards Ra; and R b is as defined in claim 1. 3. Zastosowanie wed lug zastrz. 1, zgodnie z którym stosuje si e substancj e czynn a o wzorze III w którym V oznacza OCH 3 lub NHCH 3 ; Y oznacza N; a R a ma znaczenie podane w zastrz. 1.3. Use according to claim Wherein the active ingredient of formula III is used in which V is OCH 3 or NHCH 3; Y is N; and Ra is as defined in claim 1. 4. Zastosowanie wed lug zastrz. 1, zgodnie z którym stosuje si e substancj e czynn a wybran a z grupy zwi azków I-5, III-4 i VII-1 Departament Wydawnictw UP RP Cena 4,92 z l (w tym 23% VAT) PL PL4. Use according to claim 1 1, according to which an active substance is used, selected from the group of compounds I-5, III-4 and VII-1 Department of Publications UP RP Price 4.92 PLN (including 23% VAT) PL PL
PL358784A 2000-05-03 2001-04-30 The use of strobilurins for the production of the agent PL203550B1 (en)

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