PL102452B1 - A METHOD OF PLASTICIZING CONCRETES - Google Patents

A METHOD OF PLASTICIZING CONCRETES Download PDF

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Publication number
PL102452B1
PL102452B1 PL19901377A PL19901377A PL102452B1 PL 102452 B1 PL102452 B1 PL 102452B1 PL 19901377 A PL19901377 A PL 19901377A PL 19901377 A PL19901377 A PL 19901377A PL 102452 B1 PL102452 B1 PL 102452B1
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PL
Poland
Prior art keywords
concretes
concrete
plasticizing
cement
viscosity
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PL19901377A
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Polish (pl)
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PL199013A1 (en
Inventor
Wieslaw Szudrowicz
Andrzej Sloniewski
Maria Blociszewska
Teresa Froelich
Jan Froelich
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Ts Osrodek Badawczo Rozwo
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Priority to PL19901377A priority Critical patent/PL102452B1/en
Publication of PL199013A1 publication Critical patent/PL199013A1/en
Publication of PL102452B1 publication Critical patent/PL102452B1/en

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Description

Przedmiotem wynalazku jest sposób uplastyczniania betonów, miedzy innymi i betonów sprezonych.The subject of the invention is a method of plasticizing concretes, including prestressed concretes, among others.

Znane dotychczas sposoby uplastyczniania betonów, polegajace na zastosowaniu srodków uplastyczniaja¬ cych takich jak abietyniany, produkty wytwarzane na bazie lugów posiarczynowych z dodatkami soli mineral¬ nych, produkty wytwarzane na bazie sulfonowanych zywic arylo-sulfonowych lub alkiloarylo-sulfonowych i inne makromolekularne zwiazki, powodowaly korozje ze wzgledu na zawartosc soli mineralnych, szczególnie chlorków, dodawanych razem z wyzej wymienionymi produktami do mieszanek betonowych w celu regulacji czasu wiazania i z tego powodu nie mogly byc stosowane do betonów sprezonych.Hitherto known methods of plasticizing concrete, consisting in the use of plasticizing agents such as abietates, products based on sulfite liquors with added mineral salts products, products based on sulfonated aryl sulfone resins or alkylarylsulfone resins and other macromolecular compounds caused corrosion due to the content of mineral salts, especially chlorides, added together with the above-mentioned products to concrete mixtures for the purpose of regulating setting time and therefore could not be used for prestressed concretes.

Ponadto powodowaly miedzy innymi napowietrzanie mieszanki betonowej, co z kolei wplywalo na obnizenie wytrzymalosci betonu, opóznialy wiazanie cementu, obnizaly poczatkowa wytrzymalosc betonu, a w przypadku przedozowania 2-krotnego powodowaly niszczenie mieszanki (przestawal wiazac cement). Znane dotychczas próby stosowania do mieszanek betonowych zywic na bazie melaminy i formaldehydu powodowaly przedluzenie czasu wiazania cementu. Charakterystyczna cecha tych zywic byl wysoki ciezar czasteczkowy, wyrazajacy sie lepkoscia ich 20% wodnych roztworów, wynoszaca od 10 do 412 cP w 20°C.In addition, they caused, inter alia, aeration of the concrete mix, which in turn influenced reduction of concrete strength, delayed the setting of cement, lowered the initial strength of concrete, and in the case of double overdosing, they caused the mixture to deteriorate (it stopped binding cement). Known So far, attempts to apply resins based on melamine and formaldehyde to concrete mixes have resulted in this extending the setting time of the cement. A characteristic feature of these resins was the high molecular weight, expressed as the viscosity of their 20% aqueous solutions, ranging from 10 to 412 cP at 20 ° C.

Wady te ograniczaly zakres stosowania wyzej wymienionych srodków, a nawet w wielu przypadkach uniemozliwialy stosowanie ich przy produkcji elementów prefabrykowanych.These disadvantages limited the scope of application of the above-mentioned measures, and even in many cases prevented their use in the production of prefabricated elements.

Stwierdzono nieoczekiwanie, ze mozna osiagnac uplastycznienie betonów, w tym i betonów sprezonych, bez niebezpieczenstwa korozji, unikajac przy tym opisanych wyzej wad -dodajac do mieszanek betonowych jako srodek uplastyczniajacy niskoczasteczkowa zywice melaminowo-formaldehydowa o lepkosci jej 20% wodnego roztworu mniejszej n\z 5 cP w temperaturze 20° C w ilosci 0,1-3% w stosunku do ciezaru cementu.It was unexpectedly found that it is possible to achieve plasticization of concretes, including prestressed concretes, without the risk of corrosion, while avoiding the disadvantages described above - by adding to concrete mixtures as a plasticizing agent, a low-molecular melamine-formaldehyde resin with a viscosity of 20% an aqueous solution of less n / 5 cP at 20 ° C in the amount of 0.1-3% in relation to the cement weight.

Sposób wedlug wynalazku moze byc stosowany do betonów przeznaczonych do wszystkich typów elementów prefabrykowanych, zbrojonych i sprezonych, a takze do betonów monolitycznych.The method according to the invention can be applied to concretes intended for all types prefabricated, reinforced and prestressed elements, as well as for monolithic concrete.

Sposób wedlug wynalazku dzieki polepszeniu urabialnosci, przy zachowaniu pozostalych wymaganych wlasnosci betonu, umozliwia zmniejszenie zuzycia cementu. Wplywa na podwyzszenie, szczególnie przy obróbce2 102 452 cieplnej, poczatkowej wytrzymalosci betonów w stosunku do rzeczywistej zawartosci cementu w betonie przy czym nie zmienia czasu wiazania cementu, co pozwala na skrócenie czasu wytwarzania elementów prefabrykowa¬ nych.The method according to the invention by improving the workability while maintaining the other required concrete properties, enables reduction of cement consumption. Affects the elevation, especially when machining2 102 452 the initial thermal strength of concrete in relation to the actual cement content in the concrete at which does not change the setting time of the cement, which allows to shorten the production time of precast elements all.

Przyklad. Do mieszanki betonowej o stosunku cementowo-wodnym 2,4 i konsystencji 32 sek., zageszczonej na aparacie VeBe, dodano 2% w stosunku do ciezaru cementu, niskoczasteczkowej zywicy melaminowo-formaldehydowej o lepkosci 1,5—3,5 cP i wymieszano calosc .Example. For concrete mix with a cement-water ratio of 2.4 and a consistency of 32 sec., concentrated on the VeBe apparatus, 2% in relation to the weight of the cement, low-molecular resin melamine-formaldehyde with a viscosity of 1.5-3.5 cps and mixed completely.

Tak przygotowana mieszanka betonowa zmienila konsystencje na 8 sek., a wiec z wilgotnej na prawie pólciekla. Dzialanie dodatku nie zmienilo czasu wiazania cementu, podnoszac poczatkowa wytrzymalosc betonu na sciskanie w stosunku do betonu bez srodka uplastyczniajacego wedlug wynalazku, po 3 dniach o 20%, a po 7 dniach o 30%, przy czym beton nie zmienil napowietrzenia.The concrete mix prepared in this way changed the consistency for 8 seconds, i.e. from wet to almost half-liquid. The action of the additive did not change the setting time of the cement, increasing the initial strength concrete in compression in relation to concrete without plasticizer according to the invention, after 3 days by 20%, and after 7 days by 30%, with the concrete not changing the air entrainment.

Claims (1)

1. Zastrzezenie patentowe Sposób uplastyczniania betonów przeznaczonych do wszystkich typów elementów prefabrykowanych, zbrojonych i sprezonych, a takze do betonów monolitycznych, znamienny tym, ze do mieszanki betonowej jako srodek uplastyczniajacy dodaje sie niskoczasteczkowa zywice melaminowo-formaldehydowa. której 20% wodny roztwór w temperaturze 20°C posiada lepkosc mniejsza niz 5 cP, w ilosci 0,1 do 3% w stosunku do ciezaru cementu. Prac. Poligraf. UP PRL naklad 120+13 Cena 45 zl1. Patent claim A method of plasticizing concretes intended for all types of prefabricated, reinforced and prestressed elements, as well as for monolithic concretes, characterized in that a low-molecular melamine-formaldehyde resin is added to the concrete mix as a plasticizing agent. of which a 20% aqueous solution at 20 ° C has a viscosity of less than 5 cP in an amount of 0.1 to 3% based on the weight of the cement. Wash. Typographer. UP PRL, circulation 120 + 13 Price PLN 45
PL19901377A 1977-06-20 1977-06-20 A METHOD OF PLASTICIZING CONCRETES PL102452B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL19901377A PL102452B1 (en) 1977-06-20 1977-06-20 A METHOD OF PLASTICIZING CONCRETES

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL19901377A PL102452B1 (en) 1977-06-20 1977-06-20 A METHOD OF PLASTICIZING CONCRETES

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PL199013A1 PL199013A1 (en) 1978-04-24
PL102452B1 true PL102452B1 (en) 1979-03-31

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Publication number Priority date Publication date Assignee Title
PL224172B1 (en) 2011-08-08 2016-11-30 Univ Jagielloński Catalyst for the direct decomposition of nitrogen oxide and method for producing a catalyst for the direct decomposition of nitrogen oxide

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