PH27191A - Detergent composition - Google Patents
Detergent composition Download PDFInfo
- Publication number
- PH27191A PH27191A PH38428A PH38428A PH27191A PH 27191 A PH27191 A PH 27191A PH 38428 A PH38428 A PH 38428A PH 38428 A PH38428 A PH 38428A PH 27191 A PH27191 A PH 27191A
- Authority
- PH
- Philippines
- Prior art keywords
- detergent composition
- carbon atoms
- fatty acid
- sulphonate
- composition according
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims description 29
- 239000003599 detergent Substances 0.000 title claims description 16
- 239000004094 surface-active agent Substances 0.000 claims description 12
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- 239000011734 sodium Substances 0.000 claims description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- 239000002736 nonionic surfactant Substances 0.000 claims description 9
- -1 alkali metal salt Chemical class 0.000 claims description 8
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 8
- 150000004665 fatty acids Chemical class 0.000 claims description 7
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 6
- 244000060011 Cocos nucifera Species 0.000 claims description 6
- 229910052700 potassium Inorganic materials 0.000 claims description 6
- 239000011591 potassium Substances 0.000 claims description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 102100040190 ADP-ribosylation factor-binding protein GGA2 Human genes 0.000 claims 1
- 101001037082 Homo sapiens ADP-ribosylation factor-binding protein GGA2 Proteins 0.000 claims 1
- 125000003342 alkenyl group Chemical group 0.000 claims 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 239000000463 material Substances 0.000 description 24
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 239000002253 acid Substances 0.000 description 7
- 239000004744 fabric Substances 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 239000003945 anionic surfactant Substances 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 125000002947 alkylene group Chemical group 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000003760 tallow Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- BAECOWNUKCLBPZ-HIUWNOOHSA-N Triolein Natural products O([C@H](OCC(=O)CCCCCCC/C=C\CCCCCCCC)COC(=O)CCCCCCC/C=C\CCCCCCCC)C(=O)CCCCCCC/C=C\CCCCCCCC BAECOWNUKCLBPZ-HIUWNOOHSA-N 0.000 description 2
- PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 159000000001 potassium salts Chemical class 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 2
- 229940117972 triolein Drugs 0.000 description 2
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 102000005575 Cellulases Human genes 0.000 description 1
- 108010084185 Cellulases Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 241000282320 Panthera leo Species 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 229940025131 amylases Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 229940088598 enzyme Drugs 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000001605 fetal effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 229910052816 inorganic phosphate Inorganic materials 0.000 description 1
- 229940045996 isethionic acid Drugs 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000700 radioactive tracer Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/60—Sulfonium or phosphonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Description
. vos : 27191 / A111 wr ol . I ,
This invention relates to a detergent composition, in particular to a detergent ’ composition for washing fabrics. ;
Fabric washing compositions contain, as an 3 essential ingredient, a surfactant lsystem whose role is to assist in the removal of soil from the abric and its suspension in the wah liquor. ‘suitable detergent active surfactant materiale fall into a number of classes, incpding anionic, nonionic and cationic materials. Marke ted . products contain materials selected fron one or “more: of these classes. 3 3!
The most widely used anionic surfadtant ‘materials are the alkyl benzene dulphonates and 18 "these provide satisfactory results lespedially at ‘high temperatures. There has been [a desire to find’ alternative anionic surfactants for use in : circlimstances when alkyl benzene sulphodates are jundebirable. i ji
H "Among such alternative antonid surfactants 2 yl i
Care the fatty acid ester sulphonatds (FAES) of the r ; 5 i qanefal formala : ’ i rl! - cH - coor? ] i . 805" bo 2% where rl is an alkyl group derived [from a fatty i } : . a . ;
I
. co - 27191 ; Bi eet
RE rr 27149
Cd £ yl acid, usually from a natural source, RY is a short chain alkyl group, usually methyl and Mis, for arample, an alkali metal. Thus for example,
Und tied States patent 4416809 {Magari et al., 3 assigned to Lion Corporation) disclbses a composition containing FARES, soap and the aalt of a polycarboxyl ie acid. Exempld fied FAES materials
Care those in which rl is derived From tallow and
Rr? im methyl. Ethyl or propyl are also mentioned hl 10 as possibilities for R-. i . ‘We have found, however, that the performance of such recommended FAES materials ‘is : ‘unsatisfactory when the composi tions also contain
Co low WLR nonionic surfactants. Sindh the use of 15 “such nonionic surfactants has been Shown to lead : to a number of benefits, including an overall “boosting in detergency (see GR 1241754 -
Unilever), there is a desire to improve the ipertbrmance of FNAES materials in the presence of 20 {such nonionic materials. b ! “we have now surprisingly discovered that this , object can be achieved by the use of materials in which rR? is butyl or higher alkyl. : :
Thus, according to the tnvertion; there is 295 ‘provided a detergent composition 1nE1uding A ‘
oo 27191 2H i LU , surfactant system comprising: “ i) a fatty acid ester sulphonate and ; 11) rponlonic surfactant having an HLE of less : : than 10.5 preferably less than’ 9.5; wherkin the fatty acid ester sulphonate has the general formula # r! - cH - coor? fo
Co SOM ; i where rl and R% are independently hydrocarbon
Cd 1Q groups having at least 4 carbon atdna, the aun of . the carbon atoms in groups ri and #2 being from 8 to 30, and M is a monovalent cationic species. : | The fatty acid ester sulphonate salts of the “above general formula can be produced from fatty 18 acide in conventional manner. Desirably starting jfatty acids are, for example, those} derived from tallbw, palm oil or coconut oil. Thus; ‘Lt is
Co : preferred that the group rl contains frm 12 to - ! I 1 48 ‘¢hrbon atoms. It may be fully dr substantially saturated. The group RZ may have Jower carton 4 atoms than the group rt, For instdice he group
RZ may have from 4 to 8 carbon atoms. fn ‘particular it may be butyl. { ‘\ The sum of the carbon atoms i gréups rt and 23 2 will preferably lie in the anad 12 +o 24, It oo J 27191 , is preferable also that Rr} and Rr? are different, especially when the sum of the carbon atoms in groups rl and rR? is 14 or more. A preferred FAES material is that in which ri is coconut alkyl and a RZ is butyl. \ . Mixtures of FAES materials as jdefined above g : could be used. Other FAES materials, such as the tallow methyl material, may also be included in minor amounts, but there is no particular *sdvantage in doing so. ) . 1 is preferred to use the water-sgluble malts of these anionic surfactants; spedifically ; ¥ ; the Alkali metal (sodium or Potassium) alts Sl : _therigof 18 . ;Buitable nonionic surfactants phich may be rmsd are the reaction products of Gompotinds having a hydrophobic group and a reactive hydrogen atom,
E for example aliphatic alcohols, acts, ! hides or Bh , i ne alkyl phenols with alkylene oxides, especially ethylene oxide either alone or with propylene
Jonide. Specific nonionic detergent compounds are alkyl (C, ~ Coy) phenols-ethylene dice’ condensates, the condensation proddets Br ' “aliphatic (Cg — Cig) primary or sdtondary linear 23 or branched alcohols with ethylene onide, and ‘ ’ = 5 = ; : : : ' B ; ; "
So 27191 711) ) : ’ 5 products made by condensation of ethylene oxide with the reaction products of propylene. oxide and ethylenediamine. . ; ‘When alkylene onide adducts of fatty
B materials are used as the nonionic surfactants, } “the number of alkylene oxide groups per ‘molecule “has a considerable effect upon the MLE of the ‘nonionic surfactant. The chain Length ind nature “of the fatty material is also if tential, and ? 10 i thus’ the preferred number of alkylene ofide groups . per molecule depends upon the nature and chain {length of the fatty material. ; o . i} 5 : + We have found it of advantage ‘that the weight ratio hetween the anionic surfactant and the 19 _alkonylated nonionic surfactant lids be twaen 431 and 1:4, most preferably between 33 and 1:2, ‘otherwise the benefits of the invention may not be 3 i. Lachibved. 's i “i preferred compositions accdrding to the invention include the surfactant sistem; in an amount from 2% to B0%, such as fron 4% fo J0% by weight of the composition. ; E : The surfactant system may include other mur factant materials in addition ts, the apecified 29 sulphonate and nonionic materials. ' These other : = & = | . : ;
Lo 9 CL 24) Ho 7191) . , surfactant materials may be selected from other . "anionic detergent active materials, zwitterionic ar amphoteric detergent active mateials or
G b : mixtures thereof. . o any such further surfactant meiteriils will “generally be present at a level which is no more ‘than’ 50% preferably no more than ady of the total “amount of surfactant in the composition, and might ‘be nbt over B% of the whole compos ition s \ 10 . The other anionic detergent don avertare ) “may be the usual water-soluble ake matal salts of organic aulphates and mororonatds having alkyl . {radifals containing from about 8 ed abot 22 , : b A
Jearbon atoms, the term alkyl being ised: to include 158 “the alkyl portion of higher acyl dsicals. fenampies of suitable synthetic anidnic detergent conppunds are sodium and potassium alkyl sulphates, especially those obtaindd by dsulphating
Co [higher (Cg - Cg) alcohols produded far example
From: taliam or coconut oil, sodium nd fotassium
Yalkyl (Cy — Cy) benzene sulphonatds, particularly sodibim linear secondary alkyl (C40 b ci benzene . ‘sulphonates) sodium alkyl alyceryl ‘sther
Seulphates, especially those etherd of the higher i y 29 alcohols derived from tallow or codonutiol1 and \ x ; ) | : - y= : . i | i
Co | J) 27191 + 4 , synthetic alcohols derived from petroleum sodium ’ coconut pil fatty monoglyceride sulphates and sulphonatesy sodium and potassium salts of sulphuric acid esters of higher (Cg - Gg) fatty a alcohol-alkylene aide, particularly ethylene oxide, reaction products) the reaction products of fatty acide such as coconut fatty dcids esterified with: isethionic acid and neutralised with sodium hydroxide; sodium and potassium salts of fatty . . io ¥
Co 10 acid amides of methyl taurineg alkane - ; $ “dy ‘monosulphonates such as those derived by reacting alpha-olefins (Cg = Cog) With sodidn bisulphite . and those derived from reacting paratiins with 80, and C1, and then hydrolysing with a base to , 15 product a random sulphate. | - « ri : ‘ The compositions of the invention hay contain ‘a detergency builder material, this may, be any “material capable of reducing the Ldve1 &t free calcium ions in the wash 11duor ‘and will ‘preferably provide the composi tiond with other beneficial properties such as the generation of an alkaline pH and the suspension of anil removed from the fabric. ; {
Examples of phasphoris-contathing | inorganic 23 “detergency builders, when present, include the 2 “ : Po
To Eo
Co 27191 «© 271) ’ . y : water-soluble salts, especially alkali fetal pyrophosphates, orthophosphates, arjthophosphates, : polyphosphates and phosphonates. Specific “ewamples of inorganic phosphate builders include 9 sodium and potassium tripelyphosphates, ortho phosphates and hexane taphosphates. © : : Examples of non-phosphorus—con taining ' v . v “inorganic detergency builders, when present, (inclyde water-soluble alkali metal “darbonates,
Co 10 bicatbonates, silicates and crystaflinéfand ] . ‘amorphous aluminosilicates. ki camples ‘incipde sodium carbonate (with or i thodt calcite jreeds), potassium carbonate (with o wt nou eale) te seeds), sodium and potassium bjcarbonates
Yand Lilicates. § 4 i vl Y £ ! i Examples of organic detergencyl buijders, when “present, include the alkali metal, famméiun and bh ’ 1) 4 L
Lg substituted ammonium polyacetates, learbdxylates, {palytarbonylates, polyacetyl carboxylates and _poyhydronysul phanates. Specific dnanpies include “sadium, potassium, lithium, ammon 1.1m and i a a ‘substituted ammonium salts of ethylenediamine ‘tetrhacetic acid, nitrilotriacetic acid; onydisuce inic acid, melitic dt 1d, benzene
Foolycarbasylic acids and citric acid. p vr] FC
J : - : ! ro =9 = ; ; 1 eo
J | :
oo 9 _ L419) . R715 ! 3 ) ’ .
Co It is preferred that the compclai tidne : : according to the invention be alkaline,” that is at the concentration af 1 g/1 in distilled water at 25% the pH should be at least 8, preferably at 3 least 10. To this end the compositions may “inc1lde a water-soluble alkaline salt. This salt may be a detergency builder or a nan-building ' & ‘alkaline material. : i : | Apart from the ingredients already ‘mentioned,
LJ 10 a number of optional ingredients nay also be ) present. : . : Examples of other ingredients Which may be ! ‘present in the composition include fabifc ’ - softgning agents auch as fatty famines, fabric 19 softening clay materials, lather boosters such an ‘alkapalamides, particularly the nonpethanolantdes dered from palm kernel fatty acide and coconut : oo fatty acide, lather depressants, oxygensreleasing ~ 'bleakhing agents such as sodium |* perborate and “scdiiim percarbonate, peracid bieact pretursors, ‘chidrine-relaasing bleaching agents) much an triclorotsoyanuric acid, inorgantd sats such as sodium sulphate, and, usually presant ih very minor amounts, fluorescent agents,’ per fumes ineliding deodorant per fumes, enzymes such as ! ‘ = 10 = : I oo 9 vo yr i ‘ . ’ Tes , proteases, cellulases, amylases and. lipdse, germicides and colouwrants. ' - : . The detergent compositions according to the invention may be prepared by a number of different a "methbds according to their physical, form. In the case of granular products they may ‘be prepared by gry=mi xing or coagglomeration. A dr etefred physical form is a granule incorporating a ‘ detergency builder salt an this Lis most } 4 > 10 conven tently manufactured by spray-iiry iia at least ] “part of the composition. In this Wrocess a slurry im phepared containing the heat-indenaitive : ] iconpprents of the composition such fas the {surfactant system, builder mater Lal and filler 18 Veal The slurry is spray-dried to) form base i i L powder granules with which any sol ig heattsensitive ingredients may be dgned such
Co ‘Angradients including bleaches and lenzyies. The
Vepech fied nonionic surfactants can be Viquidified -
A ! 1 ‘By melting or solvent dissolution and sprayed onto i 5 ‘the base powder granules, rather tran including 3: ; them in the slurry for spray-drying The invention will now be described in hore detatl in "the following non-limiting examples. , i : '
. Ly 2H 97191 iw! Co : : : i) x . — mA : C, .
P EXAMPLES 1 TO 6
B ~ Wash liquors were prepared in water having a fhardpess of 28° FH (equivalent to 5 free calcium ‘ton concentration of 2.9% » 1073 molar) «i The wash s ‘1 iquer contained the equivalent of 6 ast of a "composition containing (by weight) - "> "specified anionic surfactant : Hay : i py v Specified nonionic surfactant | tan ; | sodium tripolyphosphate L x bo 0 f $ Sodium carbonate ! Hex x odiun alkaline silicate : #a.mn } goaium sulphate + 40.0 ? Sodium chloride zien ' be water : b3lance i - ' : “M i3 to “ The sodium chloride was included a4 being 3 3 ; équibalent in ionic strength to o. baodsiom {pertbrate monohydrate which would te present in oo fprackice. The bleach is left out af thse / epi tment in order to avoid cousin between a § jastaboency and bleaching effect in ithe. {interpratation of the resulta. ] fg h { The wash liquors were used to Brasnia fabric “load: at a liquor to cloth ratio of sous The load , included a number of polyester morid tor to which 23 had previously been applied an amount ot cl? = 12 = Loy ; [
Lo Fo
L X i.3 . : L , ’ { 10 ! ( Ae t ad , 9 1 0 1 i 1 i) . - , ' tagged triolein. Measurement of the level of . ‘tagged triolein after washing, using standard i { wi 4 . i wt J oo ‘radio-tracer techniques, gives an indication of . . , Li F) the degree of detergency, ie. ‘oil: removal,
Co ¥ 8 obtained. ! 3 ! x
SN Bh . 1 =: ~The wash time was 20 minutes With an » ] Ti #7 , agitation of 70 rpm. Washes were isothermal at : Pw 140°C. CO ' i 8
Co In each case the nonionic surfdctant was : ; | 5 Cb wl ¥ “4 ) 10 either SYNFERONIC A7 (ex ICI) which ie principally . 1 : NT] ‘a C,a’Cys alcohol ethonylated with ‘an average of 7
J — Aad ] bt ’ moles ethylene oxide per molecule Havin an HLB of ro © 11.7, or a 113 by weight mixture ped with : Att ce a! /BYNPERONIC AX, which is a mimiert material 13 “containing an average of I moles of. ethylene oxide 3 : ’ y i 3 I pa]
Lper molecule, the mixture having ar HLBR of 9.0. “ : i. Lo oo ne 4 , The anionic surfactants used Were? ! br 4 ‘CM1 . Coconut methyl FAES > §TEXIN ES 681 A tallow methyl FAES Ge Hénkel or Coed : cH 4 > . po 1 ‘LBs 'C,. alkyl butyl FAES bv N
Nw . 12 i} v8 ¢ , : ol i “oo . CI - : ; 4 i . al i } 7 7 A
Eo ’ . : ’ § ’
Poo i
Co oo | J) 27191 Cn ,
The results obtained were as follows: ‘Exaniple No Anionic Nonionic %_soil removal 1 CM A7 ‘20.1 2 E868 a7 20.6 8 3 LE A7 ‘ 19.8 ; p CH A7/A3 26.0 a ES68 AT AS ; ‘23.9
Ce LB AT /AS ) 136.2
These results show that in the reseice of the oo 10 “higher HLE nonionic material (Examgles 1 to 3) there is very little difference between’ the aniohic agurfactants tested. In the presence of the lower HLR nonionic mixture (h7/p3) However, } "aignificant preference for the Cp uty FAES over the ‘others tested is evident. 3 A to 3 a Ek th : : ’ J
E ‘ : n
T i s .
Claims (4)
1. 6A detergent composition irc luding 20 to : CBO% by weight of a surfactant mixture af which 930 i : ’ “to 100% by weight comprises: ig : i) a fatty acid ester sulphonate; and’ a Mii) nonionic surfactant having an HLR Bf less ; o 3 3 ‘than 10.5) the ratio of (i) to (ii) lying in the r ¥ J range from 431 to 114 and wherein the fatty acid i i A “eater sulphonate has the general formulas
CL . rR! ~ cH - coor? Go 0) { ¥ 2 wr 1 v vy, ; ’ A : 7 : vo Sr ! Y 4 10 b \ 80M ) Gi fo 1 2 { J Mheréin RT and RT are independently’ alkyl or " o y f 4 - 2 alkenyl groups having at least 4 carbon atoms, the SN nro? sum bf the carbon atoms in groups R and R™ being 3 a + yy “ from 8 to 30, and M is a monovalent cgtion such 1 \ Ht 3 od i 3 19 that the fatty acid ester sulphonate idlwater , + te Lo! soluble. ! " CU & detergent composition according to claim 1 wherein the sum of the carbon atoms in yr ups i and RY is from 12 to 24 carbon atoms.
: A. A detergent composition according to claim 1 wherein the group Rr’ caontaing from 12 to IR carbon atoms.
4. A detergent composition according to claim 1, wherein the fatty acid ester sulphonate 2G is an alkali metal salt of the sulphonate of the = 1D =
Lo. Ca g314) : . . : . " He : ] 27191 CL — . ) . } : 1 butyl ester of coconut fatty acid, so that ri is - x ~ . : cocohut alky, RR” is butyl and M is sodium or . potassium. ! i ! ; : g ca, A detergent composition according to . fr : 2 claim 1 wherein the nonionic surfadtant, has an HLB . ‘of 9.9% or less. i ; : MICHAEL HULL ! " : REGINALD VEAR SCOWEN
- . DENNIS GILES . ; Inventons Lt ' - 5 4 . oo no LJ vo , Ib Mh hy | ’ ; A hs 5 = ih te \ iv 3 He : i ! : H tl <¢ Ye 3 - f % ¥ i 3 ‘ . iz { i . ! A wooo ; ‘ y y ' . : , IX H hd oy We [¥ ! ~ A , A i ; . p oh Wooo ee - k oe . , i § “ 4 fy i : : Cy . ; tL . . = lb =
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB888808041A GB8808041D0 (en) | 1988-04-06 | 1988-04-06 | Detergent composition |
Publications (1)
Publication Number | Publication Date |
---|---|
PH27191A true PH27191A (en) | 1993-04-16 |
Family
ID=10634659
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PH38428A PH27191A (en) | 1988-04-06 | 1989-04-03 | Detergent composition |
Country Status (15)
Country | Link |
---|---|
EP (1) | EP0336740B1 (en) |
JP (1) | JPH06102794B2 (en) |
KR (1) | KR960000199B1 (en) |
AU (1) | AU619266B2 (en) |
BR (1) | BR8901573A (en) |
CA (1) | CA1323818C (en) |
DE (1) | DE68920768T2 (en) |
ES (1) | ES2068240T3 (en) |
GB (1) | GB8808041D0 (en) |
IN (1) | IN167967B (en) |
MY (1) | MY104422A (en) |
OA (1) | OA09035A (en) |
PH (1) | PH27191A (en) |
TR (1) | TR24063A (en) |
ZA (1) | ZA892470B (en) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2205592C (en) * | 1995-09-18 | 2001-12-11 | Stepan Company | Heavy duty liquid detergent compositions comprising salts of alpha sulfonated fatty acid methyl esters and use of alpha-sulfonated fatty acid salts to inhibit redeposition of soilon fabric |
US5945394A (en) * | 1995-09-18 | 1999-08-31 | Stepan Company | Heavy duty liquid detergent compositions comprising salts of α-sulfonated fatty acid methyl esters and use of α-sulphonated fatty acid salts to inhibit redeposition of soil on fabric |
US6407050B1 (en) | 2000-01-11 | 2002-06-18 | Huish Detergents, Inc. | α-sulfofatty acid methyl ester laundry detergent composition with reduced builder deposits |
US6683039B1 (en) * | 2000-05-19 | 2004-01-27 | Huish Detergents, Inc. | Detergent compositions containing alpha-sulfofatty acid esters and methods of making and using the same |
US6780830B1 (en) * | 2000-05-19 | 2004-08-24 | Huish Detergents, Incorporated | Post-added α-sulfofatty acid ester compositions and methods of making and using the same |
US6534464B1 (en) | 2000-05-19 | 2003-03-18 | Huish Detergents, Inc. | Compositions containing α-sulfofatty acid ester and polyalkoxylated alkanolamide and methods of making and using the same |
US6468956B1 (en) | 2000-05-24 | 2002-10-22 | Huish Detergents, Inc. | Composition containing α-sulfofatty acid ester and hydrotrope and methods of making and using the same |
US6509310B1 (en) * | 2000-06-01 | 2003-01-21 | Huish Detergents, Inc. | Compositions containing α-sulfofatty acid esters and method of making the same |
US6764989B1 (en) | 2000-10-02 | 2004-07-20 | Huish Detergents, Inc. | Liquid cleaning composition containing α-sulfofatty acid ester |
US7485613B2 (en) | 2004-12-01 | 2009-02-03 | Venus Laboratories, Inc. | Low foaming carpet-cleaning detergent concentrate comprised of ethylene oxide adduct and without phosphates |
US7459420B2 (en) | 2004-12-01 | 2008-12-02 | Vlahakis E Van | Automatic dishwashing detergent comprised of ethylene oxide adduct and without phosphates |
WO2016160407A1 (en) * | 2015-03-31 | 2016-10-06 | Stepan Company | Detergents based on alpha-sulfonated fatty ester surfactants |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4964609A (en) * | 1972-10-25 | 1974-06-22 | ||
CA1033638A (en) * | 1974-09-11 | 1978-06-27 | The Procter And Gamble Company | Detergent compositions |
JPS54132609A (en) * | 1978-04-07 | 1979-10-15 | Nippon Oil & Fats Co Ltd | Detergent for raw wool |
JPS55108496A (en) * | 1979-02-13 | 1980-08-20 | Nippon Gousei Senzai Kk | Detergent composition |
JPS57180699A (en) * | 1981-04-30 | 1982-11-06 | Lion Corp | Granular detergent composition |
GB8515762D0 (en) * | 1985-06-21 | 1985-07-24 | Ici Plc | Surfactant composition |
DE3603580A1 (en) * | 1986-02-06 | 1987-08-13 | Henkel Kgaa | ESTERSULPHONATE CONTAINING TENSIDE CONCENTRATES AND THEIR USE |
-
1988
- 1988-04-06 GB GB888808041A patent/GB8808041D0/en active Pending
-
1989
- 1989-04-03 AU AU32398/89A patent/AU619266B2/en not_active Ceased
- 1989-04-03 TR TR89/0308A patent/TR24063A/en unknown
- 1989-04-03 MY MYPI89000418A patent/MY104422A/en unknown
- 1989-04-03 PH PH38428A patent/PH27191A/en unknown
- 1989-04-04 BR BR898901573A patent/BR8901573A/en not_active IP Right Cessation
- 1989-04-04 CA CA000595627A patent/CA1323818C/en not_active Expired - Fee Related
- 1989-04-04 ZA ZA892470A patent/ZA892470B/en unknown
- 1989-04-04 KR KR1019890004397A patent/KR960000199B1/en not_active IP Right Cessation
- 1989-04-05 IN IN85/BOM/89A patent/IN167967B/en unknown
- 1989-04-05 EP EP89303376A patent/EP0336740B1/en not_active Expired - Lifetime
- 1989-04-05 ES ES89303376T patent/ES2068240T3/en not_active Expired - Lifetime
- 1989-04-05 DE DE68920768T patent/DE68920768T2/en not_active Expired - Fee Related
- 1989-04-05 OA OA59549A patent/OA09035A/en unknown
- 1989-04-06 JP JP1087835A patent/JPH06102794B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
AU619266B2 (en) | 1992-01-23 |
BR8901573A (en) | 1989-11-21 |
KR890016151A (en) | 1989-11-28 |
EP0336740A2 (en) | 1989-10-11 |
JPH01299897A (en) | 1989-12-04 |
GB8808041D0 (en) | 1988-05-05 |
CA1323818C (en) | 1993-11-02 |
ES2068240T3 (en) | 1995-04-16 |
OA09035A (en) | 1991-03-31 |
JPH06102794B2 (en) | 1994-12-14 |
DE68920768D1 (en) | 1995-03-09 |
MY104422A (en) | 1994-03-30 |
EP0336740A3 (en) | 1990-03-28 |
KR960000199B1 (en) | 1996-01-03 |
AU3239889A (en) | 1989-10-12 |
EP0336740B1 (en) | 1995-01-25 |
ZA892470B (en) | 1990-12-28 |
IN167967B (en) | 1991-01-12 |
DE68920768T2 (en) | 1995-07-13 |
TR24063A (en) | 1991-02-22 |
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