PH27003A - Detergent composition - Google Patents

Description

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JJv03

DETERGERT COMPOST IO

Thies invention © olates Lo bhe mano dao bare of bead bk non-soap debergent PME haves, Buch hee ara composed of debergonl a ive, hod Lda and nests ! PET lero) am the third main compen cael are goes cowmod ow

Laundering fabrics, ond olomoing aur oar - .

Comune cial baci TE detergents np CL Lowes ron bain deter gant active and de loc gent badd Tbe i INET RNIEE

Cmge thor with pp tional component, Soe as ap la atwatives, Tillors, per foes, ad dye x Plo, don : example =ilicates, and Bleaching age .

Various materials have been proposood for dre bus ion ‘ ‘ 1

Can PSD Jevasitry bara, too bnproeos prope Fives of the hae, : Var dows effects have heen ebb Plate Lona ne Ler fala.

CE dm mduaye possible hat doe Toaddngg ean top dial bo improve one properly of a bar prodooes ~ Aestpimen tal effect on anothor property. : ;

Wes hiave oer found thal bac pr op ipod don can be improverd by including cellulose of oo 1 . ted le lems i Lv

This material iz eof fective to modi Loe boreal properties of a detergent bar, which ome og iver oa ehange in the cote al whi ely Vhs bar wear so cfu Tog uses, ard improve resistances tey hr Abt le frac bore, without ol hes undesirable af foots, 20 Accor din g to the present invention we provide a wd om —

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BAD ORIGIN

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Ze 3 built detergent har, of cooposibion compri sing from LO ar preferably 12.59% to A530 by we ight of non-soap detergent aebivo, from OG to H0% bry wi ight of de bergoney mei Teer, and at Toast 00 by uoight of col bulose having " . . ’ . $

TA vobd lh chennai ty Tesser Shay O08 Fg Liby on,

The end tnlamse will gene sdb. not be chemically meyel if eel Ari table dm Floceeddl cet telooo, uhbose tlk dein d ba aries soenperl ing Po ge ade, ed Cay hi oan bong am

LON gs tire,

Seb rel Todos dom ava Lab le Troan Qognes Rvs

Corporation wrder bhodr vegishor sel Vaade meets Bolla

Floc and Halwe & Conoaneder Uhedr bradde mo bo Malin Loc! . i it iw preferred that the amon orf col lulose 1 ios . ; in a range from Loto 10N by owe ight of the bar "composition, more preferably from Bobo SL ‘ Yh irevontion is particolzely appl ioalile when at : | . . . . . least a pavt of the detergent active aa an Lhe primal y aleohol sulphate of formela : 0M

A and/or fatty acyl estar aad plonate of fo nt a f

A ne

FeO IR 50.1 in which oor K ta a primary alkyl group containing fa pe. 29 Fey 292 carbon atoms, preferably 10 tn 16, Tod a f + £2

BAD ORIGINAL £ ) ~

—_— CE ————————————————————— A ————— : joes primary allyl group containing Uo to Soo a hion atome, presforahly 1 ho 4, and Mois oa calidon shy that The detergent act ive mater Pal dm water soluble. Theso ac tims pay An particular hee Fe oa Fr rey deed fram roel, but other sours wlyie ts ars peesibibo ine bode

Chaeelined palm and shear dn ‘ Witt hob mf bls sot ices Pho dng tusion of the : i

Aber emg bieapesl co Those poorer es elo Lim dn thes pate of werar of a detergent bio aiid on dmpeeesomzotodn

Cpe pores ial le prope fee

Pars which contain oven fai) osm C1 amon ts oF . i . prdmary aloo pl scl phate ayn proven Uy cerrado . . i «

Chreakans during handling and Leavesport Boa re bad Tear, - i

Tre tosion of bhe abosesinen i ciel ened tab dw ed foot ive

Ce ameliorate this oi diiow Tw. Tr balme Innab los the

Phage ho trterato a sehstanbial weld edt opt, whieh ds . E . . : advantageous Sn alloning Phe mee oof pro dster yy aleohol sulphate aupplicd in the for of an arpedows paste,

B +

Fatty acid estoy sal phomatie, or perimary 28 Teohol . 1 salphate, ar a mibure of Fhe tween moe, comm ti luke at

PO least 10%, meen poor bioud arly ad Vengo bonne Shire, on possibly a maja ity af he weight of detergent ac lie proeeenn toi a Bear compos hd on. Aven tee detergent acti oce vihieh may be deluded ds Linear op Bypapye hed abd

Ben eens sulrhonalte with an allyl ehiain Yength of 8 to pov eaphon atoms, preferably a Phyl of §3 te 1b osu bear : we fl \

ee ———————————— ee ———————————— te errr « ec «3 atoms, :

Ore or more of Bless bhaeee detaegen oa tiem may provide the whole of Fle detargontl ao bios present oon

Cother deteraent actives may bee eel, peechaps in addition te one or mars of the hheeo amg Vowel abo

Detergent aptives and fri der components are well

Char ac teriaed io detergent har Fever byrp Vente his componente ay eo rinse bord iy UE fon Seni os Agent tt hy i

CSohwartz and Perey Trp doses dese 370A el Me lomer 11 byy

Be hwarty, Perey sevd Prove by (Topher ees Peay PRNEYY Thee

Cdetorasnt actkives asable ip Rhee presses denn tion ey

Che formnd din the oevoral Cl oeape ef 0 Fae ie go nom ion din i . amphoteric, hetaine and rw Pbbarionic actives, Speci fio ! E . . . . pramples 0 f detergent actives usablo doa Addition Lo 15% those meotionsd above ine Luda alkans autnhonates, t .

Ceeenndary aloohnl osndphabes, obofin sn Teihonatos, ; mthany lated aloeohols and ethos Latest 0 chats end phe bes. : Soap will generally be Aliment beeai=ze Tt dnhibibs ! ‘ “the foymation of la theme by the panesoap de tEegen I :

Paetive. Soap would tend too plastic ine © bar and

Cbhmoretically therefore would pro Febin ary arbvanhage,

However, an important user-peeoe iva lo proper by a f bad LE NGD bars ia bhe ahility toe form A rather aod the i presence of soap reduces the rate of Lather formation : ; wa “ly tho nonesoap de teraant activo. Cones riopeen bly i is preferred that soap is absent. Tf any guanbiby of soap ‘ mo Bom ! ' 1 i , . ! ) vo.

—_— — — — —— tr Str 7] Oo? fr present Phe amount oo Coat wil gener at hie Teas Mh 2 ky welght,

Ii generals Fhe anon t of dle lergony . tad Leder pressaut wi bi bs drrom about BY te oahoet £0 ey nedght of 3 Phe bea compos Lion, pre for ably Fron Lore to AW

Examples of bud Toei comporen Leg avomn paleo mo lobile phosphate sel Le, #0. ition brodpo yp horte toate, pyrophosphate and or Elophisphuates orate ine LIRR carbonates, e.g. sodium corbhona Leva repos baad Toles,

Gag. sodium pdb iat baie bale, sooiom Spy ale, modinm citrate, trisodiam carboiyme thy 1 evry ination, om rehire

Coney Pouce dinate, sodium sod phone bod ang Peni . MONO arbosy ic acids. polyace wlabes ant oo dd wid po lysacchar Lda and aloories BV irates Sor erlang 19 agg. soolite da. Tre pear Leda vestsood rhe pte ud bder wr pect pphosphate de tergon o Ppgd Veter moss bw snc \ that phosphate procides al Teast 107 yy weight of Fhe bar Compe ion.

Budd bo HSn bars generally cont n HST or apo tion of

Fil lor which although Previa Ly dyer! esd gril fioant neon pributing ie this propoerh ees cif Rhee hag, 11 appropr dats vangs for such Filler im 5 be 20% by wadall cof the composition. The £11 Yer mass eomedoel nf aad eer suluble sal bs sunh as mevtivm sul phe bes beat possibly il 28 Cine ludes water-insoluble fl Ter, Ths $40 Ter presenh wm fy

BAD ORIGINAL J

Jfre3 ay ven all he waler Prec bob le aod ou wading ly the poze bh le amount of water insoluble F110 ds 8 Lo &0 wl?» Examples of water dsl while Tillors are bale,

Laolin, walolte and bonhan Pb ’ a Oley ingredients may lea bie pr Soy Ldn thie bay composi Bion. These ne lon Pe oi lipatos, oui. sodium ) . . . . | § «4 cadbaline md Picante, modiom cnr boncymnbhy bore Plant onme, : : !

Pla lier eihaanening agen ci mane dr ces cre ata Ls Henao ash ife 1 (Fob monn ard dedi emt deem as wel vole msc onn lb i aloehiol, color fneg ame bar dele, Ono gies, SRO EOE pact Tiere, gorado iden, peo Fomes, are Leaching agen Lm, . TE awd bbws appr aod aboad Bled This Cog blonde . Joiner ned wd Fiy de bergent bars which i generally be sigs ban Liat le rigid, enabling soli har ta be rubbed 18% agains loan lem of Paved yo OF eo me ST a bay is moabd de wale ors hoyeel andor eres UAE ays anf grins Raver i

Chemie by ib may lease lnoosleeny Eh sone Beeman i 5 plastically de formabile by hand pressure “

The hers according boo Lhis dosionbidnn may tyes

Py Cpeepared byomdcing tle Prrgrestbion toa, wi Li water, dng A

Chigh shear mie am imo con sen Lionel and hen eo brung. i

Che cellulosa may hae addin initially bul preferably dw : ;

Cadedeel al oa later stage in bhe omiciing pro erode bogie this } with the filtler(s). ALE ano laminas may De incl vieleach aE 2a described noo UE published patent application i

I t : © BAD ORIGINAL )

Co

Jee 3 2IRAIGREA. Alweinevsd Tionabo mans baer Foveme Af iy milan, a dea ibhed nome Ll pak td shoe pale ae tiation

POeFOLEN.

Trin the Feosmptoo whieh fo) teas, aU 5 pene b age Aes 3 Ly wodanht anleos tatoo thoredsn. i

The cellulase weed Sn Fram nl ors 1. - Co aed Tow

Cee] lglosn of Dboltodens Phe anpeoy ima et Ronse b

Cpom James Frise Coen Aton, Hae berm! ta Flees (Jer moy

Ln ral vedi Bhd Reactor om arb Gel Toe Feampr len 0

Laren red Talo from Blobs 8, fey, NETL Fe . ley bherl 1 ’ ’

Franbera, Wea tb Ferrin. Amy ross ad Lies fren}, melas

Aa dimicoating nae oer Geri bP fea Toveoaphy Cros famed . & Gon. Wereina tor, SHE . { . i oo i . i ! wf} "BAD ORIGINAL d : Lo

——— ee ——— rr ——— eee

S003

Eacamnle J

Si a pombier of bars wero aide, Tyme dg a general frrmu lation am follows:

Coyeorarl atoohol sulphate LON

Sryta ash 10,

Seliogn alkaline silicate ’ (aritrgdrons bas ie) DLR

MNlominiam snd phate

Carfhwetons bas ie) EA

Berl im preraprhas phe le LON . ed Pod ase car dah le na Lie oped cariahle . Caleite arable

Ia bey Léa 0

Topneed Lies dnbrodac cred with i

Fhe cle borgent active, mio [ros Yongser Lo 100 constituents,

The water could all ba in troduced ve th othe const i tush te, espeeially J f detergoh celive was : proveidec in he form of a water coonilaindng pas bez. The amount of caloite wae varied so bhatt bho tolal amino b 29 af caleite, silica gel and cellulose wo coeons ban. . - - 1

Bars were extruded, and Lhen aged for two weeh es bo allon Lheir physical propery Figs to shabilise (al Lhiough : : ; ee 0 en : } = .

BAD ORIGINAL 9) :

Loo

S{ee3 the benefits of Lhe invention ave appa eto mue hy sored than this).

Ther hardness of the bars was meray rd fy means of pann trometer, the rosa Ths being expreacsod as dep th of 0 pena tration into the bar olf a « Fan ior abe ander a

LOO gin rr 200 gm Toad applied for a sl wepbar dd time.

The rate of wear of bars was wae od by = arandard test procodure designed Lo feral o wae, Lhe esd Le being expressed as loss o fed gti ef the bere. ‘ t i 10Q The resulta of these Lesh: are mest earl dine Table A ber lone. ' ; * w= 0

BAD ORIGINAL dD -

L

Leos

Torey od :

Compre i tion Mo, os f I PTT iw vy wry YIII

Coznetd ton os

Alda rye 1 y mr ES i 2 on 8 = Yj

Collulone 7 o Oo 0 i 20 "i A 3

CMadod he 0 Ln 3 mi " 0) = 0 : : : i

Clabes 14, yf. 4, Po ' [ 70 wn

Hardness:

Fonetration ?.0 8.4 HLT BLh sun aA 1.6 @3.4

Pando 100 SL (mm) 3

Fenetration 14,0 U3.7? 0 12.0 tno aw Tu J.0 L2H ppd O00 om : "{mm) ay [ rm i. [E cw ew

Fate of wear 1.9 1.7 HLT EI «i RI LLY HL : 1.8 (weight. loans in gram) ‘ :

Tt can be seen that incorporation of silica gael or ceallulose or hooky agave a radaection in the calo of [REY fwear. Rares of compositions Toto VIouero boasted for

R20 Fesistance to fracture on impact, ow “his Flesh bars were extruded into the same foro ss oa oarront

Cepmmercial product. This consishts of on elongate bar having an overall lenglh six times ite oo viet Lh, and ; . having thiren transversely ohending dove tatiovis dnbo « = 1 dts top farce so as tog ive a reduce! thickness at Yh ees points along the length of the bar. These indentations we 1] wm 1 wD)

BAD ORIGINAL 9 [SS foc are intended to allow the boo Lev bie tied dole greater a pr aes Lor ute

Ter Leet Ue bari, sds sued hers ere fired dw ichuad by vie apsesnl and fn Ueeinel fase bo Pac dp at. Ploies tod eran prhaanod Los ar Alc ob carbon sar th x a Teaayy omiliges cof mach bar was pro biieg mn Thee ase cf Whe ear ton.

RIES: coar Lewy rae ben placed atte er loah oA presis i LO ana “pa iv oof bearer dl by cpori ing Feapy loci Peo tet oboe br farsi) batoled Tepe ther The Tadole toe apiohilby re Pesauneeed 14 al Teveinig Biv seo town te dean tive hi Jaye Sronnin other a heal floor. Phe carbon was Then ak prod dry Lhe medi way bari movies a fle hie Rhee Bags eens vera booed ane . respi bod : pli Uh crmpoz ition Corvin need les veld pel ove ann 1% si Lica gal bho boas boobe aro ss Uhr do rath hee

Crt poor moon or hitb od hes ead on deoton bation:

Chee Byeeados 2b Ghee onthe Apelor ta tie Treen dino wate re! dare bly brags er sie srl a tnanbyer of Proocmenbs babe ol f aloe Lino onc erding Long d Foecliriaa by of Shoe hay. Lith composi biong FE FLT cnn laining Pia gerd baelon i rel ta bose She peau hove aemrsnra ld Ty Slee ond ih oo

Crumb sf fy amen br nbn of Alege Pipes sabomling eng Llartinal ly of sachs bat

Wi bh owas ition To oaahdoh cen band nee Selo f 1 me eel lnlose, beneoar, Phuspe vias a vas Cobre me 1 )

AD ORIGINA- 9 —

——————————————————————————— eee eee ee eer 7 foes

The bars broke transversely across dhe ivowidth at the conteal inden bation only, sod the hroal te ivy closely

Ford Vonamet the mon bead indentation. Tho car oof The mau haiv= had ne fragments broken off, the ct hesy Bheeos had cnly one saall froagmenh Beoben of Foal the central

Pyreal Comper ition MT containing hoy bh LED of thes

Ceellalono wd BEd dies aed goes a imdb res TL to coompnei tion IYomcept that Eherey wpmton nee small

CFpagmers ta robo off, Compevsd tion Yoo aftaining 2.5% of her pal luleme and 208% of he mi lhe oa geet aaa a vesul lb oo i whieh wae near by ae good as the perma LL For copings Eon i [QE Frans af Phe ix baes brake dn halide Foo lle corned indentation gi thoat any small fragments being heoken ; aff. ne har brake approsimately abt the Fagin oben ’ 15 indentations while the remaining bay brootie at

Fhe on leo ond ona outar indentation with two small

Fragen ts baoken off.

A creer ent commercial prococt dn which thes de lorgont achive ison by) hoenmene sulphoana Ler was ested

Saree the samo way. Tw of the six bars broke clean 1v at

Ckhhe central indontation. er brole at the centre and i . .

Comer outer dndentation, The oo Lhe Lhiree bheoke pe approsimataly atoan ow ter inden bation, A mma ll numba ef fragments broke off. 29 Overall, ib was olear ry apparent hat Lhe mE em

ORIGINAL A)

BAD = ;

—_— rr ——————— EE —— <1 603 compositions TT, TT and JIT were inferior to the curren t commercial product dn bhatt there was groaber creation af fragments breaking off along lines onlending

Clongiutinal ty of bhe bad. Composition Vo owas slightly ne | . . . [per jor to the caveent commercial prodoe tin that

Lhe owas slightly less creation of small fragments and t mots of Fhe hreaks edtended direct), across The bars.

Compnsi Sions TY and VI were better obi oin that Lhe : J . t Lt . ; dinplaved teas breakage and loss foraation of sama | 1 : Fioagmenny be,

Nes comparison, bars were alae prodoced with a

Formal alien similar to the genes] formelabion for bars 1 1 - . . . : 2 but ariliving starch or gelatin rabher than : cel Talos: as a polymer ic material bo doprove Lhe bao’ s i . 15% resistance to brittle fracture. When t vated shortly

Patter the mangfac bare of the bars the dicorpora tion of staregh of gelatin did give an ioprocemecl in resistance hey bed ble feac bure, Hewes er the dopeooment was short

Cl ierdl and ced nod be obhreeved dn bare which had boen £0 bal pearl be age for Lwo weeks. : i poe . i

PAeoeasment of Feel i : Reve of compositions 1, T0, TW and WV owere tested for Lhe feel characteristics peroeiood liv Lesser. Uli = !

Lwas a subies live asseszoent by a pancol. i

Fach har was rubbed S50 Eimos on each side (by haod , . : t i i

Ju

INAL MN

» Tee! jw ee ——————— ete —— ee eee : fe 03 phi Vee aaeia deg 1 ntlibe geese Bennet oe foc Tirndah.

Melon = of a panier bof eight pandom le ee ten bod amsemail 6 were A Len asked toads Phe bes Deleon Deare Dhara En ol : : eo [EPS . Pi . - Fa eviiree ald ed water al TAT and oop arte LU bars tin

G Flore let bneoita lpr operr Dies wlio vem i) grit by Zab anton Teed i) pees te feac Cire mn foes ta Lown aif bh) , : i tid SU or!

Drie Lear oo wees moored Ten nen be Tp a poe a meade

Lo ef i Fyre dL Smerate ns ey er , 3 cer md igh ep UR Tine bee ay vied

Tit ter aid wists i, nd oe fade dy grid Uy Sash Sel Lin, erie ' qe ery ed Bley Jeeesleg Se Lim fod 1% feeb emis bey ged Lh Ses Sel bw, feed [Ponchy Bar nas Deas Drom ono vine to ten eh Be fen a twig shown Loo Lhe Preset peared Tied aed eed peed wiih a

Fresed lieve (Fyendd Tron sel faves fiaviz=h) san bo amaesamen lh Try fo pancliioio, :

The as rrr ape sear ce Tor oad hooligan Voie were ! alentabod, anil aie met ond dr Fab 3 To low : i ; = AG

BAD -

— EEE rere of 1 003 : Pov

Composition hos 1 bl re !

Collulose % © o fe ER

Silica gel % 0 De i | Da & Grit RIN nad Dat 2.4

Museshy EL aA Sede Aad

G1 imb 2.9 EL DL er : : 1 can be seen from Lhe Table | het p amnposi tion IY and composi Lion V had better arora lit compositions 1 100 and Il. j

Example 2 : Two further compositions VEIT sod TUNE were : : - iprepared similar Lo composi t ion MT hor bul wi bh difforent amounts of water. Compositics VT1T contained 135 = ocaleite but only 154 water, Commpers Pion VI contained Z2% walter which necessitated Codacing the levels of soda ash te 10. A Hoar ! VE a a wl rate of wear were measured as previously. Ki Tyee Ve sults are included in Table 1 above.

Ne can be seen from bhe table . Ane ras ing the via _— content Lo 22% gave some sof bening of tho hae and a slightly increased rate of wear.

With NSD bars containing peimary o'oohol aulpha tes as the detergent active, increasing the eater conten k 29 af the bar reduces the bara pesisionce bo breitlle wo Lh ws

A

BAD ORIGINAL [Jd re S————e i — 7c 05 frm bogre rare of compoed Fionn YTTE were suabjec ted to

Shh cheep beset For bed BERL Teac bore ae eae dbed above.

It vam fone Bho fone havs byobe india Leo picces appre laa toy ak bbe corbres whi Tee Tuo of The aia bars a apadne ed ene pelt Biome l feaoment. I'he desis tanoe Lo - Chit Ele Fras tues was bhesee fore ab loan ae good as that

Po f chmpoe ition Voor the commenred alo prredoiot with allyl i :

Prempy apes and phir ato as ae bie, This afew Pha .

Prem ae meyer at Smn oF ent Tudors was mab i: wr in possible Lo

Apher Flies abo ee baa Frein LAT ten IN wi hee b

Cmepinne dele iment ta the resistance to rattle i frome barren, re i comple JE

Fare similar bo composition VI wore nade, 113 Ceplrb i but ig eo le lase from Hahn & Co, mold wander Gheds pho d madd on . flab f Toe pion Tatty demsdity OL 7Fa Litre

Cael Habiy f Vover lr HER BO Fant le rfp iby QUREKGgA LL bre i These bars, and Fhose of composition YI were subdncted ko Bhe ocdeop best for bribe fracbare. NLL

Bae of eermpee i Dion YT Gud Uh Soka leo) broke at tho : y

Teentral indentation only «a result as good as for remposition VIL When Hahnof lock H 100 wan used, four "bars hrake at the contre, with two ssmall fragments 2a bir olen off. Twer bars broke at the centre wikbh pisces ‘ . we LF mm ; f

BAD ORIGINAL D

Ego +

—————— ee ————— eee

J]ec3 "ale broken of foal owe ent Wit tr a fb TRIS Lui braves bapeboea ab The omni be ants (I by oly eke dn Ta ! places pred Phe eee Done Care TE Teel Thi !

Chpealiagn gabters ehh Prati oped, cf Tbaed bonds wei rn : 31% fr Ca ba 1 JR. . cq ' I 3 1 a geste ral Ty sont sen gael en Py hye ornare ah probe Uy : 1

PEscamale 4 : A trea ad hoe composi Donen he par ah wing i { poy oar et ee Fh eit eb AUP ch ETT { ‘ achmi bore which © SPELT Dears ordpleeoabe GORE) a

Che he des BISA ar bao Vid ly pro Loe tian et Sliven wal bs

Dpdeapres pinned aid Sani Servo LF Cob Lerman : :

Dane lodest, ATE Udy rare Spach oo epee Tube peas Ebon ges ' : ford Foye ' Destress bose Lig 0 : evel tom Seip yp bene Tas . TL

Sot i tee opine plore : nen trarbonatb er Cooariable a bion) : Ta 0% : Alvin snl phe le Canleede ous) 1.0% :

CGewl dog Att aline gilicale

Canbydrous) : ILO

Calcite : variable : Kar) in BLOT

Lo

Water 107 : Cellulose } variable

Tope i ties introduced v ith the al : doeteragant active, ine ' constituents tral miveeel ber 30 } os

BAD ORIGINAL A) . r (4 o. \ :

foes

The parts of Lhe compos Pbtion which were varied ara cb oat sn Tahlo I below ed Fh pales oof rman pbworoard.

Fae

Composition Ho TY ¥ } 1 Yr Xt] Xr XW i | avin Fo p1LTY RLLT RULER ! 0 0 RTL

Foes Rad 0} IN Q 0" ES pL GB :

AE Mak 0 0 0 “a ak LH.N al

COL RT EU] Fa PLE oo | 0 © 3 bom CEL 10, © 1,00 10,00 toe : 0 0 0 : Eh Lo , ( oo Ha, GU pA 0 0 0 o 10.0 10.0 10.0

Caled te % Bly. BAL 20.00 Lhe ESA Ln PALL

Ler lulose 7 0 JES HN Lav, no "0 LO 0 fiabte of wear fo. 7A Eur To & ba 7. (weight loss : 15% di Qvans : "Compositions 1X to X11 show the of i” tL oof ! inteodueing increasing Aamoun te of celle loss o ikh wile En rant reduction of the amonn Ud calodte while

Clr composition remains © Sma Lar dn olbhees respon, I ig Llearly seen that thie Yeads too popes 5A

Lr cducition in the rate of wear oO f bh bapa,

Cops i Lions XPD xX show that gener al! Comimd ba cee lta are obtained Lf polass Lem . The as replaces! by sod Jom salts oF if the proporbions af thie two detergen t actives are varied.

Compositions TX. X ane XT were assocsod for of ein 1 . wo LG en :

BAD ORIGINAL A

LENNY

—_— ee ———————— TE ————— A ce—— eer wer eer 77003 elenrac ter patios dit Lhe wane des Thoab bn IFooaanp le b.

Proeny Lbs aie et ouk do thee followipg Foie 2. ber

Com piensa do fdiore Blo i X wd 3 Se Le base 0D | DLO

Sei L La ool La

Moet, tL 2 on 1 .

Sdn BI Tn A his Table shows Ue copes iD os ve add oboe i containing col halos Le co fe bioy somes fle

Cini VE ition TX.

Example 2

Teo for mad abinr sg were prarpat wel men ending a

Tm bue od cuca bose ah sma lpha le (rh ard 1 go 1% atkyl honzane sulphonats ATER) me deter gont Vive.

Again, rake of wear wae Toes bid, The pos ibhioms and i

Che pate wf we oor owe mel out le Table alow. One again ito can bar meen bed Lobe cebu Bony nf pond Tad ome leads Feyoa penn bion dn Blue rade of eee a 20

BAD ORIGINAL 9d o7foo3

Taree nv : i

Frese pat Leon I

Ars (Na) EE LL.2%

Cel dom Fed pe by prherey shan le ho 11.0%

Seti pesrophee phe Le 1.0 4.0%

Cetin ay on a be TLE LA

CF seme ven ar open es II Ln

Alm oom cpt . vo 1,

VReeliam ath add ei Ee be anbryderous ) CE LR

Galoite LU SOY

Cellulose LG a

Cha bn een 10.0% i 1

Prmpur ities in troduced with { : . (the deteraent ac bis, min . : cost A nen te ! { Batatice Lo L007

Fate mf wear (weight loss in ran) Via | Fata ; me RY mm

BAD ORIGINAL £)) oF

Claims (1)

1. 7 063 Claims :

   1. A built detergent bar composition comprising from ko 459% by weight of non-snap detergool active, from Solo 60% by weight of deltergency builder, an o at least 3 1% by weight of cellulose having & Bull daneiby less , Bhan O.b hyg/latre,

   CP. 6 bar according to claim LU wherein ob least 10% of ‘ ' : \ Cthe detergent active, by weld aht, de ~ndosnic detergent ac Livi selected from primary aleohol sotphate of 10 formila ' [O50 M :

   + . . t oa Pandsor fatly acyl ester sul phonate of fdimala J fer pt : ROCHE, R ; 3 . } 50,0 19 inowhich Cor R ie oa primary alkyl groap containing 3 Cher 29 carbon atoms, ROOds oa primary alk gl group . . ; 2 . t . Cecontaining Loto 6 carbon atoms and HM dso cation such that the detergent active materi al io weiter soluble. ‘een ~ Zo. 0 bar according to claim 2 wherein ob leas 10% hy weight of the detergent active is sn id primary alcohol : 1 pau hb pheatee, A Nn bar according to olaim 2 wherein the detergent acti also comprises alkyl benzeno sulphona ter having from 8 to 27 carbon atoms in the allyl chain thereo f. 29 5. A bar according to claim 2 whercin the cat ion Mois I ! A i BAD ORIGINA!. Og

   —— rr ——————————————————————————————— } ~7fo 03 an alkali metal. &He A har according te claim 2 wherein She bar composition contains at least d GB hy wee taht of the said primary atenhel sulphate and/or Ta tty acid ester ed phenate.

   7. A har according to claim 1 wher orn ther amount of the said cellulose is nob over 10% hy waight of the bar composition. !

   1. fA bar according too claim Towber ein bhe amoun LL of Sthe maid cellulose is 2 ta AY by weighl of the bar craps ta an. 7 fy kar according to claim A wherein “onp 1s TE betantially absent. :

   10. A bar according to olatm 1 wheroin Aes amount of . 18 de tergen tobi lder dis toY to 49% by ooiaht of the bar romposition.

   11. A bar according to claim 1 wherein the builder comprises phospate in an amount which is at least 10% : : by weight of the har composition. } 26 12. A bar according to claim 1 which & tsa contains inorganic filler in an amount which i= 5 toy AY by weight of the bar composition. : FL TZARETH AACKSOM FETTER JAMES MINERS { Inventarea) — BAD ORIGINAL. A