PH12013000331B1 - Cleaning auxiliary article for washing and washing method using the same - Google Patents
Cleaning auxiliary article for washing and washing method using the same Download PDFInfo
- Publication number
- PH12013000331B1 PH12013000331B1 PH12013000331A PH12013000331A PH12013000331B1 PH 12013000331 B1 PH12013000331 B1 PH 12013000331B1 PH 12013000331 A PH12013000331 A PH 12013000331A PH 12013000331 A PH12013000331 A PH 12013000331A PH 12013000331 B1 PH12013000331 B1 PH 12013000331B1
- Authority
- PH
- Philippines
- Prior art keywords
- washing
- auxiliary article
- cleaning auxiliary
- magnesium
- particles
- Prior art date
Links
- 238000005406 washing Methods 0.000 title claims abstract description 107
- 238000004140 cleaning Methods 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims description 24
- 239000011777 magnesium Substances 0.000 claims abstract description 73
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 56
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 56
- 239000002245 particle Substances 0.000 claims abstract description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000003599 detergent Substances 0.000 claims abstract description 17
- 239000012466 permeate Substances 0.000 claims abstract description 5
- 239000000126 substance Substances 0.000 claims description 16
- 239000000835 fiber Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 239000002689 soil Substances 0.000 abstract description 20
- 239000000047 product Substances 0.000 abstract description 17
- 238000001035 drying Methods 0.000 abstract description 8
- 239000002075 main ingredient Substances 0.000 abstract description 5
- 239000004744 fabric Substances 0.000 description 14
- 229910052739 hydrogen Inorganic materials 0.000 description 13
- 239000001257 hydrogen Substances 0.000 description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 12
- 239000004094 surface-active agent Substances 0.000 description 11
- 230000003014 reinforcing effect Effects 0.000 description 10
- 238000011156 evaluation Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000004599 antimicrobial Substances 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000009958 sewing Methods 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F39/00—Details of washing machines not specific to a single type of machines covered by groups D06F9/00 - D06F27/00
- D06F39/02—Devices for adding soap or other washing agents
- D06F39/024—Devices for adding soap or other washing agents mounted on the agitator or the rotating drum; Free body dispensers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1206—Water-insoluble compounds free metals, e.g. aluminium grit or flakes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F35/00—Washing machines, apparatus, or methods not otherwise provided for
- D06F35/005—Methods for washing, rinsing or spin-drying
- D06F35/006—Methods for washing, rinsing or spin-drying for washing or rinsing only
Abstract
The object is to suppress a generation of a half-dry odor from the laundry such as clothes after drying even when the laundry is washed and thereafter dried indoors. A cleaning auxiliary article for washing according to the invention obtained by enclosing a plurality of particles 1 containing magnesium as the main ingredient (magnesium particles) in a net body which water permeates is introduced, together with a detergent for washing, into the washing tub of a washing machine to wash the goods to be washed, thereby reducing soils remaining on fibrous products themselves by the action of metallic magnesium and preventing the generation of a half-dry odor even when the fibrous products are dried indoors.
Description
described first and second actions involved in hydrogen generation or the above-described third action of rendering the washing liquid weak alkaline.
[0022]
The average particle diameter of the magnesium particles used in the cleaning auxiliary article for washing according to the invention is preferably smaller from the viewpoint of increase in surface area per unit volume for the purpose of increasing the amount of hydrogen to be generated. However, their strength lowers and the handling thereof is also made difficult with the decreasing average particle diameter. Therefore, the average particle diameter preferably ranges from 1.0 mm to 9.0 mm, more preferably ranges from 3.0 mm to 7.0 mm, most preferably ranges from 4.0 mm to 6.0 mm from production and use viewpoints.
[0023]
The cleaning auxiliary article for washing according to the invention includes a plurality of magnesium particles enclosed in a net body which water permeates, and thus is easily put in a washing tub when used, and easily taken out of the tub after use.
[0024]
Although various natural fibers and synthetic fibers can be used as the material for this net body so long as the fibers have water resistance, polyester fibers, which are easy to dry after use and have a small coloring tendency during washing, are preferably used.
[0025]
Various weaving methods can be employed as the method of weaving this net body itself so long as water permeates the net body. Also, various enclosing means can be employed as the means of enclosing the magnesium particles in the net body, so long as the magnesium particles would not escape. However, the net body is preferably composed of a plurality of layers, or has a sewn part to which a reinforcing cloth is sewn, in order that no hole would be formed in the net body or the sewn part would not come loose even after repeated use of the net body for washing.
A grip, when attached to the net body, is convenient in the case where the net body is taken out of the washing tub or dried after use.
[0026]
The cleaning auxiliary article for washing according to the invention is introduced into the washing tub of a washing machine together with a detergent for washing for use in washing of the laundry (goods to be washed). While a larger total surface area of magnesium particles provides a greater effect of promoting the above first to third soil removal actions of a surfactant, the magnesium particles are preferably used in such an amount that the total surface area ranges from 8 cm’ to 11 cm? per liter of washing water from practical and economical viewpoints.
[0027]
The cleaning auxiliary article for washing according to the invention can be repeatedly used many times in washing until the magnesium particles are consumed and depleted.
The magnesium particles used in the cleaning auxiliary article for washing according to the invention can be produced, for example, by dripping molten magnesium into water.
[0028]
Hereinafter, the invention will be explained by way of Examples. In the meantime, the invention is not limited to specific examples which will be explained below, and can be variously modified so long as variants have substantially the same construction as the invention and provide similar actions and effects.
[0029]
A first Example of the cleaning auxiliary article for washing shown in FIG. 1 is such that a plurality of magnesium particles 1 is enclosed in a net bag 2, and that a grip 9 is attached to a corner part of the net bag 2.
[0030]
This cleaning auxiliary article for washing is prepared by the following procedures: 1) folding one rectangular sheet of net body on itself at the center part in the longitudinal direction;
CT
2) sewing two sides to form a net bag 2 (a seam not shown) ; 3) opening an unsewn side to put a plurality of magnesium particles 1 into the net bag 2 through the opening; and 4) folding one rectangular sheet of cloth body on itself at the center part in the longitudinal direction, inserting its end part into the opening part of the main body (thereby forming a grip 9), and, thereafter, sewing the opening part of the main body and this side to which the end part of the cloth body is to be sewn (thereby forming a seam 6 of the net bag) to enclose the plurality of magnesium particles 1 in the net bag 2.
[0031]
Next, a second Example of the cleaning auxiliary article for washing shown in FIG. 2 is such that a net bag is composed of two layers (an internal net body 3 and an external net body 4) for reinforcement, and that a reinforcing cloth 5 is sewn to the edge part to reinforce the sewn part, whereby the enclosed magnesium particles 1 are hard to escape. In this auxiliary article, one end of the reinforcing cloth 5 extends outward from the edge part to form a grip 9.
[0032]
This cleaning auxiliary article for washing is prepared by the following procedures: 1) arranging a plurality of magnesium particles 1 between two sheets of circular internal net bodies 3, and, thereafter, sewing the edge part of the internal net bodies 3 (thereby forming a seam 7 of the internal net body); 2) superposing two sheets of circular external net bodies 4, which are larger than the internal net bodies 3, on the upper and lower surfaces of the resultant product prepared in the above-described 1); 3) folding a rectangular cloth at the center part in the longitudinal direction, and covering the entire edge part of the external net bodies in such a manner that the inside of this folded part is along the edge part of the external net bodies (thereby forming a reinforcing cloth 5) and extending one end of the reinforcing cloth outward from the edge part of the external net bodies (thereby forming a grip 9); and 4) sewing the edge part of the external net bodies and the reinforcing cloth (thereby forming a seam 8 of the reinforcing cloth).
[0033] [Production Sample]
The cleaning auxiliary article for washing according to the invention was produced as follows: <Production of magnesium particles>
Molten metal magnesium (Mg) simple substance were introduced into water to produce magnesium particles, and the magnesium particles are sieved out to obtain approximately spherical magnesium particles having a diameter of 4.8 mm to 5.3 mm and an average weight of about 0.14 g.
[0034]
The results of analysis of the ingredients of these magnesium particles were as follows: magnesium (Mg): 99.950% by weight; iron (Fe): 0.015% by weight; aluminum (Al): 0.022% by weight; zinc (Zn): 0.010% by weight; and others: 0.003% by weight.
[0035] <Production of cleaning auxiliary article for washing>
The cleaning auxiliary article for washing according to the second Example (FIG. 2) (hereinafter referred to as the “auxiliary article”) was produced using 50 g of the magnesium particles obtained above (about 360 particles).
This auxiliary article has a circular shape having a diameter of 13 cm, and the internal net body, external net body and reinforcing cloth are made of polyester.
[0036] : <Washing test using auxiliary article>
In order to confirm the effect of the invention (a generation of a half-dry odor can be prevented from fibrous products after drying even when the fibrous products are naturally dried indoors), tests (hereinafter referred to as “washing tests”) were conducted under the following conditions while this auxiliary article was lent to 10 female testers.
¢ The respective female testers conduct the test by a washing method (such as laundry, detergent for washing, washing machine and washing conditions) commonly carried out, provided that no perfuming agent or softener is added to a detergent for washing in this test. e Washing is carried out in the following three cases: * Case 1: Washing is carried out by a common washing : method, and the goods washed are dried in the sun; * Case 2: Washing is carried out by a common washing method, and the goods washed are dried indoors; and * Case 3: Washing is carried out by a common washing method except that the auxiliary article is introduced, together with a detergent for washing, into a washing tub of a washing machine, and the goods washed are dried indoors. e The evaluation of odor is made by the respective testers smelling the odor of the dried laundry and selecting the grade corresponding to the odor from the following four grades: * Grade A: Odor is completely absent; * Grade B: No odor is present; * Grade C: Slight odor is present; and * Grade D: Odor is present.
[0037] <Evaluation results of washing test>
The evaluation results of the washing test are summarized in the following Table 1.
[0038] [Table 1]
No auxiliary No auxiliary Auxiliary article used; article used; article used; dried in the sun dried indoors dried indoors vestern | a | 0s | a ester | 0» | oo | a esters | oa | oc | a esters | a | oc | oa restr | a | oc | oa
Tester 7 C Cc ester | a | oc | oa esters | a | oc | a
[0039]
On the whole, it is evident, from the comparison between the evaluation of Case 2 (Grade B: 2 testers; Grade
C: 7 testers; and Grade D: one tester) and the evaluation of Case 3 (Grade A: 5 testers and Grade B: 5 testers), that, when the goods washed are dried indoors, the generation of odor from the laundry after drying can be prevented if the auxiliary article of the invention is introduced, together with a detergent for washing, into the washing tub of a washing machine to carry out washing.
[0040] : 16 ee
For the respective testers, 9 testers ranked the evaluation of Case 3 as better than the evaluation of Case 2, and 1 tester ranked the evaluations of these cases as > equivalent to each other. Also from this fact, it could be confirmed that, when the goods washed are dried indoors, the generation of odor from the laundry after drying can be prevented if the auxiliary article of the invention was introduced, together with a detergent for washing, into the washing tub of a washing machine to carry out washing.
[0041] 1: Magnesium particles 2: Net bag : 3: Internal net body 4: External net body 5: Reinforcing cloth 6: Seam of net bag 7: Seam of internal net body 8: Seam of reinforcing cloth 9: Grip
CR
CLEANING AUXILIARY ARTICLE FOR WASHING AND WASHING METHOD
USING THE SAME
[001]
The invention relates to a cleaning auxiliary article for washing used together with a detergent for washing during washing, in order to suppress a generation of an abnormal odor, what is called, a half-dry odor (hereinafter referred to as “half-dry odor”) from fibrous products such as clothes after drying even when such fibrous products are washed and thereafter dried indoors, and a washing method using the same.
[002]
When fibrous products such as clothes are washed and thereafter dried indoors, a half-dry odor is generated from the fibrous products after drying. Such a half-dry odor is considered to be caused by bacteria acting on oils from sebum and proteins which cannot be removed by washing (hereinafter referred to merely as “soils”).
[003]
In order to suppress the generation of a half-dry odor, Patent Document 1 discloses a technique of using a detergent into which an antimicrobial agent is incorporated, and Patent Documents 2 and 3 disclose techniques of using a softener into which an antimicrobial agent is incorporated.
Also, Patent Document 4 discloses a technique of using a decdorant including an antimicrobial agent, in order to eliminate the half-dry odor generated.
[004]
On the one hand, Patent Document 5 discloses, as the technique of utilizing particles containing magnesium, such a technique that soils can be removed with a reduced amount of detergent or without using any detergent by using a washing stone including 10% to 40% by weight of magnesium, 5% to 20% by weight of iron, 8% to 30% by weight of calcium and 25% to 40% by weight of silicon in washing using a household electric washing machine. Patent Documents 6 and 7 discloses techniques of introducing magnesium particles into water to produce hydrogen water containing active hydrogen.
PATENT DOCUMENTS
[005]
Patent Document 1: JP 2006-160822 A
Patent Document 2: JP 2001-303441 A
Patent Document 3: JP 2001-303439 A
Patent Document 4: JP 2001-070423 A
Patent Document 5: JP 2004-238602 A
Patent Document 6: JP 2008-194604 A
Patent Document 7: JP 2012-082110 A
[0006]
In order to prevent a generation of a half-dry odor, antimicrobial agents are used to suppress the grown of bacteria in the inventions disclosed in Patent Documents 1 to 3, and a deodorant is used to eliminate a half-dry odor hanging in a space in the invention disclosed in
Patent Document 4. However, unlike these inventions, the invention aims at reducing soils themselves, remaining in fibrous products after washing, which are an underlying cause of half-dry odor generation by the action of simple substance of metallic magnesium (Mg), thereby preventing the generation of a half-dry odor.
MEANS FOR SOLVING THE PROBLEMS
[0007]
In washing the fibrous products such as clothes, the lipophilic groups in a surfactant having hydrophilic groups and lipophilic groups are attached to soils, and the hydrophilic groups pull the soils apart into water, whereby the soils are removed. The inventors, however, have found that hydrogen generated by a reaction between simple substance of metallic magnesium (Mg) and water promotes a soil removing action of the surfactant, and then have accomplished this invention.
[0008]
In the invention, a cleaning article for washing obtained by enclosing a plurality of particles containing 50% by weight or more of simple substance of metallic magnesium (Mg) as the main ingredient in a net body which water permeats is used during washing to promote a soil removal action of the surfactant contained in a detergent for washing, thereby making it possible to reduce soil themselves. Therefore, it is possible to prevent a generation of a half-dry odor from fibrous products after drying even when the fibrous products are naturally dried indoors. Further, the cleaning auxiliary article for washing provides economic effects because of the unnecessity to incorporate an extra ingredient such as an antimicrobial agent in a detergent for washing, and less affects the health of hypersensitive persons.
[0009]
FIG. 1 is a perspective view showing a first Example of a cleaning auxiliary article for washing of the invention.
FIG. 2 is a perspective view showing a second
Example of the cleaning auxiliary article for washing of the invention.
FIG 3 is a perspective view showing a state where an external net body and an edge cloth have been removed from the cleaning auxiliary article for washing shown in FIG 2.
FIG. 4 is a perspective view showing an external net body provided on both upper and lower surfaces of the cleaning auxiliary article for washing shown in FIG. 2.
[0010]
The invention relates to a cleaning auxiliary article for washing which can reduce soils themselves and can prevent a generation of a half-dry odor from a fibrous product after drying even when the fibrous product is naturally dried indoors, and a washing method using the same, specifically, a cleaning auxiliary article for washing obtained by enclosing, in a net body which water permeates, a plurality of particles containing 50% by weight or more of simple substance of metallic magnesium (Mg) as the main ingredient (hereinafter referred to as “magnesium particles”), and a washing method using the same.
[0011]
The inventors have found that hydrogen contained in a washing liquid promotes the soil removal action of a surfactant, and have made the invention mainly involving the use magnesium particles during washing in order to generate hydrogen in a washing liquid during washing.
[0012]
A reaction of simple substance of metallic magnesium (Mg) with water to generate hydrogen is represented by the fellowing formula:
MG + 2H,0 Ho + Mg (OH):
[0013]
While this reaction is caused by the occurrence of an oxidation-reduction reaction with water due to the ionization tendency of magnesium, magnesium has a small ionization tendency as compared with calcium and sodium, and thus relatively slowly reacts with water at room temperature to generate hydrogen.
[0014]
The hydrogen thus generated in a washing liguid during washing is considered to promote the soil removal action of a surfactant due to its following functions.
[0015]
Firstly, hydrogen has a very small atomic diameter, and thus, when existing in a washing liquid, functions to allow a surfactant to penetrate deeply into the weave pattern of fibrous products such as clothes. Therefore, the range where soils are removed by the surfactant can be expanded. Especially in the case where the fibrous products are knitted with very thin threads, this action is exerted remarkably.
[0016]
Secondly, hydrogen functions to emulsify soils, and thus can increase the degree of soil removal by a surfactant.
[0017]
Thirdly, many soils are fundamentally acidic, and thus the soil removal action of the surfactant is promoted,
CT as described also in Patent Document 5 described above, when magnesium particles are introduced into a washing liquid to render the washing liquid weak alkaline.
[0018]
In the meantime, Patent Document 5 describes such a technique that soils can be removed with a reduced amount of detergent or without using any detergent by using a washing stone including 10% to 40% by weight of magnesium, 5% to 20% by weight of iron, 8% to 30% by weight of calcium and 25% to 40% by weight of silicon in washing using a household electric washing machine (claim 1 of Patent
Document 5). While this is a technique based on the matter that, upon contact with the washing stone including the above-described specific ingredients, water changes into weak alkaline water having reduction action whereby washing effects are obtained (paragraph [009] of Patent Document 5), and is similar to the invention in that the washing effect of a detergent (surfactant) is improved by using particles containing a metallic ingredient such as magnesium as a compound but does not focus on the above- described first and second functions of simple substance of metallic Magnesium (Mg) as in the invention. Therefore the technique described in Patent Document 5 is greatly different from the invention.
[0019]
The composition of the magnesium particles used in the cleaning auxiliary article for washing according to the invention preferably includes simple substance of metallic Magnesium (Mg) in a relatively high proportion in order to increate the amount of hydrogen to be generated since simple substance of metallic magnesium (Mg) relatively slowly reacts with water at room temperature to generate hydrogen, as described above.
[0020]
The phrase “particles containing 505 by weight or more of simple substance of metallic magnesium (Mg) as the main ingredient” used herein means particles containing simple substance of metallic magnesium (Mg) in a relatively proportion, and, specifically, the particles are those containing 50% by weight or more of simple substance of metallic magnesium (Mg), more preferably those containing 80% by weight or more thereof, and more preferably those containing substantially 100% by weight thereof (the term “substantially” means “the case where the magnesium content is considered to the exclusion of impurities, which cannot be removed by a purification method commonly known at present and employed on an on-site production basis, from the ingredients of magnesium particles”).
[0021]
Ingredients, other than the main ingredient simple substance of metallic magnesium (Mg), which can be contained in the magnesium particles include: 1) impurities such as iron (Fe), aluminum (Al) and
Zinc (Zn) which are contained in magnesium ore or associated, for example, with the magnesium refining and processing steps; and 2) substances which do not inhibit above-
Claims (7)
1. A cleaning auxiliary article for washing, being characterized by being obtained by enclosing a plurality of particles containing metal Magnesium (Mg) simple substance in an amount of 50% by weight or more in a net body which water permeates.
2. The cleaning auxiliary article for washing according to claim 1, being characterized in that the particles containing metal magnesium (Mg) simple substance in an amount of substantially 100% by weight.
3. The cleaning auxiliary article for washing according to claim 1, being characterized in that the average particle diameter of the particles from 1.0 mm to
9.0 mm.
4. The cleaning auxiliary article for washing according to claim 1, being characterized in that the net body which water permeants is made of polyester fibers.
5. The «cleaning auxiliary article for washing according to claim 1, being characterized in that the net body which water permeants has a grip.
6. The cleaning auxiliary article for washing according to claim 1, being characterized in that the particles are added in such amount that the total surface area ranges from 8 cm? to 11 cm? per liter of washing water.
7. A washing method characterized by including the step of introducing the cleaning auxiliary article for washing according to any of claims 1 to 6, together with a detergent for washing, into the washing tub of washing machine to wash the laundry.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012243302A JP5312663B1 (en) | 2012-11-05 | 2012-11-05 | Washing auxiliary equipment for washing and washing method using the same |
Publications (2)
Publication Number | Publication Date |
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PH12013000331A1 PH12013000331A1 (en) | 2015-05-11 |
PH12013000331B1 true PH12013000331B1 (en) | 2015-05-11 |
Family
ID=49529574
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PH12013000331A PH12013000331B1 (en) | 2012-11-05 | 2013-10-30 | Cleaning auxiliary article for washing and washing method using the same |
Country Status (5)
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---|---|
JP (1) | JP5312663B1 (en) |
KR (1) | KR101541966B1 (en) |
CN (1) | CN103806254B (en) |
HK (1) | HK1198186A1 (en) |
PH (1) | PH12013000331B1 (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
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JP6594755B2 (en) * | 2015-11-30 | 2019-10-23 | レック株式会社 | Alkaline ion water generator for washing machines |
CN105647688A (en) * | 2016-03-14 | 2016-06-08 | 燕山大学 | Magnesium alloy particle washing product and preparation method thereof |
JP6374135B1 (en) * | 2017-02-24 | 2018-08-15 | 株式会社宮本製作所 | Fertilizer for plant cultivation comprising washing wastewater, plant cultivation method using this fertilizer, and method for using washing wastewater as fertilizer for plant cultivation |
JP7089344B2 (en) * | 2017-04-24 | 2022-06-22 | 株式会社宮本製作所 | Bathing water reforming products and bathing methods using them |
JP6894329B2 (en) * | 2017-09-14 | 2021-06-30 | 株式会社宮本製作所 | A washing machine in which the inner surface of the washing water storage section is made of magnesium. |
JP7224025B2 (en) * | 2019-01-25 | 2023-02-17 | 株式会社宮本製作所 | Tap water reformer and tap water reforming method using this tap water reformer |
CN110592883A (en) * | 2019-09-30 | 2019-12-20 | 福建麦特新铝业科技有限公司 | Aluminum alloy auxiliary article for washing |
JP2021101902A (en) * | 2019-12-25 | 2021-07-15 | 青島海爾洗衣机有限公司QingDao Haier Washing Machine Co.,Ltd. | Washing machine |
JP7454811B2 (en) | 2019-12-26 | 2024-03-25 | 青島海爾洗衣机有限公司 | washing machine |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
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JP3660803B2 (en) * | 1998-07-06 | 2005-06-15 | 株式会社東芝 | Washing machine |
JP2001340691A (en) * | 2000-05-31 | 2001-12-11 | Hitachi Ltd | Ion removal apparatus of washing water and electric washing machine |
JP3933417B2 (en) * | 2001-06-21 | 2007-06-20 | 株式会社東芝 | Washing machine |
CN2534216Y (en) * | 2001-09-04 | 2003-02-05 | 徐永安 | Clothes-washing aid cleaning ball |
JP2004238602A (en) * | 2003-02-07 | 2004-08-26 | Iwata Kokogyo Kk | Stone for washing and small bag for washing using the same, and method for removing mold adherent to washing machine |
JP2004330011A (en) * | 2003-05-01 | 2004-11-25 | Norimi Okada | Aqueous hydrogen producing device for bath |
CN200943152Y (en) * | 2006-07-27 | 2007-09-05 | Tcl家用电器(惠州)有限公司 | Sterilizing washing machine |
CN102234902B (en) * | 2010-04-30 | 2014-12-10 | 海尔集团公司 | Method for cleaning space between inner and outer tubs of washing machine with flexible particles and washing machine capable of implementing same |
-
2012
- 2012-11-05 JP JP2012243302A patent/JP5312663B1/en active Active
-
2013
- 2013-10-30 PH PH12013000331A patent/PH12013000331B1/en unknown
- 2013-11-04 CN CN201310536211.2A patent/CN103806254B/en active Active
- 2013-11-04 KR KR1020130132787A patent/KR101541966B1/en active IP Right Grant
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2014
- 2014-11-20 HK HK14111744.0A patent/HK1198186A1/en unknown
Also Published As
Publication number | Publication date |
---|---|
KR101541966B1 (en) | 2015-08-04 |
JP2014090895A (en) | 2014-05-19 |
CN103806254A (en) | 2014-05-21 |
PH12013000331A1 (en) | 2015-05-11 |
JP5312663B1 (en) | 2013-10-09 |
KR20140058365A (en) | 2014-05-14 |
CN103806254B (en) | 2016-06-01 |
HK1198186A1 (en) | 2015-03-13 |
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