PE20000229A1 - GAS CONVERSION USING HYDROGEN PRODUCED FROM SYNTHESIS GAS TO REMOVE SULFUR FROM HYDROCARBON LIQUIDS FROM THE GAS WELL - Google Patents
GAS CONVERSION USING HYDROGEN PRODUCED FROM SYNTHESIS GAS TO REMOVE SULFUR FROM HYDROCARBON LIQUIDS FROM THE GAS WELLInfo
- Publication number
- PE20000229A1 PE20000229A1 PE1999000045A PE00004599A PE20000229A1 PE 20000229 A1 PE20000229 A1 PE 20000229A1 PE 1999000045 A PE1999000045 A PE 1999000045A PE 00004599 A PE00004599 A PE 00004599A PE 20000229 A1 PE20000229 A1 PE 20000229A1
- Authority
- PE
- Peru
- Prior art keywords
- gas
- synthesis gas
- synthesis
- conversion
- hydrogen produced
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/007—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 in the presence of hydrogen from a special source or of a special composition or having been purified by a special treatment
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0415—Purification by absorption in liquids
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
- C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0435—Catalytic purification
- C01B2203/0445—Selective methanation
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0495—Composition of the impurity the impurity being water
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/063—Refinery processes
- C01B2203/065—Refinery processes using hydrotreating, e.g. hydrogenation, hydrodesulfurisation
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0872—Methods of cooling
- C01B2203/0883—Methods of cooling by indirect heat exchange
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1047—Group VIII metal catalysts
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1094—Promotors or activators
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
- C01B2203/1241—Natural gas or methane
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1258—Pre-treatment of the feed
- C01B2203/1264—Catalytic pre-treatment of the feed
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1258—Pre-treatment of the feed
- C01B2203/1264—Catalytic pre-treatment of the feed
- C01B2203/127—Catalytic desulfurisation
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/146—At least two purification steps in series
- C01B2203/147—Three or more purification steps in series
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S208/00—Mineral oils: processes and products
- Y10S208/95—Processing of "fischer-tropsch" crude
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Gas Separation By Absorption (AREA)
Abstract
PROCEDIMIENTO PARA CONVERSION DE GAS DE SINTESIS, EL CUAL COMPRENDE : i) ELIMINAR UNA MEZCLA QUE COMPRENDE UN GAS DE HIDROCARBURO E HIDROCARBUROS DE C4+ CONTENIENDO AZUFRE, DESDE UN POZO DE GAS NATURAL; ii) SEPARAR POR LO MENOS UNA PORCION DE DICHOS HIDROCARBUROS DE C4+ CONTENIENDO AZUFRE DESDE DICHA MEZCLA; iii) HACER REACCIONAR DICHO GAS CON OXIGENO Y VAPOR PARA FORMAR UN GAS DE SINTESIS COMPRENDIENDO UNA MEZCLA DE H2 Y CO; iv) CONTACTAR UNA PORCION DE DICHO GAS DE SINTESIS CON UN CATALIZADOR DE SINTESIS DE HIDROCARBURO, DE PREFERENCIA DE FISHER-TROPSH Y HACER REACCIONAR DICHOS H2 Y CO A CONDICIONES DE REACCION EFECTIVAS PARA PRODUCIR HIDROCARBUROS; v) PRODUCIR HIDROGENO A PARTIR DE OTRA PORCION DE GAS DE SINTESIS; vi) HACER REACCIONAR DICHO HIDROGENO CON LOS HIDROCARBUROS C4+ EN PRESENCIA DE UN CATALIZADOR DE HIDRODESULFURACION EN CONDICIONES EFECTIVAS PARA ELIMINAR POR LO MENOS UNA PORCION DE DICHO AZUFREPROCEDURE FOR SYNTHESIS GAS CONVERSION, WHICH INCLUDES: i) ELIMINATING A MIXTURE THAT INCLUDES A GAS OF HYDROCARBON AND C4 + HYDROCARBONS CONTAINING SULFUR, FROM A NATURAL GAS WELL; ii) SEPARATE AT LEAST A PORTION OF SAID C4 + HYDROCARBONS CONTAINING SULFUR FROM SAID MIXTURE; iii) REACT SAID GAS WITH OXYGEN AND VAPOR TO FORM A SYNTHESIS GAS, INCLUDING A MIXTURE OF H2 AND CO; iv) CONTACTING A PORTION OF SAID SYNTHESIS GAS WITH A HYDROCARBON SYNTHESIS CATALYST, PREFERRED BY FISHER-TROPSH AND REACTING SAID H2 AND CO TO EFFECTIVE REACTION CONDITIONS TO PRODUCE HYDROCARBONS; v) PRODUCE HYDROGEN FROM ANOTHER PORTION OF SYNTHESIS GAS; vi) MAKE SAID HYDROGEN REACT WITH C4 + HYDROCARBONS IN THE PRESENCE OF A HYDRODESULFURATION CATALYST IN EFFECTIVE CONDITIONS TO REMOVE AT LEAST A PORTION OF SAID SULFUR
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/014,175 US6103773A (en) | 1998-01-27 | 1998-01-27 | Gas conversion using hydrogen produced from syngas for removing sulfur from gas well hydrocarbon liquids |
Publications (1)
Publication Number | Publication Date |
---|---|
PE20000229A1 true PE20000229A1 (en) | 2000-03-27 |
Family
ID=21763961
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PE1999000045A PE20000229A1 (en) | 1998-01-27 | 1999-01-19 | GAS CONVERSION USING HYDROGEN PRODUCED FROM SYNTHESIS GAS TO REMOVE SULFUR FROM HYDROCARBON LIQUIDS FROM THE GAS WELL |
Country Status (15)
Country | Link |
---|---|
US (1) | US6103773A (en) |
EP (1) | EP1051459B2 (en) |
JP (1) | JP4002729B2 (en) |
AR (1) | AR014482A1 (en) |
AU (1) | AU738709B2 (en) |
BR (1) | BR9907154A (en) |
CA (1) | CA2317646C (en) |
DE (1) | DE69901289T3 (en) |
MY (1) | MY121436A (en) |
NO (1) | NO20003728D0 (en) |
PE (1) | PE20000229A1 (en) |
SA (1) | SA99200195B1 (en) |
TW (1) | TW555847B (en) |
WO (1) | WO1999037736A1 (en) |
ZA (1) | ZA99251B (en) |
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US6946111B2 (en) | 1999-07-30 | 2005-09-20 | Conocophilips Company | Short contact time catalytic partial oxidation process for recovering sulfur from an H2S containing gas stream |
US6869978B2 (en) | 1999-11-17 | 2005-03-22 | Conocophillips Company | Pressure swing catalyst regeneration procedure for Fischer-Tropsch catalyst |
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CN105038880A (en) * | 2015-07-03 | 2015-11-11 | 赛鼎工程有限公司 | Method used for producing natural gas via sulfurtolerant methanation |
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CN109650335A (en) * | 2019-01-21 | 2019-04-19 | 武汉理工大学 | A kind of pressure varying adsorption of purified device for producing hydrogen and hydrogen production process |
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GB8910711D0 (en) † | 1989-05-10 | 1989-06-28 | Davy Mckee London | Process |
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GB9109747D0 (en) * | 1991-05-07 | 1991-06-26 | Shell Int Research | A process for the production of isoparaffins |
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US5769909A (en) * | 1996-05-31 | 1998-06-23 | International Fuel Cells Corp. | Method and apparatus for desulfurizing fuel gas |
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ID20211A (en) † | 1997-04-29 | 1998-10-29 | Praxair Technology Inc | HYDROGEN PRODUCTION METHOD USING SOLID ELECTROLITE MEMBRANE |
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-
1998
- 1998-01-27 US US09/014,175 patent/US6103773A/en not_active Expired - Fee Related
-
1999
- 1999-01-13 MY MYPI99000118A patent/MY121436A/en unknown
- 1999-01-14 ZA ZA9900251A patent/ZA99251B/en unknown
- 1999-01-19 PE PE1999000045A patent/PE20000229A1/en not_active Application Discontinuation
- 1999-01-22 WO PCT/US1999/001308 patent/WO1999037736A1/en active IP Right Grant
- 1999-01-22 JP JP2000528644A patent/JP4002729B2/en not_active Expired - Fee Related
- 1999-01-22 DE DE69901289T patent/DE69901289T3/en not_active Expired - Lifetime
- 1999-01-22 BR BR9907154-1A patent/BR9907154A/en not_active Application Discontinuation
- 1999-01-22 EP EP99903267A patent/EP1051459B2/en not_active Expired - Lifetime
- 1999-01-22 CA CA002317646A patent/CA2317646C/en not_active Expired - Fee Related
- 1999-01-22 AU AU23329/99A patent/AU738709B2/en not_active Ceased
- 1999-01-25 AR ARP990100284A patent/AR014482A1/en active IP Right Grant
- 1999-04-02 TW TW088101241A patent/TW555847B/en active
- 1999-05-31 SA SA99200195A patent/SA99200195B1/en unknown
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2000
- 2000-07-20 NO NO20003728A patent/NO20003728D0/en not_active Application Discontinuation
Also Published As
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WO1999037736A1 (en) | 1999-07-29 |
US6103773A (en) | 2000-08-15 |
DE69901289T3 (en) | 2009-11-05 |
CA2317646C (en) | 2009-06-09 |
JP4002729B2 (en) | 2007-11-07 |
BR9907154A (en) | 2000-10-24 |
AU2332999A (en) | 1999-08-09 |
ZA99251B (en) | 1999-09-17 |
EP1051459A1 (en) | 2000-11-15 |
EP1051459B2 (en) | 2009-04-15 |
JP2003501489A (en) | 2003-01-14 |
DE69901289D1 (en) | 2002-05-23 |
EP1051459B1 (en) | 2002-04-17 |
AU738709B2 (en) | 2001-09-27 |
DE69901289T2 (en) | 2002-08-22 |
TW555847B (en) | 2003-10-01 |
MY121436A (en) | 2006-01-28 |
CA2317646A1 (en) | 1999-07-29 |
AR014482A1 (en) | 2001-02-28 |
NO20003728L (en) | 2000-07-20 |
NO20003728D0 (en) | 2000-07-20 |
SA99200195B1 (en) | 2006-06-18 |
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