NZ755841B2 - Agrochemical combination - Google Patents
Agrochemical combination Download PDFInfo
- Publication number
- NZ755841B2 NZ755841B2 NZ755841A NZ75584118A NZ755841B2 NZ 755841 B2 NZ755841 B2 NZ 755841B2 NZ 755841 A NZ755841 A NZ 755841A NZ 75584118 A NZ75584118 A NZ 75584118A NZ 755841 B2 NZ755841 B2 NZ 755841B2
- Authority
- NZ
- New Zealand
- Prior art keywords
- calcium
- inositol
- combination
- linolenic acid
- crop
- Prior art date
Links
- 239000003905 agrochemical Substances 0.000 title claims abstract description 32
- DTOSIQBPPRVQHS-PDBXOOCHSA-N α-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 claims abstract description 138
- 239000000203 mixture Substances 0.000 claims abstract description 131
- CDAISMWEOUEBRE-GPIVLXJGSA-N Inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 claims abstract description 79
- 229960000367 Inositol Drugs 0.000 claims abstract description 78
- 229960004488 Linolenic Acid Drugs 0.000 claims abstract description 67
- 235000020661 alpha-linolenic acid Nutrition 0.000 claims abstract description 67
- 230000037039 plant physiology Effects 0.000 claims abstract description 10
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N Calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 36
- 239000011575 calcium Substances 0.000 claims description 19
- 235000013399 edible fruits Nutrition 0.000 claims description 17
- 229960005069 Calcium Drugs 0.000 claims description 16
- 229910052791 calcium Inorganic materials 0.000 claims description 16
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 14
- 235000019749 Dry matter Nutrition 0.000 claims description 7
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L Calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 4
- 229960001436 CALCIUM SACCHARATE Drugs 0.000 claims description 2
- 229940072020 Calcium Borogluconate Drugs 0.000 claims description 2
- 229960003563 Calcium Carbonate Drugs 0.000 claims description 2
- 229960004256 Calcium Citrate Drugs 0.000 claims description 2
- 229940095618 Calcium Glycerophosphate Drugs 0.000 claims description 2
- VSGNNIFQASZAOI-UHFFFAOYSA-L Calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 claims description 2
- FNAQSUUGMSOBHW-UHFFFAOYSA-H Calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 claims description 2
- UHHRFSOMMCWGSO-UHFFFAOYSA-L Calcium glycerylphosphate Chemical compound [Ca+2].OCC(CO)OP([O-])([O-])=O UHHRFSOMMCWGSO-UHFFFAOYSA-L 0.000 claims description 2
- 239000001736 Calcium glycerylphosphate Substances 0.000 claims description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L Calcium hydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 2
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L Calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 claims description 2
- 229940087373 Calcium oxide Drugs 0.000 claims description 2
- BCZXFFBUYPCTSJ-UHFFFAOYSA-L Calcium propanoate Chemical compound [Ca+2].CCC([O-])=O.CCC([O-])=O BCZXFFBUYPCTSJ-UHFFFAOYSA-L 0.000 claims description 2
- GUPPESBEIQALOS-UHFFFAOYSA-L Calcium tartrate Chemical compound [Ca+2].[O-]C(=O)C(O)C(O)C([O-])=O GUPPESBEIQALOS-UHFFFAOYSA-L 0.000 claims description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H Tricalcium phosphate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 2
- FAPWYRCQGJNNSJ-UBKPKTQASA-L calcium D-pantothenic acid Chemical compound [Ca+2].OCC(C)(C)[C@@H](O)C(=O)NCCC([O-])=O.OCC(C)(C)[C@@H](O)C(=O)NCCC([O-])=O FAPWYRCQGJNNSJ-UBKPKTQASA-L 0.000 claims description 2
- 239000001639 calcium acetate Substances 0.000 claims description 2
- 235000011092 calcium acetate Nutrition 0.000 claims description 2
- 229960005147 calcium acetate Drugs 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000001354 calcium citrate Substances 0.000 claims description 2
- 235000019299 calcium glycerylphosphate Nutrition 0.000 claims description 2
- 239000000920 calcium hydroxide Substances 0.000 claims description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 2
- 239000001527 calcium lactate Substances 0.000 claims description 2
- 229960002401 calcium lactate Drugs 0.000 claims description 2
- 235000011086 calcium lactate Nutrition 0.000 claims description 2
- 239000000292 calcium oxide Substances 0.000 claims description 2
- 235000012255 calcium oxide Nutrition 0.000 claims description 2
- 229960002079 calcium pantothenate Drugs 0.000 claims description 2
- 239000001506 calcium phosphate Substances 0.000 claims description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 2
- 235000011010 calcium phosphates Nutrition 0.000 claims description 2
- 235000010331 calcium propionate Nutrition 0.000 claims description 2
- 239000004330 calcium propionate Substances 0.000 claims description 2
- 239000001175 calcium sulphate Substances 0.000 claims description 2
- 235000011132 calcium sulphate Nutrition 0.000 claims description 2
- 239000001427 calcium tartrate Substances 0.000 claims description 2
- 235000011035 calcium tartrate Nutrition 0.000 claims description 2
- ZQWFSIZRQANUDA-WQMSYZFBSA-L calcium;(2S,3S,4S,5R)-2,3,4,5-tetrahydroxyhexanedioate;tetrahydrate Chemical compound O.O.O.O.[Ca+2].[O-]C(=O)[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O ZQWFSIZRQANUDA-WQMSYZFBSA-L 0.000 claims description 2
- KRALOLGXHLZTCW-UHFFFAOYSA-L calcium;2-acetyloxybenzoate Chemical compound [Ca+2].CC(=O)OC1=CC=CC=C1C([O-])=O.CC(=O)OC1=CC=CC=C1C([O-])=O KRALOLGXHLZTCW-UHFFFAOYSA-L 0.000 claims description 2
- 201000010099 disease Diseases 0.000 claims description 2
- 235000013337 tricalcium citrate Nutrition 0.000 claims description 2
- APVZWAOKZPNDNR-UHFFFAOYSA-L Iron(II) citrate Chemical compound [Fe+2].OC(=O)CC(O)(C([O-])=O)CC([O-])=O APVZWAOKZPNDNR-UHFFFAOYSA-L 0.000 claims 1
- NGLMYMJASOJOJY-UHFFFAOYSA-O azanium;calcium;nitrate Chemical compound [NH4+].[Ca].[O-][N+]([O-])=O NGLMYMJASOJOJY-UHFFFAOYSA-O 0.000 claims 1
- 239000011640 ferrous citrate Substances 0.000 claims 1
- 235000019850 ferrous citrate Nutrition 0.000 claims 1
- 230000015556 catabolic process Effects 0.000 abstract description 12
- 150000002148 esters Chemical class 0.000 abstract description 7
- 150000004001 inositols Chemical class 0.000 abstract description 4
- 241000196324 Embryophyta Species 0.000 description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 34
- 241000208822 Lactuca Species 0.000 description 19
- 238000009472 formulation Methods 0.000 description 18
- 235000003228 Lactuca sativa Nutrition 0.000 description 17
- 240000001016 Solanum tuberosum Species 0.000 description 17
- 229910052794 bromium Inorganic materials 0.000 description 17
- 229910052731 fluorine Inorganic materials 0.000 description 17
- 229910052739 hydrogen Inorganic materials 0.000 description 16
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 14
- 241000220223 Fragaria Species 0.000 description 14
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 14
- 240000003768 Solanum lycopersicum Species 0.000 description 12
- 125000004093 cyano group Chemical group *C#N 0.000 description 12
- 208000008313 Contusions Diseases 0.000 description 11
- 239000004480 active ingredient Substances 0.000 description 11
- 229910052801 chlorine Inorganic materials 0.000 description 11
- -1 tyl Chemical group 0.000 description 11
- 235000002595 Solanum tuberosum Nutrition 0.000 description 10
- 239000002363 auxin Substances 0.000 description 10
- 229910052740 iodine Inorganic materials 0.000 description 10
- 150000002500 ions Chemical class 0.000 description 10
- 239000003995 emulsifying agent Substances 0.000 description 9
- 239000004615 ingredient Substances 0.000 description 9
- 235000012015 potatoes Nutrition 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 8
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 239000011550 stock solution Substances 0.000 description 8
- 235000000346 sugar Nutrition 0.000 description 8
- 241000227653 Lycopersicon Species 0.000 description 7
- 238000007865 diluting Methods 0.000 description 7
- 125000001188 haloalkyl group Chemical group 0.000 description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
- PVNIIMVLHYAWGP-UHFFFAOYSA-N nicotinic acid Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 7
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 7
- 235000021012 strawberries Nutrition 0.000 description 7
- 235000013311 vegetables Nutrition 0.000 description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000004062 cytokinin Substances 0.000 description 6
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 6
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 239000012153 distilled water Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 5
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 5
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 5
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 5
- 239000002689 soil Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 125000006274 (C1-C3)alkoxy group Chemical group 0.000 description 4
- 125000004493 2-methylbut-1-yl group Chemical group CC(C*)CC 0.000 description 4
- CDAISMWEOUEBRE-LKPKBOIGSA-N D-chiro-Inositol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@H](O)[C@@H](O)[C@@H]1O CDAISMWEOUEBRE-LKPKBOIGSA-N 0.000 description 4
- QANMHLXAZMSUEX-UHFFFAOYSA-N Kinetin Chemical compound N=1C=NC=2N=CNC=2C=1NCC1=CC=CO1 QANMHLXAZMSUEX-UHFFFAOYSA-N 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- CDAISMWEOUEBRE-UHFFFAOYSA-N inositol Chemical compound OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- 230000000717 retained Effects 0.000 description 4
- 230000002195 synergetic Effects 0.000 description 4
- GWEHVDNNLFDJLR-UHFFFAOYSA-N 1,3-diphenylurea Chemical compound C=1C=CC=CC=1NC(=O)NC1=CC=CC=C1 GWEHVDNNLFDJLR-UHFFFAOYSA-N 0.000 description 3
- INAPMGSXUVUWAF-XCMZKKERSA-N 1D-myo-inositol 6-phosphate Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](OP(O)(O)=O)[C@H](O)[C@@H]1O INAPMGSXUVUWAF-XCMZKKERSA-N 0.000 description 3
- 125000005917 3-methylpentyl group Chemical group 0.000 description 3
- CDAISMWEOUEBRE-SHFUYGGZSA-N L-chiro-Inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@H]1O CDAISMWEOUEBRE-SHFUYGGZSA-N 0.000 description 3
- 241000218922 Magnoliophyta Species 0.000 description 3
- NWBJYWHLCVSVIJ-UHFFFAOYSA-N N-benzyladenine Chemical compound N=1C=NC=2NC=NC=2C=1NCC1=CC=CC=C1 NWBJYWHLCVSVIJ-UHFFFAOYSA-N 0.000 description 3
- 229910003204 NH2 Inorganic materials 0.000 description 3
- HFCYZXMHUIHAQI-UHFFFAOYSA-N Thidiazuron Chemical compound C=1C=CC=CC=1NC(=O)NC1=CN=NS1 HFCYZXMHUIHAQI-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 230000032823 cell division Effects 0.000 description 3
- 239000003630 growth substance Substances 0.000 description 3
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 description 3
- 235000021073 macronutrients Nutrition 0.000 description 3
- 239000011785 micronutrient Substances 0.000 description 3
- 235000013369 micronutrients Nutrition 0.000 description 3
- 235000016709 nutrition Nutrition 0.000 description 3
- 230000035764 nutrition Effects 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 239000005648 plant growth regulator Substances 0.000 description 3
- 229920000136 polysorbate Polymers 0.000 description 3
- 125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- 235000013619 trace mineral Nutrition 0.000 description 3
- 125000006029 2-methyl-2-butenyl group Chemical group 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- 125000001494 2-propynyl group Chemical group [H]C#CC([H])([H])* 0.000 description 2
- 241001474374 Blennius Species 0.000 description 2
- CDAISMWEOUEBRE-JMVOWJSSSA-N Cis-Inositol Chemical compound O[C@@H]1[C@H](O)[C@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-JMVOWJSSSA-N 0.000 description 2
- CDAISMWEOUEBRE-NIPYSYMMSA-N Epi-Inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](O)[C@H]1O CDAISMWEOUEBRE-NIPYSYMMSA-N 0.000 description 2
- 235000016623 Fragaria vesca Nutrition 0.000 description 2
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 2
- 229960005436 Inositol nicotinate Drugs 0.000 description 2
- 229960001669 Kinetin Drugs 0.000 description 2
- 240000008415 Lactuca sativa Species 0.000 description 2
- 229940040452 Linolenate Drugs 0.000 description 2
- CDAISMWEOUEBRE-GNIYUCBRSA-N Muco-Inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)[C@H]1O CDAISMWEOUEBRE-GNIYUCBRSA-N 0.000 description 2
- CDAISMWEOUEBRE-DCLYFUHFSA-N Neo-Inositol Chemical compound O[C@H]1[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-DCLYFUHFSA-N 0.000 description 2
- FCSHMCFRCYZTRQ-UHFFFAOYSA-N Thiocarbanilide Chemical compound C=1C=CC=CC=1NC(=S)NC1=CC=CC=C1 FCSHMCFRCYZTRQ-UHFFFAOYSA-N 0.000 description 2
- 229940029983 VITAMINS Drugs 0.000 description 2
- 229940021016 Vitamin IV solution additives Drugs 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- CDAISMWEOUEBRE-OQYPVSDDSA-N allo-inositol Chemical compound O[C@H]1[C@@H](O)[C@@H](O)[C@@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-OQYPVSDDSA-N 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000004790 biotic stress Effects 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 150000004292 cyclic ethers Chemical group 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000004491 dispersible concentrate Substances 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000009313 farming Methods 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- JTEDVYBZBROSJT-UHFFFAOYSA-N indole-3-butyric acid Chemical compound C1=CC=C2C(CCCC(=O)O)=CNC2=C1 JTEDVYBZBROSJT-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000003050 macronutrient Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 125000001844 prenyl group Chemical group [H]C([*])([H])C([H])=C(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000004546 suspension concentrate Substances 0.000 description 2
- 150000003852 triazoles Chemical class 0.000 description 2
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 2
- 239000011782 vitamin Substances 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- 229930003231 vitamins Natural products 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- DTOSIQBPPRVQHS-UHFFFAOYSA-N α-Linolenic acid Chemical compound CCC=CCC=CCC=CCCCCCCCC(O)=O DTOSIQBPPRVQHS-UHFFFAOYSA-N 0.000 description 2
- NNCAWEWCFVZOGF-UHFFFAOYSA-N 1,1-dimethylpiperidin-1-ium Chemical compound C[N+]1(C)CCCCC1 NNCAWEWCFVZOGF-UHFFFAOYSA-N 0.000 description 1
- XFNJVKMNNVCYEK-UHFFFAOYSA-N 1-Naphthaleneacetamide Chemical compound C1=CC=C2C(CC(=O)N)=CC=CC2=C1 XFNJVKMNNVCYEK-UHFFFAOYSA-N 0.000 description 1
- PRPINYUDVPFIRX-UHFFFAOYSA-N 1-Naphthaleneacetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CC=CC2=C1 PRPINYUDVPFIRX-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical class CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- 239000005971 1-naphthylacetic acid Substances 0.000 description 1
- QOPBEBWGSGFROG-UHFFFAOYSA-N 2-(1H-indol-2-yl)acetic acid Chemical class C1=CC=C2NC(CC(=O)O)=CC2=C1 QOPBEBWGSGFROG-UHFFFAOYSA-N 0.000 description 1
- AFOVBPMGZPJPKX-UHFFFAOYSA-N 2-(2-methylnaphthalen-1-yl)acetamide Chemical compound C1=CC=CC2=C(CC(N)=O)C(C)=CC=C21 AFOVBPMGZPJPKX-UHFFFAOYSA-N 0.000 description 1
- GQHUFHPHBHEKSX-UHFFFAOYSA-N 2-(2-methylnaphthalen-1-yl)acetic acid Chemical compound C1=CC=CC2=C(CC(O)=O)C(C)=CC=C21 GQHUFHPHBHEKSX-UHFFFAOYSA-N 0.000 description 1
- 125000006022 2-methyl-2-propenyl group Chemical group 0.000 description 1
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- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 1
- 240000002791 Brassica napus Species 0.000 description 1
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- 102000004082 Calreticulin Human genes 0.000 description 1
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- 239000005974 Chlormequat Substances 0.000 description 1
- JUZXDNPBRPUIOR-UHFFFAOYSA-N Chlormequat Chemical compound C[N+](C)(C)CCCl JUZXDNPBRPUIOR-UHFFFAOYSA-N 0.000 description 1
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- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
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- 239000005864 Sulphur Substances 0.000 description 1
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- 239000005712 elicitor Substances 0.000 description 1
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- 125000004494 ethyl ester group Chemical group 0.000 description 1
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- 150000002191 fatty alcohols Chemical class 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
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- 239000001963 growth media Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 230000003054 hormonal Effects 0.000 description 1
- 239000004021 humic acid Substances 0.000 description 1
- 125000000717 hydrazino group Chemical group [H]N([*])N([H])[H] 0.000 description 1
- 125000005638 hydrazono group Chemical group 0.000 description 1
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 description 1
- 125000001867 hydroperoxy group Chemical group [*]OO[H] 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- SEOVTRFCIGRIMH-UHFFFAOYSA-M indole-3-acetate Chemical compound C1=CC=C2C(CC(=O)[O-])=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-M 0.000 description 1
- MFZCIDXOLLEMOO-UHFFFAOYSA-N inositol hexanicotinate Chemical compound C=1C=CN=CC=1C(=O)OC(C(C(OC(=O)C=1C=NC=CC=1)C(OC(=O)C=1C=NC=CC=1)C1OC(=O)C=2C=NC=CC=2)OC(=O)C=2C=NC=CC=2)C1OC(=O)C1=CC=CN=C1 MFZCIDXOLLEMOO-UHFFFAOYSA-N 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
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- 230000000670 limiting Effects 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
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- 238000000034 method Methods 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000004535 oil miscible liquid Substances 0.000 description 1
- 229940006093 opthalmologic coloring agents Diagnostic Drugs 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- LUBJCRLGQSPQNN-UHFFFAOYSA-N phenylurea Chemical compound NC(=O)NC1=CC=CC=C1 LUBJCRLGQSPQNN-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 230000035479 physiological effects, processes and functions Effects 0.000 description 1
- 235000017807 phytochemicals Nutrition 0.000 description 1
- 239000003375 plant hormone Substances 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 229930000223 plant secondary metabolites Natural products 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920001521 polyalkylene glycol ether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N precursor Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N propionic acid Chemical compound CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 230000002829 reduced Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004550 soluble concentrate Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 108010050014 systemin Proteins 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- UZKQTCBAMSWPJD-FARCUNLSSA-N trans-zeatin Chemical compound OCC(/C)=C/CNC1=NC=NC2=C1N=CN2 UZKQTCBAMSWPJD-FARCUNLSSA-N 0.000 description 1
- VLCLHFYFMCKBRP-UHFFFAOYSA-N tricalcium;diborate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]B([O-])[O-].[O-]B([O-])[O-] VLCLHFYFMCKBRP-UHFFFAOYSA-N 0.000 description 1
- RVKCCVTVZORVGD-UHFFFAOYSA-N trinexapac-ethyl Chemical group O=C1CC(C(=O)OCC)CC(=O)C1=C(O)C1CC1 RVKCCVTVZORVGD-UHFFFAOYSA-N 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
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- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/06—Oxygen or sulfur directly attached to a cycloaliphatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/06—Unsaturated carboxylic acids or thio analogues thereof; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/06—Aluminium; Calcium; Magnesium; Compounds thereof
Abstract
The present invention relates to an agrochemical combination of (i) linolenic acid, a linolenic acid derivative, a linolenic acid breakdown component, or an ester thereof; and (ii) inositol, an inositol derivative or an inositol breakdown component. The invention also relates to agrochemical compositions comprising the same and the use such a combination for improving plant physiology. tions comprising the same and the use such a combination for improving plant physiology.
Description
(12) Granted patent specificaon (19) NZ (11) 755841 (13) B2
(47) Publicaon date: 2021.12.24
(54) AGROCHEMICAL COMBINATION
(51) Internaonal Patent Classificaon(s):
A01N 31/06 A01N 37/06 A01P 21/00
(22) Filing date: (73) Owner(s):
2018.03.12 CROP INTELLECT LTD
(23) Complete specificaon filing date: (74) Contact:
2018.03.12 DAVIES COLLISON CAVE PTY LTD
(30) Internaonal Priority Data: (72) Inventor(s):
GB 1703877.9 2017.03.10 PAPADOPOULOS, Apostolos
(86) aonal Applicaon No.:
(87) Internaonal Publicaon number:
8/162934
(57) Abstract:
The present invenon relates to an agrochemical combinaon of (i) linolenic acid, a nic
acid derivave, a linolenic acid breakdown component, or an ester thereof; and (ii) inositol, an
inositol derivave or an inositol breakdown component. The invenon also s to agrochemical
ions comprising the same and the use such a combinaon for improving plant physiology.
NZ 755841 B2
Agrochemical Combination
The present invention relates to agrochemical combinations of ingredients suitable for
use in agrochemical compositions and the use of the same to improve plant physiology.
Background to the Invention
Improving yield and quality in a sustainable manner has always been the challenge in
crop farming. Crop nutrition has been key to improving crop productivity once crop
protection is taken care of and it is highly supported by nutrition. Major nutrients such
as nitrogen are core to sing plant growth but increasing such nts can bring
about negative effects. Fast cell division and ion cause a weak plant which is
more vulnerable to biotic and abiotic stresses. This results in poor plant performance
and more need for inputs to reduce such negative effects. Complex interactions exist
between elements which although are to an extent understood it is not easy to manage
in a field situation. Typically, one element will block another or its availability will
cause toxicity to the plant.
Plant characteristics associated with yield and quality are weight, size, uniformity,
shelf-life, colour, sugar etc. These are highly affected by crop nutrition. Many
2O researchers have focused on life as a major requirement in the ry
particularly of able produce such as leafy .
Over the years, researchers have discovered ways to improve the application of
fertilisers to plants, e.g. using more available forms, improved uptake by sing the
residual time in the soil or on plant surface, increasing the penetration of wax layers
and formation of complexes to retain availability when soil applied. Furthermore,
phytochemicals such as auxins, cytokinins and ary metabolites have been used
to control plant growth or trigger responses of the immune system to increase resilience
to biotic stresses. Although benefits have been demonstrated using these, synergies are
very rare. Combining ients usually results in no effect or no extra benefits most
likely due to the action of the plant.
The most desirable quality teristic is the reduction of water loss which is a
measure that reflects improvements in cell structural stability, cell wall strength,
improved cell division and dry matter. Other characteristics include increase in fresh
weight and sugars, reduced rotting and improved colour.
Improving such teristics of the plant physiology is the object of the ion
through an agrochemical combination.
Description of the Invention
The present invention relates to an agrochemical combination of ingredients for use in
an agrochemical composition, and the use of such a combination to improve plant
1O physiology, to improve crop yields, and/or to improve crop quality characteristics.
In a first aspect, the invention provides a combination of:
(i) linolenic acid, a linolenic acid derivative, a nic acid breakdown
component, or an ester thereof; and
(ii) inositol, an ol derivative or an inositol breakdown component.
Component (i) is a linolenic acid, a linolenic acid derivative, a linolenic acid breakdown
component, or an ester thereof.
2O Linolenic acid is a type of fatty acid. It can refer to either of two catrienoic acids,
i.e. with an 18 carbon chain and three double bonds which are found in the cis
configuration, or a mixture of the two. The two forms of nic acid are o—linolenic
acid and or y-linolenic acid.
o—linolenic acid is ented by the chemical structure:
HOJJ\/\/\/\/\/\7\/\/\\ \
y-linolenic acid is represented by the chemical structure:
HOJJ\/\/\7\/\/\/\/\/\\ /
Component (i) may also be a linolenic acid derivative or ester thereof.
Linolenic acid and its derivatives can be represented by Formula 1.
In one embodiment, component (i) is a compound of Formula 1:
a 1:
RX 0 ‘~ CH2R17
wherein:
R116 are independently selected from H, F, Br, Cl, I, cyano, N02, C1-C3 alkyl, CH2OH,
CH20CH3, C1-C3 alkoxy, C1-C3 haloalkyl, -NR18R19, -C(=O)R19, CH2COOR19, or OR19;
R17 is independently selected from H, F, Br, Cl, I, cyano, N02, and -NH2;
R18 and R19 are independently selected from H and C1-C3 alkyl;
Rx is independently selected from H, methyl, ethyl, propyl, n-butyl, tyl, sec-butyl,
t-butyl, n-pentyl, iso-pentyl, neo-pentyl, yl, 2-methylbutyl, benzyl, , hexyl,
3-methylpentyl, octyl, 2-ethylhexyl, nonyl, decyl, undecyl, dodecyl, allyl, propargyl, 2-
-2—propenyl, cishexenyl, neryl, linalyl, citronellyl, 2-methyl-2—butenyl, trans-
2O 3-hexenyl, 3-methyl-2—butenyl, B-phenylethyl, a—phenylethyl and furfuryl;
n is 0-2; and
each— is a single or double bond, provided that at least two; are double bonds.
In one embodiment, at least 12, at least 13, at least 14, at least 15, or at least 16 of R117
are H.
In one embodiment, R17 is H and at least 14 or at least 15 of R1-16 are H.
In one embodiment, all of R1.17 are H. For example, R1_17 and Rx may all be H.
In one embodiment, two; are double bonds.
In one embodiment, Rx is H, methyl, ethyl, propyl, n-butyl, iso-butyl, sec-butyl, t-butyl,
n-pentyl, iso-pentyl, neo-pentyl, t-pentyl, ylbutyl, or phenyl.
Component (i) may also be a linolenic acid breakdown component or derivatives
thereof. Linolenic acid breakdown components and derivatives thereof may be
represented by ae 2 to 5:
Formula 2:
0 R2 R4 R5 R8 R10 OOH R14 R16
RX 0 CH2R17
Formula 3:
Formula 5
wherein:
R116 are independently ed from H, F, Br, Cl, 1, cyano, N02, C1-C3 alkyl, CH2OH,
CH20CH3, C1-C3 alkoxy, C1-C3 haloalkyl, -NR18R19, -C(=O)R19, CH2COOR19, or OR19;
R17 is ndently selected from H, F, Br, Cl, 1, cyano, N02, and -NH2;
R18 and R19 are independently selected from H and C1-C3 alkyl;
Rx is selected from H, methyl, ethyl, propyl, n-butyl, iso-butyl, sec-butyl, t-butyl, n-
pentyl, iso-pentyl, neo-pentyl, t-pentyl, 2-methylbutyl, benzyl, phenyl, hexyl, 3-
methylpentyl, octyl, lhexyl, nonyl, decyl, undecyl, dodecyl, allyl, propargyl, 2-
methyl-2—propenyl, cishexenyl, neryl, linalyl, citronellyl, 2-methyl-2—butenyl, trans-
3-hexenyl, 3-methyl-2—butenyl, B-phenylethyl, a—phenylethyl and furfuryl;
n n is 0-2; and
wherein ; may be a single or double bond.
In one embodiment, component (i) is a compound of a 6 or formula 7:
Formula 6
RX 0 CH2R17
Formula 7
RX 0 CH2R17
wherein R1-17 and RX are as defined previously.
With respect to all of Formulae 1 to 7, R1'16 may be independently selected from H, F,
Br, Cl, I, cyano, N02, OH, C1-C3 alkyl, CH2OH, or CH2OCH3. For example, R1-16 may be
independently selected from H, F, Br, Cl, I, or OH.
With t to all of Formulae 1 to 7, R17 may be H, F, Br, Cl, I, or NH2. For example
1O R17 is H.
In some embodiments, R116 are independently selected from H, F, Br, Cl, I, cyano, N02,
C1-C3 alkyl, -NR18R19 or OR19; R18 and R19 are
, C1-C3 alkoxy, C1-C3 haloalkyl,
independently selected from H and C1-C3 alkyl; andR17 is selected from H, F, Br, Cl, I,
cyano, N02, C1-C3 alkyl, C1-C3 alkoxy, C1-C3 haloalkyl, -NR18R19 or OR19.
In some embodiments, R116 are ndently selected from H, F, Br, Cl, I, cyano, N02,
-NR18R19 or OR19; R18 and R19 are independently selected from H and C1-C3 alkyl; and R17
2O is selected from H, F, Br, Cl, I, cyano, N02, -NR18R19 or OR19.
In some ments, R116 are independently selected from H, F, Br, C1 or I; and R17 is
selected from H, F, Br, C1 or I.
In some embodiments, R1'16 are H; andR17 is H.
In some embodiments, RX is selected from H, methyl, ethyl, propyl, l, iso-butyl,
sec-butyl, t-butyl, n-pentyl, iso-pentyl, neo-pentyl, t-pentyl, 2-methylbutyl, benzyl,
phenyl, hexyl or 3-methylpentyl.
In some embodiments, RX is selected from H, , ethyl, propyl, n-butyl, iso-butyl,
sec-butyl, t-butyl, n-pentyl, iso-pentyl, neo-pentyl, yl or 2-methylbutyl.
In some embodiments, RX is selected from H, methyl, ethyl, propyl, n-butyl, iso-butyl,
sec-butyl or t-butyl.
In some embodiments, RX is selected from H, , ethyl or propyl.
In one embodiment, RX is selected from H, methyl or ethyl.
In one embodiment, RX is H or methyl.
1O In one embodiment, R1'16 are independently selected from H, F, Br, C1 or I; R17 is
selected from H, F, Br, C1 or I; and at least 15 of R1-17 are H.
In one embodiment, component (i) is o—linolenic acid:
\/\/\/\/\7\/\/\\ \ .
or v-linolenic acid:
HOW\ /
In one embodiment, component (i) is linolenic acid or an ester thereof such as a C1_4
2O alkyl ester thereof, e.g. an ethyl ester thereof.
Component (i) may be applied to a plant dissolved in a solvent. A suitable solvent is
water.
The concentration of component (i) may be from about 0.1 mg/litre (mg/l) to about
500 mg/l, from about 0.3 mg/l to about 300 mg/l, from about 0.4 mg/l to about 125
mg/l, from about 0.5 mg/l to about 100 mg/l, from about 0.6 mg/l to about 75 mg/l,
from about 0.7 mg/l to about 50 mg/l, or from about 0.8 mg/l to about 35 mg/l. For
e, the concentration of component (i) may be from about 1 mg/l to about 33
mg/l . For example, the concentration of component (i) may be about 1 mg/1, about 4.5
mg/l, about 4.9 mg/l, about 30 mg/l, or about 33 mg/l.
atively, the concentration of component (i) may be from about 10 mg/litre (mg/l)
to about 500 mg/l, from about 50 to about 300 mg/l, from about 75 to about 125 mg/l,
or from about 90 to about 110 mg/l. For example, the concentration of component (i)
may be about 100 mg/l.
When d to the plant, component (i) may be applied in amount from about 0.01
g/ha to about 10.0 g/ha, from about 0.02 g/ha to about 9.0 g/ha, from about 0.03 g/ha
to about 8.0 g/ha, from about 0.05 g/ha to about 6.0 g/ha, or from about 0.1 g/ha to
about 4.5 g/ha.
Component (ii) is inositol, an inositol derivative or an inositol breakdown component.
Innositol is also known as exane-1,2,3,4,5,6-hexol and has a chemical ure:
HO OH
HO OH
OH
Inositol includes but is not limited to the following isomers: myo-, scyllo-, muco-,
chiro-, neo-, allo-, epi, and ositol. Chiro-inositol may be one of two forms: D-
chiro-inositol or L-chiro-inositol.
Component (ii) may also be an inositol derivative or an inositol breakdown component.
Inositol derivatives and inositol breakdown components may be represented by
Formula 8. In one embodiment, component (ii) is a compound represented by formula
Formula 8
Q50 OQ1
Q40 OQz
Q may be selected from OQ6 or H, halogen, cyano, N02, C1-C3 alkyl, C1-C3 haloalkyl,
and amino; and
Q1 — Q6 are independently selected from H, -P03H2, , C1-C3 alkyl, formula 9:
Formula 9
two or more of Q1 and Q2, Q3 and Q4, Q5 and Q6 may together form a group
represented by formula 10: and
Formula 10
HO O
‘(F‘r‘ .
2O wherein when one or more of Q1-Q6 is C1-C3 alkyl, the alkyl group(s) may also join to the
carbon atom of the inositol ring structure thereby forming a cyclic ether group.
In one embodiment, Q is OQ6, wherein Q6 is as defined herein.
In one embodiment, Q3, Q4, and Q5 are H, and Q, Q, and Q2 are as defined herein.
In one embodiment, Q2, Q3, Q4, and Q5 are H, and Q, and Q are as defined herein.
In one embodiment, Ql-Q5 are H, and Q is as defined herein.
In one embodiment, Ql-Q5 are H, and Q is OQ6 or H, halogen, cyano, N02, C1-C3 alkyl,
C1-C3 haloalkyl, and amino. For example, Q may be OQ6. Alternatively, Q may be H,
halogen or amino.
As used herein, the term inositol is intended to mean any stereoisomer of inositol. For
1O example, myo-inositol, D-chiro-inositol, L-chiro-inositol, muco- inositol, scyllo-
inositol, neo-inositol, allo-inositol, epi-inositol, cis-inositol or mixtures thereof.
In one embodiment, ent (ii) is selected from ol, an inositol phosphate, an
inositol sulphate, an inositol nicotinate/niacinate, or a cyclic ether inositol.
In some embodiments, component (ii) is selected from inositol, an inositol ate
or an ol te.
In one embodiment, component (ii) is inositol. For example, component (ii) may be
selected from myo-inositol, D-chiro-inositol, L-chiro-inositol, muco- inositol, scyllo-
2O inositol, neo-inositol, allo-inositol, epi-inositol and cis-inositol.
In some embodiments, component (ii) is selected from myo-inositol and D-chiro-
inositol.
Component (ii) may be applied to a plant dissolved in a solvent. A le solvent is
water.
The concentration of component (ii) may be from about 10 mg/litre (mg/l) to about
500 mg/l, from about 50 to about 300 mg/l, from about 100 mg/l to about 150 mg/l.
For example, the concentration of component (ii) may be about 100 mg/l or 150 mg/l.
When applied to the plant, component (ii) may be d in amount from about 1 to
about 80g/hectare (ha), from about 5 to about 50 g/ha, from about 10 g/ha to about 20
g/ha, or from about 5 to about 15 g/ha. For example, component (ii) may be applied in
an amount of about 10 g/ha or about 15 g/ha.
In one embodiment, the combination of (i) and (ii) further ses a source of
calcium.
The source of calcium may be selected from but not limited to the group ting of
calcium ammonium e, calcium nitrate, calcium hydroxide, calcium
cyanamide, calcium acetate, calcium acetylsalicylate, calcium borate, calcium
borogluconate, calcium carbonate, m chloride, calcium citrate, calcium ferrous
e, calcium glycerophosphate, calcium lactate, calcium oxide, calcium
pantothenate, calcium propionate, calcium saccharate, calcium sulphate, calcium
phosphate and calcium tartrate.
The source of calcium may be applied to a plant dissolved in a solvent. A suitable
solvent is water.
The concentration of the calcium source may be from about 0.025 wt% to about 20
wt%, from about 0.04 wt% to about 1 wt%, from about 0.05 wt% to about 0.25 wt%, or
2O from about 0.1 wt% to about 0.2 wt%
When applied to the plant, the source of calcium may be d in amount from about
1g to about 200kg/hectare (ha), from about 200g to about 1kg/ha, from about 400 to
about 800g/ha, or about 600g/ha.
In some embodiments, the combination of (i) and (ii) r comprises an active
ingredient ed from the group consisting of , systemin, oligouronides,
chitosan, carbanilide, calreticulin, flagellin and B-glucan-containing elicitors.
The combinations/compositions of the invention may further comprise other
conventional agrochemical ingredients such agrochemical nts (such as macro and
micro nutrients), and agro-chemically acceptable excipients. Suitable macro nutrients
include but are not limited to sources of nitrogen, phosphorous, potassium, and
sulphur. Suitable micro nutrients include but are not limited to sources of magnesium
and iron. Others include boron, cobalt, chromium, , fluoride, iodine, ese,
molybdenum, selenium, zinc etc.
Accordingly, the combinations/compositions of the invention may r comprise
one or more agrochemically able excipients. es of such components
include water, amino acids, vitamins, seaweed and other plants extracts, weak acids,
plant oils, essential oils, metabolic stimulating agents, emulsifiers, thickeners,
colouring agents, suspension agents, dispersion , carriers or excipients and
wetting agents.
As used herein, the expression "weak acid" refers to a weak organic acid such as acetic
acid, citric acid, humic acid, fulvic acid or propanoic acid; preferably the weak acid is
citric acid.
In a further , the invention provides an agrochemical composition comprising a
combination of (i) and (ii) as defined herein, and optionally one or more agrochemical
ents.
In this case, if required an emulsifier may be employed in the formulation. An
2O emulsifier may be employed to improve the dissolvability of component (i) in the
formulation. le emulsifiers for use in the compositions of the present invention
include any known agriculturally acceptable emulsifier. In particular, the emulsifier
may comprise a surfactant such as: fatty alcohol polyethylene glykol ether, typically
ryl sulphonates, ethoxylated alcohols, polyalkoxylated butyl ethers, calcium alkyl
e sulphonates, polyalkylene glycol ethers and butyl polyalkylene oxide block
copolymers as are known in the art. Nonyl phenol emulsifiers such as Triton N57(TM)
are particular examples of emulsifiers, which may be used in the compositions of the
invention, as are polyoxyethylene sorbitan esters such as polyoxyethylene sorbitan
monolaurate (sold by ICI under the trade name "Tween(TM)"). In some instances,
natural organic fiers may be preferred, particularly for organic g
applications. Coconut oils such as coconut diethanolamide is an example of such an
compound. Palm oil products such as lauryl stearate may also be used.
Suitable emulsifiers include commercially available sorbitol products such as Tween®
2o, 40, and 60.
The combination/compositions may further comprise a growth regulator.
In one embodiment, the growth regulator, or plant growth regulator, is chosen from the
group of plant hormones, or chemical compounds with analogous activity. Suitable
examples of such compounds are auxins, cytokines, lins, ne precursors
(like ethephon), or abscisic acid. In another embodiment, the growth regulator, or plant
growth regulator, is a growth inhibitor, like for example chlormequat or mepiquat
de, certain triazole or triazole like compounds, or prohexadione, daminozide,
trinexapac ethyl type compounds, or ethylene tors.
Suitable auxins include natural or synthetic chemicals that behave like the naturally
occurring auxins produced by plant enzyme systems, and the term "auxin" and "auxins"
as used herein refers to such compounds in natural and synthetic form. Indoleacetic
acids, indolbutyric acid (3-BA); naphthaleneacetamide; 2 methyl- 1-
naphthaleneacetic acid and 2—methyl-l-naphthylacetamide have hormonal activity and
may be substituted for the naturally ing auxins. It may be useful to have metal
ions present with the auxins, such as for example zinc or manganese. In preferred
embodiments, the auxin employed is selected from the group consisting of 3-
indolebutyric acid, 3-indoleacetic acid, 1-naphthylacetic acid, lebutyric acid, and
2O salts and esters thereof. Preferably, the metal ions required for a good activity are
supplied together with the auxin.
Suitable cytokinins are a class of plant regulation substances (phytohormones) that
promote cell division, or cytokinesis, in plant roots and shoots. There are two types of
cytokinins: adenine-type cytokinins represented by kinetin, zeatin, and 6-
benzylaminopurine (also referred to as BAP, 6-BAP, or 6-benzyladenine), and
urea-type cytokinins like diphenylurea (DPU), diphenylthiourea (DPTU) and
thidiazuron (TDZ). In red ments the cytokinin is selected from the group
consisting of kinetin etic or derived from seaweed), 6-BAP, l-(2—chloropyridin
yl)phenylurea (CPPU), and TDZ.
The formulations according to the invention can be d either as such or after prior
on with water, or other diluents, i.e. for example, as emulsions, suspensions,
solutions, or aerosols.
In a particular preferred embodiment, the formulation is in the form of a concentrate
which is diluted with solvent, e.g. water, prior to the actual application. In another
embodiment, the formulation is in the form of a diluted formulation containing
additional solvent, e.g. water, but retaining the same ratio/proportion of active
ingredients found in the trate.
The weight ratio of component (i) to component (ii) may generally be from about 2 : 1
to about 1 : 1200, from about 1 : 1 to about 1 : 160, from about 1 : 2 to about 1 : 140, or
from about 1 : 3 to about 1 : 120.
The weight ratio of component (i) to the calcium source may generally be from about
1 : 4,000 to about 1 : 550,000, from about 1 : 5,000 to about 1: 400,000, from about 1 :
6,000 to about 1 : 300,000, or from about 1 : 6,500 to about 1 : 240,000.
The weight ratio of component (ii) to the calcium source may generally be from about 1
2O : 500 to about 1 : 4,000, or from about 1 : 1,000 to about 1 : 3,000, or from about 1 :
1,500 to about 1 : 2,500. For example, the weight ratio of component (ii) to the calcium
source may be about 1 : 2,000.
In a further , the ion provides the use of a combination of the present
invention or an agrochemical composition of the present invention for improving plant
physiology. The combination of components (i) and (ii) of the present invention has
been found to have surprising efficacy for improving plant physiology. In particular,
the present invention has been shown to be useful in improving plant physiology in
vegetable, fruit and flowering plants. For example, the t ion has been
shown to be useful in improving plant physiology in lettuce, tomato, strawberry and
potato plants.
In a further , the invention provides the use of a combination of the present
invention or an agrochemical composition of the present invention for improving crop
yield and/or crop characteristics. The combination of components (i) and (ii) of the
t ion has been found to have surprising efficacy for improving crop yield
and/or crop characteristics. In particular, the present invention has been shown to be
useful in improving crop teristics in vegetable, fruit and flowering plants. For
e, the present invention has been shown to be useful in improving crop
characteristics in lettuce, tomato, strawberry and potato plants.
In a further aspect, the invention provides the use of a combination of the present
invention or an agrochemical composition of the present invention for reducing water
1O loss in crops. The ation of components (i) and (ii) of the present invention has
been found to have surprising efficacy for reducing water loss in crops. In particular,
the present invention has been shown to be useful in reducing water loss in vegetable,
fruit and flowering plants. For example, the present invention has been shown to be
useful in ng water loss in crops harvested from leaf vegetable plants and fruit
plants, e.g. from reducing water loss in lettuce and reducing water loss in tomatoes.
In a further aspect, the invention provides the use of a ation of the present
invention or an agrochemical ition of the present invention for increasing sugar
content in crops. The combination of components (i) and (ii) of the t invention
2O has been found to have surprising efficacy for improving sugar content in crops. In
particular, the invention has been found useful for increasing sugar content in fruit
crops. For e, the present invention has been shown to be useful in sing
sugar content in tomatoes.
In a further aspect, the invention provides the use of a combination of the present
invention or an agrochemical composition of the present invention for increasing the
proportion of dried matter in crops. The ation of components (i) and (ii) of the
present ion has been found to have surprising efficacy for increasing dried matter
in crops. In particular, the present invention has been shown to be useful for
increasing the proportion of dried matter in fruit and salad crops. For example, the
present invention has been shown to be useful in increasing dried matter in tomatoes.
In a further aspect, the invention provides the use of a combination of the present
invention or an agrochemical composition of the present invention for reducing rotting
in crops. The combination of components (i) and (ii) of the present invention has been
found to have sing efficacy for reducing rotting in crops. In ular, the present
invention has been shown to be useful in ng g in fruit, e.g. soft fruit such as
strawberries.
In a further aspect, the invention provides the use of a combination of the present
invention or an agrochemical composition of the present invention for reducing
bruising in crops. The combination of components (i) and (ii) of the present invention
has been found to have surprising efficacy for reducing bruising in crops. In particular,
1O the present ion has been shown to be useful in reducing bruising in root
vegetables, such as tubers, e.g. potatoes.
According to one aspect, the invention provides the use of a combination as defined
herein or an agrochemical composition as defined herein for:
(a) improving shelf life of a crop;
(b) improving stress tolerance of a crop;
(c) increasing fresh and dry matter content of a crop;
(d) improving fruit conformity; and/or
2O (e) increasing tolerance of a crop to disease.
The itions of the invention may further comprise other conventional
agrochemical ingredients and agrochemical excipients. Suitable agrochemical
ingredients and excipients include but are not limited to macro-nutrients, micro-
nutrients (also called phyto-nutrients), vitamins, amino acids, formulation aids
(adjuvants), complex agents, plant growth regulators and plant protection actives.
Accordingly, the compositions of the invention may further comprise one or more
agrochemical excipients.
Component (i) and component (ii) may be applied to plants simultaneously or
sequentially. For example, when the components are applied simultaneously the
components can be d as part of an emical composition sing
ent (i) and component (ii). Alternatively, when the components are applied
sequentially, the components are applied individually and the ation of the
invention is formed in situ.
Each component, either combined or individually, or the combination of components
described herein (including as agrochemical compositions) may be applied to , in
particular crop plants, in any conventional manner, e.g. by soil, water, growth medium,
seed treatment, gel, fumigation or foliar application. In some embodiments, foliar
application is preferred. The components/combinations of the invention may be
d to root systems, stems, seeds, grains, tubers, flowers, fruit, etc. as required.
Examples of means of application include spraying, e.g. by means of an electrostatic or
other conventional sprayer, or drip irrigation methods or fertigation systems, which
involve application directly to the soil, so as to allow ium and/or iron uptake
through the roots.
The components/combinations/compositions of the ion may be adapted for the
means of ation, e.g. prepared in a form suited to the required means of
ation. These adaptations may take the form of liquid or solid concentrates, which
require dilution before ation. The components/combinations/compositions may
be formed into, for e, water dispersible granules, slow or fast release es,
2O soluble concentrates, oil miscible liquids, ultra low volume liquids, emulsifiable
concentrates, dispersible concentrates, oil in water, and water in oil emulsions, micro-
ons, suspension concentrates, aerosols, capsule suspensions and seed treatment
formulations.
The components/combinations/compositions of the present invention may be prepared
using any conventional techniques and methods; for example preparing granules,
dispersible concentrates, and suspension concentrates.
The invention also relates to a formulation for administration to plants or to the
environment of plants, the formulation comprising a composition according to the
invention and a medium in which the composition may be dispersed or dissolved.
The combinations and compositions of the invention are suitable for use on most crops,
but in particular can be used for the treatment of greenhouse crops, vegetables, and
fruit crops. For example, the combinations and compositions of the invention may be
used on but not limited to cereals, oil seed rape, potatoes, sugar beet, vegetable crops,
leafy vegetables (such as lettuce), fruits (such as tomatoes and strawberries), cucurbits
and grassland.
The amount of composition or formulation applied in any particular situation will vary
depending upon a number or factors such as the crop species, the g system and
practice at the region, season, soil and other inputs. Applications timing and dosage are
important and dependent on plant growth and development stages.
As used herein, the term C1-C3 alkyl is ed to mean substituted or unsubstituted
hydrocarbon groups with a carbon chain length of between 1 and 3.
As used , the term C1-C3 haloalkyl is intended to mean hydrocarbon groups with a
carbon chain length of between 1 and 3, wherein at least one hydrogen atom has been
substituted for a halogen atom (e.g. F, Br, C1 or I).
As used herein, the term “substituted” means substituted with a substituent selected
from a halogen (F, Br, C1 or I), a hydroxy group, an alkoxy group, a nitro group, a cyano
2O group, an amino group, an azido group, an amidino group, a hydrazino group, a
hydrazono group, a carbonyl group, a carbamyl group, a thiol group, a carboxyl group
or a salt thereof and a combination thereof.
The invention will now be particularly described by way of the following non-limiting
es.
Examples
The ing abbreviations are used herein:
CaN m nitrate obtained from Sigma Aldrich
IN Inositol obtained from Sigma Aldrich
LA Linolenic acid obtained from Sigma Aldrich
Linolenate Ethyl linolenate ed from Sigma Aldrich
Mg/l means the same as mg/lt, i.e. milligrams per litre.
Each ation was diluted in distilled water.
The formulations were prepared by adding the individual components to water,
followed by mixing. The formulations were then further diluted in distilled water
(further information .
Each formulation was first prepared as a 2 litre stock solution. Each 2 litre stock
on was then applied per hectare (i.e. 2 litre/ha) having been diluted further with
distilled water to a total volume of 150 litres.
e 1 (Lettuce)
The formulations were d at 2lt/ha equivalent (diluted in 15olt of water) to cover
an area of 10,000m2. 16 plants per m2 receiving 15ml or 0.938ml per plant. A flat fan
nozzle at 1100 was used to spray the plant’s foliage.
The following treatments were tested on mechanically planted lettuce for uniformity.
2O Water loss (%) was measured as an indicator of shelf-life. The shelf-life of the lettuce
was measured by ng a harvested lettuce (cut in half) to dry at ambient
temperature for 72 hours. The weight of the lettuce was measured before and after
drying, and the weight loss calculated; this represents water loss. 10 replicates were
used for each treatment and the plants were under controlled ouse condition to
avoid external parameters affecting the results. Distilled water was used for all
treatments. Samples were collected 5 days after application.
The results are reported in Table 1 and Table 2.
The statistical significance is measured by ing the standard error of difference of
the means. If the difference between the means is higher than the LSD (least significant
difference) then the difference is statistically significant. In normalised datasets the
LSD is near the standard error of difference lied by 2. For the statistics in this
study Genstat was used to analyse the data statistically.
The concentrations below indicate the concentration of each component in the diluted
(150 litre) formulation. The tration of linolenic acid is the amount required to
apply a 100 nmol dose of linolenic acid per plant (based on 160,000 lettuce plants per
hectare).
Table 1:
Content (on Waterless Co)
InontotCtC none/1t
(LA)
Treatment 1.3 100mg/lt _
IN 30m lt
——_—
The results of the trial reported in Table 1 show that lettuce d with a combination
of linolenic acid and inositol ment 1.3) exhibited significantly lower water loss
during the period of the test compared to linolenic acid and inositol alone (treatments
1.2 and 1.1 respectively). In particular, using linolenic acid and inositol alone
(treatments 1.2 and 1.1 respectively) ed no statistically cant improvement
over control. In contrast, the combination of linolenic acid and ol (treatment 1.3)
exhibited a statistically significant improvement over the control and over either active
ingredient alone. The performance of the combination was therefore unexpected.
The concentrations below indicate the concentration of each component in the diluted
(150 litre) formulation. The tration of linolenic acid is the amount required to
2O apply a 100 nmol dose of linolenic acid per plant (based on 160,000 lettuce plants per
hectare). The concentration of CaN is a result of diluting a 20 wt% CaN stock solution
to 150 litres.
Table 2:
Cotent (at) Waterlooe Co)
4H2O (CaN)
————
LA 30m lt
Treatment 2.3 CaN . 17.7
——_—
Likewise, the results of the trial reported in Table 2 show that lettuce treated with a
combination of linolenic acid and inositol (in the presence of m nitrate)
(treatment 2.3) exhibited cantly lower water loss during the period of the test
compared to linolenic acid and inositol alone (in the presence of calcium nitrate)
(treatments 2.2 and 2.1 respectively). In particular, using linolenic acid and inositol
alone (in the presence of calcium nitrate) (treatments 2.2 and 2.1 respectively)
produced no statistically significant improvement over control (+). In st, the
combination of linolenic acid and inositol (in the presence of calcium e)
(treatment 2.3) exhibited a statistically significant improvement over the control (+)
and over either active ingredient alone. The performance of the ation was
therefore unexpected.
The formulations above were also tested on lettuce when applying at 11t/ha, 2lt/ha,
3lt/ha, 4lt/ha and 5lt/ha as a dose finding exercise. All doses ed similar results
with that of 2lt/ha providing the highest comparatively.
The ratio used (100mg/lt inositol and 30 mg/lt LA) was chosen after tests on lettuce
2O using inositol at 10mg/lt, 100mg/lt and lt and LA at 3.0 mg/lt, 30 mg/lt and
150 mg/lt showed that the synergistic ty was retained at all doses and all ratios,
with the highest results obtained when 100mg/lt inositol was combined with 30 mg/lt
LA. The other ations were also superior to the ingredients on their own.
Example 2 (Tomatoes)
Plants were sprayed three times, first at flowering, then when fruit size was 2-3mm and
again when fruit size was 20mm diameter. This was applied at 2lt/ha equivalent
diluted in 15olt of water to cover an area of 10,000m2. Measurements were taken from
the middle of the season so the fruits were not the first fruits produced.
The methodology for water loss analysis was the same as that for Example 1 above.
Sugar t was analysed using a refractometer using the sap.
Dry matter results were obtained in the following way. The freshly harvested tomatoes
were weighted, and then oven-dried at 45-50°C for 48 hours. The ried tomatoes
were then weighed. Dry matter percentage (%) is weight of is freshly ted
tomatoes/weight of oven-dried tomatoes X 100.
The results are reported in Table 3 and Table 4.
The concentrations below indicate the concentration of each component in the diluted
(150 litre) formulation. The concentration of nic acid is the amount required to
apply a 100 nmol dose of linolenic acid per plant (based on 4,500 tomato plants per
hectare). The concentration of CaN is a result of diluting a 20 wt% CaN stock on
to 150 litres.
Table 3:
ent Content (ai) Conc. Water loss Dry Matter
(%)* (%)
Control Water 100% 4.0 6.3
Treatment 3.1 Inositol (IN) 100mg/lt 4.0 6.2
Treatment 3.2 Linolenic Acid 0.84mg/lt 3.9 6.4
(LA)
Treatment 3.3 LA 3.7 6.9
LSD 0.168 0.4
The results of the trial reported in Table 3 show that tomatoes treated with a
combination of linolenic acid and inositol (treatment 3.3) exhibited significantly lower
water loss during the period of the test compared to linolenic acid and inositol alone
(treatments 3.2 and 3.1 respectively). In particular, using linolenic acid and inositol
alone (treatments 3.2 and 3.1 respectively) produced no statistically significant
improvement over control. In st, the combination of linolenic acid and inositol
(treatment 3.3) exhibited a tically significant ement over the control and
over either active ingredient alone. The performance of the combination was therefore
unexpected.
In addition, the results ed in Table 3 show that tomatoes treated with a
combination of linolenic acid and inositol (treatment 3.3) exhibited cantly
1O greater dry matter (%) compared to linolenic acid and inositol alone (treatments 3.2
and 3.1 respectively). In ular, using linolenic acid and ol alone (treatments
3.2 and 3.1 respectively) produced no statistically significant improvement over control.
In st, the combination of linolenic acid and inositol (treatment 3.3) exhibited a
statistically significant improvement over the control and over either active ingredient
alone. The performance of the combination was therefore unexpected.
The concentrations below indicate the concentration of each component in the diluted
(150 litre) formulation. The concentration of linolenic acid is the amount required to
apply a 100 nmol dose of linolenic acid per plant (based on 4,500 tomato plants per
2O hectare). The concentration of CaN is a result of diluting a 20 wt% CaN stock solution
to 150 litres.
Table 4:
Treatment Content (ai) Conc. Water loss Sugar
(%)*
contml (Jr) ca Nitrate
4H2O (CaN)
Treatment 4.1
Treatment 4.2
Treatment 43 -3.0 2.8
—————
Likewise, the s of the trial reported in Table 4 show that tomatoes treated with a
combination of linolenic acid and inositol (in the presence of calcium nitrate)
(treatment 4.3) exhibited significantly lower water loss during the period of the test
compared to linolenic acid and inositol alone (in the presence of calcium nitrate)
(treatments 4.2 and 4.1 respectively). In particular, using linolenic acid and inositol
alone (in the presence of calcium nitrate) produced no statistically cant
improvement over control (+). In contrast, the combination of linolenic acid and
inositol (in the presence of calcium nitrate) (treatment 4.3) exhibited a tically
significant improvement over the control (+) and over either active ingredient alone (in
the presence of calcium nitrate. The efficacy of the ation was therefore
unexpected.
The formulations above were also tested on tomato plants when applying at 11t/ha,
2lt/ha, 3lt/ha, 4lt/ha and 5lt/ha as a dose finding exercise. All doses produced similar
s with that of 2lt/ha providing the highest comparatively.
The ratio used (100mg/lt inositol and 2.99mg/lt LA) was chosen after tests on tomato
plants using ol at 10mg/lt, 100mg/lt and 500mg/lt and LA at g/lt,
2O 0.84mg/lt and 4.2mg/lt showed that the synergistic activity was retained at all doses
and all , with the highest results obtained when 100mg/lt ol was combined
with g/lt LA. The other combinations were also superior to the ingredients on
their own.
The formulations described above in Example 1 were also tested on tomato plants, and
similar results were observed.
Example 3 (Strawberries)
The experiment was setup in a farm in south Lincolnshire. Standard farming practice
was applied and the treatments were superimposed to that.
Appropriate replication and number of ements were decided to ensure
statistical conformity.
The strawberries grown hydroponically received 2lt/ha (in 1501t water/ha) of the
formulation applied by foliar ng 3 times at 12 days interval from flowering.
Experienced pickers collected the ripe berries for analysis on the same day of harvest.
The g test ran over 15 days with time lapse photography and calculating the
percentage coverage of fungal growth.
The concentrations below indicate the concentration of each component in the d
(150 litre) formulation. The concentration of linolenic acid is the amount required to
1O apply a 100 nmol dose of linolenic acid per plant (based on 26,000 strawberry plants
per hectare). The concentration of CaN is a result of diluting a 20 wt% CaN stock
solution to 150 litres.
The results are reported in Table 5 and Table 6.
Table 5:
Treatment Content (ai) Conc. Rot (%)
Control Water 100% 65
ent 5.1 Inositol (IN) lt 58
Treatment 5.2 nic Acid (LA) 4.83mg/lt 60
Treatment 5.3 IN 100mg/lt 23
LA 4.83mg/lt
LSD 9
The results of the trial reported in Table 5 show that strawberries treated with a
combination of nic acid and inositol (treatment 5.3) exhibited significantly lower
2O tendency to rot compared to erries treated with either linolenic acid and inositol
alone (treatments 5.2 and 5.1 respectively). In particular, using linolenic acid and
inositol alone (treatments 5.2 and 5.1 respectively) produced no statistically significant
improvement over control. In contrast, the combination of linolenic acid and inositol
(treatment 5.3) exhibited a statistically significant improvement over the control and
over either active ingredient alone. The performance of the combination was ore
unexpected.
The trations below indicate the concentration of each component in the diluted
(150 litre) formulation. The concentration of linolenic acid is the amount required to
apply a 100 nmol dose of linolenic acid per plant (based on 26,000 strawberry plants
per hectare). The concentration of CaN is a result of diluting a 20 wt% CaN stock
solution to 150 litres.
Table 6:
Treatment Content (ai)
Control (+) Ca e 4H2O
(CaN)
ent 6.1 CaN
Treatment 6.2 CaN
Treatment 6.3
Likewise, the results of the trial reported in Table 6 show that strawberries treated with
a combination of linolenic acid and inositol (in the presence of calcium nitrate)
(treatment 6.3) ted significantly lower tendency to rot compared to strawberries
treated with either linolenic acid or inositol alone (in the presence of m nitrate)
(treatments 6.2 and 6.1 respectively). In particular, using linolenic acid and inositol
alone (in the presence of calcium nitrate) produced no statistically significant
improvement over control (+). In contrast, the ation of linolenic acid and
inositol (in the ce of calcium nitrate) (treatments 6.2 and 6.1 tively)
exhibited a statistically significant improvement over the control (+) and over either
active ingredient alone. The performance of the combination was therefore
unexpected.
The formulations above were also tested on strawberry plants when applying at 11t/ha,
2lt/ha, 3lt/ha, 4lt/ha and 5lt/ha as a dose finding exercise. All doses ed similar
results with that of 2lt/ha providing the highest comparatively.
The ratio used (100mg/lt ol and 4.83mg/lt LA) was chosen after tests on
strawberry plants using inositol at 10mg/lt, 100mg/lt and lt and LA at
0.483mg/lt, 4.83mg/lt and 24.15mg/lt showed that the synergistic activity was retained
at all doses and all ratios, with the highest results obtained when 100mg/lt inositol was
combined with 4.83mg/lt LA. The other combinations were also superior to the
ingredients on their own.
The ations described above in Example 1 were also tested on strawberry plants,
and similar results were observed.
Example 4 (Potatoes)
Potatoes of the y Maris Piper were cultivated as standard farm practice in
Lincolnshire. Typical fertiliser and pesticide inputs were applied as blanket over all
treatments. The treatments were superimposed on top of the standard practice.
Bruising: Uniform potato tubers were d from 1.5m height. They were left for 10
days in a store at 22°C to promote bruising and assessed by cutting in half and scoring
the bruising with a scale from 1-10 (1 = no bruising, 10 = bruise with 2cm diameter).
The results are reported in Table 7 and Table 8.
The concentrations below indicate the concentration of each component in the diluted
(150 litre) ation. The concentration of linolenic acid is the amount required to
apply a 100 nmol dose of linolenic acid per plant (based on 24,000 potato plants per
e). The concentration of CaN is a result of ng a 20 wt% CaN stock solution
to 150 litres.
Table 7:
<ai> Bisingmu-m
Treatment 7.1 Inositol (IN) 100mg/lt _
WWW445mm
The results of the trial reported in Table 7 show that potatoes treated with a
combination of linolenic acid and inositol (treatment 7.3) ted significantly lower
tendency to bruise compared to potatoes treated with either linolenic acid or inositol
alone (treatments 7.2 and 7.1 respectively). In particular, using linolenic acid and
inositol alone (treatments 7.2 and 7.1 respectively) produced no tically significant
improvement over control. In contrast, the combination of linolenic acid and inositol
ment 7.3) eXhibited a statistically significant improvement over the control and
over either active ingredient alone. The performance of the combination was therefore
uneXpected.
The concentrations below indicate the concentration of each component in the diluted
(150 litre) formulation. The concentration of linolenic acid is the amount required to
apply a 100 nmol dose of linolenic acid per plant (based on 24,000 potato plants per
hectare). The concentration of CaN is a result of diluting a 20 wt% CaN stock solution
to 150 litres.
Table 8. Experiment on potatoes (Ca)
Treatment Content (ai) Bruising (1-10)
Control (+) Ca Nitrate 4H2O 7-5
(CaN)
ent 8.1 CaN 6.7
Treatment 8.2 CaN
Treatment 8.3
2O Likewise, the s of the trial reported in Table 8 show that potatoes treated with a
combination of linolenic acid and inositol (in the ce of calcium nitrate)
(treatment 8.3) exhibited significantly lower tendency to bruise compared to potatoes
treated with either linolenic acid or inositol alone (in the presence of calcium nitrate)
(treatments 8.2 and 8.1 tively). In particular, using inositol alone (in the
presence of calcium nitrate) (treatment 8.1) produced no statistically cant
improvement over control (+). In contrast, the ation of linolenic acid and
inositol (in the presence of calcium nitrate) (treatment 8.3) exhibited a statistically
significant improvement over the control (+) and over either active ingredient alone.
Furthermore, the magnitude of the improvement exhibited by the combination of
linolenic acid and inositol (in the presence of calcium nitrate) (treatment 8.3) with
respect to the improvement exhibited by inositol (in the presence of calcium nitrate)
(treatment 8.2) proves that there is an unexpected improvement with the combination
of ent 8.3.
The formulations above were also tested on potato plants when applying at 11t/ha,
2lt/ha, 3lt/ha, 4lt/ha and 5lt/ha as a dose finding exercise. All doses produced similar
results with that of 2lt/ha ing the highest comparatively.
The ratio used (100mg/lt inositol and 4.45mg/lt LA) was chosen after tests on potato
plants using ol at 10mg/lt, 100mg/lt and 500mg/lt and LA at 0.445mg/lt,
2O 4.45mg/lt and 22.25mg/lt showed that the synergistic activity was retained at all doses
and all ratios, with the highest results obtained when lt inositol was combined
with 4.45mg/lt LA. The other combinations were also superior to the ingredients on
their own.
The formulations described above in Example 1 were also tested on potato plants, and
similar results were observed.
Example 5
The following treatments were tested on ically planted lettuce for uniformity.
Water loss (%) was ed as an indicator of life. The shelf-life of the lettuce
was measured by allowing a harvested e (cut in half) to dry at ambient
temperature for 72 hours. The weight of the lettuce was measured before and after
drying, and the weight loss calculated; this represents water loss. 10 replicates were
used for each treatment and the plants were under controlled greenhouse condition to
avoid external parameters affecting the results. Distilled water was used for all
treatments. Samples were collected 5 days after ation.
The results are reported in Table 9.
The concentrations below indicate the concentration of each component in the diluted
(150 litre) ation. The concentration of linolenic acid is the amount required to
apply a 100 nmol dose of linolenic acid per plant (based on 16,000 lettuce plants per
hectare). The concentration of CaN is a result of diluting a 20 wt% CaN stock solution
to 150 litres.
Table 9: ments on lettuce
CaN 0.13 wt% 17.4
Inositol Phosphate 150mg/lt
Inositol Phosphate
nate
Inositol Phospahte
Linolenate
Throughout this specification and the claims that follow, unless the context requires
otherwise, the word "comprise", and variations such as "comprises" and "comprising",
will be understood to imply the inclusion of a stated r or step or group of integers
or steps but not the exclusion of any other integer or step or group of integers or steps.
The reference in this specification to any prior publication (or information derived from
it), or to any matter which is known, is not, and should not be taken as an
ledgment or admission or any form of suggestion that that prior publication (or
ation derived from it) or known matter forms part of the common general
knowledge in the field of endeavour to which this specification relates.
Claims (7)
1. An agrochemical combination comprising (i) α-linolenic acid and (ii) inositol.
2. The ation according to claim 1, wherein the combination further comprises a source of calcium.
3. The combination according to claim 2, wheraein the source of calcium is 10 selected from the group consisting of calcium ammonium nitrate, calcium nitrate, calcium hydroxide, calcium ide, calcium acetate, calcium acetylsalicylate, calcium , calcium borogluconate, calcium carbonate, calcium de, calcium citrate, m ferrous citrate, calcium glycerophosphate, calcium lactate, calcium oxide, calcium pantothenate, 15 calcium propionate, calcium saccharate, calcium sulphate, calcium phosphate and calcium tartrate.
4. An agrochemical composition comprising a combination as d in any one of claims 1 to 3.
5. Use of a combination as defined in any one of claims 1 to 3 or an emical composition as defined in claim 4 for improving plant physiology.
6. Use of a combination as defined in any one of claims 1 to 3 or an agrochemical 25 ition as defined in claim 4 for improving crop yield and/or crop quality characteristics.
7. Use of a combination as defined in any one of claims 1 to 3 or an emical composition as defined in claim 4 for: (a) improving shelf life of a crop; (b) improving stress tolerance of a crop; (c) increasing fresh and dry matter content of a crop; (d) improving fruit conformity; and/or 35 (e) increasing tolerance of a crop to disease.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1703877.9 | 2017-03-10 | ||
GB1703877.9A GB2560380B (en) | 2017-03-10 | 2017-03-10 | Agrochemical combination |
PCT/GB2018/050624 WO2018162934A1 (en) | 2017-03-10 | 2018-03-12 | Agrochemical combination |
Publications (2)
Publication Number | Publication Date |
---|---|
NZ755841A NZ755841A (en) | 2021-08-27 |
NZ755841B2 true NZ755841B2 (en) | 2021-11-30 |
Family
ID=
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