COMPLETE SPECIFICATION
JOINING METHOD OF CONCRETE STRUCTURE
I/We, Asahi te Works Co., Ltd., a body corporate organised under the laws of Japan of 12,
Tsukiji, Chuo-ku, Tokyo, 104-0045, JAPAN
hereby declare the invention, for which I/we pray that a patent may be granted to me/us, and the
method by which it is to be performed, to be particularly bed in and by the following statement:-
Total Fee Paid: NZ$250.00 – by Direct Debit (as per covering letter)
503629008_1/6858
ED at IPONZ on 25 September 2012
ED at IPONZ on 25 September 2012
Technical Problem
[0004}
In the method of pulling the rubber mounted on the
projecting portion for fitting provided on the end portion of
the concrete product by using the pulling means such as the
above—described ckle or the like and fitting it in the
recess portion of the adjoining concrete product or the method
of embedding the arrow—shaped portions of the band—shaped
rubber member having the arrow shapes on the both sides in the
groove portion for fitting provided in the concrete t,
the concrete products can be joined while the mance is
ensured in laying the te products, but there iseaproblem
that handling after laying is not possible.
In the method of lining by the concrete cast in place in
d construction, the adjoining concrete products are
y joined, thus there is a problem that unequal settling
or ground displacement at an earthquake after that cannot be
handled.
In addition, there is a problem that when a shift or a
crack occurs in the existing concrete structure as described
above,sincetheflexiblejointisextremelyexpensive,arepair
cost can be huge with the method of mounting the flexible joints
ED at IPONZ on 25 September 2012
ED at IPONZ on 25 September 2012
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earthquake, the on portion can follow it and deform to
ensure continuity and water tightness. That is, quake
resistance, continuity, and water tightness can be given
inexpensively and easily to a water l such as a sewage,
a passage and the like using a concrete structure having a
cylindrical or U—shaped cross—section.
A preferable thickness of an adhesive layer that can
ensure continuity and water tightness by such an adhesive, that
is, a preferable depth of a space between the surface of the
backuplnaterial and the inner surface of the concrete structure
is 0.75 to 1 . 25 times of a separation width between the concrete
structures.
Alnode for preferably positioning the backup al is
arrangement of an outer backup material outside the backup
material.
Moreover, another joining method of concrete structure
according to the present invention is characterized in that,
in an existing te structure having a cylindrical or
U—shaped section, a recess groove is formed.in the whole
periphery of the inner surface of the concrete structure, a
backup al of a non—polar substance is installed in a
.m-mmmw
i portion in this recess groove separated.fron1the inner surface
of the
g concrete ure, and an ve having stretch
capacity of 100 to 250% and density of 0.8 to 1.0 g/cm3 is poured
into a space between the surface of the backup material and the
inner surface of the te structure so as to form a joint
portion.
With the above method, too, the most important effect of
theabove—describedpresentinvention,thatis,theeffectthat
the adhesive does not drip down during construction and the
construction performance is excellent, the effect that even in
occurrence of unequal settling or ground displacement at an
earthquake, the adhesion portion s it and deforms to
ensurecontinuityandwatertightness,andtheeffectthatquake
resistance, continuity, and water tightness can be given
inexpensively and easily to the concrete structure can be
obtained.
One of preferred embodiments of such joining method is
formation of the existing concrete structure by laying a
pluralitytxfconcreteproductshavingaacylindricalcntU—shaped
cross—section.
Moreover, another one of the preferred embodiments of
such joining method is formation of the recess groove in the
inner surface<xfa joint portionloetween.the adjoining concrete
products. With such embodiment, by applying the present
invention to the joint portion of the ng structure in
which a plurality of concrete structures are adjacently laid,
quake resistance, continuity, and water tightness can.be given
to the ng ure when necessary without shutting off
a traffic network.
Moreover, as still another one of the preferred
embodiments of such joining method is formation of the recess
groove in a broken spot on the inner surface of the concrete
structure. With such embodiment, the broken spot can be
repairedwhennecessarywithoutshuttingoffaatrafficnetwork,
and quake resistance, continuity, and water tightness can be
given to the existing structure.
Advantage of the Invention
ing to the present invention, quake ance,
continuity, and water tightness can be given inexpensively and
easily to a concrete structure having a cylindrical or U—shaped
cross—section.
Brief Description of Drawings
Fig. l is a diagram illustrating an installed mode of a
concrete structure according to a first embodiment of the
present invention.
Fig. 2 is a center udinal sectional View
illustratingeastructureformedkn/usingtheconcretestructure
according to the embodiment.
Fig. 3 is a sectional View illustrating the concrete
structure according to the embodiment.
Fig. 4 is an A—A sectional View in Fig. 2.
Fig. 5 is a diagram for explaining an installation mode
of a joint n according to the ment.
Fig. 6 is a 8-8 sectional View in Fig. 4.
Fig. 7 is a sectional View rating a concrete
structure ing to a second embodiment of the present
ion.
Fig. 8 is a center longitudinal sectional View
illustrating a joint portion according to the embodiment.
Fig. 9 is a diagram for explaining an installation mode
of the joint portion according to the embodiment.
Fig. 10 is a diagram for explaining an installation.mode
of the joint portion according to the embodiment.
Fig. ll is a diagram for explaining an installation mode
of the joint portion according to the embodiment.
Fig. 12 is a C~C sectional view in Fig. 8.
Fig. 13 is a diagram illustrating a broken portion of a
.mwuwwmwm te structure according to a third ment of the
present invention.
Fig. 14 is a diagranlfor explaining an lation mode
i of a
3 joint portion according to the embodiment.
l Fig. 15 is a center udinal sectional View
illustrating the joint portion according to the embodiment.
Fig. 16 is a diagram illustrating an installation mode
of a concrete structure according to another embodiment of the
t invention.
Fig. 17 is a sectional View illustrating a joint portion
according to the embodiment.
Description of Embodiments
A first ment of the present invention will be
described below by referring to Figs. 1 to 6.
Ajoiningnethodofeaconcretestructureaccordingtothis
embodiment is used when a new box culvert 1 is installed between
existing box culverts 1’ in a concrete structure having a square
cylindrical cross—section or more specifically, in an
underground structure such as a sewage or the like formed by
connecting a plurality of box culverts l which are concrete
products, as illustrated in Figs. 1 and 2. The new box t
l is laid separately from the adjacent existing box culverts
1’ only by a tive predetermined separation width w and
joined to the existing box culverts 1’ through joint portions
As illustrated in Fig. 3, the box culvert 1 has a pair
of side plates 12, a bottom plate 11 continuing to the pair of
side plate 12, and a top plate 13 positioned opposite to the
tplate 11 in this embodiment and.has a square cylindrical
shapehaving51so—calledrectangularcross-sectionwithinwhich
aninternalspamslsenclosedbythesesideplatesl2,thebottom
plate 11, and the top plate 13 is built in and has joint surfaces
la on the both ends in the longitudinal direction so as to
construct an underground structure by joining the plurality of
the joint surfaces 1a. The joint e 1a has a rectangular
outer peripheral shape and a substantially rectangular inner
peripheral shape and forms a square ringed shape. In this
embodiment, as illustrated, the box culvertilwhich.is a square
cylindrical concrete product is described, but it is needless
to say that the t invention may be applied to configure
a three-face Water channel by a concrete product having a
U-shaped cross—section formed of a pair of side plates and a
bottom plate and having the upper side open.
WWW—m
WW Here, a method of joining the box culverts 1 which are
“Wu/1,1.»
concrete products according to the present invention is a
joiningnethodofconcreteproductbyjoiningthejointsurfaces
la of the box culverts 1, each having the joint surface la on
opposing both ends by a joint portion 2 formed by using an
adhesive 21. The method of g this joint portion 2 will
be bed below in detail together with the description of
the configuration of each part.
As described above and also illustrated in Figs. 4 and
6, the joint portion 2 is formed between the adjoining box
ts l and formed by disposing an outer backup material 23,
a backup seal material 22 formed.of alionwpolar substance which
is an inner backup material, and an adhesive 21 from the outer
surface side to the inner surface side of the box culvert 1.
e detail, as illustrated in Figs. 4 andéL the outer
backup material 23 is disposed in a region from a plane
connecting the outer surfaces of the adjoining box culverts l
sitionseparatedoutsideknzapredetermineddistancefrom
the inner surface of the box culvert 1. Moreover, this outer
backup material 23 has a function of positioning an end edge
on the outside of the backup seal material 22. In this
embodiment, this outer backup material 23 is disposed between
the adjoining box culvertsl.and then, the backup seal.material
22 is disposed on the inner side thereof. This outer backup
material 23 does not arily have to be provided.
As described above and also illustrated in Figs. 4 and
6, the backup seal material 22 is disposed inside the outer
backup al 23 and is a ring—shaped member having a
substantially equal thickness dimension over the whole region
and is formed of a non-polar nce. The adhesive 21 for
joining the box culverts l is poured into a space 25 between
the inner surface of this backup seal material 22 and a plane
connecting the inner surfaces of the box culverts 1. A depth
d of this space 25, that is, a distance from the inner surface
of the backup seal material 22 to the plane connecting the inner
surfaces of the box culverts l is set to 0.75 to 1.25 times of
the separation width w.
As described above and also illustrated in Figs. 4 and
6, the adhesive 21 is poured into the inner side of the backup
seal al 22 and has a function of g the adjoining
box culverts l sandwiching this adhesive 21 between them. That
is, this adhesive 21 is disposed at a position faced with the
internalspacecfiftheboxculvertlfl Here,thestretchcapacity
mmvowwtnwk
of this adhesive 21 is 100 to 250% and the y is 0.8 to
1.0 g/cm3.
That is, when the adjoining box culverts l are to be joined
together, first, the outer backup material 23 is disposed in
the space between the box culverts l as illustrated in Fig. 5,
and the backup seal material 22 is disposed in the inner side
thereof. Moreover, as illustrated in Fig. 6, a procedure of
pouring the ve 21 into the inner side of this backup seal
al 22 and waiting for the adhesive 21 to be solidified
is med. When.the adhesive 21 is1x>be poured, though not
shown, masking is performed by aInethod of attaching a masking
tape or the like on a portion adjacent to the space 23 on the
inner surface of the box culvert l and the masking is removed
after the adhesive 21 is solidified.by alnethod of removing the
g tape or the like. In the case of unequal settling or
ground displacement at an earthquake after the water l
is formed, this layer in which the adhesive 21 is provided is
deformed, and continuity and water tightness between the
adjoining box culverts l are maintained.
As illustrated as above, according to the joininglnethod
according to this embodiment, even in occurrence of unequal
settling or ground displacement at an earthquake and relative
positions of the box culverts l and 1’ are changed with that,
the adhesicuiportion by the adhesive 21 follows it and deforms,
and the continuity and water tightness can be ensured. That
is, quake resistance, continuity, and water tightness can be
given inexpensively and easily to a structure such as a water
channel including a sewage, a passage and the like using a
teproductrepresentedby1flmeboxcmlverts].and]J having
a square cylindrical cross—section.
Moreover, according to this joining method, since a
primer is not needed, reduction of the number of man—hour and
a construction period can be realized.
Furthermore, according to this construction , by
replacing one of the box culverts l constituting the structure
as necessary and forming the joint n 2 on the both sides
of this box culvert l, quake resistance, continuity, and water
tightness can be given to a structure when necessary.
Subsequently, a second embodiment of the t
invention will be described below by referring to Figs. 7 to
The joining method of a concrete ure according to
this embodiment is performed for a joint portion between
existing adjoining box culverts Al in an underground structure
such as sewage formed by connecting a plurality of the box
culverts Al which are concrete structures, each having a square
cylindrical cross—section.
The box culvert Al has a configuration substantially
similar to the box t 1 according to the above—described
first embodiment. That is, as illustrated in Fig. 7, the box
culvert Al has a pair of side plates A12, a bottom plate All
continuing to the pair of side plates A12, and a top plate A13
oppositely positioned to the bottom plate All and has a square
cylindrical form having a so-called rectangular cross—section
incorporating an internal space Als enclosed by the side plates
A12, the bottom plate All, and the top plate A13. er,
the box culvert Al has joint surfaces Ala on the both ends in
the longitudinal direction, and an underground ure is
constructed by connecting the plurality of the box ts Al
through joining them on joint surfaces Ala. The joint surface
Ala has a rectangular outer eral shape and also a
substantially rectangular inner peripheral shape and has a
square ringed shape. In this embodiment, at a portion faced
with the internal space A15 in the joint surfaces Ala, a cutout
Alt as illustrated.in Figs. 10 and 12i13provided.over the whole
periphery. Though the box culvert A1 which is a square
cylindrical concrete product as illustrated is described in
this embodiment, it is needless to say that the t
ion may be applied to a three—face water l formed
of a concrete product having a U—shaped cross—section formed
ofthepairofsideplatesAlZandthekmttomplateAllandrmving
the upper side open. The “square cylindrical cross~section”
is a concept including a form having an inner surface of the
bottom plate All swollen in an arc shape on a sectional View.
Here, a joining method of the box culvert A1 which is a
concreteproductaccordingtx>thepresentinventionisaijoining
method of a concrete product of g the joint portion A2
formed by using an adhesive A21 between the joint surfaces Ala
of the box culverts A1, each having the joint surfaces Ala on
thebothopposingends,andjoiningthem. Thenethmjofforming
this joint portion A2 will be described below in detail with
the description of the configuration of each part.
As described above and also illustrated in Fig. 12, the
joint portion A2 is formed between the cutouts Alt of the
adjoining box ts Al, and a backup seal material A22 formed
of a non—polar substance which is a backup material and the
“MlW-lwlwmhxmabyuuu.xu adhesiveA21arecfisposed,respectively,frmntheoutersurface
m side to the inner surface side of the box culvert Al as
illustrated in Figs. 8 and 12. Here, the cutout Alt is formed
by cutting away the existing box culvert A1 by using a concrete
cutter or the like. That is, a distance w2 between the side
faces of the ng cutouts Alt of the ing box culverts
Al as illustrated in Fig. 10 is larger than the distance w20
between the existing box culverts A1 as illustrated in Fig. 9.
As illustrated in Figs. 8 and 12, the backup seal material
A22 is a ring—shaped member having a substantially equal
thickness dimension over the whole region and is formed of a
non—polar substance. Moreover, the backup seal material A22
is disposed in a state contacted on the bottom surface of the
cutout Alt. The adhesive A21 for joining these box culverts
Al is poured into a space A23 n the inner surface of this
backup seal material A22 and a plane connecting the inner
surfaces of the box culverts Al . Here, a distance from the inner
surface of the backup seal material A22 to the plane ting
the inner surfaces of the box culverts A1, that is, a depth d2
of the space A28 in which the adhesive A21 is disposed is set
to the width of this space A23, that is, 0.75 to 1.25 times of
the distance w2 between the side surfaces of the opposing
cutouts Alt.
AYWM
memu.wmmmm
i The adhesive A21 is disposed and has the configuration
substantially similar to that according to the above—described
first embodiment. That is, this ve A21 is poured into
the inner side of the backup seal material A22 and has a function
of joining the adjoining box ts A1 sandwiching this
adhesive A21 as described above and also illustrated in Figs.
8 and 12. In other words, this adhesive A21 is disposed at a
position faced with the al space of the box culvert A1.
Here, the stretch capacity of this adhesive A21 is 100 to 250%
and the density is 0.8 to 1.0 g/cm3.
That is, in this embodiment, in joining the adjoiningloox
culverts A1, such a procedure is taken that the cutout Alt is
formed in each of the opposing joint surfaces Ala of the
adjoining box culverts Al as illustrated in Fig. 10, the backup
seal al A22 is contacted on the bottom surface of this
.A1t as illustrated in Fig. 11, and further, the adhesive
A21 is poured into the inner side of the backup seal material
A22 as illustrated in Fig. 12, and waiting for solidification
of the adhesive A21. When the adhesive A21 is to be poured in,
the g processing similar to that according to the
above~described first embodiment is performed. In this
embodiment, too, in occurrence of unequal settling or ground
displacement at an earthquake after a water l is formed,
the layer in which this adhesive A21 is provided is deformed,
and continuity and water tightness between the adjoining box
culverts A1 are maintained.
As described above, by means of the joining method
accordingix>thisembodiment, too,evenijioccurrence(Ifunequal
ng or ground displacement at an uake, the adhesion
n by the adhesive A21 follows it and deforms to ensure
continuity and water tightness. That is, quake resistance,
continuity, and water tightness can be given inexpensively and
easily to the structure including a water channel such as a
sewage, a passage and the like using a concrete product having
a square cylindrical or U—shaped cross—section.
Moreover, with this joining method, too, since a primer
is not , reduction of the number of man—hour and a
construction period can be realized.
[0041}
Furthermore, according to this construction method,
since all the works forming the joint portion A2 can be med
inside the box culvert Al constituting the existing structure,
no special work or processing is needed, and quake resistance,
continuity, and water tightness can be given to the existing
muuxwwwwrwx
structure formed by using the box culvert A1 when necessary
without shutting off the traffic for a long time.
s [0042]
uently,athirdembodimentofthepresentinvention
2 will be described by referring to Figs. 13 to 15.
Ajoiningnmthodofeaconcretestructureaccordingtotfids
embodiment is applied to a fracture spot le where a fracture
such as a crack or the like as illustrated in Fig. 13 occurs
in a box culvert Bl constituting an existing underground
structure such as a sewage formed by ting a plurality of
the box culverts Bl, each being a square cylindrical concrete
structure having a rectangular cross—section. This joining
method will be described below with the ption of
configuration of each part. Though the box culvert Bl, which
is a square cylindrical concrete product, is described in this
embodiment, it is needless to say that the present invention
maybeappliedTXJathree—facewaterchannelformedofeaconcrete
producthavingeaU—shapedcross—sectionformedofaapairtxfside
plates and a bottom plate and having the upper side open.
Further, the present invention may be applied to a structure
formed by casting concrete in place.
3 In this embodiment, at the fracture spot le, a cutout
Blt having ainidth dimension w3 larger than this fracture spot
le is provided on the inner surface side of the fracture portion
as illustrated.in Fig. 14. Inside this cutout, a joint n
B2 composed of disposing a backup seal material B22 formed of
anon—polarsubstancewhichiseabackupnmterialandeniadhesive
B21 is provided, respectively, from the outer surface side to
the inner surface side of the box culvert B1 similarly to that
according to the above—described second embodiment and as
illustrated in Fig. 15. Here, the cutout Blt is formed by
g away the existing box culvert B1 by using a concrete
cutter or the like.
As bed above and also illustrated in Fig. 15, the
joint portion B2 is formed inside the cutout formed in the
re portion of the box culvert B1 and constituted by
disposing the backup seal material 1322 and the adhesive B21 from
the outer surface side to the inner e side of the box
culvert Bl. Here, the cutout Blt is formeciby cutting away the
existing box culvert B1 by using a concrete cutter or the like.
As illustrated in Fig. 15, the backup seal material 822
is a member having a substantially equal thickness dimension
over the whole region and is formed of a non—polar substance.
Moreover, this backup seal material B22 is disposed in a state
contactedcnithebottomsurface(flithecutoutBlt. esive
821 for joining the re spot le of the box culvert Bl is
poured into a space B2s between the inner surface of this backup
seal material 822 and the inner surface of the box t B1
as illustrated in Fig. 15. A depth of this space B2s, that is,
the distance d3 from the inner surface of the backup seal
material B22 to the inner surface of the box culvert B1 is set
to 0.75 to 1.25 times of the width dimension w3 of the cutout
Blt.
[0047}
The adhesive B21 is disposed and has a configuration
ntially similar to that according1u>the above—described
first embodiment. That is, this adhesive B21 is poured into
the inner side of the backup seal material B22 as described above
and illustrated in Fig. 15 and has a function of joining the
fracture spot le of the box culvert Bl. In other words, this
adhesive B21 is disposed at a position with the internal
space Bls of the box culvert B1. Here, the stretch capacity
of this adhesive B21 is 100 to 250% and the density is 0.8 to
1.0 g/cm3.
That is, in this embodiment, in joining the adjoiningloox
culverts Bl, such a procedure is taken that the cutout Blt is
formed as illustrated in Fig. 14 at a spot where fracture occurs
in any of the top plate, the side walls, and the bottom plate
of the box culvert Bl forming an existing pipeline by using a
cuttingtoolsuchaseaconcretecutter,thebackupsealnmterial
822 is contacted on the bottom surface of this cutout Blt, and
r, the adhesive 821 is poured into the inner side of this
backup seal al 822 as rated in Fig. 15, and.waiting
for solidification of the adhesive 821. When the adhesive 821
is to be poured in, the masking processing similar to that
accordingtotheabove—describedfirstembodimentisperformed.
In this embodiment, too, in occurrence of unequal settling or
ground displacement at an earthquake after a water channel is
formed, the layer in which this adhesive 821 is provided is
deformed, and continuity and water tightness n the
adjoining box culverts Bl are maintained.
As described above, by means of the joining method
according to this ment, even in occurrence of unequal
settling or ground displacement at an earthquake, the on
portion by the adhesive 821 follows it and deforms to ensure
continuity and water tightness. That is, quake resistance,
continuity, and water tightness can be given inexpensively and
easily to the structure including a water channel such as a
sewage, a passage and the like using a concrete product having
a rectangular or U—shaped cross—section.
Moreover, with this joining method, too, since a primer
is not needed, reduction of the number of man—hour and a
construction period can be ed.
Furthermore, according to this construction ,
since all the works forming the joint portion B2 can be performed
inside the box culvert Bl constituting the existing structure,
no special work or processing is needed, the fracture spot le
is repaired when necessary without shutting off the traffic for
a long time, and quake resistance, continuity, and water
tightness can be given to the ng structure formed by using
the box culvert B1 or concrete cast in place.
The present invention is not limited to the
described embodiments.
For example, the joining method of the present ion
may be employed for a joint portion between a box culvert Cl
and a manhole C3 as illustrated in Figs. 16 and 17.
:2 This joint portion C2 in this mode is
§ constituted by
disposing aloackup seal material C22 and an adhesive C21 in the
order from the outer surface side of the manhole C3 in a space
formed between the lower part of the box culvert Cl and the
e C3. The backup seal material C22 in this mode is a
rod—shaped member having a circular cross—section, and a
pluralityofthemarearrangedadjacentlyinthecbpthdirection
ofthisspace. er,iJlthisnmde,easheet—shapedcovering
material C24 made of rubber, for example, is attached on the
outer surface of the manhole C3 so as to cover the backup seal
material C22. On the other hand, the adhesive C21 having
stretch capacity of 100 to 250% and density of 0.8 to 1.0 g/cm3
similar to those in the first to third embodiments is used. A
cutout C3a is provided between the adhesive C21 and an invert
C31 provided on the lpart of the e C3, and a spacer
C25 formed by a styrene foanlis inserted into this cutout C3a.
Furthermore, a mortar C26 is filled above this spacer C25 so
that the upper face becomes flush with the upper face of the
invert C31.
With the joining method in this mode, too, even in
occurrence of unequal settling or ground displacement at an
earthquake, the adhesion portion by the adhesive C21 s
it and deforms to ensure continuity and water tightness. That
www.mmmmum. is, quake resistance, continuity, and water tightness can be
“400M
given inexpensively and easily to the joint portion between the
box culvert Cl and the manhole C3.
rmore, in forming the joint portion in this mode,
since all the works can be performed inside the manhole C3, quake
resistance, continuity, and water tightness can be given when
necessary without shutting off the c for a long time.
In addition, in construction of a structure newly formed
by laying a plurality of te structures formed.in advance
prior to laying of a box culvert and the like, it is needless
to say that the g method as that in the first embodiment
of the present invention may be employed for a joint portion
between the adjoining te products.
The present ion may be also d to a structure
formedkn/casting'concretejJIplace, not limitedixnthose formed
by connecting a plurality of concrete structures formed in
advance prior to laying. That is, in a structure constituted
by a plurality of concrete structures formed by casting concrete
in place and having a gap provided between the adjoining
concrete structures, the concrete structures may be joined by
the joining method as that according to the above-described
WWW.»
second embodiment, or a broken spot of a structure formed by
casting concrete in place may be joined by the joining method
as that according to the abovewdescribed third embodiment.
x: Furthermore,ijlanexistingconcretestructureformedentirely
i by casting concrete in place, the joining method of forming a
i recess groove in the whole periphery of the inner surface,
disposing a backup seal material on a bottom surface side of
this recess groove, and pouring an adhesive on the side opposite
to the bottom surface of the recess groove of the backup seal
material. Moreover, the present invention may be applied to
a structure having other sectional shapes such as a circle, a
semi—circle and the like, not d to the rectangular
sectional shape.
Other various deformations are possible within the range
not departing from the gist of the present invention.
Reference Signs List
1, A1, B1, C1 box culvert ete t)
2, A2, 82, C2 joint portion
21, A21, B21, C21 adhesive
22, A22, B22, C22 backup seal material